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Full-Text Articles in Chemical Engineering
Decreases In The Swelling And Porosity Of Bituminous Coals During Devolatilization At High Heating Rates, Thomas K. Gale, Thomas H. Fletcher, Calvin H. Bartholomew
Decreases In The Swelling And Porosity Of Bituminous Coals During Devolatilization At High Heating Rates, Thomas K. Gale, Thomas H. Fletcher, Calvin H. Bartholomew
Faculty Publications
Concern about comparability and validity of different methods for producing coal chars for reactivity experiments has led to research on the effect of devolatilization conditions on the char physical and chemical structure. Particle diameter and porosity changes during devolatilization significantly affect char oxidation rates. In particular, physical properties of chars prepared in drop tube reactors differ greatly from chars prepared in flat flame burner experiments. Recent data indicate that the presence of oxygen in the gas atmosphere has no effect on swelling until char oxidation has begun. The present research concentrates on the effects of heating rate, particle temperature and …
Effects Of Pyrolysis Conditions On Internal Surface Areas And Densities Of Coal Chars Prepared At High Heating Rates In Reactive And Non-Reactive Atmospheres, Thomas K. Gale, Thomas H. Fletcher, Calvin H. Bartholomew
Effects Of Pyrolysis Conditions On Internal Surface Areas And Densities Of Coal Chars Prepared At High Heating Rates In Reactive And Non-Reactive Atmospheres, Thomas K. Gale, Thomas H. Fletcher, Calvin H. Bartholomew
Faculty Publications
Concern about comparability and validity of different methods for producing coal chars for reactivity experiments has led to research on the effect of devolatilization conditions on the char physical and chemical structure. Particle diameter and porosity changes during devolatilization significantly affect char oxidation rates. In particular, physical properties of chars prepared in drop tube reactors differ greatly from chars prepared in fiat flame burner experiments. Recent data indicate that the presence of oxygen in the gas atmosphere has no effect on swelling until char oxidation has begun. The present research concentrates on the effects of heating rate, particle temperature and …
Thermophoretic Sampling Of Coal-Derived Soot Particles During Devolatilization, Jinliang Ma, Thomas H. Fletcher, Brent W. Webb
Thermophoretic Sampling Of Coal-Derived Soot Particles During Devolatilization, Jinliang Ma, Thomas H. Fletcher, Brent W. Webb
Faculty Publications
Thermophoretic sampling of soot particles formed during high-temperature coal devolatilization is performed in order to examine soot particle sizes and shapes. Coal particles are injected along the centerline of a laminar flow flat flame burner, where a fuel-rich methane-air flame is used as a heat source. Volatiles released from the coal particles form a cloud of soot particles at high temperatures in the absence of oxygen. A carbon-coated microscope grid is briefly inserted into the soot cloud, where the temperature gradient between the soot particles and the cold grid surface causes the migration of soot particles and results in deposition. …