Bioresource and Agricultural Engineering Commons^™

Will Saf Turbocharge The Corn Ethanol Market?, Richard Perrin, Lilyan Fulginiti, Felipe Miranda De Souza Almeida

Cornhusker Economics

The long-run outlook for the corn ethanol industry is questionable, due to a transition to electric and hybrid vehicles. One source of hope for the long run is the potential demand for producing Sustainable Aviation Fuel (SAF). SAF is a key component in the United States Aviation Climate Action Plan, a path to net-zero greenhouse gas (GHG) emissions in the aviation industry by 2050. Demand for ethanol for SAF offers hope to the ethanol industry, but it depends a great deal on policy decisions that are being made now. Here we sketch out this story.

Based on the information available …

Producer Long-Term Marketing Opportunities With Ethanol Plants, Austin Harthoorn, Logan Lloyd, Cory Walters, Kate Brooks

Cornhusker Economics

Commodity marketing operates in a complex decision environment with constant information flow, which can conceal long-run financially profitable marketing opportunities for producers. In the corn marketing space, the competitive role of ethanol plants throughout the state may provide producers with long-run financial gains by strategically approaching marketing decisions. In this article, we characterize whether producers can gain financially from strategically marketing corn to ethanol plants. For example, do ethanol plants provide a better long-run return from pre-harvest hedging, spring sale, or harvest sale?

We investigate three important contracting times--forward contract for harvest delivery (called pre-harvest hereafter), harvest delivery, and spring …

Valorization Of Xylan In Agroforestry Waste Streams, Harrison Appiah

Graduate Theses, Dissertations, and Problem Reports

Valorization of Xylan in Agroforestry Waste Streams.

Harrison Appiah

Microwave-assisted deep eutectic solvent and gamma-valerolactone metallic chloride catalyzed conversion of xylan to furfural were investigated using a 2x3 factorial experimental design at two levels of percent microwave power, reaction time, and catalyst concentration. The levels of each factor studied were (20%, 60% microwave power, 2, 4 minutes, and 10, 20mg) respectively. The effect of three metallic chloride catalysts (LiCl, FeCl3.6H20, CuCl2) on the conversion of xylan to furfural was also investigated. The gamma-valerolactone-ferric chloride sent system exhibited the highest mean yield of furfural (56.50%). The next highest furfural yield of …

Potential Of Hemp (Cannabis Sativa L.) For Paired Phytoremediation And Bioenergy Production, Hanah T. Rheay, Emmanuel C. Omondi, Catherine E. Brewer

Agricultural and Environmental Sciences Faculty Research

Hemp (Cannabis sativa L.) is a multi-use crop that has been investigated for its potential use in phytoremediation of heavy metals, radionuclides, and organic contaminants, and as a feedstock for bioenergy production. A review of research literature indicates that hemp is a suitable crop for phytoremediation, and a competitive option for bioenergy. Coupling phytoremediation and bioenergy production from a single hemp crop is a potential solution to overcoming the economic constraints of phytoremediation projects. The current challenge is ensuring that the extracted contaminants are not introduced into the consumer marketplace. After several decades of limited research on hemp in the …

Potential Energy Generation From Agricultural Residue In Indonesia, Adrian Rizqi Irhamna

English Language Institute

Indonesia has great potential of biomass sources from their agricultural residue, which can potentially be used for alternative energy generation. This preliminary research explores the most suitable technology for energy generation from agricultural residue and its challenge for application in Indonesia. The study showed that biomass utilization via the direct combustion process is recommended for energy generation. It is also reported that the pretreatment process of drying and washing, are required to increase the fuel quality and plant efficiency.

Design Of A Portable Biogas Purification And Storage System, Anikumar Kosna, Bade Shrestha

Faculty Research and Creative Activities Award (FRACAA)

The objective of this study is to propose and design a commercial portable purification and storage system to commercialize biogas (which mainly consists of 45 - 75 % of methane and 15 - 16% of carbon dioxide), produced from household/non-commercial biogas plants. The selection of purification process is based on the portability of the purification system.

Fractionation And Characterization Of Lignin Streams From Unique High-Lignin Content Endocarp Feedstocks, Wenqi Li, Kirtley Amos, Mi Li, Yunqiao Pu, Seth Debolt, Arthur J. Ragauskas, Jian Shi

Biosystems and Agricultural Engineering Faculty Publications

Background: Lignin is a promising source of building blocks for upgrading to valuable aromatic chemicals and materials. Endocarp biomass represents a non-edible crop residue in an existing agricultural setting which cannot be used as animal feed nor soil amendment. With significantly higher lignin content and bulk energy density, endo-carps have significant advantages to be converted into both biofuel and bioproducts as compared to other biomass resources. Deep eutectic solvent (DES) is highly effective in fractionating lignin from a variety of biomass feedstocks with high yield and purity while at lower cost comparing to certain ionic liquids.

Results: In the present …

Processing Different Mixtures Of Regionally Available Resources To Create Pellets That Meet A Minimum Standard, Jacob Hixson

Masters Theses

There are several ways to produce energy today, one of the oldest is the gasification of biomass. This process uses a fire to heat the material until it starts to produce gasses that are used as fuel. There are several types of biomass that can be used, many of which have large pieces with low bulk densities. By pelletizing the biomass bulk density increases and allows the opportunity to add in other biomass materials.

There are standards for condensing large pieces of biomass to smaller pelletized materials. Pellet Fuels Institute has set minimum standards for pellets used in the different …

Biofuels From Crop Residue: Soil Organic Carbon And Climate Impacts In The Us And India, Adam Liska

Adam Liska Papers

The transformation of crop residue to soil organic carbon and CO₂ is a conserved process that occurs globally. Due to the mathematics of carbon intensity calculations found in government regulations, the amount of CO₂ emitted from crop residue per unit of energy in biofuel is largely independent of the amount of residue removed and the location of its removal, as shown by results from the US and India.

Soil organic carbon (SOC) levels are at equilibria determined by carbon inputs from plant material (+I_c) and loss from oxidation to CO₂

Are the US results relevant …

Catalytic Oxidation And Depolymerization Of Lignin In Aqueous Ionic Liquid, Lalitendu Das, Siquan Xu, Jian Shi

Biosystems and Agricultural Engineering Faculty Publications

Lignin is an integral part of the plant cell wall, which provides rigidity to plants, also contributes to the recalcitrance of the lignocellulosic biomass to biochemical and biological deconstruction. Lignin is a promising renewable feedstock for aromatic chemicals; however, an efficient and economic lignin depolymerization method needs to be developed to enable the conversion. In this study, we investigated the depolymerization of alkaline lignin in aqueous 1-ethyl-3-methylimidazolium acetate [C₂C₁Im][OAc] under oxidizing conditions. Seven different transition metal catalysts were screened in presence of H₂O₂ as oxidizing agent in a batch reactor. CoCl₂ and …

The Irreversible Momentum Of Clean Energy, Barack Obama

US Department of Energy Publications

The release of carbon dioxide (CO₂) and other greenhouse gases (GHGs) due to human activity is increasing global average surface air temperatures, disrupting weather patterns, and acidifying the ocean. Left unchecked, the continued growth of GHG emissions could cause global average temperatures to increase by another 4°C or more by 2100 and by 1.5 to 2 times as much in many midcontinent and far northern locations. Although our understanding of the impacts of climate change is increasingly and disturbingly clear, there is still debate about the proper course for U.S. policy—a debate that is very much on display …

Evaluation Of Flocculation, Sedimentation, And Filtration For Dewatering Of Scenedesmus Algae, Nicholas A. Rhea, Jack Groppo, Czarena Crofcheck

Biosystems and Agricultural Engineering Faculty Publications

Algae can be used as a feedstock for agricultural fertilizers, livestock and poultry feeds, anaerobic digestion, and biofuel production. For each end product, the requirements for moisture content (or solids content) vary, such that a desirable water removal strategy needs to be adaptable to varying levels of water removal. Flocculation, sedimentation, and filtration were evaluated as possible strategies for thickening and dewatering of algae. The goal of this study was to validate that algae cells treated by such means could be processed by vacuum belt filters and to determine the conditions under which the solids content could be increased to …

Thawing Out: The Role Of The Arctic Council Service In A Melting Arctic, Taylor J. Enos

Pell Scholars and Senior Theses

With the changing natural and political climate of the Arctic, conflicts over resource extraction and navigation will become inevitable. Empowering an intergovernmental institution like the Arctic Council Service may be the only solution. This paper analyzes the importance and history of the Arctic as a political environment, which is prone to abuse in the very near future at the hands of Russia and the United States.

Application Of Recycled Media And Algae-Based Anaerobic Digestate In Scenedesmus Cultivation, Xinyi E, Czarena Crofcheck, Mark Crocker

Biosystems and Agricultural Engineering Faculty Publications

To make large-algae cultivation systems sustainable, commercial fertilizer inputs should be minimized. One means of achieving this is to maximize the recycle of nutrients used in algae cultivation. In addition to recycling nutrient-containing water from algae harvesting and dewatering, after harvesting algal biomass can be used as a substrate for anaerobic digestion, which can then generate mineralized nutrients to be used for further cultivation. In this study, the effect of recycling media and using mineralized nutrients during Scenedesmus cultivation was investigated. The recycled media proved to be able to support cell growth with nutrient replenishment, and it could be recycled …

Engineering, Nutrient Removal, And Feedstock Conversion Evaluations Of Four Corn Stover Harvest Scenarios, Reed L. Hoskinson, Douglas L. Karlen, Stuart J. Birrell, Corey W. Radtke, W. W. Wilhelm

Douglas L Karlen

Crop residue has been identified as a near-term source of biomass for renewable fuel, heat, power, chemicals and other bio-materials. A prototype one-pass harvest system was used to collect residue samples from a corn (Zea mays L.) field near Ames, IA. Four harvest scenarios (low cut, high-cut top, high-cut bottom, and normal cut) were evaluated and are expressed as collected stover harvest indices (CSHI). High-cut top and high-cut bottom samples were obtained from the same plot in separate operations. Chemical composition, dilute acid pretreatment response, ethanol conversion yield and efficiency, and thermochemical conversion for each scenario were determined. Mean grain …

U.S. Billion-Ton Update: Biomass Supply For A Bioenergy And Bioproducts Industry, Robert D. Perlack, Laurence M. Eaton, Anthony F. Turhollow Jr., Matt H. Langholtz, Craig C. Brandt, Mark E. Downing, Robin L. Graham, Lynn L. Wright, Jacob M. Kavkewitz, Anna M. Shamey, Richard G. Nelson, Bryce J. Stokes, William L. Rooney, David J. Muth Jr., J. Richard Hess, Jared M. Abodeely, Chad Hellwinckel, Danial De La Torre Ugarte, Daniel C. Yoder, James P. Lyon, Timothy G. Rials, Timothy A. Volk, Thomas S. Buchholz, Lawrence P. Abrahamson, Robert P. Anex, Thomas B. Voigt, William Berguson, Don E. Riemenschneider, Douglas Karlen, Jane M. F. Johnson, Robert B. Mitchell, Kenneth P. Vogel, Edward P. Richard Jr., John Tatarko, Larry E. Wagner, Kenneth E. Skog, Patricia K. Lebow, Dennis P. Dykstra, Marilyn A. Buford, Patrick D. Miles, D. Andrew Scott, James H. Perdue, Robert B. Rummer, Jamie Barbour, John A. Stanturf, David B. Mckeever, Ronald S. Zalesny Jr., Edmund A. Gee, P. Daniel Cassidy, David Lightle

Douglas L Karlen

The Report, Biomass as Feedstock for a Bioenergy and Bioproducts Industry: The Technical Feasibility of a Billion-Ton Annual Supply (generally referred to as the Billion-Ton Study or 2005 BTS), was an estimate of “potential” biomass within the contiguous United States based on numerous assumptions about current and future inventory and production capacity, availability, and technology. In the 2005 BTS, a strategic analysis was undertaken to determine if U.S. agriculture and forest resources have the capability to potentially produce at least one billion dry tons of biomass annually, in a sustainable manner—enough to displace approximately 30% of the country’s present petroleum …

Development Of Sustainable Corn Stover Harvest Strategies For Cellulosic Ethanol Production, Stuart J. Birrell, Douglas L. Karlen, Adam Wirt

Douglas L Karlen

To prepare for a 2014 launch of commercial scale cellulosic ethanol production from corn/maize (Zea mays L.) stover, POET-DSM near Emmetsburg, IA has been working with farmers, researchers, and equipment dealers through “Project Liberty” on harvest, transportation, and storage logistics of corn stover for the past several years. Our objective was to evaluate seven stover harvest strategies within a 50-ha (125 acres) site on very deep, moderately well to poorly drained Mollisols, developed in calcareous glacial till. The treatments included the following: conventional grain harvest (no stover harvest), grain plus a second-pass rake and bale stover harvest, and single-pass …

Transformation Of Swine Manure And Algal Consortia To Value-Added Products, Mahmoud A. Sharara

Graduate Theses and Dissertations

The swine production sector is projected to grow globally. In the past, this growth manifested itself in increased herd sizes and geographically concentrated production. Although economically sound, these trends had negative consequences on surrounding ecosystems. Over-application of manure resulted in water quality degradation, while long-term storage of manure slurries was found to promote release of potent GHG emissions. There is a need for innovative approaches for swine manure management that are compatible with current scales of production, and increasingly strict environmental regulations.

This study aims to investigate the potential for incorporating gasification as part of a novel swine manure management …

First Proof Of Concept Of Sustainable Metabolite Production From High Solids Fermentation Of Lignocellulosic Biomass Using A Bacterial Co-Culture And Cycling Flush System, Wanying Yao, Sue E. Nokes

Biosystems and Agricultural Engineering Faculty Publications

To improve the lignocellulose conversion for ABE in high solids fermentation, this study explored the feasibility of cycling the process through the cellulolytic or/and solventogenic phases via intermittent flushing of the fermentation media. Five different flushing strategies (varying medium ingredients, inoculum supplement and cycling through phases) were investigated. Flushing regularly throughout the cellulolytic phase is necessary because re-incubation at 65 °C significantly improved glucose availability by at least 6-fold. The solvents accumulation was increased by 4-fold using corn stover (3-fold using miscanthus) over that produced by flushing only through the solventogenic phase. In addition, cycling process was simplified by re-incubating …

Methane Production By A Packed-Bed Anaerobic Digester Fed Dairy Barn Flush Water, Sean Richard Thomson

Master's Theses

Packed-bed digesters are an alternative to covered lagoon digesters for methane production and anaerobic treatment of dilute wastewaters such as dairy barn flush water. The physical media of packed-beds retain biofilms, often allowing increased treatment rates. Previous studies have evaluated several types of media for digestion of dilute wastewaters, but cost and media fouling have setback commercial development. A major operational cost has been effluent recirculation pumping.

In the present effort, a novel approach to anaerobic digestion of flush dairy water was developed at pilot-scale: broken walnut shells were used as a low-cost packed-bed medium and effluent recirculation was replaced …

Reply To ‘Co2 Emissions From Crop Residue-Derived Biofuels’, Adam Liska, Haishun Yang, Matthew P. Pelton, Andrew E. Suyker

Adam Liska Papers

The soil organic carbon (SOC) model that we used was parameterized with data from arable land under normal farming conditions in North America, Europe, Africa and Asia, but the equation is insensitive to changes in tillage, soil texture and moisture. The model has reasonable accuracy, however, in predicting changes in SOC, residue remaining and CO₂ emissions from initial SOC, carbon inputs from residue, and daily temperature; the shoot-to-root ratio used in the geospatial simulation was 0.29 (that is, root carbon is 29% of total aboveground carbon), which did not underestimate carbon input to soil (Supplementary Figure 2 in Ref. …

Uncertainties In Life Cycle Greenhouse Gas Emissions From U.S. Beef Cattle, Quentin M. Dudley, Adam Liska, Andrea K. Watson, Galen E. Erickson

Adam Liska Papers

Beef cattle feedlots are estimated to contribute 26% of U.S. agricultural greenhouse gas (GHG) emissions, and future climate change policy could target reducing these emissions. Life cycle assessment (LCA) of GHG emissions from U.S. grain-fed beef cattle was conducted based on industry statistics and previous studies to identify the main sources of uncertainty in these estimations. Uncertainty associated with GHG emissions from indirect land use change, pasture soil emissions (e.g. soil carbon sequestration), enteric fermentation from cattle on pasture, and methane emissions from feedlot manure, respectively, contributed the most variability to life cycle GHG emissions from beef production. Feeding of …

Co2 Recycling Using Microalgae For The Production Of Fuels, Michael H. Wilson, John Groppo, Andrew Placido, S. Graham, S. A. Morton Iii, Eduardo Santillan-Jimenez, Aubrey Shea, Mark Crocker, Czarena Crofcheck, Rodney Andrews

Center for Applied Energy Research Faculty and Staff Publications

CO₂ capture and recycle using microalgae was demonstrated at a coal-fired power plant (Duke Energy’s East Bend Station, Kentucky). Using an in-house designed closed loop, vertical tube photobioreactor, Scenedesmus acutus was cultured using flue gas as the CO₂ source. Algae productivity of 39 g/(m² day) in June–July was achieved at significant scale (18,000 L), while average daily productivity slightly in excess of 10 g/(m² day) was demonstrated in the month of December. A protocol for low-cost algae harvesting and dewatering was developed, and the conversion of algal lipids—extracted from the harvested biomass—to diesel-range hydrocarbons via catalytic …

Phanerochaete Chrysosporium Pretreatment Of Biomass To Enhance Solvent Production In Subsequent Bacterial Solid-Substrate Cultivation, Wanying Yao, Sue E. Nokes

Biosystems and Agricultural Engineering Faculty Publications

This study investigated pretreatment of corn stover using solid substrate cultivation (SSC) of Phanerochaete chrysosporium (P. chrysosporium) to improve subsequent accessibility to cellulose. Thereafter, Clostridium thermocellum (C. thermocellum) was directly inoculated onto the pretreated biomass to accomplish hydrolysis, followed by solventogenesis by introducing Clostridium beijerinckii (C. beijerinckii).

An enzyme suite containing laccase, lignin peroxidase and manganese peroxidase activity was detected during the cultivation of P. chrysosporium on corn stover within 288 h at an initial moisture content 𝓌_H2O = 80% (mass of water/total mass). Incubation factors, such as substrate moisture content and cultivation …

Opportunities For Energy Crop Production Based On Subfield Scale Distribution Of Profitability, Ian J. Bonner, Kara G. Cafferty, David J. Muth, Mark D. Tomer, David E. James, Sarah A. Porter, Douglas L. Karlen

David J. Muth

Incorporation of dedicated herbaceous energy crops into row crop landscapes is a promising means to supply an expanding biofuel industry while benefiting soil and water quality and increasing biodiversity. Despite these positive traits, energy crops remain largely unaccepted due to concerns over their practicality and cost of implementation. This paper presents a case study for Hardin County, Iowa, to demonstrate how subfield decision making can be used to target candidate areas for conversion to energy crop production. Estimates of variability in row crop production at a subfield level are used to model the economic performance of corn (Zea mays L.) …

Opportunities For Energy Crop Production Based On Subfield Scale Distribution Of Profitability, Ian J. Bonner, Kara G. Cafferty, David J. Muth, Mark D. Tomer, David E. James, Sarah A. Porter, Douglas L. Karlen

Douglas L Karlen

Incorporation of dedicated herbaceous energy crops into row crop landscapes is a promising means to supply an expanding biofuel industry while benefiting soil and water quality and increasing biodiversity. Despite these positive traits, energy crops remain largely unaccepted due to concerns over their practicality and cost of implementation. This paper presents a case study for Hardin County, Iowa, to demonstrate how subfield decision making can be used to target candidate areas for conversion to energy crop production. Estimates of variability in row crop production at a subfield level are used to model the economic performance of corn (Zea mays L.) …

Influence Of Media Composition On The Growth Rate Of Chlorella Vulgaris And Scenedesmus Acutus Utilized For Co2 Mitigation, Czarena L. Crofcheck, Xinyi E, Aubrey Shea, Michael D. Montross, Mark Crocker, Rodney Andrews

Biosystems and Agricultural Engineering Faculty Publications

Atmospheric carbon dioxide levels have increased since the industrial revolution due to increasing combustion of fossil fuels. One possible CO₂ mitigation strategy is the use of microalgae for mitigation of CO₂. This paper focuses on the influence of media composition on the growth rate of two microalgae strains, Chlorella vulgaris and Scenedesmus actus. A KNO₃ based medium was found to work better for Chlorella, while a urea based equivalent worked better for Scenedesmus. The urea based media investigated here resulted in growth similar to that found with previously reported KNO₃ based media. …

Soil Organic Carbon Dynamics In Agriculture: Model Development And Application From Daily To Decadal Timescales, Matthew P. Pelton

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

Soil carbon (C) is the largest terrestrial C pool globally, containing more C than the atmosphere and biosphere. Soil organic carbon (SOC) is a source and sink of CO₂ emissions to and from the atmosphere, thus influencing future climate change. Understanding SOC dynamics is also important for maintaining C stocks to sustain and improve crop yields. An existing model to estimate changes in SOC due to respiration was modified to operate in three computational platforms: MS Excel, MS Excel with Visual Basic for Applications, and supercomputing. This model was validated against CO₂ flux data from a 9-year field …

Influence Of Flue Gas Components On The Growth Rate Of Chlorella Vulgaris And Scenedesmus Acutus, Czarena Crofcheck, Aubrey Shea, Michael D. Montross, Mark Crocker, Rodney Andrews

Biosystems and Agricultural Engineering Faculty Publications

Atmospheric carbon dioxide levels have increased since the industrial revolution due to the increase in combustion of fossil fuels. One possible alternative strategy is the use of microalgae for CO₂ capture and recycling. Major components in coal-derived flue gas that may accumulate and effect algae growth include both sulfur oxides and fly ash. However, in practical application, sulfur oxides will be converted quickly to the acid product (H₂SO₄) in the aerobic aqueous conditions of algae cultivation. In this article, the influence of elevated H₂SO₄ levels and the presence of coal-derived fly ash …

Review Of Us And Eu Initiatives Toward Development, Demonstration, And Commercialization Of Lignocellulosic Biofuels, Venkatesh Balan, David Chiaramonti, Sandeep Kumar

Civil & Environmental Engineering Faculty Publications

Advanced biofuels produced from lignocellulosic biomass offer an exciting opportunity to produce renewable liquid transportation fuels, biochemicals, and electricity from locally available agriculture and forest residues. The growing interest in biofuels from lignocellulosic feedstock in the United States (US) and the European Union (EU) can provide a path forward toward replacing petroleum-based fuels with sustainable biofuels which have the potential to lower greenhouse gas (GHG) emissions. The selection of biomass conversion technologies along with feedstock development plays a crucial role in the commercialization of next-generation biofuels. There has been synergy and, even with similar basic process routes, diversity in the …