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Ph Responsive, Adhesive Hydrogels Based On Reversible Catechol - Boronic Acid Complexation, Ameya Ravindra Narkar

Dissertations, Master's Theses and Master's Reports - Open

Smart hydrogel adhesives with tunable properties consist of adhesive moieties in the polymer network that respond to external stimuli like pH, temperature, etc. Responsiveness of smart adhesives to pH, in particular, is important because of the simple actuation mechanism and the ability to achieve facile bonding and debonding upon command. Covalently crosslinked hydrogel adhesives were prepared by employing an N-HEAA (hydroxyethyl acrylamide) backbone embedded with dopamine methacrylamide (DMA), a marine mussel inspired adhesive protein and 3-acrylamido phenylboronic acid (AAPBA), to determine the effect of pH on the interfacial binding properties of the hydrogel adhesive with a borosilicate glass substrate. Swelling …