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Full-Text Articles in Biomedical Engineering and Bioengineering
Synthesis And Characterization Of Hazelnut Oil-Based Biodiesel, Yixiang Xu, Milford Hanna
Synthesis And Characterization Of Hazelnut Oil-Based Biodiesel, Yixiang Xu, Milford Hanna
Biological Systems Engineering: Papers and Publications
The demand for diesel fuel far exceeds the current and future biodiesel production capabilities of the vegetable oil and animal fat industries. New oilseed crops that do not compete with traditional food crop are needed to meet existing energy demands. Hybrid hazelnut oil is just such an attractive raw material for production of biodiesel. Hazelnut oil was extracted from hybrid hazelnuts and the crude oil was refined. Hazelnut oil-based biodiesel was prepared via the transesterification of the refined hazelnut oil with excess methanol using an alkaline catalyst. The effects of reaction temperature, time and catalyst concentration on the yield of …
A Continuous Process For The Glycerolysis Of Soybean Oil , Hossein Noureddini, D W. Harkey, M R. Gutsman
A Continuous Process For The Glycerolysis Of Soybean Oil , Hossein Noureddini, D W. Harkey, M R. Gutsman
Papers in Biomaterials
A continuous process for the glycerolysis of soybean oil with pure and crude glycerol, the co-product from the transesterification of soybean oil was investigated in a pilot plant. The process was equipped with a motionless and a high-shear mixer. The experimental studies explored the effects of variations in mixing intensity, temperature, reactant flow rates, and reactant stoichiometry on the formation of MG and DC. The developed process resulted in high conversion of TC to MC. The most favorable conditions were 230°C, 40 mL/min total flow, 25 mm of reaction time, 2.5:1 molar ratio of glycerol/soybean oil, and 3600 rpm for …
A Continuous Process For The Conversion Of Vegetable Oils Into Methyl Esters Of Fatty Acids, Hossein Noureddini, D Harkey, V Medikonduru
A Continuous Process For The Conversion Of Vegetable Oils Into Methyl Esters Of Fatty Acids, Hossein Noureddini, D Harkey, V Medikonduru
Papers in Biomaterials
A continuous process for the transesterification of triglycerides to methyl esters was investigated in a pilot plant. The process was equipped with a motionless and a high-shear mixer. The experimental studies explored variations in the mixing intensity, stoichiometry, and catalyst concentration on the overall conversion. The combined as well as individual effect of mixers was examined. The developed process resulted in high conversions of vegetable oils into methyl esters. Conversion of triglycerides to methyl esters in excess of 98% was achieved. Larger excess amounts of alcohol favored higher conversions. The motionless and high-shear mixers each provided adequate mixing for the …
Glycerolysis Of Fats And Methyl Esters., Hossein Noureddini, V Medikonduru
Glycerolysis Of Fats And Methyl Esters., Hossein Noureddini, V Medikonduru
Papers in Biomaterials
The glycerolysis of methyl esters and triglycerides with crude glycerol. a coproduct from the transesterification of triglycerides, was studied. Three procedures were followed ior this conversion. The first procedure was a one-step glycerolysis with methyl esters. The second procedure was a two-step process. This proced~~irnev olved an initial partial glycerolysis with methyl esters, followed by fat glycerolysis. The third procedure u,as a simultaneous glycerolysis n,ith methyl esters and triglycerides. In the glycerolysis with methyl esters, the removal of methanol is vital to the production of mono- and diglycerides. Methanol was removed either by drawing vacuum on the reactor or by …
Kinetics Of Transesterification Of Soybean Oil, Hossein Noureddini, D Zhu
Kinetics Of Transesterification Of Soybean Oil, Hossein Noureddini, D Zhu
Papers in Biomaterials
Transesterification of soybean oil with methanol was investigated. Three stepwise and reversible reacttons are believed to occur. The effect of variations in mixing intensity (Reynolds number = 3,100 to 12,400) and temperature (30 to 70'CJ on the rate oireaction were studied while the molar ratio of alcohol to triglycerol (6:l) and the concentration of catalyst (0.20 wt% based on soybean oil) were held constant. The variations in mixing intensity appear to effect the reaction parallel to the variations in temperature. A reaction mechanism consisting of an initial mass transfer-controlled region followed by a kinetically controlled region is proposed. The experimental …
A Continuous Process For The Conversion Of Vegetable Oils Into Biodiesel, Hossein Noureddini, D Harkey, V Medikonduru
A Continuous Process For The Conversion Of Vegetable Oils Into Biodiesel, Hossein Noureddini, D Harkey, V Medikonduru
Papers in Biomaterials
Over the last few years fatty acid methyl esters have assumed importance as research has intensified on the utilization of vegetable oils and animal fats derivatives from liquid fuels (better known as biodiesel).Traditional batch processing has been an still is the most widely used process for this coversion. New and more efficient processing schemes. for large scale production of biodiesel for fuelfile1 purposes, is a. key for commercialization of biodiesel. In this, study a continuous process for the transesterification of triglycerides to methyl esters was investigated. This process is based a combined high shear and motionless reactor system. The experimental …
Improved Conversion Of Plant Oils And Animal Fats Into Biodiesel And Co-Product , Praveen R. Muniyappa, Scott C. Brammer, Hossein Noureddini
Improved Conversion Of Plant Oils And Animal Fats Into Biodiesel And Co-Product , Praveen R. Muniyappa, Scott C. Brammer, Hossein Noureddini
Papers in Biomaterials
Increased environmental awareness and depletion of resources are driving to develop alternative fuel from renewable resources that are environmentally more acceptable. Esters of fatty acids (bio-diesel, derived from the transesterification vegetable oils, have properties similar to components of peh-oleior~. based diesel fuel Cost has been a major factor slowing the commercializatio of bio-diesel! Glycerol is the coproduct of the esterification process. In this work the feasibility of the glyc-erol of vegetable oil. with crude glycerol derived from the transesterification of the vegetable oils and animal fats was studied. Utilization of the crude co-product of the biodiesel process was investi-gated for …