Biomedical Engineering and Bioengineering Commons^™

Zsm-5 Coatings On β-Sic Monoliths: Possible New Structured Catalyst For The Methanol-To-Olefins Process, B. Madani, S. Ivanova, B. Louis, Jean-Philippe Tessonnier, M. J. Ledoux, C. Pham-Huu

Jean-Philippe Tessonnier

Structured zeolite/silicon carbide composites were succesfully synthesized by ZSM-5 coatings deposited on macroscopic â-SiC foams with medium surface area. A homogeneous coverage of the support (30 wt % zeolite) by ZSM-5 crystals, having 1 ím average size, was reached after a double-coating procedure. The ZSM-5/â-SiC composite materials were characterized by BET, XRD, SEM, and H/D exchange methods. 27Al MAS NMR analysis revealed that all aluminum was present in a tetrahedral coordination, thus sitting in the zeolite framework. The existence of a nanoscopic layer of silica and silicon oxycarbide on the surface of the support ensures the strong anchoring of the …