Engineering Commons^™

Advances In Additively Manufactured Titanium Alloys By Powder Bed Fusion And Directed Energy Deposition: Microstructure, Defects, And Mechanical Behavior, Hongyi Y. Ma, J. C. Wang, Peng Qin, Y. J. Liu, L. Y. Chen, L. Q. Wang, Laichang Zhang

Research outputs 2022 to 2026

Ti and its alloys have been broadly adopted across various industries owing to their outstanding properties, such as high strength-to-weight ratio, excellent fatigue performance, exceptional corrosion resistance and so on. Additive manufacturing (AM) is a complement to, rather than a replacement for, traditional manufacturing processes. It enhances flexibility in fabricating complex components and resolves machining challenges, resulting in reduced lead times for custom designs. However, owing to distinctions among various AM technologies, Ti alloys fabricated by different AM methods usually present differences in microstructure and defects, which can significantly influence the mechanical performance of built parts. Therefore, having an in-depth …

Revised Semiempirical Approach To Predict The Occurrence Of Twinning In Titanium Alloys, Chirag Dhirajlal Rabadia, Syed Faraz Jawed, Jincheng Wang, Milind Siddhpura, Arti Siddhpura

Research outputs 2014 to 2021

A revised semiempirical approach, considering the average values of the valence electron to atom ratio (e/a̅) and a difference in atomic radii of alloying element/s and the base element (Δr¯), is proposed to predict the twin formation in titanium alloys. The revised e/ā versus Δr¯ diagram is plotted, considering the reported results of 90 titanium alloys fabricated using various processing methods. A new twin/slip boundary has been plotted and recommended based on the revised e/ā versus Δr¯ diagram. The conventional maximum limit reported for the twinning in titanium alloys is e/ā = 4.20; however, it has been found that twinning …

A Review On Alpha Case Formation And Modeling Of Mass Transfer During Investment Casting Of Titanium Alloys, R. Sharon Uwanyuze, Janos E. Kanyo, Sarah F. Myrick, Stefan Schafföner

Materials Science and Engineering Faculty Research & Creative Works

Titanium alloys have excellent corrosion resistance, high temperature strength, low density, and biocompatibility. Therefore, they are increasingly used for aerospace, biomedical, and chemical applications. Investment casting is a well-established process for manufacturing near-net-shape intricate parts for such applications. However, mass transfer arising from metal-mold reactions is still a major problem that drastically impairs the surface and properties of the castings. Although there have been astounding developments over the past 20 years, they remain scattered in various research papers and conference proceedings. This review summarizes the current status of the field, gaps in the scientific understanding, and the research needs for …

Study Of Laser Based Additive Manufacturing For Titanium And Copper Alloys, Congyuan Zeng

LSU Doctoral Dissertations

Material processing by laser is increasingly applied in industrial applications for its outstanding characteristics, such as localized heating, high efficiency, and high manufacturing precision. In this study, two kinds of laser material processing strategies were investigated, namely laser surface engineering and laser-powder-bed fusion additive manufacturing, with pure titanium and copper alloys as target materials, respectively.

For laser surface engineering related studies, the work includes the investigation of the dynamic interactions between titanium and pure nitrogen or ambient air under transient laser processing conditions. Thanks to the in-situ synchrotron X-ray diffraction tests, the high-temperature reaction steps between titanium and pure nitrogen/ambient …

Review On Machining Of Additively Manufactured Nickel And Titanium Alloys, Navneet Khanna, Kishan Zadafiya, Tej Patel, Yusuf Kaynak, Rizwan Abdul, Rahman Rashid, Ana Vafadar

Research outputs 2014 to 2021

The machining of nickel and titanium-based superalloy components is very expensive and involves unusually high lead times compared with other engineering metals such as steels and aluminum. This has led to the development of most suitable additive manufacturing (AM) processes to fabricate these difficult-to-machine metals into near-net shape parts, thereby reducing the lead time and material waste, and significantly increasing productivity. Nonetheless, finish machining is still required on the AMed metal components to meet the dimensional and surface requirements of the application. Several research studies have investigated the machinability of AMed nickel and titanium alloy workpieces and have compared the …

Corrosion Behavior And Characteristics Of Passive Films Of Laser Powder Bed Fusion Produced Ti-6al-4v In Dynamic Hank’S Solution, Liang-Yu Chen, Hong-Yue Zhang, Chuanbo Zheng, Hong-Yu Yang, Peng Qin, Cuihua Zhao, Sheng Lu, Shun-Xing Liang, Linjiang Chai, Lai-Chang Zhang

Research outputs 2014 to 2021

The corrosion behavior of laser powder bed fusion produced (L-PBF-produced) titanium alloys involving flowing body fluid is still unclear. Therefore, this work investigates in vitro corrosion behavior and the characteristics of passive films formed on L-PBF-produced Ti–6Al–4V in both static and dynamic Hank’s solutions. Electrochemical measurements, immersion tests, X-ray photoelectron spectroscopy and scanning electron microscopy were conducted. In comparison to the L-PBF-produced Ti–6Al–4V in static Hank’s solution, the samples showed lower charge transfer resistance and higher passivation current density (anodic current density as well) in dynamic Hank’s solution. Meanwhile, a more apparent deposition of apatite and hydroxyapatite is found on …

Deformation And Toughness Behavior Of Β -Type Titanium Alloys Comprising C15-Type Laves Phase, C. D. Rabadia, Y. J. Liu, S. F. Jawed, L. Q. Wang, H. Sun, L. C. Zhang

Research outputs 2014 to 2021

Laves phases are effective in tailoring the mechanical properties of alloys used for structural engineering applications. Therefore, it is an emerging research significance to investigate the deformation features of alloys comprising a Laves phase. In this work, the Ti–33Zr–xFe–yCr (x = 5, 7 wt% and y = 2, 4 wt%) alloys were designed in such a way that a Laves phase would form in the investigated Ti–33Zr–xFe–yCr alloys and later, cast by cold crucible levitation melting. All the as-cast alloys exhibit a face-centered cubic C15-type Laves phase along with a dominant β phase. The volume fraction of C15 Laves phase …

Mechanical Performance Of Ebm Ti-6al-2sn-4zr-2mo Influenced By The Effects Of Different Hot Isostatic Pressing Treatments, Miguel Lopez

Open Access Theses & Dissertations

Electron Beam Melting (EBM) is an additive manufacturing process that presents a lower level of internal defects in comparison to Selective Laser Melting (SLM). Pairing Hot Isostatic Pressing (HIP) with Additive Manufactured metal parts, sub-surface voids can be eliminated through high pressure and temperature. This significantly improves fatigue life, impact toughness, creep, rupture strength, and tensile ductility. In this investigation, Ti-6Al-2Sn-4Zr-2Mo samples manufactured in the Arcam's Q20 system will be tested as per ASTM E8 Standard Test Methods for Tension Testing of Metallic Materials. Different variants of Hot Isostatic Pressing (HIP) treatments were analyzed and compared. Tensile testing was performed …

Evaluation Of Microstructure Variation Of Tc11 Alloy After Electroshocking Treatment, Lechun Xie, Chang Liu, Yanli Song, Haojie Guo, Zhongqi Wang, Lin Hua, Liqiang Wang, Lai-Chang Zhang

Research outputs 2014 to 2021

Electro-shocking treatment (EST) has been investigated as a pathway to optimise the microstructure and mechanical properties of titanium alloys. The thermal conditions introduced by EST resulted in a phase transformation from α to β. The fraction of β phase decreased from 25.27% to 19.47% after EST for 0.02 s, which was possibly caused by the recrystallization of α phase. The application of EST for 0.04 s resulted in an increase in volume fraction of the β phase to 26.95%. The energy introduced by EST resulted in changes to the direction and intensity of texture within the microstructure with the texture …

Microstructure And Mechanical Behavior Of Metastable Beta Type Titanium Alloys, Chirag Dhirajlal Rabadia

Theses: Doctorates and Masters

Current biomaterials such as stainless steel, Co-Cr alloys, commercially pure titanium and Ti-6Al- 4V either possess poor mechanical compatibility and/or produce toxic effects in the human body after several years of usage. Consequently, there is an enormous demand for long-lasting biomaterials which provide a better combination of mechanical, corrosion and biological properties. In addition to this, alloys used in high-strength applications possess either high-strength or large plasticity. However, a high-strength alloy should possess a better blend of both strength and plasticity when used in high-strength applications. Metastable β-titanium alloys are the best suited alloys for biomedical and high-strength applications because …

Beta-Type Ti-Nb-Zr-Cr Alloys With Large Plasticity And Significant Strain Hardening, Syed F. Jawed, Chirag D. Rabadia, Y. J. Liu, L. Q. Wang, Y. H. Li, X. H. Zang, Laichang C. Zhang

Research outputs 2014 to 2021

A series of Ti-25Nb-8Zr-xCr (x = 0, 2, 4, 6, 8 wt%) alloys were designed based on DV-Xα cluster method and e=a-Δr diagram with an anticipation to obtain high plasticity and significant strain hardening. The designed alloys were produced through cold crucible levitation melting technique in order to effectively investigate their micro-structures and mechanical properties. The addition of Cr significantly enhances the β stability in the microstructures of the Ti-25Nb-8Zr-xCr alloys. Both yield strength and hardness of the studied alloys increase due to the effect of solid-solution strengthening. By contrast, the plasticity, maximum strength and strain hardening rate are influenced …

Deformation And Strength Characteristics Of Laves Phases In Titanium Alloys, Chirag D. Rabadia, Y. J. Liu, Liang-Yu Chen, Syed F. Jawed, L. Q. Wang, Hongqi Sun, Laichang Zhang

Research outputs 2014 to 2021

The superior reinforcement nature of Laves phases make them suitable for high-strength applications. Therefore, investigations on the deformation and strength characteristics of Laves phases are useful in development of an improved Laves phase-reinforced alloy. In this work, the Vickers micro-indentation method is used to evaluate and compare the deformation and strength characteristics of a hexagonal close-packed Laves phase (C14-type) in Ti-35Zr-5Fe-6Mn (wt%) and a face-centered cubic Laves phase (C15-type) in Ti-33Zr-7Fe-4Cr (wt%), considering the same volume fraction of Laves phase (~7.0%) in these alloys. Moreover, the effects of higher volume fraction of Laves phase (19.4%) on indentation-based deformation features are …

Nanoindentation Characterization On Local Plastic Response Of Ti-6al-4v Under High-Load Spherical Indentation, Yan Wen, Lechun Xie, Zhou Wang, Liqiang Wang, Weijie Lu, Laichang Zhang

Research outputs 2014 to 2021

After high-load spherical indentation treatment, the variations of hardness on the plastic zone of Ti-6Al-4V were investigated via nanoindentation method. The hardness within the center of plastic zone was measured by nanoindenter, and the magnitude decreased gradually along the depth, which were caused by the different extent of plastic deformation under the residual imprint. The microstructure of indentation were observed using scanning electron microscope (SEM) before and after surface etching, and the results showed that the microhardness revealed the average hardness of α and β phases of Ti-6Al-4V. The maximum hardness reached 6.438 GPa in the depth of 132 μm. …

Effect Of Weld Nugget Size On Failure Mode And Mechanical Properties Of Microscale Resistance Spot Welds On Ti–1al–1mn Ultrathin Foils, Feng Chen, Shiding Sun, Zhenwu Ma, G Q. Tong, Xiang Huang

Department of Electrical and Computer Engineering: Faculty Publications

We use tensile–shear tests to investigate the failure modes of Ti–1Al–1Mn microscale resistance spot welds and to determine how the failure mode affects the microstructure, microhardness profile, and mechanical performance. Two different failure modes were revealed: interfacial failure mode and pullout failure mode. The welds that fail by pullout failure mode have much better mechanical properties than those that fail by interfacial failure mode. The results show that weld nugget size is also a principal factor that determines the failure mode of microscale resistance spot welds. A minimum weld nugget size exists above which all specimens fail by pullout failure …

Advanced Manufacturing Of Titanium Alloys For Biomedical Applications, Nicholas C. Mavros

ETD Archive

In metallurgy, Titanium has been a staple for biomedical purposes. Its low toxicity and alloying versatility make it an attractive choice for medical applications. However, studies have shown the difference in elastic modulus between Titanium alloys (116 GPa) and human bone (40-60 GPa) contribute to long term issues with loose hardware fixation. Additionally, long term studies have shown elements such as Vanadium and Aluminum, which are commonly used in Ti-6Al-4V biomedical alloys, have been linked to neurodegenerative diseases like Alzheimers and Parkinsons. Alternative metals known to be less toxic are being explored as replacements for alloying elements in Titanium alloys. …

Processing, Microstructure And Mechanical Properties Of Beta-Type Titanium Porous Structures Made By Additive Manufacturing, Yujing Liu

Theses: Doctorates and Masters

Tissue engineering through the application of a low modulus, high strength format as a potential approach for increasing the durability of bone implants has been attracting significant attention. Titanium alloys are widely used for biomedical applications because of their low modulus, high biocompatibility, specific strength and corrosion resistance. These reasons affirm why titanium alloy is selected as the specific material to research. The development of low modulus biomaterials is considered to be an effective method to remove the mismatch between biomaterial implants and surrounding bone tissue, thereby reducing the risk of bone resorption. So far, Ti–24Nb–4Zr–8Sn alloy (abbreviated hereafter as …

Simulation Of Superplastic Forming Of Circular Edge-Welded Envelopes, Olga Tulupova

The 8th International Conference on Physical and Numerical Simulation of Materials Processing

No abstract provided.

3d Fe Modelling Of Die Stress And Wear In Non-Isothermal Forging Of Ti–6al–4v Turbine Blade, Shiyuan Luo, Dahu Zhu, Lin Hua, Dongsheng Qian, Sijie Yan

The 8th International Conference on Physical and Numerical Simulation of Materials Processing

No abstract provided.

Equiaxed Ti-Based Composites With High Strength And Large Plasticity Prepared By Sintering And Crystallizing Amorphous Powder, Lehua Liu, Chao Yang, L. M. Kang, Yan Long, Zhiyu Xiao, Peijie Li, Laichang Zhang

Research outputs 2014 to 2021

High-performance titanium alloys with an equiaxed composite microstructure were achieved by sintering and crystallizing amorphous powder. By introducing a second phase in a β-Ti matrix, series of optimized Ti-Nb-Fe-Co-Al and Ti-Nb-Cu-Ni-Al composites, which have a microstructure composed of ultrafine-grained and equiaxed CoTi₂ or (Cu,Ni)Ti₂ precipitated phases surrounded by a ductile β-Ti matrix, were fabricated by sintering and crystallizing mechanically alloyed amorphous powder. The as-fabricated composites exhibit ultra-high ultimate compressive strength of 2585MPa and extremely large compressive plastic strain of around 40%, which are greater than the corresponding ones for most titanium alloys. In contrast, the alloy fabricated by …

Understanding The Mechanical Response Of Built-Up Welded Beams Made From Commercially Pure Titanium And A Titanium Alloy, Anil Patnaik, Narendra Poondla, Craig Menzemer, Tirumalai Srivatsan

Craig Menzemer

During the last two decades, titanium has gradually grown in stature, strength and significance to take on the recognition of being a modern and high performance metal that is noticeably stronger and concurrently lighter than the most widely chosen and used steels in a spectrum of industrial applications. Technological innovations have necessitated reduction of part weight, cost and lead time, including concurrent enhancement of performance of structural parts and components made using titanium and its alloys. This has provided the impetus to develop economically viable structural design methodologies and specifications, while at the same time bringing forth innovative and economically …

Understanding The Mechanical Response Of Built-Up Welded Beams Made From Commercially Pure Titanium And A Titanium Alloy, Anil Patnaik, Narendra Poondla, Craig Menzemer, Tirumalai Srivatsan

Anil Patnaik

During the last two decades, titanium has gradually grown in stature, strength and significance to take on the recognition of being a modern and high performance metal that is noticeably stronger and concurrently lighter than the most widely chosen and used steels in a spectrum of industrial applications. Technological innovations have necessitated reduction of part weight, cost and lead time, including concurrent enhancement of performance of structural parts and components made using titanium and its alloys. This has provided the impetus to develop economically viable structural design methodologies and specifications, while at the same time bringing forth innovative and economically …

Bio-Medicinal Application For Plasma Electrolytic Oxidation Of Metals, Zunjian Yang

Theses

Plasma electrolytic oxidation (PEO), a novel method for forming ceramic coatings on metals, has been researched extensively in recent times. By applying high voltage between dielectric thin films, a plasma micro-arc is induced through penetration of breakdown in film boiling layer. Such a method takes advantage of high processing time, low equipment requirement and advanced coating performance.

Titanium alloys, Ti-6Al-4V and pure Titanium Grade 2, are two of most common Titanium alloys in daily use. Both of such Titanium alloys show great potential utilization in bio-medicinal application, especially in implants, for its excellent biocompatibility, high tensile strength, and high elastic …

On The Use Of Critical Distance Theories For The Prediction Of The High Cycle Fatigue Limit Stress In Notched Ti–6al–4v ☆, David Lanning, Theodore Nicholas, George Haritos

Dr. George K. Haritos

Methods are investigated for predicting the high cycle fatigue (HCF) lives of notched cylindrical Ti–6Al–4V specimens using critical distance concepts that employ the stress distribution in the vicinity of the notch. Cylindrical fatigue specimens had circumferential V-notches with a range of elastic stress concentration factors (kt=1.97–4.07). Notched and unnotched specimens were cycled to failure using a step-loading technique to generate points on a Haigh (Goodman) diagram for a constant fatigue life of 106 cycles. Finite element solutions were generated to provide stress distributions for the notched gage sections. The stress distributions were used in the search for a critical distance …

Notch Size Effects In Hcf Behavior Of Ti–6al–4v, George Haritos, Theodore Nicholas, David Lanning

Dr. George K. Haritos

The high cycle fatigue (HCF) behavior of Ti–6Al–4V is investigated for cylindrical specimens having three sizes of geometrically similar circumferential V-notches, each with an elastic stress concentration factor, K_t, of approximately 2.78. A step loading technique for obtaining a point on a constant life (10⁶ cycles) Haigh diagram from a single test specimen was implemented. Tests were performed at stress ratios of R=0.1, 0.5, and 0.8 for specimens machined from two different product forms of Ti–6Al–4V, bar and plate forgings. Results indicate that while there is a definite notch size effect in the Ti–6Al–4V bar within …

Transient Liquid Phase Bonding Of Titanium-, Iron- And Nickel- Based Alloys, A. H. M. Esfakur Rahman

Theses and Dissertations

The operating temperature of land-based gas turbines and jet engines are ever-increasing to increase the efficiency, decrease the emissions and minimize the cost. Within the engines, complex-shaped parts experience extreme temperature, fatigue and corrosion conditions. Ti-based, Ni-based and Fe-based alloys are commonly used in gas turbines and jet engines depending on the temperatures of different sections. Although those alloys have superior mechanical, high temperature and corrosion properties, severe operating conditions cause fast degradation and failure of the components. Repair of these components could reduce lifecycle costs. Unfortunately, conventional fusion welding is not very attractive, because Ti reacts very easily with …

The Wear Behavior Of Cross-Linked Uhmwpe Under Dry And Bovine Calf Serum-Lubricated Conditions

A.S. Md Abdul Haseeb

The present study was performed to investigate the effects of gamma radiation on the wear behavior of unirradiated and irradiated ultra-high-molecular-weight polyethylene (UHMWPE) against Ti-6Al-4V under dry and lubricated conditions at different applied loads. The UHMWPE specimens were exposed directly to nominal doses of 0, 25, 40, 50, and 100 kGy. Scanning electron microscope (SEM) analysis of the worn surface of UHMWPE and Ti-6Al-4V was performed to understand the mechanism of wear involved between the contact surfaces during wear testing. From the wear test results, there were significant differences between the wear of unirradiated UHMWPE and UHMWPE irradiated at 25, …

The Wear Behavior Of Cross-Linked Uhmwpe Under Dry And Bovine Calf Serum-Lubricated Conditions

A.S. Md Abdul Haseeb

The present study was performed to investigate the effects of gamma radiation on the wear behavior of unirradiated and irradiated ultra-high-molecular-weight polyethylene (UHMWPE) against Ti-6Al-4V under dry and lubricated conditions at different applied loads. The UHMWPE specimens were exposed directly to nominal doses of 0, 25, 40, 50, and 100 kGy. Scanning electron microscope (SEM) analysis of the worn surface of UHMWPE and Ti-6Al-4V was performed to understand the mechanism of wear involved between the contact surfaces during wear testing. From the wear test results, there were significant differences between the wear of unirradiated UHMWPE and UHMWPE irradiated at 25, …

Biomedical Technology: Supporting Movement, Petros Katsioloudis

STEMPS Faculty Publications

According to the National Institute on Disability and Rehabilitation Research, an estimated 8.5 million children 21 years and younger have a disability (Jans & Stoddard, 1999). After about a decade, with the development of new and sophisticated materials (aluminum alloys, titanium alloys, and carbon fibers) and the integration of electronics, it was then possible to significantly improve the performance of prostheses, built with the so-called endo skeletal (or skeletal-modular) method (Mora, Beratni & Pedrotti, 2006).

Titanium Alloyed With Boron, Seshacharyulu Tamirisakandala, Daniel B. Miracle, Raghavan Srinivasan, Jay S. Gunasekera

Mechanical and Materials Engineering Faculty Publications

Small additions of boron to conventional titanium alloys have been found to produce significant changes to the microstructures and associated properties. Grain refinement and improved strength and stiffness are first-order effects, which lead to possibilities for developing novel and affordable processing methodologies and to enhance performance over conventional titanium alloys. In this article, we introduce this new class of titanium alloys and describe unique formability benefits achieved via engineering microstructures.

In-Vitro Characterization Of Boronized Titanium Alloy By Means Of Corrosion And Electrochemical Impedance Spectroscopy Methods In Simulated Body Fluids, David Anthony Panus

Theses

Titanium and titanium alloys are becoming the backbone of medical implants and prosthetics. Titanium alloys are used because of its high biocompatibility and similarity to bone. However, titanium and titanium alloys have a low wear resistance. Titanium and titanium alloys are susceptible to particle erosion, which can cause inflammation, infection, and even implant rejection. Boronizing titanium alloy improves titanium's wear resistance and also improves corrosion resistance.

The target of this research was to characterize the corrosion characteristics of both unboronized and boronized titanium using both electrochemical corrosion methods and Electrochemical Impedance Spectroscopy (ELS) in simulated body fluid. Using electrochemical methods …