Engineering Commons^™

Extending The Low-Temperature Operation Of Sodium Metal Batteries Combining Linear And Cyclic Ether-Based Electrolyte Solutions, Haoyu Zhu, Hui Xiong

Materials Science and Engineering Faculty Publications and Presentations

Nonaqueous sodium-based batteries are ideal candidates for the next generation of electrochemical energy storage devices. However, despite the promising performance at ambient temperature, their low-temperature (e.g., < 0 °C) operation is detrimentally affected by the increase in the electrolyte resistance and solid electrolyte interphase (SEI) instability. Here, to circumvent these issues, we propose specific electrolyte formulations comprising linear and cyclic ether-based solvents and sodium trifluoromethanesulfonate salt that are thermally stable down to −150 °C and enable the formation of a stable SEI at low temperatures. When tested in the Na||Na coin cell configuration, the low-temperature electrolytes enable long-term cycling down to −80 °C. Via ex situ physicochemical (e.g., X-ray photoelectron spectroscopy, cryogenic transmission electron microscopy and atomic force microscopy) electrode measurements and density functional theory calculations, we investigate the mechanisms responsible for efficient low-temperature electrochemical performance. We also report the assembly and testing between −20 °C and −60 °C of full Na||Na₃V₂(PO₄)₃ coin cells. The cell tested at −40 °C shows an initial discharge capacity of 68 mAh g⁻¹ with a capacity retention of approximately 94% after 100 cycles at 22 mA g⁻¹.

An Evaluation Of Energy Consumption Comparing Conventional Water Treatment Plants To Microfiltration And Ultrafiltration Water Treatment Plants, Danielle Larsen

All Theses

The use of low-pressure, hollow fiber microfiltration (MF) and ultrafiltration (UF) membranes has become increasingly prominent in drinking water treatment plant configurations over the past 30 years. At the same time, the topics of energy efficiency and sustainability in industry are becoming progressively more important. Although MF and UF are highly successful in filtration, they are generally thought of as significant energy consumers; however, the data have not yet been available to compare multiple plants in various contexts to determine the factors that most affect energy use. This research compares the energy use of MF and UF treatment plants to …

Applications Of Agent-Based Modeling (Abm) In Enhancing Facility Operation And Management, Ali Khodabandelu, Jee Woong Park

Civil and Environmental Engineering and Construction Faculty Research

Agent-based modeling (ABM), as a relatively new simulation technique, has recently gained in popularity in the civil engineering domain due to its uniquely advantageous features. Among many civil engineering applications, ABM has been applied to facility operation and management, such as energy consumption management, as well as the enhancement of maintenance and repair processes. The former studies used ABM to manage energy consumption through simulating human energy-related behaviors and their interactions with facilities, as well as electrical, heating, and cooling systems and appliances, while the latter used ABM to enhance maintenance process through facilitating coordination, negotiation, and decision making between …

Optimizing Speed Profiles For Sustainable Train Operation With Wayside Energy Storage Systems, Leon A. Allen

Dissertations

Large hauling capability and low rolling resistance has put rail transit at the forefront of mass transportation mode sustainability in terms of congestion mitigation and energy conservation. As such, rail vehicles are one of the least energy-intensive modes of transportation and least environmentally polluting. Despite, these positives, improper driving habits and wastage of the braking energy through dissipation in braking resistors result in unnecessary consumption, extra costs to the operator and increased atmospheric greenhouse gas emissions.

This study presents an intelligent method for the optimization of the number and locations of wayside energy storage system (WESS) units that maximize the …

Development And Testing Of A 1:70 Scale Model Wind Turbine Of The Iea Reference 15 Mw Floating Offshore System, Amber Parker

Electronic Theses and Dissertations

This thesis presents the development of a 1/70th scale performance-matched wind turbine intended for wind and wave basin model testing of commercially viable floating wind turbine structures based off of the International Energy Agency (IEA) Wind 15 MW design. The focus of this demonstration is to test active blade pitch response controls and to provide an experimental dataset for use by modelers and industry for future turbine improvements. Future research is planned to test the turbine in conjunction with an actively damping hull to test the interactions between the two control systems.

Outlined in this thesis are the methods of …

Economic Feasibility Analysis Of Variable-Speed Pumps By Simulating 15 Multiple Water Distribution Systems, Conrad B. Truettner, Brian D. Barkdoll

Michigan Tech Publications

The UN Sustainability Goals address measures to reduce environmental pollution. Water distribution systems (WDSs) use electric energy, which pollutes the atmosphere through, at least partly, the burning of coal. This study simulates, through modeling, variable-speed pumps (VSPs) on 15 different real WDSs on the network solver EPANET and analyzes the payback period. An algorithm is introduced here to select the optimal pump speed pattern to save the most energy while satisfying the constrain of sufficient pressure at all times and all locations. It was found that five of the 15 systems operated unsuccessfully using a VSP, due to the VSP …

Study Of Methods For Developing Waste Lubricant Recovery, Sh T. Poyonov, S M. Turabdjanov

Technical science and innovation

The article provides analytical information on the study of methods of treatment of used engine oils. The issues of ecological safety of storage, processing and use of automobile waste are considered. The problems of ecological safety of application of lubricants are inseparable from utilization of OWS, which are currently one of the most common man-caused waste that negatively affects all objects of environment - atmosphere, soil and water. It has been shown that water pollution by waste oil accounts for 20% of total techno-genic pollution, or 60% of petroleum product pollution. The study determined that obtaining oils with characteristics superior …

Rational Synthesis Of Ultra-Small And Durable Platinum-Based Catalysts For Renewable Energy Applications, Fahim Bin Abdur Rahman

Theses and Dissertations

Ultrasmall supported platinum nanoparticles (Pt NPs) are often used in two promising renewable energy production technologies – hybrid-sulfur water splitting for actively catalyzing H2SO4 decomposition and in fuel cells for the oxygen reduction reaction (ORR). However, the stability of Pt NPs under reaction conditions is the ultimate challenge for these processes. Two prevalent ways to overcome this challenge are improving stability by anchoring Pt onto a secondary metal or doping heteroatoms into the support. This dissertation covers the rational design, synthesis, and stabilization of Pt-based catalysts in these two ways to achieve durable catalytic performance with desired activity and selectivity. …

Two-Dimensional Materials: From Fundamental To Application, Guangyu Zhang, Geng Long, Shenghuang Lin, Lede Xian, Yan Jiang, Hao Wu, Shuopei Wang, Na Li

Bulletin of Chinese Academy of Sciences (Chinese Version)

The rapid development of the information society puts forward an ever-increasing urgent need for information storage, processing, and transmission capabilities. With the ending of Moore's Law, the semiconductor industry urgently needs to find new solutions. Lowdimensional materials are considered to be a new breakthrough in the semiconductor industry in the post-Moore era, because of the size characteristics of atomic-level thickness, the structural advantage of no dangling bonds on the surface, and the sensitivity to electrical and optical control methods caused by a large specific surface area. Songshan Lake Materials Laboratory has introduced a group of top scientists and established a …

Resource Availability And Implications For The Development Of Plug‐In Electric Vehicles, Ona Egbue, Suzanna Long, Seong Dae Kim

Engineering Management and Systems Engineering Faculty Research & Creative Works

Plug‐in electric vehicles (PEVs) have immense potential for reducing greenhouse gas emissions and dependence on fossil fuels, and for smart grid applications. Although a great deal of research is focused on technological limitations that affect PEV battery performance targets, a major and arguably equal concern is the constraint imposed by the finite availability of elements or resources used in the manufacture of PEV batteries. Availability of resources, such as lithium, for batteries is critical to the future of PEVs and is, therefore, a topic that needs attention. This study addresses the issues related to lithium availability and sustainability, particularly supply …

Resource Availability And Implications For The Development Of Plug‐In Electric Vehicles, Ona Egbue, Suzanna Long, Seong Dae Kim

Engineering Management and Systems Engineering Faculty Research & Creative Works

Plug‐in electric vehicles (PEVs) have immense potential for reducing greenhouse gas emissions and dependence on fossil fuels, and for smart grid applications. Although a great deal of research is focused on technological limitations that affect PEV battery performance targets, a major and arguably equal concern is the constraint imposed by the finite availability of elements or resources used in the manufacture of PEV batteries. Availability of resources, such as lithium, for batteries is critical to the future of PEVs and is, therefore, a topic that needs attention. This study addresses the issues related to lithium availability and sustainability, particularly supply …

Characterization, Design, And Optimization Of Dual-Purpose Wind Turbines And Frost Protection Fans, Ethan Narad

Master's Theses

This thesis report outlines the creation of a MATLAB tool to design reversible machines that can function as both wind turbines and as agricultural frost protection fans. Frost protection fans are used to prevent crop loss during radiative freeze events during which a temperature inversion is present. Such a dual-purpose machine fundamentally has the constraint that it must use symmetric airfoils, so a suite of tools for automatically designing an optimized wind turbine blade with symmetric airfoils using the Blade Element Momentum (BEM) theory approach is presented. The BEM code is then re-derived and adapted for use with a frost …

Assessing The Potential And Pathways For Renewable Energy Transformations In Orleans, California, Malcolm Prescott Moncheur De Rieudotte

Cal Poly Humboldt theses and projects

In what is now known as the state of California in the United States, the Karuk Tribe is interested in deploying a renewable-powered microgrid in the rural community of Orleans to improve electricity system reliability and resilience to address a wide range of challenges, including extreme events such as wildfires. This study assesses the potential of local distributed renewable energy and battery storage to meet Orleans' energy needs today and in the increasingly electrified future using an energy model. It also identifies existing cultural and social priorities for energy technology along with structural barriers to renewable energy adoption and the …

Techno-Economic Feasibility Of Electrifying Food Markets In Nigeria With Biogas Hybrid Mini-Grids, Demi Temitope Ogunwo

Cal Poly Humboldt theses and projects

This thesis explored the feasibility of electrifying a food market in an urban city in Nigeria with a hybrid biogas-powered mini-grid. Under the Energizing Economies Initiative of the Rural Electrification Agency of Nigeria, nine markets in the country currently receive constant access to electricity via hybrid mini-grid systems. As a majority of these systems are diesel-solar-battery systems, this thesis explored the use of biogas generators as a substitute for diesel generators in hybrid mini-grids for food markets. A fruit and vegetable market in Ketu, Lagos was used as a case study for the research. The research for this thesis was …

The Implementation Of Advanced Digitalization In The Oil And Gas Industry, Ensieh Rezafar

Walden Dissertations and Doctoral Studies

AbstractThe immature advanced digitalization in the oil and gas industry can limit access to the potential value of mature progressive digitalization. Oil and gas leaders must expedite the implementation of advanced digitalization to increase organizational proficiencies and reduce costs and losses. Grounded in Pettigrew and Whipp’s dimensions of strategic change theory, the purpose of this qualitative multiple case study was to explore strategies some leaders in the oil and gas industry used to implement advanced digitalization. The participants were seven leaders in two oil service companies in North America involved in the successful implementation of progressive digitalization. Data were collected …

Artificial Intelligence-Based Material Discovery For Clean Energy Future, Reza Maleki, Mohsen Asadnia, Amir Razmjou

Research outputs 2022 to 2026

Artificial intelligence (AI)-assisted materials design and discovery methods can come to the aid of global concerns for introducing new efficient materials in different applications. Also, a sustainable clean future requires a transition to a low-carbon economy that is material-intensive. AI-assisted methods advent as inexpensive and accelerated methods in the design of new materials for clean energies. Herein, the emerging research area of AI-assisted material discovery with a focus on developing clean energies is discussed. The applications, advantages, and challenges of using AI in material discovery are discussed and the future perspective of using AI in clean energy is studied. This …

Clean Process To Utilize The Potassium-Containing Phosphorous Rock With Simultaneous Hcl And Kcl Production Via The Steam-Mediated Reactions, Yunshan Wang, Lufang Shi, Houli Li, Yixiao Wang, Zhiying Wang, Xuebin An, Mingzhu Tang, Gang Yang, Jun He, Jing Hu, Yong Sun

Research outputs 2022 to 2026

In this paper, a clean process based on the steam-mediated reactions for simultaneous HCl and KCl production using the potassium (K)-containing phosphorous rock as a precursor is proposed. Through hydrochloric acid (HCl) leaching, not only the generation of H₃PO₄and CaCl₂ (via further precipitation) were realized but also the acid-insoluble residue [phosphorous-rock slag (PS)] rich in elements, that is, K, Al, Si, and so on, in the form of microcline (KAlSi₃O₈) and quartz (SiO₂) was obtained and became readily available for further HCl and KCl generation. Over 95 % of …

Energy Planning Model Design For Forecasting The Final Energy Consumption Using Artificial Neural Networks, Haidy Eissa

Theses and Dissertations

“Energy Trilemma” has recently received an increasing concern among policy makers. The trilemma conceptual framework is based on three main dimensions: environmental sustainability, energy equity, and energy security. Energy security reflects a nation’s capability to meet current and future energy demand. Rational energy planning is thus a fundamental aspect to articulate energy policies. The energy system is huge and complex, accordingly in order to guarantee the availability of energy supply, it is necessary to implement strategies on the consumption side. Energy modeling is a tool that helps policy makers and researchers understand the fluctuations in the energy system. Over the …

Lessons Learned From Bp: Deepwater Horizon And The Transition To Renewables, Daniel Valle

Journal of Global Awareness

This paper analyzes the gradual transition of British Petroleum (BP), one of the world's largest oil and gas companies, into a renewable energy company focused on sustainability and the reduction of carbon emissions. BP's leadership and ethical practices are compared before and after the 2010 Deepwater Horizon disaster. The purpose of the comparison and the broader analysis of the transition is to identify how effective leadership can be used to transform a company with a suspect social responsibility record into a leader among its peers. Lessons learned from the disaster, and the subsequent transition conclude the research.

Modeling Electric Energy Generation In Ercot During Extreme Weather Events And The Impact Renewable Energy Has On Grid Reliability, Adam R. Ruthford, Bivin Sadler

SMU Data Science Review

This paper shows the inadequacy of current grid backup supplies, their ongoing threat to grid reliability, and the increased risk of customer blackouts. This paper also examines reliability concerns caused by renewable energy sources under more normal operating conditions. This paper seeks to model the impacts of extreme weather on ERCOTs grid. Unusual weather patterns require that the electrical grid operates in conditions outside normal operating parameters. Electrical system demand can spike well above normal levels. At the same time, weather influences can change the operating envelope of electrical generation equipment. The ERCOT grid has changed from its’ traditional mix …

Efficient Management Of Nitrogen And Phosphorus At Centralized Water Reclamation Facilities, Helene Kassouf

USF Tampa Graduate Theses and Dissertations

A variety of process configurations are employed at municipal water reclamation facilities (WRFs), such as 5-stage Bardenpho, oxidation ditch, modified Ludzack-Ettinger (MLE) process, and sidestream recycle. However, all of these configurations face certain challenges in achieving optimum treatment of nitrogen and phosphorus. In this dissertation, the driving objectives were to: (1) quantitatively assess the fate of nitrogen and phosphorus (mass fluxes) at a treatment facility that employs biological nutrient removal, aerobic digestion, and sidestream recycle, (2) evaluate the performance of a microbial fuel cell (MFC) as a technology to remove nitrogen from sidestreams at a treatment plant that employs that …

Modeling Portfolios Of Low Carbon Energy Generation Under Deep Uncertainty, Franklyn Kanyako

Doctoral Dissertations

In the 2015 Paris Agreement, nearly every country pledge through the Nationally Determined Contributions (NDCs) increased adoption of low carbon energy technologies in their energy system. However, allocating investments to different low carbon energy technologies under rising demand for energy and budget constraints, uncertain technical change in these technologies involves maneuvering significant uncertainties among experts, models, and decision-makers. We examine the interactions of low carbon energy sources (LCES) under the condition of deep uncertainty. Deep uncertainty directly impacts the understanding of the role of low carbon energy technologies in climate change mitigation and how much R&D investment should be allocated …

Vermont Transportation Energy Profile 2021, Jonathan Dowds, Dana Rowangould

University of Vermont Transportation Research Center

Slightly more than one-third of the total energy consumed in Vermont is used for transportation (see Figure E-1). Transportation energy is overwhelmingly derived from fossil fuels, with over 95% coming in the form of gasoline and diesel fuel. Transportation is also the largest source of greenhouse gas (GHG) emissions in the State, accounting for 39.1% GHGs in 2017.

Consequently, the 2016 Vermont Comprehensive Energy Plan (CEP) included three goals and nine supporting objectives related to reducing transportation sector energy consumption and GHG emissions (VDPS, 2016). The 2021 Vermont Transportation Energy Profile (“the Profile”) is the fifth installment of a biannual …

Why Indonesia Needs A New Energy Paradigm, Aditya Prasetyo

English Language Institute

The problem of Indonesia's dependence on petroleum as its main energy source can be overcome by instead using an energy mix. This study focuses on optimal utilization of other energy resources that can help to meet the demand for energy in Indonesia and help to reduce its dependence on oil, thereby preventing a future energy crises.

Dynamic Hvac Energy Management Using Commercial Building Occupancy Metrics & Neural Networks, Krishna Chaitanya Jagadeesh Simma

Civil Engineering ETDs

With the rise of technology use in buildings, it is now possible to collect data that can be used to improve building energy consumption. One factor that has significant impact on building energy consumption is occupancy. Recent studies have shown promising results in obtaining occupancy information from existing infrastructure such as WiFi router networks. However, these existing frameworks require additional investments through software upgrades, added infrastructure, computational resources, and may raise occupant privacy concerns. Additionally, with occupant thermal comfort statistics being lower than ASHAREA specified standards, a novel approach for indoor climate control is needed. To address the limitations in …

Cal Poly Wind Power: Wind Turbine Prototype, Sophie A. Spencer, Maggie Nevrly, Michael Reyna, Loi Q. Nguyen

Mechanical Engineering

The Cal Poly Wind Power (CPWP) club is competing in the Collegiate Wind Competition (CWC) hosted by the National Renewable Energy Laboratory (NREL). The CWC is hosted annually by NREL to increase the number of skilled workers prepared to work in the wind energy industry. Our senior project team is one of several design teams contributing to the CPWP prototype turbine design including the pitching mechanism, blade design, generator, and shaft. The scope of this project is to design the yaw mechanism, tower, and nacelle. The goal is to create components that function well with other planned components and are …

Sustainable Energy Storage, Jacob S. Grillo, Alyse C. Coonce, Jack R. Linchey, Nick P. Schnorr

Mechanical Engineering

This Final Design Review document covers the work we, students at California Polytechnic State University – San Luis Obispo, have performed in collaboration with Mr. Harish Bhutani and Dr. Mohammad Noori. The project’s intent is to create an energy storage system for off-grid and developing region applications using alternative technologies to lithium-ion battery storage. We plan to manufacture and assemble a scale model of the energy storage system to prove effectiveness and practicality. This system will store enough energy to power basic appliances and essential devices for a house or community. The chosen design direction will be a flywheel, as …

2021 Department Of Energy Collegiate Wind Competition Electrical System, Grayson Capers, Shane Alayvilla, Justin Rodrigues

Electrical Engineering

In this work, the implementation of the electrical system for Cal Poly’s 2021 Department of Energy Collegiate Wind Competition turbine is described. The mission of this project was to complete the turbine testing tasks to the best of the team’s ability. This system includes an off the shelf slotless permanent magnet synchronous generator and rectifier to produce a DC voltage. To maximize the power output at below-rated wind speeds, current sensors, voltage sensors, and a dynamic load with variable resistance were designed and tested. To curtail the power and rotor speed in high wind events, the turbine was equipped with …

Diversifying Nuclear Technology: A Technical Analysis On Small Modular Reactors And Its Impact On Nuclear Energy Policy, Carolina Lugo Mejia, Marcos Lugo

Helm's School of Government Conference - American Revival: Citizenship & Virtue

The energy policy debate in the United States has revolved around the diversification of energy sources while promoting advantageous economic profits. One drive for this has been the discussion of anthropogenic, environmental endangerment concerns (Vlassopoulous 2011, 104). However, despite the environmental concerns, the U.S. has for some time only relied on one type of energy source—fossil fuels. Fossil fuels are categorized as natural gas, coal, petroleum, and other gases responsible (U.S. Energy Administration 2019). Natural gas is responsible for 38.4%, coal for 23.4%, petroleum for 0.4%, and other gases for 0.3% of the U.S.’s electrical generation (U.S. Energy Administration 2019). …

Next Generation Energy Storage: An Examination Of Lignin-Based Carbon Composite Anodes For Sodium Ion Batteries Through Modeling And Simulation, Dayton G. Kizzire

Doctoral Dissertations

The current energy market relies heavily on fossil fuel sources; however, we are amidst a momentous shift towards wind, solar, and water based renewable energies. Large-scale energy storage allows renewable energy to be stored and supply the grid with consistent energy despite changing weather conditions. Improvements to large-scale energy storage in terms of cost, safety, and sustainability are crucial to wide-scale adoption. A promising candidate for large-scale energy storage are sodium-ion batteries using hard carbon anodes. Sodium is globally available, cheaper, and more sustainable than lithium, but requires a different anode structure. A sustainable hard carbon anode with excellent Li-ion …