Engineering Commons^™

Improving The Reliability Of Aquatic Biogeochemical Models: Integrating Information And Optimizing Complexity, Cory P. Mcdonald

Dissertations, Master's Theses and Master's Reports - Open

No abstract provided.

Long-Range Pollution Transport: Trans-Atlantic Mechanisms And Lagrangian Modeling Methods, Robert Christopher Owen

Dissertations, Master's Theses and Master's Reports - Open

Over the past several decades, it has become apparent that anthropogenic activities have resulted in the large-scale enhancement of the levels of many trace gases throughout the troposphere. More recently, attention has been given to the transport pathway taken by these emissions as they are dispersed throughout the atmosphere. The transport pathway determines the physical characteristics of emissions plumes and therefore plays an important role in the chemical transformations that can occur downwind of source regions. For example, the production of ozone (O₃) is strongly dependent upon the transport its precursors undergo. O₃ can initially be formed …

Development Of Measurement And Modeling Techniques To Quantify Atmospheric Deposition Of Persistent, Bioaccumulative And Toxic Chemicals In The Great Lakes, Mark D. Rowe

Dissertations, Master's Theses and Master's Reports - Open

Measurement and modeling techniques were developed to improve over-water gaseous air-water exchange measurements for persistent bioaccumulative and toxic chemicals (PBTs). Analytical methods were applied to atmospheric measurements of hexachlorobenzene (HCB), polychlorinated biphenyls (PCBs), and polybrominated diphenyl ethers (PBDEs). Additionally, the sampling and analytical methods are well suited to study semivolatile organic compounds (SOCs) in air with applications related to secondary organic aerosol formation, urban, and indoor air quality.

A novel gas-phase cleanup method is described for use with thermal desorption methods for analysis of atmospheric SOCs using multicapillary denuders. The cleanup selectively removed hydrogen-bonding chemicals from samples, including much of …

Planning And Adaptation Measures For Urban Slum Communities In West Africa : Stochastic Rainfall Modeling Applied To Domestic Rainwater Harvesting And Climate Change Adaptation, Joshua R. Cowden

Dissertations, Master's Theses and Master's Reports - Open

Over half of the world’s population is living in urban settlements, and most urban growth is occurring in developing countries. These countries’ economies are often unable to accommodate these rural-urban immigrations, resulting in millions of people settling in insecure communities known as urban slums. Current efforts to prevent urban slums include UN-HABITAT strategies to upgrade slums and stimulate urban/regional development. Urban metabolism analysis, which studies material and energy flows/stocks through urban processes, help decision-makers better understand their urban system. Nine lessons from past urban metabolism studies are presented to assist in finding answers on how to best solve urban slum …

Nitrogen Oxides In The North Atlantic Troposphere: Impacts Of Boreal Wildfire And Anthropogenic Emissions, Maria Val Martin

Dissertations, Master's Theses and Master's Reports - Open

Nitrogen oxides play a crucial role in the budget of tropospheric ozone (O sub(3)) and the formation of the hydroxyl radical. Anthropogenic activities and boreal wildfires are large sources of emissions in the atmosphere. However, the influence of the transport of these emissions on nitrogen oxides and O sub(3) levels at hemispheric scales is not well understood, in particular due to a lack of nitrogen oxides measurements in remote regions. In order to address these deficiencies, measurements of NO, NO sub(2) and NO sub(y) (total reactive nitrogen oxides) were made in the lower free troposphere (FT) over the central North …

Regulation Issues And Prediction Of Natural Estrogen Loads For Wastewater Treatment Plants, Michelle E. Jarvie

Dissertations, Master's Theses and Master's Reports - Open

No abstract provided.

Countermeasures Against Scour At Bridge Abutments, Hua Li

Dissertations, Master's Theses and Master's Reports - Open

Scour at bridge abutments can cause damage or failure of bridges and result in excessive repairs, loss of accessibility, or even death. To mitigate abutment scour, both clear-water and live-bed laboratory experiments in a compound channel were performed using parallel walls and spur dikes as countermeasures, respectively. In addition, collars were tested under clear-water conditions only. It was found that both parallel walls and spur dikes can efficiently protect the abutment from scour provided that they are properly designed. Design guidelines were discussed for both countermeasures. Preliminary clear-water tests of collars as countermeasures against scour showed some promising results although …

Selected Chemoautotrophic Processes In Wastewater Treatment: Low Temperature Nitrification Inhibition By An Azo Dye And Biofiltration For Odor Control Of Hydrogen Sulfide, Ronald W. Martin Jr.

Dissertations, Master's Theses and Master's Reports - Open

Biochemical processes by chemoautotrophs such as nitrifiers and sulfide and iron oxidizers are used extensively in wastewater treatment. The research described in this dissertation involved the study of two selected biological processes utilized in wastewater treatment mediated by chemoautotrophic bacteria: nitrification (biological removal of ammonia and nitrogen) and hydrogen sulfide (H2S) removal from odorous air using biofiltration.

A municipal wastewater treatment plant (WWTP) receiving industrial dyeing discharge containing the azo dye, acid black 1 (AB1) failed to meet discharge limits, especially during the winter. Dyeing discharge mixed with domestic sewage was fed to sequencing batch reactors at 22oC and 7oC. …

Reaction Control In Quiescent Systems Of Free-Radical Retrograde-Precipitation Polymerization, Vijaya Raghavan Tirumala

Dissertations, Master's Theses and Master's Reports - Open

Free-radical retrograde-precipitation polymerization, FRRPP in short, is a novel polymerization process discovered by Dr. Gerard Caneba in the late 1980s. The current study is aimed at gaining a better understanding of the reaction mechanism of the FRRPP and its thermodynamically-driven features that are predominant in controlling the chain reaction.

A previously developed mathematical model to represent free radical polymerization kinetics was used to simulate a classic bulk polymerization system from the literature. Unlike other existing models, such a sparse-matrix-based representation allows one to explicitly accommodate the chain length dependent kinetic parameters.

Extrapolating from the past results, mixing was experimentally shown …