Engineering Commons^™

Catalytic Transfer Hydrogenation Reactions Of Lipids, Alexander Asiedu

Civil & Environmental Engineering Theses & Dissertations

Catalytic transfer hydrogenation (CTH) of lipids was investigated using 2-propanol as hydrogen donor for producing liquid hydrocarbons, e.g. jet fuels. The main sources of lipids selected in this study were waste cooking oil (WCO) and oil-laden algae-derived biofuel intermediate (BI). Two different catalysts were employed in this study, namely activated carbon and trimetallic-doped zeolite.

The CTH reaction was between WCO and 2-propanol in a continuous flow reactor over a packed-bed activated carbon at near atmospheric pressure. Results revealed a high level of alkenes and aromatics compounds, which are not stable and are not environmentally unfriendly. To reduce these compounds in …

Application Of A Biodegradable And Recyclable Chelating Agent For Ash Removal From Algae, Temitope George Daramola

Civil & Environmental Engineering Theses & Dissertations

Ash is inherent in algae biomass and it causes operational difficulties, equipment failure, and disposal issues during biomass conversion to biofuels and bioproducts. The objectives of this study are to (i) investigate the use of the biodegradable chelating agent for reducing ash content of algae and (ii) evaluate the potential of regeneration and recycle of the chelating agent for multiple uses. Conventionally, ethylenediamine-tetraacetic acid (EDTA) has been studied extensively to remove ash from biomass. However, EDTA is non-biodegradable and causes environmental issues at the disposal.

Nitrilotriacetic acid (NTA) is a biodegradable chelating agent and was used in this study for …

Challenges Of Designing And Operating A Pilot Scale Short Residence Time Continuous Hydrothermal Flash Hydrolysis Reactor For High Slurry Load Biomass Processing, Mason James Martin

Civil & Environmental Engineering Theses & Dissertations

Increasing demand for renewable energy, fuels, and bioproducts has resulted in a push for increasingly efficient and economically favorable biomass pretreatment methods. Flash Hydrolysis, (FH) a promising biomass pretreatment method, has been extensively studied at a laboratory scale. FH employs a continuous subcritical hydrothermal process capable of fractionating microalgae for lipid and protein recovery. FH is unique in that the residence time is very short (~ 10 s). Maintaining this residence time was key in designing a scaled pilot flash hydrolyzing unit (FHU). We have developed a one of its kind pilot FHU capable of increasing the processing output of …

Measuring And Modeling Bare Desert Wind Erosion From Steppe Grassland Of Northern China As Affected By Soil Moisture And Climate, Nicholas Morgan Potter

Civil & Environmental Engineering Theses & Dissertations

Soil erosion by wind has been found to be negatively related to soil water content, as evidenced by that for a given area, such a soil erosion can be much less in a wet than a dry year. However, few studies have examined the functional relationship between wind erosion and soil moisture, primarily due to lack of field measured data. The objectives of this study were to: 1) measure wind erosion in field using a portable wind tunnel devised and made by the author; 2) use the measured data to calibrate/validate a wind erosion model previously developed by the author; …

Sidestream Ras Fermentation For Stable Bio-P Combined With Short Cut Nitrogen Removal In An A/B Process, Lindsey Elise Ferguson

Civil & Environmental Engineering Theses & Dissertations

It is well known that soluble organic carbon (sCOD), especially in the form of volatile fatty acids (VFA), is critical to achieving reliable enhanced biological phosphorus removal (EBPR) in biological nutrient removal (BNR) processes. Consistent and reliable EBPR in systems treating wastewaters deficient in sCOD may be accomplished by the addition of VFA and sCOD – rich fermentate produced by the fermentation of primary sludge, return / waste activated sludge (RAS / WAS), or other suitable carbon sources. The solids retention time (SRT) of fermenters being used to supplement carbon in sidestream EBPR processes must be controlled such that complex …