Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 7 of 7
Full-Text Articles in Engineering
Nanoscale Spectroscopy In Energy And Catalytic Applications, Yi Ding
Nanoscale Spectroscopy In Energy And Catalytic Applications, Yi Ding
Electronic Theses and Dissertations
Emerging societal challenges such as the need for more sustainable energy and catalysis are requiring more sensitive and versatile measurements at the nanoscale. This is the case in the design and optimization of new materials for energy harvesting (solar cells) and energy storage devices (batteries and capacitors), or for the development of new catalysts for carbon sequestration or other reactions of interest. Hence, the ability to advance spectroscopy with nanoscale spatial resolution and high sensitivity holds great promises to meet the demands of deeper fundamental understanding to boost the development and deployment of nano-based devices for real applications. In this …
Analysis Of Residual Stress And Damage Mechanisms Of Thermal Barrier Coatings Deposited Via Ps-Pvd And Eb-Pvd, Linda Rossmann
Analysis Of Residual Stress And Damage Mechanisms Of Thermal Barrier Coatings Deposited Via Ps-Pvd And Eb-Pvd, Linda Rossmann
Electronic Theses and Dissertations
Thermal barrier coatings (TBCs) are critical to gas turbine engines, as they protect the components in the hot section from the extreme temperatures of operation. The current industry standard method of applying TBCs for turbine blades in jet engines is electron-beam physical vapor deposition (EB-PVD), which results in a columnar structure that is valued for its high degree of strain tolerance. An emerging deposition method is plasma-spray physical vapor deposition (PS-PVD), capable of producing a variety of customizable microstructures as well as non-line-of-sight deposition, which allows more complex geometries to be coated, or even multiple parts at once. The pseudo-columnar …
Lithium Polysulfide Battery With Improved Capacity And Cycle Performance Using Carbon Black Coated Free-Standing Carbon Cloth, Zhen Wei
Electronic Theses and Dissertations
Lithium ion batteries (LIBs) have been used in various applications such as portable electronics, grid storages, and electric vehicles (EVs). Despite its commercial success, further advancement of the battery is necessary to satisfy the increasing demands for low-cost and high- performance energy storage devices as LIB is reaching its theoretical limits. Lithium sulfur battery (LSB) is one of the promising candidates for the next generation energy storage technologies. LSB uses sulfur cathode which is a low-cost and earth abundant material with an extremely high theoretical capacity of 2600 Wh kg-1. Although there have been numerous researches aiming to establish the …
Interfacial Behavior In Polymer Derived Ceramics And Salt Water Purification Via 2d Mos2, Hao Li
Interfacial Behavior In Polymer Derived Ceramics And Salt Water Purification Via 2d Mos2, Hao Li
Electronic Theses and Dissertations
In the present dissertation, the behavior of the internal potential barrier in a polymer-derived amorphous SiAlCN ceramic was studied by measuring its complex impedance spectra at various dc bias as well as different testing and annealing temperatures. The complex impedance spectra of the polymer-derived a-SiAlCN were measured under various dc bias voltages in a temperature range between 50 and 150°C, as well as different annealing temperatures (1100-1400 °C). All spectra, regardless of temperature and bias, consist of two semi-circular arcs, corresponding to the free-carbon phase and the interface, respectively. The impedance of the free-carbon phase is independent of the bias, …
Fabrication And Characterization Of Nonlinear Optical Ceramics For Random Quasi-Phase-Matching, Xuan Chen
Fabrication And Characterization Of Nonlinear Optical Ceramics For Random Quasi-Phase-Matching, Xuan Chen
Electronic Theses and Dissertations
A number of technologies rely on the conversion of short laser pulses from one spectral domain to another. Efficient frequency conversion is currently obtained in ordered nonlinear optical materials and requires a periodic spatial modulation of their nonlinear coefficient which results in a narrow bandwidth. One can trade off efficiency for more spectral bandwidth by relaxing the strict phase-matching conditions and achieve nonlinear interaction in carefully engineered disordered crystalline aggregates, in a so-called random quasi-phase-matching (rQPM) process. In this dissertation, we examine appropriate fabrication pathways for (1-x)Pb(Mg1/3Nb2/3)O3-xPbTiO3 (PMN-PT) and ZnSe transparent ceramics for applications in the mid-IR. The main challenge …
Development Of S-Nitroso-N-Acetylpenicillamine (Snap) Impregnated Medical Grade Polyvinyl Chloride For Antimicrobial Medical Device Interfaces, Corbin Feit
Electronic Theses and Dissertations
In the clinical setting, polyvinyl chloride (PVC) accounts for 25% of all polymers used in medical device applications. However, medical devices fabricated with PVC, such as endotracheal tubes, extracorporeal circuits (ECCs), or intravenous catheters suffer from thrombosis and infection. Mortality associated with hospital associated infections (HAIs) exceed 100,000 deaths each year. One method to overcome these challenges is to develop bioactive polymers with nitric oxide (NO) release. Nitric oxide exhibits many physiological roles including, antibacterial, antithrombic, anti-inflammatory activity. In this study, Tygon® PVC tubing was impregnated with a NO donor molecule, S-nitroso-N-acetylpenicillamine (SNAP), via a simple solvent-swelling-impregnation method, where polymer …
Development Of In Vitro Point Of Care Diagnostics (Ivpcd) Based On Aptamers Integrated Biosensors, Nileshi Saraf
Development Of In Vitro Point Of Care Diagnostics (Ivpcd) Based On Aptamers Integrated Biosensors, Nileshi Saraf
Electronic Theses and Dissertations
The global market for the medical diagnostic industry is worth 25 billion dollars in the United States and is expected to grow exponentially each year. Presently available methods for biodetection, such as immunoassays, chemiluminescence and fluorescent based assays are expensive, time consuming and require skilled labor with high-end instruments. Therefore, development of novel, passive colorimetric sensors and diagnostic technologies for detection and surveillance is of utmost importance especially in resource constrained communities. The present work focusses on developing novel and advanced in vitro biodiagnostic tools based on aptamer integrated biosensors for an early detection of specific viral proteins or small …