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Engineering Commons

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2019

Missouri University of Science and Technology

Doctoral Dissertations

Anode corrosion

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Improving Base Metal Electrowinning, Charles Ebenezer Abbey Jan 2019

Improving Base Metal Electrowinning, Charles Ebenezer Abbey

Doctoral Dissertations

"In zinc electrowinning, Mn oxidizes to form MnO2 on Pb-Ag anodes, cell walls and pipes. MnO2 reduces anode corrosion but also leads to short circuits and maintenance issues. MnO2 is thought to interact with chloride ions and produce oxidized chlorine species. The interactions between Mn and Cl are not well understood. Bench scale experiments were conducted to investigate the effects of the manganese to chloride ratio on anode corrosion rate and electrolyte chemistry using rolled Pb-Ag anodes. Increasing the average Mn/Cl- ratio from ~7:1 to ~11:1 reduced the anode corrosion rate. Anode scales produced ...