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Open Access. Powered by Scholars. Published by Universities.®

2019

Missouri University of Science and Technology

Doctoral Dissertations

Chemical Engineering

Computation fluid dynamics

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Full-Text Articles in Engineering

Developing And Evaluating A Partition-Cavity Solar Thermochemical Reactor For Syngas Production Via Computational Fluid Dynamics, Han Zhang Jan 2019

Developing And Evaluating A Partition-Cavity Solar Thermochemical Reactor For Syngas Production Via Computational Fluid Dynamics, Han Zhang

Doctoral Dissertations

"Solar thermochemical processes are attractive since they have the advantages of storing solar energy as chemical fuels. In this dissertation, a partition-cavity solar thermochemical reactor was developed, and the heat and mass transfer of the solar thermochemical processes were numerically analyzed in this directly-irradiated reactor.

The reduction reaction of two-step CeO2/CeO2-δ solar redox process was investigated using the coupling of computational fluid dynamics (CFD) and discrete element method (DEM). The reduction rate was studied based on the catalyst textual properties and the reaction condition. The results revealed that the increase of catalyst specific surface area and the …