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Full-Text Articles in Engineering
Polymeric Impulsive Actuation Mechanisms: Development, Characterization, And Modeling, Yongjin Kim
Polymeric Impulsive Actuation Mechanisms: Development, Characterization, And Modeling, Yongjin Kim
Doctoral Dissertations
Recent advances in the field of biomedical and life-sciences are increasingly demanding more life-like actuation with higher degrees of freedom in motion at small scales. Many researchers have developed various solutions to satisfy these emerging requirements. In many cases, new solutions are made possible with the development of novel polymeric actuators. Advances in polymeric actuation not only addressed problems concerning low degree of freedom in motion, large system size, and bio-incompatibility associated with conventional actuators, but also led to the discovery of novel applications, which were previously unattainable with conventional engineered systems. This dissertation focuses on developing novel actuation mechanisms …
Progress Toward Durable Icephobic Materials, Matthew J. Coady
Progress Toward Durable Icephobic Materials, Matthew J. Coady
Electronic Thesis and Dissertation Repository
Ice accumulation is a major engineering challenge in many fields including aerospace, power generation, transportation, and infrastructure. A variety of solutions are being researched to address this challenge. Perhaps the most promising method of combating ice accumulation is by applying coatings with low values of interfacial ice adhesion strength, τice. Icephobic materials are those with ice adhesion below 100 kPa, and it has been shown that passive delamination can occur on surfaces with τice below 20 kPa. While various low adhesion surfaces have been prepared, durability concerns pervade applications where surfaces experience repeated icing or freeze-thaw cycles, …
Production Optimization Of Ring-Banded Spherulitic Crystals Of Poly (3-Butylthiophene-2,5-Diyl) Using Controlled Solution Evaporation, Frederick Paul Henderson Iii
Production Optimization Of Ring-Banded Spherulitic Crystals Of Poly (3-Butylthiophene-2,5-Diyl) Using Controlled Solution Evaporation, Frederick Paul Henderson Iii
Materials Engineering
Conductive polymers can carry a charge due to the presence of excess electrons along the carbon backbone. By growing these polymers into crystals, the usual insulative isotropic matrix that polymers form will be replaced with anisotropic regions where conduction is possible parallel to the crystal lattice growth direction. In previous research, while growing sphere shaped crystals it was observed that a few would exhibit rings that formed parallel to the circumference of the sphere. In this project, the conditions to produce this ring structure were examined by looking at two polymer solutions (with carbon disulfide or dichlorobenzene as solvent) and …
Chemical Stability And Performance Influence Of Choice Substituents And Core Conjugation Of Organic Semiconductors, Jack Ly
Doctoral Dissertations
Realizing organic based active materials for electronic devices, such as thin film transistors and photovoltaics, has been long sought after. Advancement in the field driven by chemists, engineers, and physicists alike have bolstered organic based semiconductor performance levels to rival those of traditional inorganic amorphous silicon-based devices. Within the field of organic semiconductors (OSC), two categories of active materials may be generalized: (1) polymer and (2) small molecule semiconductors. Each class of OSC inherently have their own advantages and disadvantages. Polymer semiconductors (PSC) allow a wide range in tunability via choice monomers and side chain engineering to illicit desirable energy …
Compression Set Improvement Of Thermoplastic Vulcanizates For High Temperature Tubing, Mitchell Valaitis
Compression Set Improvement Of Thermoplastic Vulcanizates For High Temperature Tubing, Mitchell Valaitis
Williams Honors College, Honors Research Projects
It was hypothesized that increasing the curative level of the fluorocarbon rubber (FKM) used in manufacturing of thermoplastic vulcanizate (TPV) materials would decrease the compression set values of the TPV enough for it to be suitable as a flexible, lightweight alternative to high operating temperature thermoset rubber tubing currently being used for power steering hose. First, promising TPV formulations were identified by varying the polyamide (PA) and FKM used in a Brabender mixer. Four different types of polyamide and four different types of FKM were investigated, with two of the FKM types and one polyamide type identified as being promising. …
Multidimensional Mass Spectrometry Of Chemonic™ Ccg-6 Nonionic Surfactant With Separation By Polarity And Shape, Charles Johnson
Multidimensional Mass Spectrometry Of Chemonic™ Ccg-6 Nonionic Surfactant With Separation By Polarity And Shape, Charles Johnson
Williams Honors College, Honors Research Projects
Chemonic™ CCG-6 surfactant is a water-soluble poly(ethylene glycol) (PEG) conjugated alkyl glyceride emollient. This surfactant exists as a complex mixture of a glycerol cores conjugated with poly(ethylene glycol) branches (PEGylation) that were partially esterified with caprylic (C8) and capric (C10) acids. These may be esterified on one, two, or all three arms of the glyceride. The architecture of the structures in this mixture was studied using multidimensional mass spectrometry (MS). Mass spectrometry was interfaced with ultra-performance liquid chromatography (UPLC) and ion mobility (IM) separation. The mixture was separated by reversed-phase LC, oligomers of the star-branched polymer were separated according to …