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Articles 1 - 30 of 53
Full-Text Articles in Engineering
Elementary Studies Of Twisted Bilayer Graphene, Branden P. Burns, Yong P. Chen
Elementary Studies Of Twisted Bilayer Graphene, Branden P. Burns, Yong P. Chen
The Summer Undergraduate Research Fellowship (SURF) Symposium
In the nanotechnology field, some existing materials and applications are harmful to the environment, not efficient for certain tasks, or too expensive to be fully utilized. Graphene is a strong and cheap material that can be used to improve current nanotechnologies for more practical uses in society. Twisted bilayer graphene (TBG) is an orientation of graphene layers that exhibit different properties than regular bilayer graphene. It is made by placing a single layer of graphene on top of another at an angle with respect to the other lattice orientation. Understanding the characteristics of TBG is important to uncover more physics …
Silver Oxide-Graphene Sensor For Hydrogen Peroxide, Austin D. Scherbarth, L Stanciu
Silver Oxide-Graphene Sensor For Hydrogen Peroxide, Austin D. Scherbarth, L Stanciu
The Summer Undergraduate Research Fellowship (SURF) Symposium
A nonenzymatic, amperometric sensor for Hydrogen Peroxide (H2O2) was designed by drop coating glassy carbon electrodes (GCEs) with Silver Oxide (Ag2O). Combining Ag2O with Graphene Oxide and a polymer, PEDOT, was also attempted in order to increase stability and electrochemical properties. Using metal oxides along with Graphene Oxide for sensors has been done quite a bit, but Ag2O itself has not been research extensively. So, in order to produce the best H2O2 sensor, the configuration of all components had to be optimized. Three different Ag2O …
Graphene Decorated Substrates And Their Interfacial Characteristics, Anurag Kumar
Graphene Decorated Substrates And Their Interfacial Characteristics, Anurag Kumar
Open Access Dissertations
Carbon nanotubes and graphene have been extensively studied for their excellent properties. As research on carbon expands, two major issues face the scientific community: (i) Expanding the scale of synthesis and (ii) Integration of different carbon structures for improved functionality. While significant advancements have been made in large-scale synthesis, room for improvement remains. As the scale of production increases, issues such as time, cost and energy that may otherwise not be very significant, begin to play greater roles. Thus, in order to effectively transition from laboratory prototypes to industrial products, a synthesis method that can address these issues is strongly …
Nanostructured Tin-Based Anodes For Lithium Ion Batteries With X-Ray Absorption Fine Structure Studies, Dongniu Wang
Nanostructured Tin-Based Anodes For Lithium Ion Batteries With X-Ray Absorption Fine Structure Studies, Dongniu Wang
Electronic Thesis and Dissertation Repository
The practical applications of lithium ion batteries are highly dependent on the choice of electrodes, where boosting the materials innovations to design and achieve high capacity, excellent cycling performance, rate capability, low-cost and safe electrode materials provide the best solution. Based on this, tin-based anodes have gained great attention due to its high theoretical capacity, low cost and nontoxic nature to environment. Nevertheless, it undergoes significant volume variation(259%)during the operation of the battery, leading to pulverization and significant capacity fade. Thus, the practical application of tin-based anodes is still quite challenging. This thesis tackles issues related to tin-based anodes. It …
Development Of Nanostructured Limpo4 (M=Fe, Mn) As Cathodes For High Performance Lithium-Ion Batteries, Jinli Yang
Development Of Nanostructured Limpo4 (M=Fe, Mn) As Cathodes For High Performance Lithium-Ion Batteries, Jinli Yang
Electronic Thesis and Dissertation Repository
Olivine LiFePO4 has garnered the most interest because of its environmental benignity, high safety and theoretical capacity. However, the major limitation for LiFePO4 is the intrinsically poor electronic conductivity and ionic conductivity. The sluggish kinetics for LiFePO4 could be overcome by reducing the size, coating with conductive carbon, or doping with isovalent ions. The decrease of the size to nanoscale could shorten the diffusion time of Li ions in LiFePO4 during intercalation/deintercalation process, but the nano-size active material usually accompanies with low tap density. Carbon coating and carbon addition could alleviate the poor electronic conductivity. However, …
Fe, Co And Ni Adatoms Adsorbed On Silicene: A Dft Study, Kent Gang '14, Siva Gangavarapu '14, Matthew Deng '14, Glenn W. "Max" Mcgee, Ron Hurlbut, Michael Lee Dao Kang, Sean Ng Peng Nam, Harman Johll, Tok Eng Soon
Fe, Co And Ni Adatoms Adsorbed On Silicene: A Dft Study, Kent Gang '14, Siva Gangavarapu '14, Matthew Deng '14, Glenn W. "Max" Mcgee, Ron Hurlbut, Michael Lee Dao Kang, Sean Ng Peng Nam, Harman Johll, Tok Eng Soon
Student Publications & Research
Two-dimensional materials have attracted much research attention given their intriguing properties. The latest member of this class of materials is silicene. In this work, we investigate the adsorption of Fe, Co and Ni adatoms on silicene using plane-wave density functional theory calculations within the Perdew-Burke-Ernzerhof parameterization of the generalized gradient approximation for the exchange-correlation potential. In particular, we calculate the binding energy, magnetization, and projected electronic configurations of these adatoms adsorbed at different sites on the silicene. Our calculations show that the hole site (i.e. in the centre of a hexagonal-like arrangement of Si atoms) is the most stable configuration …
Enhanced 3-Dimensional Carbon Nanotube Based Anodes For Li-Ion Battery Applications, Chi Won Kang
Enhanced 3-Dimensional Carbon Nanotube Based Anodes For Li-Ion Battery Applications, Chi Won Kang
FIU Electronic Theses and Dissertations
A prototype 3-dimensional (3D) anode, based on multiwall carbon nanotubes (MWCNTs), for Li-ion batteries (LIBs), with potential use in Electric Vehicles (EVs) was investigated. The unique 3D design of the anode allowed much higher areal mass density of MWCNTs as active materials, resulting in more amount of Li+ ion intake, compared to that of a conventional 2D counterpart. Furthermore, 3D amorphous Si/MWCNTs hybrid structure offered enhancement in electrochemical response (specific capacity 549 mAhg-1). Also, an anode stack was fabricated to further increase the areal or volumetric mass density of MWCNTs. An areal mass density of the anode …
A Significant Improvement In The Superconducting Properties Of Mgb2 By Co-Doping With Graphene And Nano-Sic, K S B De Silva, X Xu, Xiaolin Wang, D Wexler, D Attard, F Xiang, S. X. Dou
A Significant Improvement In The Superconducting Properties Of Mgb2 By Co-Doping With Graphene And Nano-Sic, K S B De Silva, X Xu, Xiaolin Wang, D Wexler, D Attard, F Xiang, S. X. Dou
Shi Xue Dou
The effects of graphene (G) and nanosilicon carbide (SiC) co-doping on the superconducting properties of MgB2 were studied using bulk samples. SiC remains one of the best dopants which can significantly improve the high field performance, while graphene is emerging as a new dopant for MgB2, which can improve the zero field critical current density (Jc). The superconducting properties characterized by Jc, the intergrain connectivity, and the critical fields were significantly improved by the use of both SiC and graphene as dopants.
The Effect Of Reduced Graphene Oxide Addition On The Superconductivity Of Mgb2, K S. B De Silva, S Gambhir, Xiaolin Wang, X Xu, W X. Li, David L. Officer, D Wexler, G G. Wallace, S. X. Dou
The Effect Of Reduced Graphene Oxide Addition On The Superconductivity Of Mgb2, K S. B De Silva, S Gambhir, Xiaolin Wang, X Xu, W X. Li, David L. Officer, D Wexler, G G. Wallace, S. X. Dou
Shi Xue Dou
Reduced graphene oxide (rGO) and highly reduced chemically converted graphene (ICCO) samples were prepared under different processing condition! and were doped into MgBz by a diffusion process at 800 °C for 10 houn. It was demonstrated that a small addition rCCG can significantly improve the supcn;onducting properties of MgBz. Doping of M8B2 with 1 mol% of rCCG resulted in a Ie of 5.45 X lOS A cm-2 at 20 K in self-fields, which il nearly 32% improvement over that of the undopcd sample. This is a significant improvement as most carbon sources adversely affect the Ie performance: at the zero …
Graphene Micro-Substrate Induced High Electron-Phonon Coupling In Mgb2, W X. Li, X Xu, K S. B De Silva, F X. Xiang, S X. Dou
Graphene Micro-Substrate Induced High Electron-Phonon Coupling In Mgb2, W X. Li, X Xu, K S. B De Silva, F X. Xiang, S X. Dou
Shi Xue Dou
Electron-phonon coupling strength was studied in graphene-MgB2 composites to explore the possibilities for a higher superconducting transition temperature (Tc). For the first time in the experimental work on MgB2, the Raman active E2g mode was split into two parts: a softened mode corresponding to tensile strain and a hardened mode attributed to the carbon substitution effect. The tensile strain effect is suggested to improve Tc of graphene-MgB2 composites because it increases the electron-phonon coupling strength of MgB2.
Superconducting Properties Of Graphene Doped Magnesium Diboride, Xun Xu, Wenxian Li, Xiaolin Wang, S. X. Dou
Superconducting Properties Of Graphene Doped Magnesium Diboride, Xun Xu, Wenxian Li, Xiaolin Wang, S. X. Dou
Shi Xue Dou
Graphene, carbon in the form of monolayer sheets, has revealed astonishing and unique chemical and physical properties, which have made it an extremely active research topic in both materials science and physics (Novoselov, K. S. et al., 2004). Through chemical and materials integration, graphene is being actively exploited in a range of technological applications (Stankovich, S. et al., 2006). Superconductors can carry electrical current without any energy dissipation. The combination of both graphene and a superconductor into a composite has great potential for electrical devices and large scale applications. MgB2, a superconductor with a simple composition and two-gap feature has …
Dependence Of Magnetoelectric Properties On Sintering Temperature For Nano-Sic-Doped Mgb2/Fe Wires Made By Combined In Situ/Ex Situ Process, Wenxian Li, Rong Zeng, Jiazhao Wang, Y Li, S. X. Dou
Dependence Of Magnetoelectric Properties On Sintering Temperature For Nano-Sic-Doped Mgb2/Fe Wires Made By Combined In Situ/Ex Situ Process, Wenxian Li, Rong Zeng, Jiazhao Wang, Y Li, S. X. Dou
Shi Xue Dou
Very fine nano-SiC particles (nm) were doped into a MgB2 superconductor. The influence of self-field supercurrent on the high-field performance of the nano-SiC-doped MgB2/Fe wires is discussed based on comparison of the critical current densities of the in situ processed nano-SiCdoped MgB2 wires and those of the nano-SiC-doped MgB2/Fe wires processed by the combination of in situ/ex situ methods.
Preparation And Characterisation Of Graphene Composite Hydrogels, Nicholas J. Whiteside, Gordon G. Wallace, Marc In Het Panhuis
Preparation And Characterisation Of Graphene Composite Hydrogels, Nicholas J. Whiteside, Gordon G. Wallace, Marc In Het Panhuis
Gordon Wallace
Stable dispersions containing graphene and gellan gum are used to form composite films. Incorporation of graphene into the gellan gum matrix results in mechanical reinforcement and electrical conductivity at low and high graphene loading fractions, respectively. Graphene-containing gellan gum hydrogel films are prepared by immersion of composite films in Ca2+ cross-linking solutions. The resulting hydrogels are electrically conducting and exhibit reinforcement compared to the corresponding gellan gum hydrogels. 2013 Elsevier B.V.
Tuning The Performance Of Nanocarbon-Based Gas Sensors Through Nanoparticle Decoration, Shumao Cui
Tuning The Performance Of Nanocarbon-Based Gas Sensors Through Nanoparticle Decoration, Shumao Cui
Theses and Dissertations
Tin dioxide (SnO2) is a well–known gas sensing material, but it becomes sensitive only at elevated temperatures (e.g., above 200 °C). Nanoparticles (NPs) combined with nanocarbons, such as carbon nanotubes (CNTs) and graphene, form a new class of hybrid nanomaterials that can exhibit fascinating gas sensing performance due to tunable electron transfer between NPs and nanocarbons induced by gas adsorption. Indeed, sensors made of SnO2 NPs&ndascoated CNTs have shown outstanding room–temperature sensing performance to various gases, including those that are undetectable by either SnO2 or CNTs alone.
The objectives of this dissertation study are to synthesize …
Probing Bonding And Dynamics At Heterogeneous Adsorbate/Graphene Interfaces, Eric Charles Mattson
Probing Bonding And Dynamics At Heterogeneous Adsorbate/Graphene Interfaces, Eric Charles Mattson
Theses and Dissertations
Graphene-based materials are becoming an astoundingly promising choice for many relevant technological and environmental applications. Deriving graphene from the reduction of graphene oxide (GO) is becoming a popular and inexpensive route toward the synthesis of these materials. While the desired product from GO reduction is pristine graphene, defects and residual oxygen functional groups inherited from the parent GO render reduced graphene oxide (RGO) distinct from graphene. In this work, the structure and bonding for GO and RGO is investigated to the end of a working understanding of the composition and properties of these materials. In situ selected area electron diffraction …
The Effect Of Reduced Graphene Oxide Addition On The Superconductivity Of Mgb2, K S. B De Silva, S Gambhir, Xiaolin Wang, X Xu, W X. Li, David L. Officer, D Wexler, G G. Wallace, S. X. Dou
The Effect Of Reduced Graphene Oxide Addition On The Superconductivity Of Mgb2, K S. B De Silva, S Gambhir, Xiaolin Wang, X Xu, W X. Li, David L. Officer, D Wexler, G G. Wallace, S. X. Dou
Gordon Wallace
Reduced graphene oxide (rGO) and highly reduced chemically converted graphene (ICCO) samples were prepared under different processing condition! and were doped into MgBz by a diffusion process at 800 °C for 10 houn. It was demonstrated that a small addition rCCG can significantly improve the supcn;onducting properties of MgBz. Doping of M8B2 with 1 mol% of rCCG resulted in a Ie of 5.45 X lOS A cm-2 at 20 K in self-fields, which il nearly 32% improvement over that of the undopcd sample. This is a significant improvement as most carbon sources adversely affect the Ie performance: at the zero …
Carbon Nanotube/Graphene Nanocomposite As Efficient Counter Electrodes In Dye-Sensitized Solar Cells, Josef Velten, Attila J. Mozer, Dan Li, David Officer, G G. Wallace, Ray Baughman, A Zakhidov
Carbon Nanotube/Graphene Nanocomposite As Efficient Counter Electrodes In Dye-Sensitized Solar Cells, Josef Velten, Attila J. Mozer, Dan Li, David Officer, G G. Wallace, Ray Baughman, A Zakhidov
Gordon Wallace
We demonstrated the replacement of the Pt catalyst normally used in the counter electrode of a dye-sensitized solar cell (DSSC) by a nanocomposite of dry spun carbon multi-walled nanotube (MWNT) sheets with graphene flakes (Gr-F). The effectiveness of this counter electrode on the reduction of the triiodide in the iodide/triiodide redox (I−/I− 3 ) redox reaction was studied in parallel with the use of the dry spun carbon MWNT sheets alone and graphene flakes used independent of each other. This nanocomposite deposited onto fluorinated tin-oxide-coated glass showed improved catalytic behavior and power conversion efficiency (7.55%) beyond the use of the …
Flexible Free-Standing Graphene-Silicon Composite Film For Lithium-Ion Batteries, Jiazhao Wang, Chao Zhong, Shulei Chou, Hua Liu
Flexible Free-Standing Graphene-Silicon Composite Film For Lithium-Ion Batteries, Jiazhao Wang, Chao Zhong, Shulei Chou, Hua Liu
Shulei Chou
Flexible, free-standing, paper-like, graphene-silicon composite materials have been synthesized by a simple, one-step, in-situ filtration method. The Si nanoparticles are highly encapsulated in a graphene nanosheet matrix. The electrochemical results show that graphene-Si composite film has much higher discharge capacity beyond 100 cycles (708 mAh g− 1) than that of the cell with pure graphene (304 mAh g− 1). The graphene functions as a flexible mechanical support for strain release, offering an efficient electrically conducting channel, while the nanosized silicon provides the high capacity.
Graphene Wrapped Lifepo4/C Composites As Cathode Materials For Li-Ion Batteries With Enhanced Rate Capability, Yi Shi, Shulei Chou, Jia-Zhao Wang, David Wexler, Hui-Jun Li, Hua-Kun Liu, Yuping Wu
Graphene Wrapped Lifepo4/C Composites As Cathode Materials For Li-Ion Batteries With Enhanced Rate Capability, Yi Shi, Shulei Chou, Jia-Zhao Wang, David Wexler, Hui-Jun Li, Hua-Kun Liu, Yuping Wu
Shulei Chou
To reduce the reaction time, electrical energy consumption, and cost, LiFePO4/C/graphene has been synthesized by a rapid, one-pot, microwave-assisted hydrothermal method within 15 min at a temperature of 200 °C, followed by sintering at 600 °C for 2 h under a H2/Ar (5:95, v/v) atmosphere. The microstructure and morphology of the LiFePO4/C/graphene products were characterized by means of X-ray diffraction, Raman spectroscopy, field emission scanning electron microscopy, and transmission electron microscopy. The carbon coated LiFePO4/C nanoparticles, around 200 nm in size, are thoroughly wrapped by crumpled micrometer-size graphene sheets. In this kind of structure, the bridging graphene nanosheets can form …
Nano-Particles In Multi-Scale Composites And Ballistic Applications, Jason Gibson
Nano-Particles In Multi-Scale Composites And Ballistic Applications, Jason Gibson
Electronic Theses and Dissertations
Carbon nanotubes, graphene and nano sized core shell rubber particles have all been extensively researched for their capability to improve mechanical properties of thermoset resins. However, there has been a lack of research on their evaluation for energy absorption in high velocity impact scenarios, and the fundamental mechanics of their failure mechanisms during highly dynamic stress transfer through the matrix. This fundamental research is essential for laying the foundation for improvement in ballistic performance in composite armor. In hard armor applications, energy absorption is largely accomplished through delamination between plies of the composite laminate. This energy absorption is accomplished through …
Terahertz Antenna Phase Shifters Using Integrally-Gated Graphene Transmission-Lines, Pai-Yen Chen, Christos Argyropoulos, Andrea Alu
Terahertz Antenna Phase Shifters Using Integrally-Gated Graphene Transmission-Lines, Pai-Yen Chen, Christos Argyropoulos, Andrea Alu
Department of Electrical and Computer Engineering: Faculty Publications
We propose the concept and design of terahertz (THz) phase shifters for phased antenna arrays based on integrally- gated graphene parallel-plate waveguides (GPPWGs). We show that an active transmission-line may be realized by combining GPPWGs with double-gate electrodes, in which the applied gate voltage can control the guiding properties of the gated sections. This may enable the realization of THz electronic switches and tunable loaded-lines for sub mm-wave antenna systems. Based on these active components, we theoretically and numerically demonstrate several digital and analog phase shifter designs for THz frequencies, with a wide range of phase shifts and small return …
Synthesis Of Graphene And Its Applications For Dye-Sensitized Solar Cells, Hui Wang
Synthesis Of Graphene And Its Applications For Dye-Sensitized Solar Cells, Hui Wang
Dissertations, Master's Theses and Master's Reports - Open
Graphene, which is a two-dimensional carbon material, exhibits unique properties that promise its potential applications in photovoltaic devices. Dye-sensitized solar cell (DSSC) is a representative of the third generation photovoltaic devices. Therefore, it is important to synthesize graphene with special structures, which possess excellent properties for dye-sensitized solar cells.
This dissertation research was focused on (1) the effect of oxygen content on the structure of graphite oxide, (2) the stability of graphene oxide solution, (3) the application of graphene precipitate from graphene oxide solution as counter electrode for DSSCs, (4) the development of a novel synthesis method for the three-dimensional …
Effect Of Sintering Temperature On The Superconducting Properties Of Graphene Doped Mgb2, K S B De Silva, X Xu, Sanjeev Gambhir, D C K Wong, W X Li, Q Y. Hu
Effect Of Sintering Temperature On The Superconducting Properties Of Graphene Doped Mgb2, K S B De Silva, X Xu, Sanjeev Gambhir, D C K Wong, W X Li, Q Y. Hu
Australian Institute for Innovative Materials - Papers
A comprehensive study on the effects of sintering temperature on graphene-doped MgB2 superconductor was conducted. Graphene has emerged as an effective dopant that is capable of improving the critical current density (J-{\rm c}) and flux pinning at a very low doping level, with only a slight reduction of the critical temperature (T-{\rm c}). MgB2 undoped and graphene-doped bulk samples were prepared by the in situ method and sintered within a temperature range from 650 to 950 {\circ}\hbox{C}. It is surprising to note that at the doping level of 1 at.% the sample sintered at 850 {\circ}\hbox{C} shows a J\rm c …
Reduced Graphene Oxide With Superior Cycling Stability And Rate Capability For Sodium Storage, Yunxiao Wang, Shulei Chou, Hua-Kun Liu, S X. Dou
Reduced Graphene Oxide With Superior Cycling Stability And Rate Capability For Sodium Storage, Yunxiao Wang, Shulei Chou, Hua-Kun Liu, S X. Dou
Australian Institute for Innovative Materials - Papers
Sodium ion battery is a promising electrical energy storage system for sustainable energy storage applications due to the abundance of sodium resources and their low cost. In this communication, the electrochemical properties of sodium ion storage in reduced graphene oxide (RGO) were studied in an electrolyte consisting of 1 M NaClO4 in propylene carbonate (PC). The experimental results show that the RGO anode allowed significant sodium ion insertion, leading to higher capacity at high current density compared to the previously reported results for carbon materials. This is due to the fact that RGO possesses higher electrical conductivity and is a …
Covalently Linked Biocompatible Graphene/Polycaprolactone Composites For Tissue Engineering, Sepidar Sayyar, Eoin Murray, Brianna C. Thompson, Sanjeev Gambhir, David L. Officer, Gordon G. Wallace
Covalently Linked Biocompatible Graphene/Polycaprolactone Composites For Tissue Engineering, Sepidar Sayyar, Eoin Murray, Brianna C. Thompson, Sanjeev Gambhir, David L. Officer, Gordon G. Wallace
Australian Institute for Innovative Materials - Papers
Two synthesis routes to graphene/polycaprolactone composites are introduced and the properties of the resulting composites compared. In the first method, mixtures are produced using solution processing of polycaprolactone and well dispersed, chemically reduced graphene oxide and in the second, an esterification reaction covalently links polycaprolactone chains to free carboxyl groups on the graphene sheets. This is achieved through the use of a stable anhydrous dimethylformamide dispersion of graphene that has been highly chemically reduced resulting in mostly peripheral ester linkages. The resulting covalently linked composites exhibit far better homogeneity and as a result, both Young's modulus and tensile strength more …
Manganosite-Microwave Exfoliated Graphene Oxide Composites For Asymmetric Supercapacitor Device Applications, Dennis Antiohos, Kanlaya Pingmuang, Mark Romano, Stephen Beirne, Tony C. Romeo, Phil Aitchison, Andrew I. Minett, Gordon G. Wallace, Sukon Phanichphant, Jun Chen
Manganosite-Microwave Exfoliated Graphene Oxide Composites For Asymmetric Supercapacitor Device Applications, Dennis Antiohos, Kanlaya Pingmuang, Mark Romano, Stephen Beirne, Tony C. Romeo, Phil Aitchison, Andrew I. Minett, Gordon G. Wallace, Sukon Phanichphant, Jun Chen
Australian Institute for Innovative Materials - Papers
Graphene based materials coupled with transition metal oxides are promising electrode materials in asymmetric supercapacitors owing to their unique properties which include high surface area, good chemical stability, electrical conductivity, abundance, and lower cost profile over time. In this paper a composite material consisting of graphene oxide exfoliated with microwave radiation (mw rGO), and manganosite (MnO) is synthesised in order to explore their potential as an electrode material. The composite material was characterised by scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and Raman spectroscopy. Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) were used to explore …
Organic Solvent-Based Graphene Oxide Liquid Crystals: A Facile Route Toward The Next Generation Of Self-Assembled Layer-By-Layer Multifunctional 3d Architectures, Rouhollah Jalili, Seyed Hamed Aboutalebi, Dorna Esrafilzadeh, Konstantin Konstantinov, Simon E. Moulton, Joselito M. Razal, Gordon G. Wallace
Organic Solvent-Based Graphene Oxide Liquid Crystals: A Facile Route Toward The Next Generation Of Self-Assembled Layer-By-Layer Multifunctional 3d Architectures, Rouhollah Jalili, Seyed Hamed Aboutalebi, Dorna Esrafilzadeh, Konstantin Konstantinov, Simon E. Moulton, Joselito M. Razal, Gordon G. Wallace
Australian Institute for Innovative Materials - Papers
We introduce soft self-assembly of ultralarge liquid crystalline (LC) graphene oxide (GO) sheets in a wide range of organic solvents overcoming the practical limitations imposed on LC GO processing in water. This expands the number of known solvents which can support amphiphilic self-assembly to ethanol, acetone, tetrahydrofuran, N-dimethylformamide, N-cyclohexyl-2-pyrrolidone, and a number of other organic solvents, many of which were not known to afford solvophobic self-assembly prior to this report. The LC behavior of the as-prepared GO sheets in organic solvents has enabled us to disperse and organize substantial amounts of aggregate-free single-walled carbon nanotubes (SWNTs, up to 10 wt …
A Significant Improvement In Both Low- And High-Field Performance Of Mgb2 Superconductors Through Graphene Oxide Doping, K S B De Silva, S H Aboutalebi, Xun Xu, Xiaolin Wang, W X Li, Konstantin Konstantinov, S X. Dou
A Significant Improvement In Both Low- And High-Field Performance Of Mgb2 Superconductors Through Graphene Oxide Doping, K S B De Silva, S H Aboutalebi, Xun Xu, Xiaolin Wang, W X Li, Konstantin Konstantinov, S X. Dou
Australian Institute for Innovative Materials - Papers
The effects of graphene oxide (GO) doping on the superconducting properties of MgB2 were studied using bulk samples made by the diffusion method. Homogeneous dispersions of GO in tetrahydrofuran were obtained through a novel synthesis method, which is then chemically doped with MgB2. It was found that GO doping significantly improves the critical current density, under both low and high magnetic fields, which distinguishes GO from all the other elements doped into MgB2 so far. 2013 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
Facile Synthesis Of Reduced Graphene Oxide/Mwnts Nanocomposite Supercapacitor Materials Tested As Electrophoretically Deposited Films On Glassy Carbon Electrodes, Widsanusan Chartarrayawadee, Simon E. Moulton, Chee O. Too, Byung C. Kim, Rao Yepuri, Anthony C. Romeo, Gordon G. Wallace
Facile Synthesis Of Reduced Graphene Oxide/Mwnts Nanocomposite Supercapacitor Materials Tested As Electrophoretically Deposited Films On Glassy Carbon Electrodes, Widsanusan Chartarrayawadee, Simon E. Moulton, Chee O. Too, Byung C. Kim, Rao Yepuri, Anthony C. Romeo, Gordon G. Wallace
Australian Institute for Innovative Materials - Papers
This paper reports on a facile synthesis method for reduced graphene oxide (rGO)/multi-walled carbon nanotubes (MWNTs) nanocomposites. The initial step involves the use of graphene oxide to disperse the MWNTs, with subsequent reduction of the resultant graphene oxide/MWNTs composites using l-ascorbic acid (LAA) as a mild reductant. Reduction by LAA preserves the interaction between the rGO sheets and MWNTs. The dispersion-containing rGO/MWNTs composites was characterized and electrophoretically deposited anodically onto glassy carbon electrodes to form high surface area films for capacitance testing. Pseudo capacitance peaks were observed in the rGO/MWNTs composite electrodes, resulting in superior performance with capacitance values up …
A Facile Route To Synthesize Transition Metal Oxide/Reduced Graphene Oxide Composites And Their Lithium Storage Performance, Chongjun Zhao, Shulei Chou, Yunxiao Wang, Cuifeng Zhou, Hua-Kun Liu, S X. Dou
A Facile Route To Synthesize Transition Metal Oxide/Reduced Graphene Oxide Composites And Their Lithium Storage Performance, Chongjun Zhao, Shulei Chou, Yunxiao Wang, Cuifeng Zhou, Hua-Kun Liu, S X. Dou
Australian Institute for Innovative Materials - Papers
Transition metal oxide (Mn3O4, Fe2O3, Co3O4, and ZnO) and reduced graphene oxide (RGO) composites were successfully synthesized via a hydrothermal method using the direct reaction between the corresponding metal powder and graphene oxide (GO). In this process, the GO can be reduced by transition metal powder in water, and the nanosized metal oxide can be obtained, and homogeneously mixed with and wrapped by RGO to form a metal oxide/RGO composite at the same time. X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, and scanning and transmission electron microscopy were used to characterize the as-prepared materials. The different experimental parameters, including reactants, …