Engineering Commons^™

New Topics On Nanoindentation Of Polymers And Composite Materials, Ricardo Martinez-Hernandez

Open Access Theses & Dissertations

In this study, nanoindentation was used to determine Young's modulus of homogeneous plastic materials as well as inhomogeneous epoxy woven fabric composites using various indenters. In the first part, homogeneous PMMA and polycarbonate were characterized using conical and spherical indenters. The conventional approach of the inverse analysis was modified in order to account for effects obtained during spherical nanoindentation. The experimental results were verified using FEA analysis in ABAQUS. It was found that viscous effects were present in conical nanoindentations which led to an overestimation of contact stiffness. The second part, the response of carbon and glass fiber woven fabric …

An Exploration Of Social Media Use Among Multiply Minoritized Lgbtq Youth, Alfie Leanna Lucero

Open Access Theses & Dissertations

This study responds to a need for research in a fast-growing and significant area of study, that of exploring, understanding, and documenting the numerous ways that multiply marginalized LGBTQ youth between the ages of 14 and 17 use social media. The primary research question examined whether social media provide safe spaces for multiply minoritized LGBTQ youth to express and explore issues of sexuality and gender. In addition, the study explores and categorizes multiple ways that the participants interact with social media and makes comparisons to prior work with more general populations. The study provides descriptions of the participants in terms …

Exploring New Concepts In Directional Solidification By Electron Beam Melting And Selective Laser Melting, Edwin Martinez

Open Access Theses & Dissertations

Unlike more conventional directional solidification, electron and laser-beam melting technologies involve building 3D components through layer-by-layer melt/solidification thermal cycling which creates novel, directional microstructural architectures. In this study we compared various the columnar microstructures of various components manufactured by EBM and SLM; image composite observations of columnar microstructural architectures in Cu, Co-29-Cr-6Mo-0.2C alloy, Ni-22Cr-9Mo-4Nb (alloy 625) fabricated by electron beam melting (EBM), and Ni-19Cr-19Fe-5Nb-1Al (alloy 718) by selective laser melting (SLM) as well as stainless steel 17-4 PH (SLM). Cu produced discontinuous columns of Cu2O precipitates while the Co-base alloy exhibited similar columns of Cr23C6 precipitates. The alloy 625 produced …

Rbd2po4: Room Temprature Synthesis, Chemical And Structural Stablity Upon Heating, Masoud Mollaee

Open Access Theses & Dissertations

Monoclinic RbD2PO4 polycrystals were synthesized via the room temperature crystallization of RbH2PO4 dissolved in D2O. Powder x-ray diffraction (XRD) data collected at T=25 ºC indicate that this deuterated compound crystallizes in space group P21/m with unit cell parameters a=7.688í?, b=6.192í?, c=4.781í? and β=109.02°, and is isomorphic with the intermediate-temperature phase of its hydrogenated counterpart rubidium dihydrogen phosphate (RDP). We found no evidence of previously reported [Phase Transitions 80, 17 (2007)] polymorphic phase transition in rubidium dideuterium phosphate (DRDP) upon heating from room temperature to 210 ºC. All lattice parameters vary smoothly within this temperature range, demonstrating that the P21/m phase …

Model Fusion: A New Approach To Processing Heterogeneous Data, Omar Ochoa

Open Access Theses & Dissertations

In many practical situations, it is necessary to extract

information from data of different types. For example, in geosciences, several sources of data can be used to determine the interior structure of the earth: the first arriving waves from earthquakes and from man-made sources, measurements of the earth's gravity field, measurements of the dispersion of surface waves generated by earthquakes, etc. At present, most existing data processing techniques deal only with data of one type.

A joint use of all the information derived from multiple types of data sources is an important theoretical and practical challenge. Such a joint use …

Novel Copper (Ii) Mediated Transfection Nano-Systems And Biological Properties Of Pyridinium Surfactants, Sarit Pal

Open Access Theses & Dissertations

Efficacy of gene therapy is relied upon the improvement of gene delivery vectors into mammalian cells. Although viral-based polynucleotide carriers are still considered as the most common method for gene delivery but the cost effectiveness, nonspecific lethal immune response has evoked the renaissance of non-viral synthetic delivery systems. An initial discovery by Felgnar et al showed Cationic Liposomes (CLs) (having an overall positive charge) when mixed with DNA to form CL-DNA complexes can enhance the transfer of polynucleotides into cells followed by its expression. Presently, a flurry of experimental works is taking place for the better understanding of structural characterization …

Inkjet Based Personalized Screening Platform For Cancer Therapy, Jorge Ivan Rodriguez

Open Access Theses & Dissertations

The new paradigm of personalized medicine is beginning to affect clinical practice. In particular, many of the advances in genomics and proteomics have made personalized screening and therapeutic inventions possible. On chip, cellomics approaches to screening and intervention are becoming more commonplace. Cancer therapies may benefit from the rise in `-omics' technologies. In addition, the availability of rapid screening data is crucial to mitigate cancer propagation and increase the possibility of patient recovery. This study is an endeavor to develop a cellomic anticancer drug screening process based on inkjet printing. Previous research has demonstrated that inkjet based screening can reliably …

Design Of A Biomass-To-Biorefinery Logistics System Through Bio-Inspired Metaheuristic Optimization Considering Multiple Types Of Feedstocks, Isidoro Trueba

Open Access Theses & Dissertations

Bioenergy has become an important alternative source of energy to alleviate the reliance on petroleum energy. Bioenergy offers significant potential to mitigate climate change by reducing life-cycle greenhouse gas emissions relative to fossil fuels. The Energy Independence and Security Act mandate the use of 21 billion gallons of advanced biofuels including 16 billion gallons of cellulosic biofuels by the year 2022. It is clear that Biomass can make a substantial contribution to supplying future energy demand in a sustainable way. However, the supply of sustainable energy is one of the main challenges that mankind will face over the coming decades. …

Structure And Electronic Properties Of Pure And Nitrogen Doped Nanocrystalline Tungsten Oxide Thin Films, Vemnkata Rama Sesha Ravi Kumar Vemuri

Open Access Theses & Dissertations

Tungsten oxide (WO₃) is a multifunctional material which has applications in electronics, sensors, optoelectronics, and energy-related technologies. Recently, electronic structure modification of WO₃ to design novel photocatalysts has garnered significant attention. However, a fundamental understanding of nitrogen induced changes in the structure, morphology, surface/interface chemistry, and electronic properties of WO₃ is a prerequisite to producing materials with the desired functionality and performance. Also, understanding the effect of thermodynamic and processing variables is highly desirable in order to derive the structure-property relationships in the W-O/W-O-N material system. The present work was, therefore, focused on studying the effects …

Printable Biodegradable Hydrogel For Skin Wound Dressing Using Inkjet Printing Technology, Maria G. Yanez

Open Access Theses & Dissertations

Chronic wounds are becoming more frequent. Foot ulcers affect approximately 10% - 15% of patients with diabetes throughout their lifetimes, and by 2025, it is estimated the prevalence of diabetes will be 250 million people in the worldwide. There is increased potential for patients with peripheral neuropathy and peripheral vascular disease to suffer more foot injuries. These conditions reduce the normal pain sensations and healing of minor traumas, allowing the development of chronic non-healing ulcers, often preceding lower-extremity amputation. These types of wounds are very difficult to treat and sometimes take months or even years to heal because of many …

Investigation Into The Operation And Safety Of Freeway Auxiliary Lanes: Towards Uniform Design Guidelines, Yubian Wang

Open Access Theses & Dissertations

Freeways operate closest to the purest form of uninterrupted traffic flow. There is no constant interruption to traffic flow (such as stop sign and traffic signal), and access is limited to ramp locations. Therefore, at freeways, bottlenecks, if exist, are usually caused by merging and diverging traffic at ramp locations. Bottleneck removal at freeway ramp areas can reduce average freeway commuter delay. Currently, engineers may add auxiliary lanes at ramp areas to mitigate or remove bottlenecks.

The American Association of State Highway Transportation Officials (AASHTO) publication A Policy on Geometric Design of Highways and Streets, commonly known as the "Green …

A Method To Reduce Plastic Shrinkage Cracking Of Concrete Using Re-Vibration Technique, Mustafa Abushaala Aldalinsi

Open Access Theses & Dissertations

One of the problems that reduce durability; thus, performance of concrete is the development of plastic shrinkage cracking (PSC). Traditionally, the development of PSC has been minimized by controlling its exposure to weather conditions or by adding fibers. In this study, concrete re-vibration was used as an alternative technique to control PSC because of the limited availability of fibers in the developing countries. In this study, the wait time after slab casting and before vibration was selected to be 90 minutes while length of re-vibration time was varied from 15 to 45 seconds. Also, the water-cement ratios were selected to …

Post-Pareto Optimality Methods For The Analysis Of Large Pareto Sets In Multi-Objective Optimization, Victor Manuel Carrillo

Open Access Theses & Dissertations

Multiple objective optimization involves the simultaneous optimization of more than one, possibly conflicting, objectives. Multiple objective optimization problems arise in a variety of real-world applications. In general, the main difference between single and multi-objective optimization is that in multi-objective optimization there is usually no single optimal solution, but a set of equally good alternatives with different trade-offs, also known as Pareto-optimal solutions. There are two general approaches to solve multiple objective optimization problems: mathematical methods and meta-heuristic methods. The first approach involves the aggregation of the attributes into a linear combination of the objective functions, also known as scalarization. The …

Method Development For A Chemical And Biological Analysis Of Glucocorticoids In Wastewater, Maria Carmen Lozano

Open Access Theses & Dissertations

Glucocorticoids are a class of steroid hormones that can either be produced synthetically or naturally by the adrenal glands. The synthetic glucocorticoids are highly prescribed in the United States for their anti-inflammatory and immunosuppressive properties to treat a variety of ailments and diseases; however, these have been implicated in a number of adverse human conditions such as obesity, metabolic syndrome, immune-suppression, delayed puberty, adrenal insufficiency and Cushing Syndrome, among others. Ongoing research has shown that synthetic and natural hormones are transported to aquatic environments via mammalian excretion or wastewater effluent, and as a result, the release of glucocorticoids into the …

Experimental Study On The Fabrication Of Advanced Materials For Energy Applications Using High Energy Mechanical Milling, Ashvin Kumar Narayana Swamy

Open Access Theses & Dissertations

The reaction of aluminum (Al) powder with water has the potential for on demand hydrogen generation. Conventional Al powders, however, react with water slowly due to a highly protective oxide layer on the particle surface. Current methods for Al activation involve harmful and expensive materials. The nano-scale Al powders also remain very expensive and have problems such as a large amount of oxide on the surface. The use of aluminum in an energy generation cycle is also hindered by the fact that, although Al is the most abundant metal in the Earth's crust, its recovery from ore consumes a lot …

The Standardization Of Printable Materials And Direct-Write Systems, Jessica Lynn Porras

Open Access Theses & Dissertations

The standardization of Printable Materials and Direct-Write Systems addresses the many areas of Printing Nano Engineering that lack standards. Printing Nano Engineering is a new method of manufacturing electronics that utilize direct-write system with printing principles to manufacture electronic components.

Standards need to be developed for the different direct-write systems and printable materials in order to provide compatibility amongst printed electronics and to allow the optimization for direct-writ s e systems, and printable materials associated with these systems. There are many different types of direct-write systems in industry; each system involves different methods for printing that incorporates the limiting parameters …

Surface Plasmon Polaritons And Waveguide Modes At Structured And Inhomogeneous Surfaces, Javier Polanco

Open Access Theses & Dissertations

In chapter 1, properties of a p-polarized surface plasmon polariton are studied, propagating circumferentially around a portion of a cylindrical interface between vacuum and a metal, a situation investigated earlier by M. V. Berry (J. Phys. A: Math. Gen. 8, (1975) 1952). When the metal is convex toward the vacuum this mode is radiative and consequently is attenuated as it propagates on the cylindrical surface. An approximate analytic solution of the dispersion relation for this wave is obtained by an approach different from the one used by Berry, and plots of the real and imaginary parts of its wave number …

Manufacturing Nerve Guidance Conduits By Stereolithography For Use In Peripheral Nerve Regeneration, Mireya Aidee Perez

Open Access Theses & Dissertations

Nerve regeneration techniques have been studied in great depth in recent years. Peripheral nerve injuries, in particular, can be caused by accidents, falls, athletic injuries, etc. Current methods of repair include direct suturing of the 2 injured nerve ends or the use of autografts, when a nerve section is taken from another area of the body. Both methods have a series of limitations which have led researchers to study alternative methods of repair. Nerve guidance conduits may provide a viable solution because they can be modified and adapted to the patient's needs. Some conduits already exist on the market and …

Development Of Advanced Polymer Nanocomposite Capacitors, Md Rajib

Open Access Theses & Dissertations

With the development of modern technology, the demand of high energy density dielectric capacitor devices is increasing for its significant role in stationary power systems, mobile devices, and pulse power applications. Among the different energy storage devices, polymer film based dielectric capacitor is still one of the most widely used energy storage devices mainly due to its high energy density, significant higher charge/discharge rate and low cost. To further enhance the energy density, high dielectric ceramic inclusions have been embedded in the polymer matrix; however, the temperature influence on the energy density has not been investigated. Therefore, in this research …

Dielectric And Complex Impedance Properties Of Tetravalent Hafnium (Hf 4+) Integrated Cobalt Ferrite, Luis Javier Sanchez

Open Access Theses & Dissertations

The work presented in this thesis was carried out to understand the effects of tetravalent hafnium (Hf4+) ion on the crystal structure and phase, surface morphology, electrical, dielectric and complex impedance properties of cobalt ferrite (CoFe2O4; CFO). Hafnium incorporated cobalt ferrite, CoFe2-xHfxO4, with x = 0.00, 0.05, 0.075, 0.10, 0.15 and 0.20 were prepared by the standard solid state ceramic synthesis method. X-ray diffraction (XRD) and scanning electron microscopy (SEM) characterizations were performed to determine the structural properties. Most important aspect of this study is to explore the dielectric and complex impedance properties as a function of variable temperature (T=300-1000 …

Thermal Barrier Coatings (Tbc's) For High Heat Flux Thrust Chambers, Christopher Michael Bradley

Open Access Theses & Dissertations

The last 30 years materials engineers have been under continual pressure to develop materials with a greater temperature potential or to produce configurations that can be effectively cooled or otherwise protected at elevated temperature conditions. Turbines and thrust chambers produce some of the harshest service conditions for materials which lead to the challenges engineers face in order to increase the efficiencies of current technologies due to the energy crisis that the world is facing. The key tasks for the future of gas turbines are to increase overall efficiencies to meet energy demands of a growing world population and reduce the …

Development And Testing Of An Ignition Physics Test Facility And An Oxygen/Methane Swirl Torch Igniter, Jesus Roberto Flores

Open Access Theses & Dissertations

There are many advantages to LOX/methane propulsion, such as in-situ resource utilization from Mars and the Moon, and simplicity of ground operations due to its non-toxic nature. There exists a lack of fundamental understanding of the ignition physics, and flame characteristics of these propellants when related to rocket propulsion, which has created undesirably long design cycles and flight hardware that is not optimized. Motivated by these issues, a study of the ignition physics of a shear coaxial injector is proposed, in which the flow field dynamics and ignition transients will be observed through a visually accessible combustion chamber. The main …

Microstructure And Properties For Titanium Aluminide Superalloy Prototypes Fabricated By Electron Beam Melting And Thermally Processed, Jennifer Hernandez

Open Access Theses & Dissertations

Gamma TiAl has been considered to be an ideal replacement for Ni-base superalloy aerospace applications, particularly in weight-critical applications. While bulk, fully dense gamma-TiAl is 50% less dense than Ni-base superalloys, it also has excellent mechanical properties at high temperature (up to ~800°C). Pre alloyed (Ti-48Al-2Cr-2Nb) powder was used to fabricate solid, fully dense (3.85 g/cm3) components and foam components with densities ranging from 0.33 g/cm³ to 0.46 g/cm³ by electron beam melting (EBM). A 10:1 blend of 2-phase TiAl (Ti-48Al-2Cr-2Nb in ^a/_o) : Inconel 625 (Ni-22Cr-6Mo-2Nb in ^a/_o) pre-alloyed powders produced …

A Damage-Trap Interfacial Design To Improve Impact Resistance Of Polymers, Md Shariful Islam

Open Access Theses & Dissertations

Polymer materials such as Polycarbonate (PC), Polymethyl methacrylate (PMMA) have numerous applications in transparent armor which includes body and face shield, helmet, windows of the armored vehicle etc. The most challenging part of these applications is to ensure the safety of the people. These materials are often subjected to impact loading, so it is important to study the failure of these materials under impact loading. An experimental study has been made to investigate the impact damage in transparent layered materials. Impact experiments were carried out on various monolithic specimens and layered specimens for both two types of materials at different …

Analysis Of Vehicle Interactions On Interstate Highways: Discrete Choice And Linear System Approaches, Alicia Romo

Open Access Theses & Dissertations

The research in this dissertation developed statistical and linear system models to predict driving behavior according to driver attributes, vehicle characteristics, car-following dynamics and/or driving conditions. The scope of this research was limited to the interaction of two vehicles traveling in the same direction on interstate highways.

The statistical models proposed in this research investigated the contributions of the different vehicle types on the manner and likelihood of collision. Discrete choice models were used to estimate the probability of the types of collision (rear-end, angle and sideswipe) as functions of driver attributes, striking and struck vehicle types, pre-crash driving actions …

3d Printing For The Rapid Prototyping Of Structural Electronics, Rodolfo Salas

Open Access Theses & Dissertations

In business, the time required to shepherd a new product through the phases of concept, design, prototypes, through manufacture and finally making the product available for sale (together known as: Time to Market) is critical to the success and profitability of the next generation of products. The use of relatively new technologies, known as 3D Printing, which allow the fabrication of complex tridimensional shapes within hours of a completed CAD design without the need for tooling or molds, has significantly reduced the time required for a designer to physically hold a part designed only hours before and to perform form …

Structural, Optical And Electrical Properties Of Yttrium-Doped Hafnium Oxide Nanocrystalline Thin Films, Abhilash Kongu

Open Access Theses & Dissertations

Hafnium oxide (HfO2) has emerged as the most promising high-k dielectric for Metal-Oxide-Semiconductor (MOS) devices and has been highlighted as the most suitable dielectric materials to replace silicon oxide because of its comprehensive performance. In the present research, yttrium-doped HfO2 (YDH) thin films were fabricated using RF magnetron sputter deposition onto Si (100) and quartz with a variable thickness. Cross-sectional scanning electron microscopy coupled with Filmetrics revealed that film thickness values range from 700 A° to 7500 A°. Electrical properties such as AC Resistivity and current-voltage (I-V) characteristics of YDH films were studied. YDH films that were relatively thin (<1500 A°) crystallized in monoclinic phase while thicker films crystallized in cubic phase. The band gap (Eg) of the films was calculated from the optical measurements. The band gap was found to be ∼5.60 eV for monoclinic while it is ∼6.05 eV for cubic phase of YDH films. Frequency dependence of the electrical resistivity (ρac) and the total conductivity of the films were measured. Resistivity decreased (by three orders of magnitude) with increasing frequency from 100 Hz to 1 MHz, attributed due to the hopping mechanism in YDH films. Whereas, while ρac∼1Ω-m at low frequencies (100 Hz), it decreased to ∼ 104 Ω-cm at higher frequencies (1 MHz). Aluminum (Al) metal electrodes were deposited to fabricate a thin film capacitor with YDH layer as dielectric film thereby employing Al-YDH-Si capacitor structure. The results indicate that the capacitance of the films decrease with increasing film thickness. A detailed analysis of the electrical characteristics of YDH films is presented.

A Hybrid Modelling Approach For Maintenance And Rehabilitation Treatment Effectiveness Of Asphalt Pavements In Texas, Daniel Saenz

Open Access Theses & Dissertations

Analysis tools in pavement management systems are critical to assist transportation agencies in developing the most adequate maintenance and rehabilitation program. The significant elements are not only the type of treatment selected and its cost, but also the quantification of its short-term and long-term effectiveness and the timing of intervention. Methodologies with complex statistical approaches and performance model theories have been previously implemented in their derivation, but they may not be suitable or accurate. Therefore, it is imperative to factor in engineering experience in their assessment. In this thesis, a hybrid modelling approach was presented to systematically introduce expert knowledge …

Synthetic Asphaltene As A Novel Dye In Dye Sensitized Solar Cells Dsscs, Hassan Sharif

Open Access Theses & Dissertations

This dissertation approves the possibility of the first time use of synthetic asphaltene as new dye in dye sensitized solar cells. In which the conversion efficiency of synthetic asphaltene DSSC has improved up to 2.0 %. Synthetic asphaltene sample was prepared from the starting material as in literature and applied for various solar cell parameters of TiO2 based dyesensitized solar cell DSSC. DSSCs were fabricated using the synthetic asphaltene as dye. Different variables and parameters were carried out to test the photovoltaic performance of the cells, these parameters include open-circuit voltage, short-circuit current; fill factor. The first result was obtained …

Adsorption Of Arsenic, Chromium, And Uranium From Saline Water On Clinoptilolite And The Treatment Of The Spent Regenerant By Duffusion Dialysis, Mutiu Olaitan Tanimola

Open Access Theses & Dissertations

Among various water purification and recycling technologies, adsorption is a fast, inexpensive and universal method. The development of low-cost adsorbents has led to the rapid growth of research interests in this field. The objective of this present study is the optimization of process parameters in adsorption of arsenic, chromium and uranium ions. The adsorption behavior of natural zeolite (clinoptilolite) has been studied in order to determine its applicability in treating water containing arsenic, chromium and uranium. The multiple adsorption of arsenic As (V), trivalent chromium Cr (III)] and uranium (VI) on natural zeolite (clinoptilolite) in single component and multiple component …