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Articles 1 - 30 of 522
Full-Text Articles in Engineering
Synthesis Of Mn3o4-Encapsulated Graphene Sheet Nanocomposites Via A Facile, Fast Microwave Hydrothermal Method And Their Supercapacitive Behaviour, Li Li, Kuok Hau Seng, Zhixin Chen, Hua-Kun Liu, Ivan P. Nevirkovets, Zaiping Guo
Synthesis Of Mn3o4-Encapsulated Graphene Sheet Nanocomposites Via A Facile, Fast Microwave Hydrothermal Method And Their Supercapacitive Behaviour, Li Li, Kuok Hau Seng, Zhixin Chen, Hua-Kun Liu, Ivan P. Nevirkovets, Zaiping Guo
Faculty of Engineering and Information Sciences - Papers: Part A
Well-crystallized Mn3O4-anchored reduced graphene oxide (rGO) nanocomposites have been successfully synthesized via a facile, effective, energy-saving, and scalable microwave hydrothermal technique for potential application as supercapacitor material. Integrating these nanostructures resulted in a strong synergistic effect between the two materials, consequently leading to a hybrid composite with higher specific capacitance compared to the bare Mn3O4 nanoparticles. The results from different sorts of characterization indicate that the Mn3O4 particles were deposited and anchored on graphene sheets. The capacitance value of the rGO(31.6%)–Mn3O4 nanocomposite reached 153 F/g, much higher than that of the bare Mn3O4 (87 F/g) at a scan rate of …
Privacy Issues And Solutions In Social Network Sites, Xi Chen, Katina Michael
Privacy Issues And Solutions In Social Network Sites, Xi Chen, Katina Michael
Associate Professor Katina Michael
The boom of the internet and the explosion of new technologies have brought with them new challenges and thus new connotations of privacy. Clearly, when people deal with e-government and e-business, they do not only need the right to be let alone, but also to be let in secret. Not only do they need freedom of movement, but also to be assured of the secrecy of their information. Solove [6] has critiqued traditional definitions of privacy and argued that they do not address privacy issues created by new online technologies. Austin [7] also asserts: “[w]e do need to sharpen and …
Indian Millennials: Are Microchip Implants A More Secure Technology For Identification And Access Control?, Christine Perakslis, Katina Michael
Indian Millennials: Are Microchip Implants A More Secure Technology For Identification And Access Control?, Christine Perakslis, Katina Michael
Associate Professor Katina Michael
This mixed methods study with a sequential explanatory strategy explored qualitatively the statistically significant quantitative findings relative to Indian respondents’ perceptions about RFID (radio frequency identification) transponders implanted into the human body. In the first analysis phase of the study, there was a significant chi-square analysis reported (χ2 = 56.64, df = 3, p = .000) relative to the perception of small business owners (N = 453) that implanted chips are a more secure form of identification and/or access control in organizations and the respondents’ country of residence. Countries under study included Australia, India, the UK and US. The country …
The Value Of Government Mandated Location-Based Services In Emergencies In Australia, Anas Aloudat, Katina Michael, Roba Abbas, Mutaz Al-Debei
The Value Of Government Mandated Location-Based Services In Emergencies In Australia, Anas Aloudat, Katina Michael, Roba Abbas, Mutaz Al-Debei
Associate Professor Katina Michael
The adoption of mobile technologies for emergency management has the capacity to save lives. In Australia in February 2009, the Victorian Bushfires claimed 173 lives, the worst peace-time disaster in the nation’s history. The Australian government responded swiftly to the tragedy by going to tender for mobile applications that could be used during emergencies, such as mobile alerts and location services. These applications, which are becoming increasingly accurate with the evolution of positioning techniques, have the ability to deliver personalized information direct to the citizen during crises, complementing traditional broadcasting mediums like television and radio. Indeed governments have a responsibility …
Microstructure Evolution And Alloying Elements Distribution Between The Phases In Powder Near-B Titanium Alloys During Thermo-Mechanical Processing, Mansur Ahmed, Azdiar A. Gazder, Dmytro G. Savvakin, Orest M. Ivasishin, E V. Pereloma
Microstructure Evolution And Alloying Elements Distribution Between The Phases In Powder Near-B Titanium Alloys During Thermo-Mechanical Processing, Mansur Ahmed, Azdiar A. Gazder, Dmytro G. Savvakin, Orest M. Ivasishin, E V. Pereloma
Faculty of Engineering - Papers (Archive)
In the present study, two powders near-β Ti alloys having a nominal composition of Ti-5Al-5Mo-5V-XCr-1Fe (X = 1–2, wt%) were studied. The alloys were produced via the blended elemental powder metallurgy technique using hydrogenated Ti powder. Microstructure evolution and the distribution of the alloying elements between the phases were investigated after each step of thermo-mechanical processing (TMP). Microstructures were refined through the TMP in both alloys. Porosity was reduced with deformation at 1173 K (900 °C) in the β phase field. The β → α phase transformation occurred during soaking at 1023 K (750 °C) in the α + β …
Development Of Reliability-Based Design For Railway Prestressed Concrete Sleepers, Sakdirat Kaewunruen, Alexander Remennikov, Martin H. Murray
Development Of Reliability-Based Design For Railway Prestressed Concrete Sleepers, Sakdirat Kaewunruen, Alexander Remennikov, Martin H. Murray
Faculty of Engineering - Papers (Archive)
Faster and heavier train services are a driven improvement aspect for leaner and more profitable transport logistics of either passengers or freights. Ballasted rail track has been adopted for modern railways because of its many superior advantages in design, construction, short- and long-term maintenance, sustainability, financial capital and life cycle cost. An important element of the railway track system, which distributes the wheel load to the formation and holds the rail gauge, is the railway sleeper. Field data has raised concerns about design techniques for prestressed concrete (PC) sleepers. Most current design codes for these rely on allowable stresses and …
Commentary On: Mann, Steve (2012): Wearable Computing, Katina Michael, M.G. Michael
Commentary On: Mann, Steve (2012): Wearable Computing, Katina Michael, M.G. Michael
Associate Professor Katina Michael
In Professor Steve Mann- inventor, physicist, engineer, mathematician, scientist, designer, developer, project director, filmmaker, artist, instrumentalist, author, photographer, actor, activist- we see so much of the paradigmatic classical Greek philosopher. I recall asking Steve if technology shaped society or society shaped technology. He replied along the lines that the question was superfluous. Steve instead pointed to praxis, from which all theory, lessons or skills stem, are practiced, embodied and realized. Steve has always been preoccupied by the application of his ideas into form. In this way too, he can be considered a modern day Leonardo Da Vinci.
Book Review: Securing The Cloud: Cloud Computer Security Techniques And Tactics, Katina Michael
Book Review: Securing The Cloud: Cloud Computer Security Techniques And Tactics, Katina Michael
Associate Professor Katina Michael
With so much buzz around Cloud Computing, books like this one written by Winkler are much in demand. Winkler’s experience in the computing business shines through and as readers we are spoiled with a great deal of useful strategic information- a jam packed almost 300 page volume on securing the cloud.
In Memoriam: Associate Professor Dr Elaine Lawrence, Katina Michael
In Memoriam: Associate Professor Dr Elaine Lawrence, Katina Michael
Associate Professor Katina Michael
Despite being a graduate of the rigorous Bachelor of Information Technology at the University of Technology, Sydney (UTS) in 1996, I was unfortunate in that I missed being taught by Associate Professor Elaine Lawrence who began working at UTS in 1990 as a Lecturer in Computing Science. Dr Lawrence became a senior lecturer in 2000, and subsequently an associate professor in 2006. Our paths crossed in 2002 when I was tasked to deliver a new course entitled “eBusiness Principles” in my first year of lecturing at the University of Wollongong, and after an initial scurry to find an adequate textbook, …
Sousveillance And The Social Implications Of Point Of View Technologies In The Law Enforcement Sector, Katina Michael, M.G. Michael
Sousveillance And The Social Implications Of Point Of View Technologies In The Law Enforcement Sector, Katina Michael, M.G. Michael
Associate Professor Katina Michael
Policing today has become a high-tech affair; especially in the provision of incident event tracking and reporting systems increasingly being used to provide evidence in a court of law. These in-car video (ICV) and body worn recording systems are said to increase convictions and eliminate false claims made by defendants, providing documentary support to police officers and their associated actions in an incident. But today, new technologies such as smart phones equipped with cameras and global positioning system chipsets can also be found in the hands of the everyday citizen, used to capture everyday happenings and distributed to social networks …
Book Review: Security Risk Management: Building An Information Security Risk Management Program From The Ground Up, Katina Michael
Book Review: Security Risk Management: Building An Information Security Risk Management Program From The Ground Up, Katina Michael
Associate Professor Katina Michael
In an age of outsourcing tasks that are not considered to be a core competency of the business, organisations have often relied on external consultants for matters pertaining to security. In actual fact, most companies could have utilized existing skill-sets in-house to produce a security risk management program, if only they knew what steps to take, and how to go about it all. Evan Wheeler in his book on information security risk management does just that- he equips professionals tasked with security, with the thinking required to create a program that is more preoccupied with the complex strategic-level questions than …
Location Privacy Under Dire Threat As Uberveillance Stalks The Streets, Katina Michael, Roger Clarke
Location Privacy Under Dire Threat As Uberveillance Stalks The Streets, Katina Michael, Roger Clarke
Associate Professor Katina Michael
Location tracking and monitoring applications have proliferated with the arrival of smart phones that are equipped with onboard global positioning system (GPS) chipsets. It is now possible to locate a smart phone user down to 10 metres of accuracy on average. Innovators have been quick to capitalise on this emerging market by introducing novel pedestrian tracking technologies which can denote the geographic path of a mobile user. At the same time there is contention by law enforcement personnel over the need for a warrant process to track an individual in a public space. This paper considers the future of location …
Microstructural Characterisation Of Railhead Damage In Insulated Rail Joints, C Rathod, David Wexler, Tara Chandra, Huijun Li
Microstructural Characterisation Of Railhead Damage In Insulated Rail Joints, C Rathod, David Wexler, Tara Chandra, Huijun Li
Faculty of Engineering - Papers (Archive)
As an integral part the railway network infrastructure, insulated rail joints (IRJs) electrically isolate track segments providing critical feedback to both track signaling and train position detection systems. Because of the discontinuous nature of IRJs, accumulated damage at the railhead is high. Failure modes include plastic flow of metal across joints, bolt and fishplate failures, delamination of insulated material and, as a result of rolling contact fatigue, end post and endpost surface damage. In the current investigation, microstructural changes in the vicinity of endposts of IRJs made from both surface coated and uncoated rail are investigated using techniques of optical …
Hot Deformation Of Cast And Extruded Tial: An In-Situ Diffraction Study, Thomas Schmoelzer, Klaus-Dieter Liss, Svea Mayer, Kun Yan, Mark H. Reid, Rian J. Dippenaar, Matthew Peel, Helmut Clemens
Hot Deformation Of Cast And Extruded Tial: An In-Situ Diffraction Study, Thomas Schmoelzer, Klaus-Dieter Liss, Svea Mayer, Kun Yan, Mark H. Reid, Rian J. Dippenaar, Matthew Peel, Helmut Clemens
Faculty of Engineering - Papers (Archive)
Intermetallic TiAl alloys are a class of innovative high-temperature materials which are developed to replace the substantially denser Ni-base alloys in low-pressure turbine blades of jet engines. By streamlining the production process of these parts, a substantial decrease in production costs can be achieved. To this end, a profound knowledge of the microstructural processes occurring during hot deformation is a prerequisite. To investigate the microstructural development during forming operations, cast and extruded as well as only cast specimens were hot-deformed and the microstructural development investigated in-situ by means of a novel diffraction method. This powder diffraction method utilizes the behavior …
Investigation Of Phase Composition And Nanoscale Microstructure Of High-Energy Ball-Milled Mgcu Sample, Zongqing Ma, Yongchang Liu, Liming Yu, Qi Cai
Investigation Of Phase Composition And Nanoscale Microstructure Of High-Energy Ball-Milled Mgcu Sample, Zongqing Ma, Yongchang Liu, Liming Yu, Qi Cai
Australian Institute for Innovative Materials - Papers
The ball milling technique has been successfully applied to the synthesis of various materials such as equilibrium intermetallic phases, amorphous compounds, nanocrystalline materials, or metastable crystalline phases. However, how the phase composition and nanoscale microstructure evolute during ball milling in various materials is still controversial due to the complex mechanism of ball milling, especially in the field of solid-state amorphization caused by ball milling. In the present work, the phase evolution during the high-energy ball milling process of the Mg and Cu (atomic ratio is 1:1) mixed powder was investigated. It was found that Mg firstly reacts with Cu, forming …
Enhanced X-Ray Imaging For A Thin Film Cochlear Implant With Metal Artefacts Using Phase Retrieval Tomography, B D. Arhatari, Alexander R. Harris, Antonio G. Paolini, Andrew G. Peele
Enhanced X-Ray Imaging For A Thin Film Cochlear Implant With Metal Artefacts Using Phase Retrieval Tomography, B D. Arhatari, Alexander R. Harris, Antonio G. Paolini, Andrew G. Peele
Australian Institute for Innovative Materials - Papers
Phase retrieval tomography has been successfully used to enhance imaging in systems that exhibit poor absorption contrast. However, when highly absorbing regions are present in a sample, so-called metal artefacts can appear in the tomographic reconstruction. We demonstrate that straightforward approaches for metal artefact reconstruction, developed in absorption contrast tomography, can be applied when using phase retrieval. Using a prototype thin film cochlear implant that has high and low absorption components made from iridium (or platinum) and plastic, respectively, we show that segmentation of the various components is possible and hence measurement of the electrode geometry and relative location to …
One-Pot Synthesis Of Colloidal Silicon Quantum Dots And Surface Functionalization Via Thiol-Ene Click Chemistry, Xiaoyu Cheng, Richard Gondosiswanto, Simone Ciampi, Peter J. Reece, J Justin Gooding
One-Pot Synthesis Of Colloidal Silicon Quantum Dots And Surface Functionalization Via Thiol-Ene Click Chemistry, Xiaoyu Cheng, Richard Gondosiswanto, Simone Ciampi, Peter J. Reece, J Justin Gooding
Australian Institute for Innovative Materials - Papers
A solution method for preparing surface functionalized colloidal silicon quantum dots (SiQDs) is presented. SiQDs prepared by this method are reasonably monodispersed and can be further functionalized via thiol-ene click reactions to introduce specific functionalities (i.e. -NH2, -COOH, -SO 3 -, alkane, alkene).
Structure Determination Of An Amorphous Compound Alb4h11, Xuenian Chen, Yongsheng Zhang, Yongli Wang, Wei Zhou, Douglas A. Knight, Teshome B. Yisgedu, Zhenguo Huang, Hima Kumar Lingam, Beau Billet, Terrence J. Udovic, Gilbert M. Brown, Sheldon G. Shore, Christopher Wolverton, Ji-Cheng Zhao
Structure Determination Of An Amorphous Compound Alb4h11, Xuenian Chen, Yongsheng Zhang, Yongli Wang, Wei Zhou, Douglas A. Knight, Teshome B. Yisgedu, Zhenguo Huang, Hima Kumar Lingam, Beau Billet, Terrence J. Udovic, Gilbert M. Brown, Sheldon G. Shore, Christopher Wolverton, Ji-Cheng Zhao
Australian Institute for Innovative Materials - Papers
No abstract provided.
A Novel Route To Copper(Ii) Detection Using 'Click' Chemistry-Induced Aggregation Of Gold Nanoparticles, Carol Hua, William H. Zhang, Swahnnya De Almeida, Simone Ciampi, Danmar Gloria, Guozhen Liu, Jason Brian Harper, J Justin Gooding
A Novel Route To Copper(Ii) Detection Using 'Click' Chemistry-Induced Aggregation Of Gold Nanoparticles, Carol Hua, William H. Zhang, Swahnnya De Almeida, Simone Ciampi, Danmar Gloria, Guozhen Liu, Jason Brian Harper, J Justin Gooding
Australian Institute for Innovative Materials - Papers
A simple colorimetric method for the detection of copper ions in water is described. This method is based on the 'click' copper(i)-catalyzed azide-alkyne cycloaddition reaction and its use in promoting the aggregation of azide-tagged gold nanoparticles by a dialkyne cross-linker is described. Nanoparticle cross-linking, evidenced as a colour change, is used for the detection of copper ions. The lowest detected concentration by the naked eye was 1.8 μM, with the response linear with log(concentration) between 1.8-200 μM. The selectivity relative to other potentially interfering ions was evaluated.
The Synthesis Of Lamellar Nano Mgb2 Grains With Nanoimpurities, Flux Pinning Centers And Their Significantly Improved Critical Current Density, Zongqing Ma, Yongchang Liu, Qi Cai
The Synthesis Of Lamellar Nano Mgb2 Grains With Nanoimpurities, Flux Pinning Centers And Their Significantly Improved Critical Current Density, Zongqing Ma, Yongchang Liu, Qi Cai
Australian Institute for Innovative Materials - Papers
MgB2 superconductors with unique microstructures were rapidly fabricated at low temperatures, and exhibited significantly improved critical current density (Jc). According to the microstructure observations, the prepared samples consisted of lamellar nano MgB2 grains with many embedded nanoimpurities (about 10 nm). The formation of these lamellar nano MgB2 grains is associated with the presence of a local Mg-Cu liquid at sintering temperatures as low as 575°C. The ball milling treatment of the original powders also plays a positive role in the growth of lamellar grains. Based on an analysis of the relationship between resistivity and temperature, the lamellar nano MgB2 grains …
Kfe2se2 Is The Parent Compound Of K-Doped Iron Selenide Superconductors, Weijie Li, Hao Ding, Zhi Li, Peng Deng, Kai Chang, Ke He, Shuaihua Ji, Lili Wang, Xu-Cun Ma, Jiang-Ping Hu, Xi Chen, Qi-Kun Xue
Kfe2se2 Is The Parent Compound Of K-Doped Iron Selenide Superconductors, Weijie Li, Hao Ding, Zhi Li, Peng Deng, Kai Chang, Ke He, Shuaihua Ji, Lili Wang, Xu-Cun Ma, Jiang-Ping Hu, Xi Chen, Qi-Kun Xue
Australian Institute for Innovative Materials - Papers
We elucidate the existing controversies in the newly discovered K-doped iron selenide (KxFe2ySe2z) superconductors. The stoichiometric KFe2Se2 with ffiffiffi 2 p ffiffiffi 2 p charge ordering was identified as the parent compound of KxFe2ySe2z superconductor using scanning tunneling microscopy and spectroscopy. The superconductivity is induced in KFe2Se2 by either Se vacancies or interacting with the antiferromagnetic K2Fe4Se5 compound. In total, four phases were found to exist in KxFe2ySe2z: parent compound KFe2Se2, superconducting KFe2Se2 with ffiffiffi 2 p ffiffiffi 5 p charge ordering, superconducting KFe2Se2z with Se vacancies, and insulating K2Fe4Se5 with ffiffiffi 5 p ffiffiffi 5 p Fe vacancy order. …
Gating The Charge State Of Single Fe Dopants In The Topological Insulator Bi 2 Se 3 With A Scanning Tunneling Microscope, Canli Song, Yeping Jiang, Yi-Lin Wang, Zhi Li, Lili Wang, Ke He, Xi Chen, Xu-Cun Ma, Qi-Kun Xue
Gating The Charge State Of Single Fe Dopants In The Topological Insulator Bi 2 Se 3 With A Scanning Tunneling Microscope, Canli Song, Yeping Jiang, Yi-Lin Wang, Zhi Li, Lili Wang, Ke He, Xi Chen, Xu-Cun Ma, Qi-Kun Xue
Australian Institute for Innovative Materials - Papers
Low-temperature scanning tunneling microscope (STM) is exploited to study directly the atomic and electronic structures of single Fe dopants in topological insulator Bi2Se3 thin films. Fe atoms predominantly and isovalently substitute for two distinct Bi sites at the subsurface with charge neutrality. In the vicinity of Fe substitutions, circular depressions in STM topography and sharp rings in spatially resolved conductance map, whose diameters apparently depend on the tunneling conditions, are observed. We show that the phenomena correlate well with the switching between Fe3+ and Fe2+ charge states due to the gate effect of the tunneling tip, as further evidenced by …
A Battery Composed Of A Polypyrrole Cathode And A Magnesium Alloy Anode-Toward A Bioelectric Battery, Yong Kong, Caiyun Wang, Yang Yang, Chee O. Too, Gordon G. Wallace
A Battery Composed Of A Polypyrrole Cathode And A Magnesium Alloy Anode-Toward A Bioelectric Battery, Yong Kong, Caiyun Wang, Yang Yang, Chee O. Too, Gordon G. Wallace
Australian Institute for Innovative Materials - Papers
A bioelectric battery can be implanted into the human body and relies on oxygen in the internal body fluid to produce electrical energy. In this work, a battery that uses polypyrrole doped with a biological polyelectrolyte (dextran sulfate, an anti-coagulant) as the cathode and bioresorbable Mg alloy (AZ61) as the anode was developed. This battery exhibited a discharge capacity of 565 mA h g-1 in phosphate buffered saline (PBS, pH = 7.4), a commonly used electrolyte in biological research; offering a specific energy density of similar to 790W h kg-1. The electrochemical properties of the cathode, anode …
Anisotropic And Excellent Magnetocaloric Properties Of La 0.7ca0.3mno3 Single Crystal With Anomalous Magnetization, J.C Debnath, Rong Zeng, Jung Ho Kim, Dapeng Chen, S X. Dou
Anisotropic And Excellent Magnetocaloric Properties Of La 0.7ca0.3mno3 Single Crystal With Anomalous Magnetization, J.C Debnath, Rong Zeng, Jung Ho Kim, Dapeng Chen, S X. Dou
Australian Institute for Innovative Materials - Papers
Magnetic properties and the magnetocaloric effect (MCE) have been investigated in La0.7Ca0.3MnO3 single crystal with applied field along both the ab-plane and the c-direction. Due to the magnetocrystalline anisotropy, the crystal exhibits anisotropy in the MCE. Upon application of a 5 T field, the magnetic entropy changes (SM), reaching values of 7.668 J/(kg K) and 6.412 J/(kg K) for both the ab-plane and the c-direction, respectively. A magnetic entropy change of 3.3 J/(kg K) was achieved for a magnetic field change of 1.5 T at the Curie temperature, TC = 245 K. Due to the absence of grains in the …
High Field (14 T) Magneto Transport Of Sm/Prfeaso, R S. Meena, Shiva Kumar Singh, Anand Pal, Anuj Kumar, R Jha, K V.R Rao, Yi Du, Xiaolin Wang, V P. Awana
High Field (14 T) Magneto Transport Of Sm/Prfeaso, R S. Meena, Shiva Kumar Singh, Anand Pal, Anuj Kumar, R Jha, K V.R Rao, Yi Du, Xiaolin Wang, V P. Awana
Australian Institute for Innovative Materials - Papers
We report high field magneto transport of Sm/PrFeAsO. Below spin density wave transition (TSDW), the magneto-resistance (MR) of Sm/PrFeAsO is positive and increasing with decreasing temperature. The MR of SmFeAsO is found to be 16%, whereas it is 21.5% in the case of PrFeAsO, at 2.5K under applied magnetic field of 14 Tesla (T). In the case of SmFeAsO, the variation of isothermal MR with field below 20 K is nonlinear at lower magnetic fields (3.5 T). On the other hand, PrFeAsO shows almost linear MR at all temperatures below 20 K. The anomalous behavior of MR being …
Ferroelectric And Ferromagnetic Nanofibers: Synthesis, Properties And Applications, A Jalalian, A M. Grishin, S X. Dou
Ferroelectric And Ferromagnetic Nanofibers: Synthesis, Properties And Applications, A Jalalian, A M. Grishin, S X. Dou
Australian Institute for Innovative Materials - Papers
As first time, ferroelectric (Ba0.85Ca0.15)(Ti0.9Zr0.1)O3 (BCTZ), biocompatible (Na0.5K0.5)NbO3 (NKN), and ferromagnetic Y3Fe5O12 (YIG) nanofibers were synthesized by sol-gel assisted electrospining technique. Non-woven, bead-free 100 μm long fiber mat was formed from close-packed nanocrystals after calcination in air at 800°C (BCTZ and NKN) and 1100°C (YIG). BCTZ fibers are 200 nm in width whereas NKN and YIG fibers have smaller 50-100 nm diameter. X-ray diffraction and Raman spectroscopy show that BCTZ and NKN crystallized in tetragonal and rhombohedral polar phases in the vicinity of morphotropic phase boundary. …
Vapor Phase Polymerization Of Edot From Submicrometer Scale Oxidant Patterned By Dip-Pen Nanolithography, Cathal D. O'Connell, Michael J. Higgins, Hiroshi Nakashima, Simon E. Moulton, Gordon G. Wallace
Vapor Phase Polymerization Of Edot From Submicrometer Scale Oxidant Patterned By Dip-Pen Nanolithography, Cathal D. O'Connell, Michael J. Higgins, Hiroshi Nakashima, Simon E. Moulton, Gordon G. Wallace
Australian Institute for Innovative Materials - Papers
Some of the most exciting recent advances in conducting polymer synthesis have centered around the method of vapor phase polymerization (VPP) of thin films. However, it is not known whether the VPP process can proceed using significantly reduced volumes of oxidant and therefore be implemented as part of nanolithography approach. Here, we present a strategy for submicrometer scale patterning of the conducting polymer poly(3,4-ethylenedioxythiophene) (PEDOT) via in situ VPP. Attolitre (10-18 L) volumes of oxidant "ink" are controllably deposited using dip-pen nanolithography (DPN). DPN patterning of the oxidant ink is facilitated by the incorporation of an amphiphilic block copolymer …
The Role Of Unbound Oligomers In The Nucleation And Growth Of Electrodeposited Polypyrrole And Method For Preparing High Strength, High Conductivity Films, Wen Zheng, Joselito M. Razal, Geoffrey M. Spinks, Van-Tan Truong, Philip G. Whitten, Gordon G. Wallace
The Role Of Unbound Oligomers In The Nucleation And Growth Of Electrodeposited Polypyrrole And Method For Preparing High Strength, High Conductivity Films, Wen Zheng, Joselito M. Razal, Geoffrey M. Spinks, Van-Tan Truong, Philip G. Whitten, Gordon G. Wallace
Australian Institute for Innovative Materials - Papers
Polypyrrole is a material with immensely useful properties suitable for a wide range of electrochemical applications, but its development has been hindered by cumbersome manufacturing processes. Here we show that a simple modification to the standard electrochemical polymerization method produces polypyrrole films of equivalently high conductivity and superior mechanical properties in one-tenth of the polymerization time. Preparing the film as a series of electrodeposited layers with thorough solvent washing between layering was found to produce excellent quality films even when layer deposition was accelerated by high current. The washing step between the sequentially polymerized layers altered the deposition mechanism, eliminating …
Effect Of Frozen Spin On The Magnetocaloric Property Of La0.7ca0.3coo3 Polycrystalline And Single Crystal Samples, J C. Debnath, R Zeng, J H. Kim, P Shamba, Dapeng Chen, S X. Dou
Effect Of Frozen Spin On The Magnetocaloric Property Of La0.7ca0.3coo3 Polycrystalline And Single Crystal Samples, J C. Debnath, R Zeng, J H. Kim, P Shamba, Dapeng Chen, S X. Dou
Australian Institute for Innovative Materials - Papers
Polycrystalline (PC) and single crystalline (SC) samples of La0.7Ca0.3CoO3 (LCCO) with the perovskite structure were synthesized by conventional solid-state reaction and the floating-zone growth method. We conducted isothermal magnetization measurements of the PC and SC samples at temperatures from 2.8 K to 140 K, and evaluated the magnetic entropy change (−ΔSM) under zero field cooling (ZFC) and field cooling (FC) to 2.8 K. An interesting result has been obtained, where the −ΔSM–T curves in the low temperature range show totally different features between the ZFC and FC cooling procedures. The −ΔS …
Why Do Girls Sustain More Anterior Cruciate Ligament Injuries Than Boys? A Review Of The Changes In Oestrogen And Musculoskeletal Structure And Function During Puberty, Catherine Y. Wild, Julie R. Steele, Bridget J. Munro
Why Do Girls Sustain More Anterior Cruciate Ligament Injuries Than Boys? A Review Of The Changes In Oestrogen And Musculoskeletal Structure And Function During Puberty, Catherine Y. Wild, Julie R. Steele, Bridget J. Munro
Australian Institute for Innovative Materials - Papers
Sport is the leading cause of injury among adolescents and girls incur more non-contact anterior cruciate ligament (ACL) ruptures than boys, with this gender disparity in injury incidence apparent from the onset of puberty. Although the mechanisms for this gender disparity in ACL injuries are relatively unknown, hormonal, anatomical and biomechanical factors have been implicated. Puberty is associated with rapid skeletal growth and hormonal influx, both of which are thought to contribute to alterations in ACL metabolic and mechanical properties, as well as changes in lower limb strength and flexibility, ultimately influencing landing technique. Therefore, the aim of this review …