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Full-Text Articles in Engineering

Development Of A Compression Test Device For Investigating Interaction Between Diffusion Of Biodiesel And Large Deformation In Rubber Dec 2011

Development Of A Compression Test Device For Investigating Interaction Between Diffusion Of Biodiesel And Large Deformation In Rubber

A.S. Md Abdul Haseeb

Motivated by environmental and economic factors, biodiesel has been introduced to partially replace the diminishing stock of petroleum-based fuel. However, the use of biodiesel such as palm biodiesel is placing additional demands on automotive components, e.g. rubber components, due to a compatibility issue in the fuel system. In engineering applications where hostile environments are involved, the long-term mechanical response of rubber components is affected by interactions existed between diffusion of liquids into the material and fluctuating multiaxial loading. Hence, it is crucial to investigate the durability of rubber components in this aggressive environment. A number of studies on static immersion …


Membrane Biodiesel Production And Refining Technology: A Critical Review, Abdul Aziz Abdul Raman Dec 2011

Membrane Biodiesel Production And Refining Technology: A Critical Review, Abdul Aziz Abdul Raman

Abdul Aziz Abdul Raman

Membranes processes for the production and refining of biodiesel are being increasingly reported. Membrane technology has attracted the interest of researchers for its ability to provide high purity and quality biodiesel fuel besides its remarkable biodiesel yields. Membranes have numerous numbers of useful properties such as resistance to mechanical, chemical and thermal stress, high available surface area per unit volume, high selectivity, and ability to control the components contact between the two phases makes them potential. These properties have made them to be potential candidates for both upstream and downstream biodiesel production and refining applications. In this regards, this paper …


Investigations Of Transesterification Of Canola Oil With Methanol And Ethanol For A New Efficient Method Of Biodiesel Production, Krupal Pal Nov 2011

Investigations Of Transesterification Of Canola Oil With Methanol And Ethanol For A New Efficient Method Of Biodiesel Production, Krupal Pal

Electronic Thesis and Dissertation Repository

Transesterification of vegetable oil to biodiesel is a multistep process affected by mass transfer, mixing and chemical reaction equilibrium. Attempts have been made in this study to overcome these limitations by gradually feeding oil into a pool of alcohol. This approach provided large excess of alcohol to allow reaction to proceed further as well as allowed easy dispersion of oil into the alcohol. As a result improved conversion of feed, higher yield and better product quality were achieved. Comparisons have been made with other methods to show the differences and highlight improvements. Reactions were conducted at various reaction conditions for …


Effect Of Different Corrosion Inhibitors On The Corrosion Of Cast Iron In Palm Biodiesel Nov 2011

Effect Of Different Corrosion Inhibitors On The Corrosion Of Cast Iron In Palm Biodiesel

A.S. Md Abdul Haseeb

Biodiesel is currently in regular use as an alternative fuel over conventional petroleum diesel. However, corrosion of automotive materials is one of the concerns related to biodiesel compatibility issues. In addition, auto-oxidation of biodiesel can also enhance the corrosiveness of biodiesel. The present study aims to investigate inhibition effect of ethylenediamine (EDA), n-butylamine (nBA), tert-butylamine (TBA) against corrosion of cast iron. Static immersion tests in biodiesel in the presence (100 ppm) and absence of different corrosion inhibitors were carried out at room temperature for 1200 hours. At the end of the test, corrosion characteristic was investigated by weight loss measurements …


Effect Of Different Corrosion Inhibitors On The Corrosion Of Cast Iron In Palm Biodiesel Nov 2011

Effect Of Different Corrosion Inhibitors On The Corrosion Of Cast Iron In Palm Biodiesel

A.S. Md Abdul Haseeb

Biodiesel is currently in regular use as an alternative fuel over conventional petroleum diesel. However, corrosion of automotive materials is one of the concerns related to biodiesel compatibility issues. In addition, auto-oxidation of biodiesel can also enhance the corrosiveness of biodiesel. The present study aims to investigate inhibition effect of ethylenediamine (EDA), n-butylamine (nBA), tert-butylamine (TBA) against corrosion of cast iron. Static immersion tests in biodiesel in the presence (100 ppm) and absence of different corrosion inhibitors were carried out at room temperature for 1200 hours. At the end of the test, corrosion characteristic was investigated by weight loss measurements …


Development And Implementation Of A Fault Mitigating Control System For A Biodiesel Plug-In Hybrid Electric Vehicle For The Ecocar: The Next Challenge Competition, Sean Christopher Carter Sep 2011

Development And Implementation Of A Fault Mitigating Control System For A Biodiesel Plug-In Hybrid Electric Vehicle For The Ecocar: The Next Challenge Competition, Sean Christopher Carter

Doctoral Dissertations and Master's Theses

The automotive industry is continuously developing, and with it hybrid vehicle technology is a growing field of interest. The design of the electric vehicle is a pressing matter and grows in complexity with new powertrain components such as power inverters and transmission systems that use electric motors. As a control system develops, the architecture always comes back to systems engineering documentation to find safety protocols, solutions to problems through fault testing, and validating and verifying the control architecture throughout the whole process. Testing and evaluation plans are required more than ever and are constantly being updated and implemented in today's …


Effect Of Temperature On The Corrosion Behavior Of Mild Steel Upon Exposure To Palm Biodiesel Apr 2011

Effect Of Temperature On The Corrosion Behavior Of Mild Steel Upon Exposure To Palm Biodiesel

A.S. Md Abdul Haseeb

Recently biodiesel, as an alternative fuel is getting more significance to replace diesel fuel completely or partially. However, corrosion of automotive materials in biodiesel is a major concern as this can reduce engine life. This study aims to investigate the corrosion behavior of mild steel at three different temperatures such as room temperature, 50 and 80 °C. Static immersion tests in B0 (diesel), B50 (50% biodiesel in diesel), B100 (biodiesel) were carried out for 1200 h. At the end of the tests, corrosion characteristic was investigated by weight loss measurements and changes of the exposed metal surface. Fuels were analyzed …


Compatibility Of Automotive Materials In Biodiesel: A Review Mar 2011

Compatibility Of Automotive Materials In Biodiesel: A Review

A.S. Md Abdul Haseeb

Use of biodiesel in automobile can significantly reduce our dependence of fossil fuel and help reduce environmental pollution. However, there are concerns over the compatibility of currently used automotive materials in biodiesel. A few automobile manufacturers extended their warranty only to lower blends of biodiesel (e.g. B5). Higher blends (e.g. B50 or B100) are still not covered by warranty. In automobile fuel system, metallic materials like ferrous alloy and non-ferrous alloys, and elastomers come in contact with fuel. Biodiesel, having different chemical characteristics from diesel, can interact with materials in a different way. It can cause corrosive and tribological attack …


Degradation Of Physical Properties Of Different Elastomers Upon Exposure To Palm Biodiesel Mar 2011

Degradation Of Physical Properties Of Different Elastomers Upon Exposure To Palm Biodiesel

A.S. Md Abdul Haseeb

Biodiesel, as an alternative fuel, is gradually receiving more popularity for use in internal combustion engines. However questions continue to arise with regard to its compatibility with elastomeric materials. The present work aims to investigate the comparative degradation of physical properties for different elastomers [e.g. ethylene propylene diene monomer (EPDM), silicone rubber (SR), polychloroprene (CR), polytetrafluroethylene (PTFE) and nitrile rubber (NBR)] upon exposure to diesel and palm biodiesel. Static immersion tests in B0(diesel), B10 (10% biodiesel in diesel), B20, B50 and B100(biodiesel) were carried out at room temperature (25 °C) for 1000 h. Different physical properties like, changes in weight …


Biodiesel Separation And Purification: A Review, Abdul Aziz Abdul Raman Feb 2011

Biodiesel Separation And Purification: A Review, Abdul Aziz Abdul Raman

Abdul Aziz Abdul Raman

Conventional technologies used for biodiesel separation such as gravitational settling, decantation, filtration and biodiesel purification such as water washing, acid washing, and washing with ether and absorbents have proven to be inefficient, time and energy consumptive, and less cost effective. The involvement of membrane reactor and separative membrane shows great promise for the separation and purification of biodiesel. Membrane technology needs to be explored and exploited to overcome the difficulties usually encountered in the separation and purification of biodiesel. In this paper both conventional and most recent membrane technologies used in refining biodiesel have been critically reviewed. The effects of …


A Critical Review On Recent Methods Used For Economically Viable And Eco-Friendly Development Of Microalgae As A Potential Feedstock For Synthesis Of Biodiesel, Yogesh C. Sharma, Bhaskar Singh, John Korstad Jan 2011

A Critical Review On Recent Methods Used For Economically Viable And Eco-Friendly Development Of Microalgae As A Potential Feedstock For Synthesis Of Biodiesel, Yogesh C. Sharma, Bhaskar Singh, John Korstad

College of Science and Engineering Faculty Research and Scholarship

Microalgae are being considered as a viable feedstock for large-scale production of biodiesel. However, though it may look simpler to obtain lipids from microalgae, the overall process of choosing an algal strain, cultivation, harvesting, dewatering, and extraction of oil is quite complicated and not economically prudent at this time. A thorough understanding of algae and the overall biodiesel production process discussed in this paper is vital so that focused research might lower the costs involved. Various diverse species of microalgae are currently being used as feedstocks for biofuel. Heterotrophic culture may be preferred over photoautotrophic cultivation. For cultivation, specially fabricated …


Latest Developments On Application Of Heterogenous Basic Catalysts For An Efficient And Eco Friendly Synthesis Of Biodiesel: A Review, Yogesh C. Sharma, Bhaskar Singh, John Korstad Jan 2011

Latest Developments On Application Of Heterogenous Basic Catalysts For An Efficient And Eco Friendly Synthesis Of Biodiesel: A Review, Yogesh C. Sharma, Bhaskar Singh, John Korstad

College of Science and Engineering Faculty Research and Scholarship

Heterogeneous catalysts are now being tried extensively for biodiesel synthesis. These catalysts are poised to play an important role and are perspective catalysts in future for biodiesel production at industrial level. The review deals with a comprehensive list of these heterogeneous catalysts which has been reported recently. The mechanisms of these catalysts in the transesterification reaction have been discussed. The conditions for the reaction and optimized parameters along with preparation of the catalyst, and their leaching aspects are discussed. The heterogeneous basic catalyst discussed in the review includes oxides of magnesium and calcium; hydrotalcite/layered double hydroxide; alumina; and zeolites. Yield …


Biodiesel Feasibility Study: An Evaluation Of Material Compatibility; Performance; Emission And Engine Durability Jan 2011

Biodiesel Feasibility Study: An Evaluation Of Material Compatibility; Performance; Emission And Engine Durability

A.S. Md Abdul Haseeb

Biodiesel, derived from the transesterification of vegetable oils or animal fats, is composed of saturated and unsaturated long-chain fatty acid alkyl esters. In spite of having some application problems, recently it is being considered as one of the most promising alternative fuels in internal combustion engine. From scientific literatures, this paper has collected and analyzed the data on both advantages and disadvantages of biodiesel over conventional diesel. Since the aim of this study is to evaluate the biodiesel feasibility in automobiles, the first section is dedicated to materials compatibility in biodiesel as compared to that in diesel. The highest consensus …


A Packed Bed Membrane Reactor For Production Of Biodiesel Using Activated Carbon Supported Catalyst, Abdul Aziz Abdul Raman Jan 2011

A Packed Bed Membrane Reactor For Production Of Biodiesel Using Activated Carbon Supported Catalyst, Abdul Aziz Abdul Raman

Abdul Aziz Abdul Raman

In this study, a novel continuous reactor has been developed to produce high quality methyl esters (biodiesel) from palm oil. A microporous TiO 2/Al 2O 3 membrane was packed with potassium hydroxide catalyst supported on palm shell activated carbon. The central composite design (CCD) of response surface methodology (RSM) was employed to investigate the effects of reaction temperature, catalyst amount and cross flow circulation velocity on the production of biodiesel in the packed bed membrane reactor. The highest conversion of palm oil to biodiesel in the reactor was obtained at 70°C employing 157.04g catalyst per unit volume of the reactor …


A Novel Biodiesel And Glycerol Carbonate Production Plant, Nghi T. Nguyen, Yaşar Demirel Jan 2011

A Novel Biodiesel And Glycerol Carbonate Production Plant, Nghi T. Nguyen, Yaşar Demirel

Yaşar Demirel Publications

Crude glycerol is the byproduct of biodiesel production plant and the economic value of glycerol may affect the profitability of the biodiesel production plant. As the production rate of bioglycerol increases, its market values drop considerably. Therefore, conversion of bioglycerol into value-added products can reduce the overall cost, hence, leading to a more economical biodiesel production plant. In a direct carboxylation reaction, CO2 reacts with glycerol to produce glycerol carbonate and water. This study presents a direct comparison of the economic analysis of the conventional biodiesel production plant and the possible next generation biodiesel-glycerol carbonate production plant. At the …


Analysis Of The Performance Of Peanut Fame In A Single Cylinder Idi Engine And Investigations Of Neat Methyl Ester Influence On Fuel Quality, Jeffery Lewis Jan 2011

Analysis Of The Performance Of Peanut Fame In A Single Cylinder Idi Engine And Investigations Of Neat Methyl Ester Influence On Fuel Quality, Jeffery Lewis

Electronic Theses and Dissertations

Author's abstract: To meet evolving standards set forth by the U.S. EPA and U.S. Energy Policy it is necessary to consider a variety of feedstock for biofuels synthesis and to understand the role individual fatty acids contribute to the overall performance. It is the belief of the authors that excess peanut production would provide an excellent source for high quality biodiesel feedstock, and the complete property and combustion analysis of the fatty acid components will provide insight for future biofuel developments. The preliminary investigations of the project focused on the combustion performance and thermal efficiency of peanut FAME and its …


A Novel Biodiesel And Glycerol Carbonate, Yasar Demirel, N. Nguyen Dec 2010

A Novel Biodiesel And Glycerol Carbonate, Yasar Demirel, N. Nguyen

YASAR DEMIREL

Crude glycerol is the byproduct of biodiesel production plant and the economic value of glycerol may affect the profitability of the biodiesel production plant. As the production rate of bioglycerol increases, its market values drop considerably. Therefore, conversion of bioglycerol into value-added products can reduce the overall cost, hence, leading to a more economical biodiesel production plant. In a direct carboxylation reaction, CO2 reacts with glycerol to produce glycerol carbonate and water. This study presents a direct comparison of the economic analysis of the conventional biodiesel production plant and the possible next generation biodiesel-glycerol carbonate production plant. At the end …