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1996

Faculty Publications

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Articles 1 - 30 of 38

Full-Text Articles in Engineering

Detection For A Statistically-Known, Time-Varying Dispersive Channel, David W. Matolak, S. G. Wilson Dec 1996

Detection For A Statistically-Known, Time-Varying Dispersive Channel, David W. Matolak, S. G. Wilson

Faculty Publications

Detection for the statistically known channel (SKC) is aimed at obtaining good performance in situations where our statistical knowledge of a time-varying channel is good, and where other equalization/detection schemes are either too complex to implement, or their performance is limited due to the rapidity of channel fading, or where we are simply unable to perform channel estimation. By using a statistical characterization of the channel, we develop a new detector that performs maximum-likelihood sequence estimation (MLSE) (given the channel model) on blocks of N symbols. Both symbol-spaced and fractionally spaced samples are used, to obtain two different detectors, that …

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Three-Dimensional Display Utilizing A Diffractive Optical Element And An Active Matrix Liquid Crystal Display, Gregory P. Nordin, M. W. Jones, S. T. Kowel, J. H. Kulick, R. G. Lindquist Dec 1996

Three-Dimensional Display Utilizing A Diffractive Optical Element And An Active Matrix Liquid Crystal Display, Gregory P. Nordin, M. W. Jones, S. T. Kowel, J. H. Kulick, R. G. Lindquist

Faculty Publications

We describe the design, construction, and performance of the first real-time autostereoscopic three-dimensional (3-D) display based on the partial pixel 3-D display architecture. The primary optical components of the 3-D display are an active-matrix liquid crystal display and a diffractive optical element (DOE). The display operates at video frame rates and is driven with a conventional VGA signal. Three-dimensional animations with horizontal motion parallax are readily viewable as sets of stereo images. Formation of the virtual viewing slits by diffraction from the partial pixel apertures is experimentally verified. The measured contrast and perceived brightness of the display are excellent, but …

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Remotely Possible? Simple Remote Access To The Network, Margaret Sylvia Nov 1996

Remotely Possible? Simple Remote Access To The Network, Margaret Sylvia

Faculty Publications

Remote access to the library is possible without a magic wand. we have seen increased use of the library in recent years, either because of, or despite, the possibility of remote access. One reason may be that some full-text material is still only available inside the library. Remote access was first implemented in the St. Mary's University Academic Library in 1991, shortly after the installation of the first network in the library. Various options for remote access are compared and contrasted, including the EA/2 solution.

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Characterization Of Sr‐Doped Lamno3 And Lacoo3 As Cathode Materials For A Doped Lagao3 Ceramic Fuel Cell, Kevin Huang, Man Feng, John B. Goodenough, Michael Schmerling Nov 1996

Characterization Of Sr‐Doped Lamno3 And Lacoo3 As Cathode Materials For A Doped Lagao3 Ceramic Fuel Cell, Kevin Huang, Man Feng, John B. Goodenough, Michael Schmerling

Faculty Publications

Energy dispersive spectrometry line scan and ac impedance spectroscopy were used in this study to investigate the chemical reactions between two cathode materials, La0.84Sr0.16MnO3 (LSM), La0.5Sr0.5CoO3-δ (LSC), and the electrolyte La0.9Sr0.1Ga0.8Mg0.2O2.85 (LSGM). Significant interdiffusions of Co into LSGM and Ga into LSC were found at an LSC/LSGM interface even at relatively low fabrication temperatures. In contrast, only small interdiffusions of Mn into LSGM and Ga into LSM were detected at the LSM/LSGM interface even though it was fired at 1470°C. The …

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A Comprehensive Modeling Environment For The Simulation Of Groundwater Flow And Transport, S. J. Owen, Norman L. Jones, J. P. Holland Sep 1996

A Comprehensive Modeling Environment For The Simulation Of Groundwater Flow And Transport, S. J. Owen, Norman L. Jones, J. P. Holland

Faculty Publications

A comprehensive graphical modeling environment has been developed to address the needs of the computer simulation of groundwater flow and transport. The Department of Defense Groundwater Modeling Systems (GMS), developed at the Engineering Computer Graphics Laboratory at Brigham Young University, is part of a multi-year project funded through the Department of Defense, Department of Energy and Environmental Protection Agency. GMS is a graphically based software tool providing facility through all aspects of the groundwater flow and transport modeling process. Facilities include geometric modeling of hydrostratigraphy, two- and three-dimensional mesh generation, graphically based model input for specific flow and transport codes, …

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Bounding Elastic Constants Of An Orthotropic Polycrystal Using Measurements Of The Microstructure, Brent L. Adams, M. J. Beran, T. A. Mason, Ted Olsen Sep 1996

Bounding Elastic Constants Of An Orthotropic Polycrystal Using Measurements Of The Microstructure, Brent L. Adams, M. J. Beran, T. A. Mason, Ted Olsen

Faculty Publications

We show how information about the elastic stiffness and compliance of an orthotropic polycrystal may be obtained from measurements of the statistical properties of the microstructure. We begin by discussing the statistical properties of the governing equations and the hierarchy that results when the equations are averaged. Perturbation solutions are obtained in terms of low-order statistical information. Using methods previously developed, we derive bounds for the elastic stiffnesses and compliances. A heirarchy of bounds is derived using the statistical information obtained from measurements of the microstructure. We discuss the methods used to obtain the correlation functions of the microstructure and …

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A Comparison Of Traffic Models: Part 1, Framework, Hong Lo, Wei-Hua Lin, Lawrence Liao, Elbert Chang, Jacob Tsao Aug 1996

A Comparison Of Traffic Models: Part 1, Framework, Hong Lo, Wei-Hua Lin, Lawrence Liao, Elbert Chang, Jacob Tsao

Faculty Publications

This report defines a framework for comparing dynamic traffic models. It emphasizes four dimensions: functionality, traffic dynamics, route choice dy namics, and overall network performance. The first dimension compares the models through a check-list of model functions. Regarding the last three comparison dimensions, a total of five networks and twelve scenarios are defined. These test scenarios are designed to accentuate model properties and differences. Also included in the report are a list of performance measures for comparison purpose, and a discussion of the interpretation of results.

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Dynamic Traffic Assignment For Automated Highway Systems: A Two-Lane Highway With Speed Constancy, H.-S. Jacob Tsao Aug 1996

Dynamic Traffic Assignment For Automated Highway Systems: A Two-Lane Highway With Speed Constancy, H.-S. Jacob Tsao

Faculty Publications

Dynamic traffic assignment through analytical modeling and optimization has been widely accepted by the IVHS R&D community as a promising traffic control tool for understanding and relieving traffic congestion on conventional highways and city streets. Due to the completely controlled nature of AHS traffic, dynamic assignment of AHS traffic is even more promising. One added dimension of complexity associated with AHS dynamic traffic assignment is lane assignment. Lane changes, for fully utilizing AHS capacity or for exiting, incur disturbances to and hence reduction of longitudinal flow. Intelligent lane assignment is necessary to ensure a high rate of successful exiting, to …

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Characterization Of The Si/Sio2 Interface Formed By Remote Plasma Enhanced Chemical Vapor Deposition From Sih4/N2O With Or Without Chlorine Addition, Young-Bae Park, Xiaodong Li, Shi-Woo Rhee Jul 1996

Characterization Of The Si/Sio2 Interface Formed By Remote Plasma Enhanced Chemical Vapor Deposition From Sih4/N2O With Or Without Chlorine Addition, Young-Bae Park, Xiaodong Li, Shi-Woo Rhee

Faculty Publications

The Si/SiO2interface formed by remote plasma enhanced chemical vapor deposition (RPECVD) at low temperature with SiH4/N2O or SiH4/N2O/Cl2 was studied and compared with thermal oxidation. The interface of the CVD SiO2 without chlorine addition is rougher than that with chlorine addition. But the surface roughness of CVD SiO2 films increases with chlorine addition. The thermal oxidation induces strong interface strains, and the strains generated by the CVD SiO2 without chlorine addition are stronger and are distributed more nonuniformly than those by the chlorinated SiO2. …

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Microstructure And Deposition Rate Of Aluminum Thin Films From Chemical Vapor Deposition With Dimethylethylamine Alane, Byoung-Youp Kim, Xiaodong Li, Shi-Woo Rhee Jun 1996

Microstructure And Deposition Rate Of Aluminum Thin Films From Chemical Vapor Deposition With Dimethylethylamine Alane, Byoung-Youp Kim, Xiaodong Li, Shi-Woo Rhee

Faculty Publications

Deposition of aluminumfilm from DMEAA in the temperature range of 100–300 °C has been studied. In this temperature range, there is a maximum deposition rate at around 150 °C. The film deposited at 190 °C has elongated blocklike grain shapes, which are ∼600 nm in width and 930 nm in length. Grains in the film deposited at 150 °C showed an equiaxed structure with grain size in the range of 100–300 nm in a film with 600 nm thickness. Aluminum oxide particle inclusion was observed especially at high deposition temperature. Plausible reaction pathways of DMEAA dissociation were suggested to explain …

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Low-Frequency Noise In 4h-Silicon Carbide Junction Field Effect Transistors, J. W. Palmour, M. E. Levinshtein, S. L. Rumyantsev, Grigory Simin May 1996

Low-Frequency Noise In 4h-Silicon Carbide Junction Field Effect Transistors, J. W. Palmour, M. E. Levinshtein, S. L. Rumyantsev, Grigory Simin

Faculty Publications

Low frequency noise in 4H‐silicon carbide junction field effect transistors (JFETs) has been investigated. JFETs with a buried p + n junction gate were manufactured by CREE Research Inc. Very low noise level has been observed in the JFETs. At 300 K the value of Hooge constant α is as small as α∼10−5 and the α value can be decreased by an appropriate annealing to α∼2×10−6. It has been shown that even these extremely low noise values are determined not by the volume noise sources but by the noise at the SiC–SiO2 interface.

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Dependence Of The Normalized Radar Cross Section Of Water Waves On Bragg Wavelength-Wind Speed Sensitivity, David G. Long, R. Scott Collyer, David V. Arnold May 1996

Dependence Of The Normalized Radar Cross Section Of Water Waves On Bragg Wavelength-Wind Speed Sensitivity, David G. Long, R. Scott Collyer, David V. Arnold

Faculty Publications

Measurements of the normalized radar cross section (O) made by the YSCAT ultrawideband scatterometer during an extended deployment on the Canada Centre for Inland Waters (CCIW) Research Tower located at Lake Ontario are analyzed and compared with anemometer wind measurements to study the sensitivity of O to the wind speed as a function of the Bragg wavelength. This paper concentrates on upwind and downwind azimuth angles in the wind speed range of 4.5-12 m/s. While YSCAT collected measurements of O at a variety of frequencies and incidence angles, this paper focuses on frequencies of 2.0, 3.05, 5.30, 10.02, and 14.0 …

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Grain-Boundary Structure Effects On Intergranular Stress Corrosion Cracking Of Alloy X-750, Brent L. Adams, Ted Olsen, N. Panayotou, Y. Pan Apr 1996

Grain-Boundary Structure Effects On Intergranular Stress Corrosion Cracking Of Alloy X-750, Brent L. Adams, Ted Olsen, N. Panayotou, Y. Pan

Faculty Publications

This work was supported by the Department of Energy under Grant No. DE-FG02-88ER 45355. TO was supported by the National Science Foundation during her 1993-94 stay at the Institute for Advanced Studies (Princeton) under grant DMS-9304580. The authors wish to acknowledge helpful discussion with Carol Nichols, John Hack, Gino Palumbo, Karl Aust, and Gary Was. It is well known that the properties and behavior of grain boundaries are strongly affected by local chemistry and atomic structure. This paper focuses on the mesoscale description of grain boundary structure (i.e. the five crystallographic degrees of freedom) and correlations with intergranular stress corrosion …

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Calibration Of Spaceborne Scatterometers Using Tropical Rain Forests, David G. Long, Gary B. Skouson Mar 1996

Calibration Of Spaceborne Scatterometers Using Tropical Rain Forests, David G. Long, Gary B. Skouson

Faculty Publications

Wind scatterometers are radar systems designed specifically to measure the normalized radar backscatter coefficient (O) of the ocean's surface in order to determine the near-surface wind vector. Postlaunch calibration of a wind scatterometer can be performed with an extended-area natural target such as the Amazon tropical rain forest. Rain forests exhibit a remarkably high degree of homogeneity in their radar response over a very large area though some spatial and temporal variability exist. The authors present a simple technique for calibrating scatterometer data using tropical rain forests, Using a polynomial model for the rolloff of O with incidence angle, the …

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Constraints On Initial Ahs Deployment And The Concept Definition Of A Shuttle Service For Ahs Debut, H.-S. Jacob Tsao Feb 1996

Constraints On Initial Ahs Deployment And The Concept Definition Of A Shuttle Service For Ahs Debut, H.-S. Jacob Tsao

Faculty Publications

The concept of automated highway system (AHS) was motivated primarily by its potential for large capacity and safety gains without requiring significant right-of-way acquisition. However, highway automation involves a multitude of design options as well as systems issues. Compounded by the crucial dimension of evolving the current highway system towards the mature AH& there exist a large number of possible evolutionary paths to AHS. Perhaps due to the immense complexity, little attention has been paid to the evolution dimension.Particularly important and difficult in defining a deployment sequence is the very first step,i.e. the first user service involving fully automated (hands-off …

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Stage Definition For Ahs Deployment And An Ahs Evolutionary Scenario, H.-S. Jacob Tsao Feb 1996

Stage Definition For Ahs Deployment And An Ahs Evolutionary Scenario, H.-S. Jacob Tsao

Faculty Publications

The concept of automated highway systems (AHS) as a means to solve the fast-worsening highway congestion problem has received renewed attention recently. Pros and cons of various mature AHS have been a subject of intense study. However, such discussions are nothing but intellectual exercises unless the issue of how to evolve the current highway systems towards these mature AHS can be resolved. There exist a large number of different possible mature AHS. The additional dimension of evolution leads to an even larger number of possible evolutionary scenarios. This paper proposes an approach to defining evolutionary scenarios and illustrates it with …

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Variable-Complexity Trellis Decoding Of Binary Convolutional Codes, David W. Matolak, S. G. Wilson Feb 1996

Variable-Complexity Trellis Decoding Of Binary Convolutional Codes, David W. Matolak, S. G. Wilson

Faculty Publications

Considers trellis decoding of convolutional codes with selectable effort, as measured by decoder complexity. Decoding is described for single parent codes with a variety of complexities, with performance "near" that of the optimal fixed receiver complexity coding system. Effective free distance is examined. Criteria are proposed for ranking parent codes, and some codes found to be best according to the criteria are tabulated, Several codes with effective free distance better than the best code of comparable complexity were found. Asymptotic (high SNR) performance analysis and error propagation are discussed. Simulation results are also provided.

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Linear Programming With Inequality Constraints Via Entropic Perturbation, Jacob Tsao, Shu-Cherng Fang Jan 1996

Linear Programming With Inequality Constraints Via Entropic Perturbation, Jacob Tsao, Shu-Cherng Fang

Faculty Publications

A dual convex programming approach to solving linear programs with inequality constraints through entropic perturbation is derived. The amount of perturbation required depends on the desired accuracy of the optimum. The dual program contains only non-positivity constraints. An ϵ-optimal solution to the linear program can be obtained effortlessly from the optimal solution of the dual program. Since cross-entropy minimization subject to linear inequality constraints is a special case of the perturbed linear program, the duality result becomes readily applicable. Many standard constrained optimization techniques can be specialized to solve the dual program. Such specializations, made possible by the simplicity of …

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Coded Modulation For Satellite Broadcasting, Robert H. Morelos-Zaragoza, Oscar Y. Takeshita, Hideki Imai, Marc P. C. Fossorier, Shu Lin Jan 1996

Coded Modulation For Satellite Broadcasting, Robert H. Morelos-Zaragoza, Oscar Y. Takeshita, Hideki Imai, Marc P. C. Fossorier, Shu Lin

Faculty Publications

In this paper, three-level block coded 8-PSK modulations, suitable for satellite broadcasting of digital TV signals, are presented. A design principle to achieve unequal error protection is introduced. The coding scheme is designed in such a way that the information bits carrying the basic definition TV signal have a lower error rate than the high definition information bits. The large error coefficients, formally associated with standard mapping by set partitioning, are reduced by considering a nonstandard partition of an 8-PSK signal set. The bits-to-signal mapping induced by this partition allows the use of suboptimal low-complexity soft-decision decoding of binary block …

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Use Of A Hydrogen Anode For Nitrate Waste Destruction, E. E. Kalu, Ralph E. White, D. T. Hobbs Jan 1996

Use Of A Hydrogen Anode For Nitrate Waste Destruction, E. E. Kalu, Ralph E. White, D. T. Hobbs

Faculty Publications

No abstract provided.

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Galvanostatic Pulse And Pulse Reverse Plating Of Zinc–Nickel Alloys From Sulfate Electrolytes On A Rotating Disc Electrode, Branko Popov, M. Ramasubramanian, S. N. Popova, Ralph E. White, Ken-Ming Yin Jan 1996

Galvanostatic Pulse And Pulse Reverse Plating Of Zinc–Nickel Alloys From Sulfate Electrolytes On A Rotating Disc Electrode, Branko Popov, M. Ramasubramanian, S. N. Popova, Ralph E. White, Ken-Ming Yin

Faculty Publications

Galvanostatic pulse and pulse reverse techniques have been used to study the plating of zinc–nickel alloys in the presence of nonyl phenyl polyethylene oxide. The effects of average current density, rotation speed of disc electrode and the presence of nonyl phenyl polyethylene oxide in the electrolyte on deposition of zinc–nickel alloys were evaluated. Zinc–nickel plating bath solution chemistry was studied by determining the equilibrium concentrations at various pH levels. It was found that the alloy composition was determined by solution equilibria, mass transfer of the electroactive species within the diffusion layer and by the surface coverage of nonyl phenyl polyethylene …

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Galvanostatic Pulse And Pulse Reverse Plating Of Zinc-Nickel Alloys From Sulfate Electrolytes On A Rotating Disc Electrode, Branko N Popov, M. Ramasubramanian, S. N. Popova, Ralph E. White, K-M. Yin Jan 1996

Galvanostatic Pulse And Pulse Reverse Plating Of Zinc-Nickel Alloys From Sulfate Electrolytes On A Rotating Disc Electrode, Branko N Popov, M. Ramasubramanian, S. N. Popova, Ralph E. White, K-M. Yin

Faculty Publications

Galvanostatic pulse and pulse reverse techniques have been used to study the plating of zinc–nickel alloys in the presence of nonyl phenyl polyethylene oxide. The effects of average current density, rotation speed of disc electrode and the presence of nonyl phenyl polyethylene oxide in the electrolyte on deposition of zinc–nickel alloys were evaluated. Zinc–nickel plating bath solution chemistry was studied by determining the equilibrium concentrations at various pH levels. It was found that the alloy composition was determined by solution equilibria, mass transfer of the electroactive species within the diffusion layer and by the surface coverage of nonyl phenyl polyethylene …

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Analysis Of Transient Hydrogen Uptake By Metal Alloy Particles, Wenlin Zhang, Supramaniam Srinivasan, Harry J. Ploehn Jan 1996

Analysis Of Transient Hydrogen Uptake By Metal Alloy Particles, Wenlin Zhang, Supramaniam Srinivasan, Harry J. Ploehn

Faculty Publications

This paper describes a new approach to solving the equations comprising the shrinking core model for diffusion and reaction of a chemical species in a solid spherical particle. The reactant adsorbs on the particle surface, diffuses into the particle's interior, and reacts with the particle to form a solid product. The shrinking core model assumes a fast reaction rate compared to reactant diffusion so that the reaction is localized in the interfacial zone between the unreacted solid core and the surrounding shell of reacted product. Analytical solutions of the governing conservation equations usually invoke the pseudo-steady state (PSS) approximation which …

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Linear Algebra Used To Determine Independent Half‐Cell Equations, D. H. Coleman, Ralph E. White Jan 1996

Linear Algebra Used To Determine Independent Half‐Cell Equations, D. H. Coleman, Ralph E. White

Faculty Publications

No abstract provided.

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A Multiphase Mathematical Model Of A Nickel/Hydrogen Cell, Pauline De Vidts Jan 1996

A Multiphase Mathematical Model Of A Nickel/Hydrogen Cell, Pauline De Vidts

Faculty Publications

No abstract provided.

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A Model For The Galvanostatic Deposition Of Nickel Hydroxide, Mahesh Murthy, Gowri S. Nagarajan, John W. Weidner, John W. Van Zee Jan 1996

A Model For The Galvanostatic Deposition Of Nickel Hydroxide, Mahesh Murthy, Gowri S. Nagarajan, John W. Weidner, John W. Van Zee

Faculty Publications

A mathematical model is presented for the galvanostatic deposition of Ni(OH)2 films in stagnant Ni(NO3)2 solutions. The objective is to quantify the anomalous deposition behavior reported previously in which the utilization of the electrochemically generated OH– species decreased drastically as the concentration of Ni(NO3)2 increased beyond 0.1 M. For example as the Ni(NO3)2 concentration increased from 0.1 to 2.0 M, the deposition rate decreased by a factor of ten at 2.5 mA/cm2. At this high ratio of concentration to current density, a comparison with Faraday's …

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Anodic Oxidation Of Ethylenediaminetetraacetic Acid On Platinum Electrode In Alkaline Medium, S. N. R. Pakalapati, Branko N. Popov, Ralph E. White Jan 1996

Anodic Oxidation Of Ethylenediaminetetraacetic Acid On Platinum Electrode In Alkaline Medium, S. N. R. Pakalapati, Branko N. Popov, Ralph E. White

Faculty Publications

The anodic oxidation of ethylenediaminetetraacetic acid (EDTA) was studied in alkaline medium on a smooth platinum electrode. Bulk electrolysis indicated that stable organic intermediates (formaldehyde and glyoxal) are formed during the oxidation of EDTA and that complete oxidation to CO2 can be achieved. The proposed pathway suggests that the acetate groups in EDTA are initially oxidized, generating formaldehyde and ethylenediamine. The rest potential of EDTA (0.066 to 0.164 V vs. Hg/HgO) was observed to be higher than for other organic species. In alkaline medium, very little EDTA oxidation was found to occur on bare platinum. Limiting-current behavior due to …

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The Effects Of Multiple Electroplated Zinc Layers On The Inhibition Of Hydrogen Permeation Through An Iron Membrane, D. H. Coleman, G. Zheng, Branko N. Popov, Ralph E. White Jan 1996

The Effects Of Multiple Electroplated Zinc Layers On The Inhibition Of Hydrogen Permeation Through An Iron Membrane, D. H. Coleman, G. Zheng, Branko N. Popov, Ralph E. White

Faculty Publications

The Devanathan-Stachurski permeation technique was used to investigate the rate of hydrogen permeation through an iron membrane with consecutively electroplated zinc layers. Hydrogen evolution rates and hydrogen permeation rates were followed as functions of time at different applied potentials. Hydrogen evolution and permeation decreased with each successive zinc layer until finally reaching an average decrease of 93 and 96%, respectively, as compared with bare iron. Hydrogen surface coverage, exchange current density, absorption-adsorption reaction constant, and hydrogen recombination constant were estimated on bare iron and on zinc-plated iron. It was found that the decrease in the permeation rate of hydrogen through …

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Anomalous Codeposition Of Fe-Ni Alloys And Fe-Ni-Sio2 Composites Under Potentiostatic Conditions, M. Ramasubramanian, S. N. Popova, Branko N. Popov, Ralph E. White, K. M. Yin Jan 1996

Anomalous Codeposition Of Fe-Ni Alloys And Fe-Ni-Sio2 Composites Under Potentiostatic Conditions, M. Ramasubramanian, S. N. Popova, Branko N. Popov, Ralph E. White, K. M. Yin

Faculty Publications

A mathematical model has been developed to describe the electrodeposition of Fe-Ni alloys and Fe-Ni-SiO2 composites under potentiostatic conditions. This model can be used to predict the polarization behavior, partial current densities, and alloy composition of each of the components as a function of the applied potential. Fe-Ni-SiO2 samples were deposited on platinum rotating disk electrodes from sulfate electrolytes under potentiostatic conditions, and the results obtained were compared to the model. The model predictions were found to agree well with the experimental observations for the Fe-Ni and Fe-Ni-SiO2 systems.

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Determination Of Transport And Electrochemical Kinetic Parameters Of Bare And Copper-Coated Lani4.27Sn0.24 Electrodes In Alkaline Solution, G. Zheng, Branko N. Popov, Ralph E. White Jan 1996

Determination Of Transport And Electrochemical Kinetic Parameters Of Bare And Copper-Coated Lani4.27Sn0.24 Electrodes In Alkaline Solution, G. Zheng, Branko N. Popov, Ralph E. White

Faculty Publications

Electrochemical properties of bare and copper-coated LaNi4.27Sn0.24 electrodes were investigated in alkaline solution. The exchange current density, polarization resistance, and equilibrium potential were determined as functions of the state of charge in the electrodes. The symmetry factors for bare and copper-coated electrodes were estimated to be 0.53 and 0.52, respectively. By using a constant current discharge technique, the hydrogen diffusion coefficient in bare and coated LaNi4.27Sn0.24 was estimated to be 6.75 × 10–11 cm2/s.

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