Engineering Commons^™

A Dynamic Model Of Fill-And-Draw Reactor Utilizing An Inhibitory Substrate, Yun-Fei Ko

Theses

A dynamic model of a fill-and-draw reactor has been developed, which includes a number of operational parameters, the fraction of total cycle time devoted to fill, reaction and draw, and the concentration of the toxic substance in the feed to the reactor.

Operating diagrams have been generated, from which one can choose suitable operating parameters.

The model has been solved numerically for Andrews kinetics ( substrate inhibition ), and tested experimentally, using a 5-liter fill-and-draw reactor with phenol as sole carbon source and a pure culture of Pseudomonas putida. Results compared very well to the model predictions.

Formation Of Light Hydrocarbons And Soot In The Pyrolysis Reactions Of Chloro, Dichlorobenzene, Acetylene And Benzene In An Atmosphere Of Hydrogen, Larry Jiyuan Zhu

Theses

The kinetics of thermal decomposition of chlorobenzene and dichlorobenzene in a hydrogen and helium atmosphere were further studied to investigate formation of soot and light hydrocarbons. The experiments were performed at atmosphere pressure with residence times rangeing from 0.2 to 1.2 seconds, and the temperature ranges of 850°C to 925°C for chlorobenzene and 870°C to 910°C for dichlorobenzene. Flame ionization detectors, which were connected to GC columns, were utilized for the qualitative and quantitative analysis of the reaction products. A methyl silicone capillary column was used analyzing of heavy aromatics and a Carbosive G was used to analyze light hydrocarbons. …

A Study On The Poly(Ethylene Terephthalate)/Flouropolymer Blends, Chyan-Nin Chiu

Theses

The rate of crystallization of Polyethylene terephthalate) (PET) can be improved by blending it with polyethylene co chlorotrifluoroethylene) (ECTFE; tradename Halar) so that it can be suitable for injection molding. The special advantage of this method is that molecular weight of the blend will not decrease so much as by adding nucleating agents. That is to say, the mechanical strength of the blend will not decrease very much compared with that of virgin PET.

High-Energy, Curable Polycyclopentadiene Binder For Solid Rocket Propellants, Jian Guo Ning

Theses

Diels Alder polymerization of cyclopentadiene ( CPD ) has been carried out at 170°C under inert atmosphere. The resulted polymer has a low bulk viscosity, 7.4 cps, and a number average molecular weight M_n up to 3000. This liquid Prepolymer is curable with maleic anhydride. With ammonium perchlorate, aluminum, and maleic anhydride, a high energy solid propellant has been formulated with this polymer. Via bomb calorimeter, Instron, and density measurement, it was found that this propellant has a better heat of combustion, tensile strength, and solid loading than that of the commercial rocket propellant based on hydroxyl terminated polybutadiene.

Determination Of Aromatic Amines By Diazonium Salt, Hong-Hue Hsu

Theses

There are many analytical methods used in the identification of aniline by the production of various colors upon treatment with certain reagents. In this work a new inexpensive, easy and sensitive methods to quantitate aniline is developed. The change of absorbance is large enough to measure with a difference of only 1 ppm in the aniline concentration.

In this method, the reagent (2,4-dinitrodiazonium sulphate) which reacts with aniline produces a yellow color. Formation of this color (which absorbs at 486 nm) indicates the presence of aniline. The amount of aniline can be determined by measuring the absorbance at 486 nm. …

A Silicon Photodiode Array For Soft X-Ray Sensing, Chih-Te Hu

Theses

An array of 30 x 30 sensing cells including logic within each cell and a self-scan address circuit are described. A unique scintillation technique is used to increase the threshold sensitivity 60dB for X-ray photon sensing beyond that obtainable with conventional photodiode sensors. Simulations for the sensing cell and some additional logic elements are based on SPICE version 2G5 and HILO 3. Worst case analysis includes variations in threshold voltage V_TP and V_TN for the CMOS circuit components. The final CMOS chip dimension using MOSIS 1.2 micron rules is 10mm x 10mm base on the 80 …

Study Of The Structure And Capacity Of Construction Industry In Pakistan, Tayyab A. Ansari

Theses

The construction industry is the second largest sector in Pakistan's economy after agriculture. It is a fragmented industry which includes very small and very large contracting groups. It includes professional groups such as architects, engineers, management personnel etc. Major part of this industry is dominated by material's suppliers, vendors etc.

In the light of the developments which have taken place particularly over the last ten years, the study has covered the capacity of the construction industry in terms of estimated output, availability of manpower, demand and production of building materials , financial problems, credit, quality of work, the role of …

On Conventional And Harmonic Load Flow Analysis, Ranjit B. Pradhan

Theses

In conventional power flow analysis, simultaneous linear equations numbering in thousands must be solved repeatedly and in many instances on-line. Luckily the matrix of coefficients of these equations is sparse with a few elements in each row. Therefore for a faster solution and to save computer memory, sparsity must be exploited and an optimal ordering of the equations must be sought. When considering harmonics, the number of the simultaneous equations to be solved is multiplied and therefore, considering sparsity and optimal ordering is doubly important.

In this thesis a software package for optimizing computation time and memory requirements through exploitation …

System Performance Criteria In Cdma Networks Using Gold Codes, Yong H. Kim

Theses

First, we have presented the autocorrelation and crosscorrelation properties for periodic and aperiodic binary sequences. The generation of binary sequences using shift registers with feedback was reviewed. We have also included correlation properties for the Gold codes.

Next, we discussed Gold code generation for the balanced and unbalanced Gold codes.

Thirdly, we investigated the number of simultaneous users in a CDMA system using Gold codes for the worst case and the average case of mutual interference.

Finally, we simulated the probability of interference exceeding a threshold value, and the average crosscorrelation value caused by interference in a CDMA network which …

Modeling And Simulation Of Robot Arms With Flexible Links, John G. Danis

Theses

The design of lightweight robot arms introduces a degree of flexiblity in the individual links which renders the arm difficult to control. Solution of the control problem requires accurate and detailed mathematical models of the arm dynamics. A comprehensive survey of the current literature in this area has shown that although many such models exist, there is a great diversity in their structure, function, and applicability. The different objectives and techniques of model development which lead to this diversity are examined and summarized in this thesis. Bases for classification of the mathematical models and techniques of development are established, and …

An Analysis Of The Dense Packing Of Disks : A Computer Simulated Approach, Jir-Yih Tsaur

Theses

This thesis is concerned with the analysis of dense packing of hard disks. The Voronoi diagram and the geometric neighbours were first computed. The average number of geometric neighbours of a disk is six. It is thus more efficient to choose structural neighbours from among the geometric neighbours than from among all other disks.

Through the Monte Carlo simulation by Rosato et. al., disk configurations after pouring and subsequent shaking were provided for analysis. The mean number of geometric neighbours and the average coordination number were computed. The angular distribution of the structural neighbours was discussed. The packing fraction increases …

An Investigation Of Electrical And Optical Properties Of Reactively Sputtered Silicon Nitride And Amorphous Hydrogenated Silicon Thin Films, Tae Hoon Kim

Theses

Thin films of silicon nitride and amorphous hydrogenated silicon were prepared by radio frequency reactive sputter deposition and their properties optimized for their use as low temperature passivation coatings for optoelectronic devices. The effect of various sputter deposition parameters on the conduction and optical properties were studied. Infrared spectrophotometry and ellipsometry were used to determined the optical properties of the films whereas the electrical properties were determined from current-voltage measurements of MIS capacitors.

Typical parameters of a sputter deposition run for the best Si₃N₄ films were: base pressure, 1-2x10^-6 torr; sputtering pressure, 5 mtorr; nitrogen partial …

Agitation Requirements For Complete Dispersion Of Emulsions, Dun-Huang Tsai

Theses

An investigation on the minimum agitation speed required to achieve complete dispersion in liquid-liquid systems has been carried out. A model based on the momentum balance for a droplet and on Kolmogoroff's theory of isotropic turbulence was used for the prediction of the role of the most important variables on the minimum agitation speed. The equation so derived can be expressed in terms of a number of non- dimensional groups (such as Re, Ar, and Su). For geometrically similar systems the equation contains only one adjustable parameter ( to be determined experimentally) in the form of the proportionality constant correlating …

Bead Design For Biodegradation Of 2-Chlorophenol Using Microorganisms Entrapped In Alginate Gel, Fayaz Lakhwala

Theses

The performance of immobilized cell reactors varies with a number of parameters, one of which is proper bead design. A mixed microbial population from a waste water treatment plant was immobilized in calcium alginate gel. The viability of these organisms was studied in a microassay reactor by varying parameters such as concentration of calcium chloride, concentration of sodium alginate, temperature of operation, biomass concentration within the beads and concentration of a model compound (2-chlorophenol). The effect of storage on viability over a period of three months was also investigated. It was found possible to have access to active biomass by …

Biosynthesis Of Amine Oxides Using Calcium-Alginate Immobilized Hog Liver Microsomes : An Evaluation Of Process And Reactor Design, Ioannis I. Valvis

Theses

An evaluation of the biocatalytic ability and the potential utilization of Calcium-alginate immobilized hepatic microsomes (beads) for the biosynthesis of amine oxides has been performed, To accomplish this task, the following three areas Were investigated: immobilization, catalytic biooxidation ability, and reactor configurations.

Immobilization was found to result in higher yields over free microsomes at the expense of higher cofactor requirements. Refrigerated drying of immobilized micro-somes appears to be a better storage technique than wet storage in buffer. Smaller beads resulted in higher rates than larger beads, but size did not affect the overall yield.

Chlorpromazine (CPZ), diphenylamine (DPA) and 4-hydroxy-2,2,6,6-tetramethylpiperidine …

Sorptive And Geotechnical Characteristics Of Kaolinite, Chi-Yuan Shih

Theses

The sorption/desorption behavior of phenol and chlorobenzene as well as their influence on geotechnical characteristics of kaolinite were studied. The results reveal that the sorption process follows closely with the Freundlich adsorption isotherm whereas the sorption/desorption ratio depends upon the characteristics of organic compounds.

A series of geotechnical properties tests was also undertaken after achieving equilibrium at different concentrations of organic compounds. It was found that the parameters such as liquid limit, plastic limit, optimum moisture content, and dry density increase with an increasing-concentration of organic compounds.

The relationship between the geotechnical, properties and sorption behavior of soils provides the …

Use Of Recirculation Reactor To Study Biodegradation Of 2-Chlorophenol, Kai-Chung Yang

Theses

The performance of immobilized cells in the treatment of hazardous waste was investigated using a recirculation flow reactor run in a batch mode. A mixed microbial population from a municipal wastewater treatment plant was immobilized in calcium alginate gel. The bio-oxidation ability of these microbes towards a model toxin (2-chlorophenol) was studied. The process parameters studied were as follows:

1. Flow rate of the recycle stream;
2. Biomass loading;
3. Spiking concentration of 2-chlorophenol;
4. Use of buffered vs. non-buffered defined medium.

Dissolved oxygen concentration was monitored using a flow Clark-type dissolved oxygen probe. Oxygen consumption was correlated with the biodegradation of 2-chlorophenol. Physical …

Investigation Of Different Cmos Dram Sense Amplifier Configurations In Vlsi, Bihju Chiu

Theses

Sense amplifiers are particularly difficult circuits to design. In this work, only CMOS sense amplifiers are considered. There are typically two configurations of CMOS sense amplifiers: the cross-connected flip flop configuration and the current-mirror configuration. They are widely used nowadays with various modifications. These improved configurations are simulated and optimized with SPICE package, and their relative performances are also compared in this thesis.

An Improved Method Of Gas Chromatographic Determination Of Trace Organic Vapors In Ambient Air Collected In Canisters, Yong-Jin Shen

Theses

An improved method for analysis and quantitation of volatile organic compounds in ambient air has been developed. Samples are collected in evacuated SUMMA polished stainless steel canisters using a sampling flow apparatus with a critical orifice as flowrate controller. Analysis of VOCs in the collected air is carried out by cryogenically concentrating the sample, then thermally transfering it onto the head of a capillary column in a gas chromatograph. The column effluent is measured by a parallel flame ionization detector (FID), and electron capture detector (ECD). The problems associating with quantitative transfer of the sample to the initial cryofocusing loop …

Design Of A Fiber Optic Oxygen Sensor Based On Immobilized Hemoglobin, Mendu Govind Raj

Theses

The fiber optic Oxygen sensor consists of a thin layer of immobilized deoxyhemoglobin at the common end of a bifurcated fiber. Immobilization is done using the alginate gel procedure. The immobilized reagent is separated from the standard oxygen sample by the gel with or without semi-permeable membrane, and the entire configuration is enclosed in an oxygen free sample cell. Light from a tungsten-halogen lamp, filtered through a 405nm filter is passed through one arm of a bifurcated fiber to the sample cell. The reflected intensity (a highly polished aluminum foil or a plate is placed at the bottom of the …

Investigation Of Forces In The Course Of The Water Jet--Work Piece Interaction, Hung-Yuan Li

Theses

This study is concerned with the dynamic of the interaction between the water jet and the work-piece. The piezoelectric transducer was used to construct an experimental setup. The simultaneous use of the constructed setup and strain gage enables us to validate the experimental procedure. The forces in the impingment zone were measured at different operational conditions. Totally about 400 different combinations of these conditions were tested. It was found that the force is mainly determined by the diameter of the sapphire. The effects of the abrasive size , abrasive flow rate, the diameter of the carbide tube, and the stand-off …

A Dynamic Model Of A Fill-And-Draw Reactor And Its Implications For Hazardous Waste Treatment, Shing-Hwa Chang

Theses

A dynamic model of a fill-and-draw reactor has been developed, which includes a number of operational parameters such as the draw-down volume, the fraction of total cycle time devoted to fill, reaction, and draw, and the concentration of the toxic substance in the feed to the reactor. The model has been solved numerically for two cases, one assuming Monod kinetics, and one considering substrate inhibition (Andrews kinetics).

The conversions achieved with this type of reactor have been compared to that of a conventional activated sludge (CSTR) design. These results indicate that for most practical settings of the operating parameters, the …

Synergistic Fillers In Polymer Concrete : New Composites, Syed Hassan Javed

Theses

The objective of this study was to examine the effects of synergistic fillers on underwater construction, burning and mechanical properties of polymer portland cement concrete(PPCC).

Fine grains of hydrous calcium sulfate, Trihydrated alumina, Calcium carbonate and fibrous unhydrous calcium sulfate were examined in PPCC. It has been observed that these synergistic filler improves the mechanical property (stress) and reduce the average time of burning of PPCC. With fixed quantity of polymer, the deterioration of PPCC in water increases by replacing the sand with above stated fillers.

Wastewater Treatment : Phenol Extraction By Liquid Membrane, Jan-Ming Hou

Theses

Two models for the extraction of phenol by means of liquid surfactant membranes is presented in which external mass transfer around w/o emulsion drop, phase and chemical equilibria are taken into account.

The nonlinear coupled P.D.E.'s is solved under assumptions to get a close-formed analytical approximate solution. The experimental results on the batch extraction of phenol are found to be satisfactory simulated by one of the proposed models provided that phenol concentration is higher than 0.01N. The model requires no adjustable parameter thus it can predict the extraction behavior without doing experiments.

Determination Of Polycyclic Aromatic Hydrocarbons From Incineration Emission Samples, Robert Cebula

Theses

Stack emissions from five sources (one pulverized coal combustion operation, three sewage sludge incineration operations and one gray tin refractory operation) were sampled by use of U.S. EPA Modified Method 5 isokinetic sampling unit for vapor and particulate effluent. The sampling unit provided XAD-2 resin samples, polytetrafluoroethylene and glass fiber filters and impinger washings of dichloromethane. The resins were soxhlet extracted using dichloromethane (DCM) and the filters were soxhlet extracted using DCM followed by acetone. Fractionation of extracts was accomplished by thin layer chromatography. The resulting fractions were analyzed for polycyclic aromatic hydrocarbons (PAH), nitro-PAH and quinone-PAH by high-performance liquid …

Recycled Plastics As Fillers In Polymer Cement Concrete Composites, Shian-Jong Liu

Theses

How to handle the plastic waste is a big task for the modern society in environmental protection. People already focus on it, especially in PET soft drink bottles. Although PET bottle can be reclaimed, its usages are restricted due to the limitation in color and difficulty in purification.

On the other side, concrete is the most common material for human beings to used [sic] in construction. Concrete has good compressive strength, but poor [sic] in flexural and tensile strengths, which limits its applications. So, scientists try to improve its properties by adding the polymer into the conventional concrete, to enhance …

Softening Response Of Concrete In Direct Tension, Teresa Cintora

Theses

Due to the increased attention in nonlinear fracture mechanics and numerical methods of cementitious material, it has become necessary to have a reliable investigation of the post-peak softening response of concrete under direct uniaxial loading. But due to the brittleness of the material previous researchers have encountered great difficulty in obtaining complete data regarding the load-deformation behavior. This study uses a strain-controlled testing method and therefore the post-peak curve can be more easily obtained. Based on these results a unique formula for the normalized load vs. deformation curve has been proposed to be applied in fracture analysis applications.

A Model For The Determination Of Market Based Pricing Of Telecommunication Products, Katherine J. Sullivan

Theses

The deregulation of AT&T, has impacted telecommunication product pricing in the U.S. market. Previously, pricing had been based on cost plus mark-up, as stipulated by regulatory commissions. Now, pricing decisions require consideration of the competitive impact, consumer demand for the product, corporate pricing objectives and marketing strategies. This paper proposes a pricing process that is relevant for this new environment which enables the product manager to price properly.

The method proposed utilizes microeconomic theory and takes into account the product test price, unit cost, opportunity cost, nonprice factor cost and consumer demand. Incorporating a number of different pricing strategies, it …

Synthesis And Characterization Of A Novel Blocked Isocyanate Dental Adhesive Based On Diphenylmethane - 4, 4' - Diisocyanate, Yangming Lin

Theses

The dental adhesive monomers based on diphenylmethane - 4,4 - diisocyanate (MDI) were prepared and studied in this research. The diisocyanate, MDI, was first reacted with hydroxyethyl methacrylate (HEMA) to form an intermediate adduct. This adduct had an active isocyanate end group. It was then bonded with o-chlorophenol (OCP), a blocking agent, to produce a blocked isocyanate monomer.

The new blocked isocyanate (HEMA-MDI-OCP) was found to have an average value of more than 1200 psi in tensile tests measuring its adhesion to dentin slices.

Thermal Desorption Of Hazardous And Toxic Organic Compounds From Soil Matrices : Dichloromethane, Chloroform, Benzene, Toluene, 1-Chloronaphthalene, 1, 2, 4-Trichlorobenzene, Arun S. Chemburkar

Theses

This research project was undertaken to understand the process of desorption/removal of organic compounds from soil matrices under the influence of temperature and gas purging. The project was divided in two parts :

A. Plug deposition experiments: Columns packed with soil matrices were purged with an inert gas under isothermal conditions. Organic compounds were then introduced as a plug on the front of the column by on-line injection. The rate of passage (due to sequential adsorption/desorption) of the plug through the various soil matrices was measured by a gas chromatograph equipped with a flame ionization detector (FID). The compounds studied …