Engineering Commons^™

Battery Design, Construction, And Characterization For Small Motor Use Focusing On Anodic Zinc For Electron Flow, Amber Veach

Chemical Engineering Undergraduate Honors Theses

This thesis explores the construction, characterization, and application of anodic zinc batteries for powering a small electric motor for the ChemE Car competition. Two zinc galvanic cell batteries were studied: zinc-carbon and zinc-air batteries. Prototype batteries were constructed and tested for voltage, amperage, and power production. In the zinc-carbon trials, a 3:1 mixture of manganese dioxide and graphite was determined to be the best cathode for power production. The size which allowed for sufficient power while maintaining the smallest footprint on the car was a zinc can six cm tall and two cm in diameter. Analysis of paper zinc-air battery …

Understanding And Controlling Failure Mechanisms Of The Zinc Anode For Rechargeable Alkaline Batteries, Michael J. D'Ambrose

Dissertations and Theses

In the coming years, the transformation of the electric grid will be in part enabled by safe, low-cost, and reliable large-scale rechargeable battery energy storage systems. Zinc (Zn) alkaline electrodes hold great importance and promise in the battery technology community as they satisfy the safety and cost requirements, yet their behavior in real world application is still poorly understood.

Two experimental studies were carried out, the first of which investigates failure mechanisms and material evolution during cycling of 27 zinc-manganese dioxide (Zn-MnO₂) cells in 37 wt% potassium hydroxide (KOH) electrolyte wherein the percent utilization of the theoretical capacity …

Study Of Contamination Resulting From Historical Mining Within The Old Lead Belt: Mineral Fork Watershed, 2021-2022, Tessa Nicole Mortensen

Masters Theses

“The Old Lead Belt in Missouri has been mined extensively over the past two hundred years, and with historical mining practices often not meeting modern environmental protection standards many areas have significant soil and water contamination as a result. This study focuses on the Mineral Fork River’s watershed in Washington County, Missouri, which includes portions of four separate Superfund sites. In this study, we exam the impact of historical mining on the health of alluvial systems, as evaluated by lead, zinc, and barium (barite) concentrations in the suspended and sediments within tributaries of the Mineral Fork River system. To relate …

Predictive Computational Materials Modeling With Machine Learning: Creating The Next Generation Of Atomistic Potential Using Neural Networks, Mashroor Shafat Nitol

Theses and Dissertations

Machine learning techniques using artificial neural networks (ANNs) have proven to be effective tools to rapidly mimic first principles calculations. These tools are capable of sub meV/atom accuracy while operating with linear scaling with respect to the system size. Here novel interatomic potentials are constructed based on the rapid artificial neural network (RANN) formalism. This approach generates precise force fields for various metals that have historically been difficult to describe at the atomic scale. These force fields can be utilized in molecular dynamics simulations to provide new physical insights. The RANN formalism, which is incorporated into a LAMMPS molecular dynamics …

A Comparison Of Zinc Levels In Runoff From Rubberized Hot Mix Asphalt And Conventional Pavement, Peter A. Duin

Cal Poly Humboldt theses and projects

High levels of dissolved zinc in water bodies can be toxic to aquatic organisms. There are currently over 40 waterways in California that have on occasion been in exceedance of Clean Water Act minimum toxicity threshold standards for zinc. Recycled tires that contain 1-2% zinc by mass are commonly used in California paving formulations known as Rubberized Hot Mix Asphalt (RHMA). The addition of tires to RHMA increases the zinc content of the pavement in comparison to conventional HMA. This research assesses the zinc content and leaching rate of RHMA in field and laboratory settings to estimate its contribution of …

Micro-Analysis Of Contaminants In Suspended Load And Bank Deposits From The Mineral Fork Creek Watershed In Potosi, Missouri, 2019-2020, William Joseph Miller

Masters Theses

”There are rising concerns pertaining to water contamination produced by toxic heavy metal contaminants such as lead and zinc. For this study, lead, zinc, and barite are three identified contaminants currently threatening Missouri water supplies. A microanalysis of the amounts of lead, zinc, and barite in the water of Mineral Fork Creek was conducted, involving both field and laboratory work. The purpose of the study was to determine the levels of lead, zinc, and barite contaminants, contributing to Big River, by Mineral Fork Creek, in Potosi Missouri, Washington County.

This research study uses a quantitative micro-analysis approach to determine the …

Development Of Investment Casting Method For Production Of Metal Foams For Tissue Engineering, Justin Aaron Womack

Theses and Dissertations

Ideal biomaterials for bone tissue regeneration are bone-mimicking structures that present a fully interconnected porous structure, have similar mechanical properties to bone, and exhibits a specific biodegradation behavior that is at the same rate as adjoining cell growth. Metals have high wear resistance, ductility, impact strength, and strain energy absorption capacity compared to other materials, which makes them suitable candidates for tissue engineering scaffolds. Magnesium and zinc are of interest for bone tissue regeneration for their biocompatibility and mechanical properties close to human bone. A newly developed process, presented in this thesis, for the creation of porous magnesium and zinc …

Controlled Release Of Corrosion Inhibitors: Zinc And Magnesium Containing Sodium Chromate, Andrew Thomas

Williams Honors College, Honors Research Projects

Corrosion can be combated by multiple methods, where the primary purpose is to minimize degradation of metal surfaces. Corrosion inhibitors are one of the most effective methods of corrosion protection. Inhibitors are substances that minimize corrosion in aggressive environments, with only a low concentration required. The inhibitors are chemically adsorbed on the surface of the metal and a protective thin film is formed . The mechanism of the inhibitors could be described as anodic, cathodic, or a mix of the two. Anodic inhibitors, also known as passivation inhibitors, alter an anode reaction. Corrosion potential of the metal is shifted to …

Degradable Zinc Material Characteristics And Its Influence On Biocompatibility In An In-Vivo Murine Model, Roger J. Guillory Ii

Dissertations, Master's Theses and Master's Reports

Biodegradable stents based on zinc have been under development since their introduction in 2013. While metallic zinc is highly ductile, it unfortunately lacks the mechanical strength required for arterial stents. This has led to the development of an abundance of novel zinc-based materials, with the aim of improving the mechanical strength without sacrificing too much ductility. Although these materials are intended to function and slowly degrade within an artery, most zinc-based materials have been developed without deep consideration for their biological effects.

The present work explores the biological effects elicited by zinc-based materials implanted within the arterial system. The biological …

Improving Base Metal Electrowinning, Charles Ebenezer Abbey

Doctoral Dissertations

"In zinc electrowinning, Mn oxidizes to form MnO₂ on Pb-Ag anodes, cell walls and pipes. MnO₂ reduces anode corrosion but also leads to short circuits and maintenance issues. MnO₂ is thought to interact with chloride ions and produce oxidized chlorine species. The interactions between Mn and Cl are not well understood. Bench scale experiments were conducted to investigate the effects of the manganese to chloride ratio on anode corrosion rate and electrolyte chemistry using rolled Pb-Ag anodes. Increasing the average Mn/Cl^- ratio from ~7:1 to ~11:1 reduced the anode corrosion rate. Anode scales produced with Mn/Cl …

Electrochemical Properties Of Crystalline Polymorphs Of Mno2 In Aluminum And Zinc Metal Batteries, Subhadip Pal

Dissertations and Theses

The widespread use of non-renewable fossil fuels has led to societal problems like global warming and climate change. Electrochemical energy storage can enable the integration of renewable energy sources that are inherently intermittent (solar, wind, etc.) into the electric grid, though major advances in cost, cycle life, and safety are necessary to have a global impact on the energy landscape. Both aluminium (Al) and zinc (Zn) metals are earth abundant, low-cost, safe, and exhibit high coulombic capacities, which make them promising electrode materials for “beyond lithium-ion” battery chemistries. However, the electrochemical feasibility and charge storage mechanisms of alternative Al and …

Removal Of Iron, Zinc, And Copper From Waters Impacted By Acid Mine Drainage Using Natural Zeolite, Mackayla Janae Thyfault

Open Access Theses & Dissertations

In this research, the adsorption behavior of zeolites with respect to iron (Fe), zinc (Zn), and copper (Cu) has been studied in order to assess its application to heavy metal removal in polluted settings caused by acid mine drainage (AMD). The St. Cloud zeolitic deposit used in this project was characterized using a sieve analysis; the effective diameter and coefficient of uniformity were calculated. Batch studies were performed, and the samples were analyzed using ICP-OES. Batch studies used metal concentrations ranging from 50 mg/L to 650 mg/L. Freundlich, Linear, Langmuir, and BET adsorption isotherms were applied and evaluated to the …

Toward The Synthesis And Characterization Of Pb-Doped Zns Nanocrystals For Solar Energy Applications, Allison Durr

Online Theses and Dissertations

Efficient and affordable energy conversion and energy storage technologies are required to meet society’s increasing demands. Semiconductor nanocrystals are particularly attractive materials for solar energy conversion applications, as their tunable optoelectronic properties can be manipulated to both optimize the absorbance of solar photons and to afford desirable electronic properties. Further tunability of binary semiconductor nanocrystal systems can be realized through substitutional doping. However, doping can be difficult, as the dopants can cause significant lattice strain in the host crystals. Lead-doped ZnS nanocrystals are one promising material for the conversion of solar photons into storable fuels such as hydrogen gas. The …

Aqueous Zinc Removal Using Nanoparticle Treated Natural Fibers, Daniel Zieske

Graduate Theses & Non-Theses

The objective of this thesis research is to evaluate and enhance a recently developed water treatment technology. The technology was previously successful in removing airborne mercury from coal fired power plant flue gas, and has since been demonstrated to remove aqueous copper and cadmium. The technology uses natural coconut fibers impregnated with metal nanoparticles using a proprietary technique. A series of batch tests determined that both the treated and untreated natural fibers were capable of removing over 90% of aqueous zinc from a synthetic solution made by dissolving ZnCl2 salts in deionized water. Further testing with a bench scale continuous …

Interdiffusion And Impurity Diffusion In Magnesium Solid Solutions, Catherine Kammerer

Electronic Theses and Dissertations

Magnesium, being lightweight, offers potential to be developed into extensive structural applications. The transportation segment has particular interest in Mg and Mg alloy for applications where reduced vehicle weight is proportional to increased fuel efficiency. Aluminum and zinc are two of the most common alloying elements in commercial Mg alloys. They improve the physical properties of Mg through solid solution strengthening and precipitation hardening. Diffusion plays a key role in the kinetics of and microstructural development during solidification and heat treatment. However, there is limited diffusion data available for Mg and Mg alloys. In particular, because Al is monoisotopic, tracer …

Polarization Of Galvanic Point Anodes For Corrosion Prevention In Reinforced Concrete, Margareth Dugarte

USF Tampa Graduate Theses and Dissertations

The polarization performance of two types of commercial galvanic point anodes for protection of reinforced steel around patch repairs was investigated. Experiments included measurement of the polarization history of the anode under constant current impressed by galvanostatic circuits and in reinforced concrete slabs. The tests revealed, for both types of anodes, a potential-current function (PF) indicating relatively little anodic polarization from an open circuit potential at low current levels, followed by an abrupt increase in potential as the current approached an apparent terminal value. Aging of the anodes was manifested by a continually decreasing current output in the concrete tests, …

Traps And Trap Distribution In Commercial Zinc Sulphides Phosphors Silver Activated And Poisoned With Cobalt, Zohra Safinaz El Calamawy

Archived Theses and Dissertations

No abstract provided.

The Effect Of Germanium On The Current Efficiency In The Electrolysis Of Pure Zinc Sulfate Solution, Keith R. Bock

Bachelors Theses and Reports, 1928 - 1970

It has long been recognized that electrolytic zinc cells are extremely sensitive to impurities. In fact, cer­tain impurities present in amounts as low as 0.1 mg/1 cause a serious loss of current efficiency. Also, the presence of several impurities in the electrolyte may accelerate the detrimental effect of each impurity.

The Mechanical Production Of Zinc Dust, Charles A. Schroer

Bachelors Theses and Reports, 1928 - 1970

The object of this thesis is to produce zinc dust suitable for zinc leach purification, by direct application of a mechanical force on a stream of molten zinc.The project is a continuation of work done by Mr. D. S. Gleason, while working for his Master of Science degree in the spring of 1952.

Electrowinning Of Zinc By Mercury Cathode, Tor O. Notevarp

Bachelors Theses and Reports, 1928 - 1970

The problem was the investigation of electrowinning of zinc by using a mercury cathode, employing a neutral solution of zinc sulphate and containing small amounts of zinc, in the order of ten grams zinc per liter and less. The purpose of this study was on the base of the laboratory experiments to investigate the operational data that might possibly be applied in practice or industry.

Vacuum Distillation Of Zinc And Cadmium From Zinc Leach Purification Cake, Stiles R. Slosson

Bachelors Theses and Reports, 1928 - 1970

The term "vacuum distillation" is used to des­cribe the process employed when certain elements are separated either from their mother compounds or from one another by distilling them under reduced atmos­pheric pressure.

Polarographic Analysis Applied To Metallurgical Solutions And Products, Donald W. Johnson

Bachelors Theses and Reports, 1928 - 1970

The polarograph has been applied to a large number of chemical and metallurgical analyses, and is especially applicable to solution control analysis and to the deter­mination of minute quantities of ions in the presence of large amounts of other ions.

Electro-Galvanizing From A Purified Ammonium Sulphate Leach Of Anaconda Zinc Calcine, Phillip J. Mischkot Jr.

Bachelors Theses and Reports, 1928 - 1970

Ever since the introduction of metal products into our civilization, especially those of iron and steel, man has been confronted with the problems of corrosion prevention. As the agents which are conducive to cor­rosion cannot be completely eliminated, it has been necessary for man to develop processes and materials that will retard the degeneration of the metals that are so important to our industrialized world.

Separation Of Cadmium From Zinc In The Purification Step Of The Leaching Cycle, L. C. Powell

Bachelors Theses and Reports, 1928 - 1970

The purpose of this investigation is to determine the effect of the factors listed previously by conducting a series of tests that will indicate the ex­tent to which the purification is influenced by time, temperature, zinc oust size, zinc dust quantity, iron concentration, two stage precipitation, and aeration.

A Study Of The Diffusion Of Electroplated Coatings In The Solid State., Michael R. Writt

Bachelors Theses and Reports, 1928 - 1970

The term diffusion means an equalization or homogenization of diverse materials. Specifically ap­plied to metals, diffusion is the interchange of atoms. It is, in effect, an invasion of one crystal lattice by the atoms of one or more other crystal lattices. Therefore, the study of diffusion must involve the geometry and physics of crystal lattices as well as their energies.

The Solubility Of Zinc Ethyl Xanthate In Water, Thomas M. Mckenzie

Bachelors Theses and Reports, 1928 - 1970

A determination of the solubility of zinc ethyl xanthate was attempted by measuring the refractive index of a saturated solution of that salt. The small increment in refractive index effected by adding zinc ethyl xanthate to water in saturation quantities rendered measurements difficult and of dubious accuracy.

Zinc Plating Magnesium, Howard Wilbur Adam

Bachelors Theses and Reports, 1928 - 1970

Magnesium and magnesium alloys are becoming more and more important in modern industry. Their use in the aviation industry has been greatly curtailed because of their comparatively poor resistance to corrosion especially in moist atmospheres. Many methods have been adopted to improve their resistance to corrosion.

The Recovery Of Zinc From Butte Mine Waters, Edmond M. Fern

Bachelors Theses and Reports, 1928 - 1970

Very little work has been done towards the recovery of zinc from mine water because the zinc content of the water is generally low. As different from copper, which can very easily be replaced by iron in any of its solutions, zinc is very high up in the electro-chemical series and so the few metals above zinc, most of which are rare and hence expensive, cannot be used to replace zinc from its solution.

The Age-Hardening Of Aluminum With Mgzn2, Sidney E. Worthen

Bachelors Theses and Reports, 1928 - 1970

The purpose of this thesis is to investigate the age-hardening of aluminum with magnesium and zinc in such proportions as to conform to the compound MgZn₂.

Because of a lack of time and proper equipment, the only property investigated was the hardness as indicated by the Rockwell Superficial Hardness Tester.

A Study Of The Concentration Of A Copper-Zinc Ore., Kenneth L. M. Dodd

Bachelors Theses and Reports, 1928 - 1970

The ore under investigation in this thesis is a copper-zinc ore which came from the state of New Mexico. The exact location is unobtainable. The purpose of the investigation was to determine the most effective means of concentration of the valuable min­erals present in the ore.