Engineering Commons^™

Lead Doped Carbon Nanofibers In Li-Ion Batteries, Omar Torres

Theses and Dissertations

Lead acid batteries have been a very reliable rechargeable battery since its inception in the mid-1800s. Lithium-Ion batteries have been sought out for their light-weight and capacity of holding large amounts of energy in a small amount of space. Few studies have been conducted in the use of lead in lithium-ion batteries.

In this thesis, lead-doped carbon nanofibers were produced by using the Forcespinning® method and used as an anode on a lithium-ion battery. The morphology, material characterization and thermal properties of the anode material were analyzed using the Scanning Electron Microscopy (SEM), Energy Dispersive X-Ray Spectroscopy (EDS), Thermogravimetric Analysis …

Fibers For Skin Regeneration, Astrid Michelle Rodriguez Negron

Theses and Dissertations

This thesis presents the successful development of biocompatible Polyvinyl Butyral (PVB), PVB/Polylysine and PVB/Tannic Acid (TA)/Polylysine fibers from an ethanol solution, Polyhydroxybutyrate (PHB), PHB/Polylysine, PHB/TA/Polylysine fibers from a chloroform solution and Chitosan (CH)/Pullulan (PL)/TA and CH/PL/TA/Polylysine fibers from an aqueous solution. The fibers were mass produced utilizing the Forcespinning® (FS) technology. The morphology of the fibers was characterized using a scanning electron microscope (SEM) and the fibers average diameter was calculated. The thermal properties of the fibers were characterized using a thermogravimetric analyzer (TGA) and a differential scanning calorimeter (DSC). The antibacterial activity of the fibers was assessed using against …

Design Of A Multidirectional Wear Testing Device For Simulating Wear Of Biocompatible Materials Used In Joint Implants, Carlos A. Rodriguez Betancourth

Theses and Dissertations

In the present work, a novel multidirectional pin-on-disc wear testing device designated CNC-POD (computer-numerical-control pin-on-disc) capable of replicating the cross-shear motions experienced by a prosthesis in vivo was designed and developed in the UTRGV in order to evaluate the wear resistance of new biomaterials. The CNC-POD consists of six temperature-controlled pin-on-disc stations mounted on a two-axis CNC table (X-Y). Each pin-on-disc station is load-programmable up to 510 Newtons (115 pounds). The CNC table allows the machine to reproduce a wide range of 2D patterns in millimeter scale on the six stations under a specific load. Friction force is measured during …

The Effect Of Heat Generation In The Railroad Bearing Thermoplastic Elastomer Suspension Element On The Thermal Behavior Of Railroad Bearing Assembly, Oscar Osvaldo Rodriguez

Theses and Dissertations

Understanding the internal heat generation of the railroad bearing elastomer suspension element during operation is essential to predict its dynamic response and structural integrity, as well as to predict the thermal behavior of the complete railroad bearing assembly including the bearing adapter. The latter is essential for sensor selection and placement within the adapter (e.g., typical temperature sensors have operating ranges of up to 125°C or 257°F). The internal heat generation is a function of the loss modulus, strain, and frequency. Based on experimental studies, estimations of internally generated heat within the thermoplastic elastomer pad were obtained. The calculations show …

The Use Of Mixed Organic/Ionic Liquid Electrolytes With Forcespun Metal Oxides/Carbon Microfiber Electrodes In Lithium Ion Batteries, Jahaziel Villarreal

Theses and Dissertations

Conventional Lithium-Ion Battery (LIB) electrolytes have serious safety concerns because of highly flammability. In order to mitigate this drawback, alternative electrolytes with low volatility and non-flammable need to be synthesis. Ionic liquids (ILs) and mixed organic ionic liquid electrolytes (MOILEs) are the most suitable replacement for the highly flammable commercial organic electrolytes. In this academic investigation, a new perspective on the electrochemical performance of the ionic liquid EMI-TFSI as an alternate non-flammable electrolyte. In parallel, the use of Forcespun nanofibers as binder-free anodes will be analyzed to further improve overall electrochemical performance.

Buffer Controlled Cache For Low Power Multicore Processors, Marven Calagos

Theses and Dissertations

This thesis proposes a buffered dual access mode cache to reduce power consumption in multicore caches for embedded systems. This cache is called Buffer Controlled Cache (BCC cache). The proposed scheme introduces a pre-cache buffer to determine how to access the cache. The proposed cache shows better prediction rates and lower power consumption than conventional caches, such as Phased cache and Way-prediction cache. For single core implementation, Simplescalar and Cacti simulators have been used for these simulations using SPEC2000 benchmark programs. The experimental results show that the proposed cache improves the power consumption by 37%-42% over the conventional caches. Multi2Sim …

Superharmonic Resonance Of Second Order For Electrostatically Actuated Mems Cantilevers, Martin Amador Botello

Theses and Dissertations

The nonlinear dynamics of electrostatically actuated micro-electro-mechanical system (MEMS) cantilever resonators are investigated. The applied Alternating Current (AC) voltage is in the realm of superharmonic resonance of the second order (near one-fourth of the natural frequency of the resonator) and hard excitations. Method of Multiple Scales (MMS) and Reduced Order Models (ROMs) are used to solve the dimensionless partial differential equation (PDE) of motion along with boundary and initial conditions. MMS transforms the PDE of motion into zero-order and first-order problems. ROMs uses mode shapes of vibration for undamped cantilever resonator as a basis of functions. ROM is …

Ensemble Machine Learning To Predict Family Consent For Organ Donation, Md Ehsan Khan

Graduate Dissertations and Theses

There is ever increasing disparity between number of organs needed for transplantation and numbers available for donation to save lives. As a result, thousands of people die every year waiting for organs. Therefore, it is now more important than ever before to take serious actions to decrease this disparity. One way to bridge gap between organ demand and supply is to increase family consent for organ donation. This research studied the factors associated with family consent. Machine Learning approach had been used in very few literature to understand factors related to family consent. This study uses six Ensemble Machine Learning …

Utilizing Data Mining Techniques And Ensemble Learning To Predict Development Of Surgical Site Infections In Gynecologic Cancer Patients, John R. Mcdonough

Graduate Dissertations and Theses

Surgical site infections are costly to both patients and hospitals, increase patient mortality, and are the most common form of a hospital acquired infection. Gynecological cancer surgery patients are already at higher risk of developing an infection due to the suppression of their immune system. This research leverages popular data mining techniques to create a prediction model to identify high risk patients. Implemented techniques include logistic regression, naive Bayes, recursive partitioning and regression trees, random forest, feed forward neural network, k-nearest neighbor, and support vector machines with linear kernel. Weighted stacked generalization was implemented to improve upon the individual base …

Image Series Prediction Via Convolutional Recurrent Neural Networks With Limited Training Data, Zao Zhang

Graduate Dissertations and Theses

This thesis focuses on developing deep learning algorithms that can be used to forecast the image series under limited training data. Specifically, we study the problem of using a pine tree's existing appearance images to predict its future appearance images.

Cyber-Physical Embedded Systems With Transient Supervisory Command And Control: A Framework For Validating Safety Response In Automated Collision Avoidance Systems, Daniel K. Trembley

Graduate Dissertations and Theses

The ability to design and engineer complex and dynamical Cyber-Physical Systems (CPS) requires a systematic view that requires a definition of level of automation intent for the system. Since CPS covers a diverse range of systemized implementations of smart and intelligent technologies networked within a system of systems (SoS), the terms “smart” and “intelligent” is frequently used in describing systems that perform complex operations with a reduced need of a human-agent. The difference between this research and most papers in publication on CPS is that most other research focuses on the performance of the CPS rather than on the correctness …

Side-Information For Steganography Design And Detection, Tomas Denemark

Graduate Dissertations and Theses

Today, the most secure steganographic schemes for digital images embed secret messages while minimizing a distortion function that describes the local complexity of the content. Distortion functions are heuristically designed to predict the modeling error, or in other words, how difficult it would be to detect a single change to the original image in any given area. This dissertation investigates how both the design and detection of such content-adaptive schemes can be improved with the use of side-information.

We distinguish two types of side-information, public and private: Public side-information is available to the sender and at least in part also …

Growth And Characterization Of Gallium Oxide Thin Films And Devices, Jorge Castillo

Theses and Dissertations

Gallium oxide has promising physical and electrical properties for power applications and optoelectronics. thermally grown oxide developed from sputtered GaN layers and gallium oxide substrates will be characterized. The study will evaluate a variety of temperatures in order to investigate the advantages and disadvantages on each of the synthetization techniques.

Des And Tdes Performance Evaluation For Non-Pipelined And Pipelined Implementations In Vhdl Using The Cyclone Ii Fpga Technology, Edni Del Rosal

Theses and Dissertations

Two ongoing issues that engineers must face in the new era of data analytics are performance and security. Field Programmable Gate Arrays (FPGAs) offer a new solution for optimizing the performance of applications while the Data Encryption Standard (DES) and the Triple Data Encryption Standard (TDES) offer a mean to secure information. In this thesis we present a Non-Pipelined and Pipelined, in Electronic Code Book (EBC) mode, implementations in VHDL of these two commonly utilized cryptography schemes. Using Altera Cyclone II FPGA as our platform, we design and verify the implementations with the EDA tools provided by Altera. We gather …

Study Of Latent Heat Thermal Energy Storage Systems For Concentrated Solar Power Plants, Hermes Chirino

Theses and Dissertations

Concentrated Solar Power (CSP) using phase change material (PCM) as the storage medium in the Thermal Energy Storage (TES) system is a promising technology for large scale utilization of solar thermal energy because heat latent heat thermal energy storage (LHTES) systems can store more energy as the latent heat during the melting process.

This study analyzes the different dimensionless parameters from the 1-D transient enthalpy-based mathematical model used to simulate the heat transfer and flow within the LHTES system. These dimensionless parameters are varied and analyzed with the main objective of increasing thermal energy storage efficiency and exergy efficiency of …

Effect Of Processing Parameters On The Electrochemical Performance Of Forcespun Metal Oxide/Carbon Composite Fibers For Li-Ion Batteries, Howard A. Campos

Theses and Dissertations

Metal oxides have been gaining interest as electrode materials for rechargeable Li-ion batteries due to various properties including low cost, low toxicity, and high theoretical capacity. In this research work the effect of two different metal oxide/carbon fiber composites, Fe3O4/C and ZnO/C, on the electrochemical performance for Li-ion batteries will be explored. This is also the first time that results are reported, to the best of our knowledge, of these fiber composites through the Forcespinning ® method. Scanning electron microscopy (SEM), Energy-Dispersive X-ray Analysis (EDS), X-ray photoelectron spectroscopy (XPS), powder X-ray diffraction (XRD), and electrochemical analysis were used to investigate …

Security Evaluation Of Virtualized Computing Platforms, Ganesh Reddy Gunnam

Theses and Dissertations

In this thesis, security experiments were conducted to evaluate embedded security protocol performance of two leading server operating systems, Apple’s MAC OS server LION Vs. Microsoft’s Windows server 2012 R2 OS under different types of security attack. Furthermore, experiments were conducted to understand and evaluate the effect of virtualization using Hyper-V with Windows 2012 R2 OS on MAC hardware platform. For these experiments, connection rate, connection latency, non-paged pool allocations and processor core utilization for different OS, virtual machines, and under different traffic types were measured.

Design Of Metal Oxides/Metal Sulfides For The Improvement Of Sodium Ion Batteries, David E. Flores

Theses and Dissertations

Herein, the improvement in performance for sodium ion batteries (NIBs) is discussed from available literature and work conducted in the laboratory setting to demonstrate the ability of sodium to perform in the world of energy storage. The reason that sodium is being explored as an alternative to Lithium in energy storage devices is because of the potential depletion of the lithium in the world causing lithium prices to surge. Researchers show that many Sn, Sb, Ge, and other composites perform well as anode materials within NIBs. The research conducted in the dissertation applies the Forcespinning method to produce fibers for …

Single Tower Crane Allocation Models Using Ant Colony Optimization, Carlos Abelardo Trevino

Theses and Dissertations

The construction industry greatly benefits from the utilization of heavy machines and equipment to accomplish successful projects. Tower cranes, in specific, have a crucial role in the transportation of material loads across the site. Because these machines are fixed to the ground, it is essential for planners and managers to position them in a location that provides the most efficient transfer of materials possible. This is commonly known as the tower crane allocation problem, and many researchers have attempted to optimize the tower crane location using mathematical, artificial intelligence, and simulation approaches. However, many works from the literature contain critical …

Characterization Of Lift And Drag On Two Dimensional Airfoils With And Without Sinusoidal Leading Edges, Gregorio I. Acosta

Theses and Dissertations

An experimental investigation was taken on a 63-021 NACA airfoil, to characterize lift and drag and how the effects of sinusoidal leading edges affect the aerodynamic properties. A theoretical model is also purposed by implementing a perturbation on thin-airfoil theory.

Two sets of airfoils were machined and tested inside a low-speed open circuit wind tunnel. Data from a pressure scanner and particle image velocity will give an insight of how the modified leading edges affect the aerodynamic properties. A Fourier series expansion was used to solve for the lifting-line model, by use of thin-airfoil theory and complex number theory.

Algan/Gan Hemt By Magnetron Sputtering System, Roman Garcia Perez

Theses and Dissertations

In this thesis, the growth of the semiconductor materials AlGaN and GaN is achieved by magnetron sputtering for the fabrication of High Electron Mobility Transistors (HEMTs). The study of the deposited nitrides is conducted by spectroscopy, diffraction, and submicron scale microscope methods. The preparation of the materials is performed using different parameters in terms of power, pressure, temperature, gas, and time. Silicon (Si) and Sapphire (Al2O3) wafers are used as substrates. The chemical composition and surface topography of the samples are analyzed to calculate the materials atomic percentages and to observe the devices surface. The instruments used for the semiconductors …

Development Of Lower Rio Grande River Water Quality Transportation Numerical Model For Bi-National River Management, Jose O. Gonzalez

Theses and Dissertations

Traditionally, water quality modelling has focused on modelling individual water bodies. However, water quality management problems must be analyzed at the larger scale to include influences from various water bodies that are interconnected. This paper provides a study on the hydrologic and quality transportation calculation by developing a hydrodynamic (unsteady state) channel routing model using a water-balanced approach. A one dimension Lagrangian river model was developed and applied to the 210 plus miles for the lower Rio Grande River Basin from the Falcon Dam to the head water of Brownsville that pours onto the Gulf of Mexico. This model can …

Multi-Functional System For Biomedical Application Using Ac Electrokinetics, Rakesh Guduru

Theses and Dissertations

Manipulation of fluids in a small volume is often a challenge in the field of Microfluidics. While many research groups have addressed this issue with robust methodologies, manipulating fluids remains a scope of study due to the ever-changing technology (Processing Tools) and increase in the demand for “Lab-On-a-Chip” devices in biological applications. This thesis peruses the flow pattern of the orthogonal electrode pattern and circular electrode providing, examples of the flow patterns and the process micromixing. Characteristics of a multifunctional system were demonstrated using orthogonal electrode and circular electrode patterned device. Conductivity of the fluids were chosen such they reflect …

A Simple Multi-Core Functional Cache Design Simulator, Rano Mal

Theses and Dissertations

This paper presents a flexible multi-core cache memory simulator to design and evaluate memory hierarchies for general-purpose or embedded processors. The proposed simulator needs to work with Pin, which is an open-source dynamic instrumentation tool provided by Intel. The Pin intercepts the execution of instructions and generates a sequence code (traces) to feed into the simulator for any selected benchmark programs, such as SPEC2006, SPLASH2, or PARSEC. We have a plan to release this simulator as an open-source (like Pin) to support research and/or academic community for their simulation works. In addition, we expect more functions can be updated on …

Understanding The Surface Fouling Mechanism Of Ultrananocrystalline Diamond Microelectrodes Using Microfluidics For Neurochemical Detection, An-Yi Chang

Doctoral Dissertations

Electrochemical methods are widely used for chronic neurochemical sensing, but thus far, the organic solution redox reactions fouled the electrodes' surface. It caused the reduction of sensitivity and the electrodes' lifetime.

Here, we present the boron-doped nanocrystalline diamond microelectrodes (BDUNCD) as the next generation electrode material for neurochemical sensor development. To aid in long-term chronic monitoring of neurochemicals, they have a wide window of electrochemical potential, extremely low background current, and excellent chemical inertness. The main research goal is to reduce the rate of electrode fouling due to the reaction by-products, and significantly extend their useful lifetime.

We systematically characterize …

Electrochemical Behavior Of Dense Electrodes For Impedancemetric Nox Sensors, Nabamita Pal

Doctoral Dissertations

NOx (NO and NO2) exhaust gas sensors for diesel powered vehicles have traditionally consisted of porous platinum (Pt) electrodes along with a dense ZrO2 based electrolyte. Advancement in diesel engine technology results in lower NOx emissions. Although Pt is chemically and mechanically tolerant to the extreme exhaust gas environment, it is also a strong catalyst for oxygen reduction, which can interfere with the detection of NOx at concentrations below 100 ppm. Countering this behavior can add to the complexity and cost of the conventional NO x sensor design. Recent studies have shown that dense electrodes are less prone to heterogeneous …

Full Simulation For The Qweak Experiment At 1.16 And 0.877 Gev And Their Impact On Extracting The Pv Asymmetry In The N→Δ A Transition, Hend Abdullah Nuhait

Doctoral Dissertations

The Qweak project is seeking to find new physics beyond the Standard Model. It is aimed to measure the weak charge of the proton, which has never been measured, at 4% precision at low momentum transfer. The experiment is performed by scattering electrons from protons and exploiting parity violation in the weak interaction at low four-momentum transfer.

In this experiment, two measurements were considered: which are elastic and inelastic. The elastic is to measure the proton's weak charge. In addition, the inelastic asymmetry measurement, which will extract the low energy constant dΔ. That measurement works in the neutral current …

Stretching The Limits Of Dynamic Range, Shielding Effectiveness, And Multiband Frequency Response, Matthew J. Hartmann

Doctoral Dissertations

In this dissertation, an RF MEMS variable capacitor suitable for applications requiring ultrawide capacitive tuning ranges is reported. The device uses an electrostatically tunable liquid dielectric interface to continuously vary the capacitance without the use of any moving parts. As compared to existing MEMS varactors in literature, this device has an extremely simple design that can be implemented using simple fabrication methods that do not necessitate the use of clean room equipment. In addition, this varactor is particularly suited for incorporating a wide range of liquid dielectric materials for specific tuning ratio requirements.

Additionally, the shielding effectiveness performance of graphene-doped …

Trihalomethane, Dihaloacetonitrile, And Total N-Nitrosamine Precursor Adsorption By Carbon Nanotubes: The Importance Of Surface Oxides And Pore Volume, Erin Needham

Graduate Theses and Dissertations

As drinking water sources become increasingly impaired, enhanced removal of natural organic matter (NOM) may be required to curb formation of disinfection byproducts (DBPs) upon chlor(am)ination. While carbon nanotubes (CNTs) can adsorb NOM, their properties for DBP precursor adsorption have not been elucidated. Nine types of CNTs were assessed for trihalomethane (THM), dihaloacetonitrile (DHAN), and total N-nitrosamine (TONO) precursor adsorption. Batch isotherm experiments were completed with lake water and, to simulate an impaired condition, effluent from a wastewater treatment plant (WWTP). Adsorption varied with CNT type and dose, with TONO precursors having the highest percent removals from WWTP effluent (up …

Effect Of Column Axial Load On Skewed Smf Rbs Connection Demands, Clovis Desrochers

Graduate Theses and Dissertations

Steel buildings in high seismic areas often require special structural systems to transfer large lateral forces induced by earthquake accelerations. The selection of an appropriate seismic steel system (braced frame, moment frame, shear wall, etc.) is often influenced by architectural considerations. Moment frame configurations offer the most architectural flexibility, but are limited by code prequalification requirements that limit the use of non-orthogonal (skewed) beam-column connection geometries. A recent study has investigated laterally skewed moment frame connections, indicating that skew increases the potential for column twist and column flange yielding; however, it is unclear how realistic column axial loads will affect …