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Full-Text Articles in Engineering

Fission Product Thermodynamics, Solubility, And Extraction In Molten Salts And Lead, Richard Lee Fitzhugh Aug 2024

Fission Product Thermodynamics, Solubility, And Extraction In Molten Salts And Lead, Richard Lee Fitzhugh

Theses and Dissertations

Chemical behavior of fission products in systems relevant to two major advanced nuclear reactor systems, namely the lead-cooled fast reactor (LFR) and molten-salt reactor (MSR), has been studied with a heavy emphasis on thermodynamics. The behavior of fission products in molten salts is examined from a theoretical perspective, with an emphasis on the standard state used to define the thermodynamic activity. A standard state extrapolated from infinite dilution behavior, which is fairly common practice in electrochemistry, is found to facilitate faster, easier, and simpler analysis while retaining much of the accuracy of the complex Modified Quasichemical Model. Inductively-coupled plasma mass …


Benchmarking Of A Sco2 Heat Exchanger Flow Loop, David Velasco Apr 2024

Benchmarking Of A Sco2 Heat Exchanger Flow Loop, David Velasco

Doctoral Dissertations and Master's Theses

Heat transfer of supercritical carbon dioxide (sCO2) was studied experimentally by commissioning a sCO2 flow loop featuring a horizontal tube-in-tube counterflow heat exchanger with a circular cross section. The main objective was to establish experimental heat transfer research capabilities for sCO2 at Embry-Riddle Aeronautical University’s (ERAU) Thermal Science Lab. sCO2 experiences a drastic change in thermophysical properties near its critical point that results in unique heat transfer characteristics. The high pressures at which sCO2 exists make the large gradients in thermophysical and transport properties difficult to study, experimentally and numerically. However, understanding the heat transfer characteristics and thermophysical behavior of …