Engineering Commons^™

Momentum Of Particles From Time-Of-Flight Measurements, Joseph Best

Senior Theses

In order to find the momentum of particles from time of flight measurements, I used a program called Geant4 to simulate experiments. I made a simple two detector setup, and I recreated a real world experiment. I spent a lot of time learning to code in C++ so I could use Geant4 correctly. I simulated these experiments shooting electrons, muons, and pions through the geometry and measured the time at two points in their flight. Subtracting the second time from the first gave me the time of flight distribution for each particle. I used ROOT to draw histograms of the …

Guided Wave Based Integrated Structural Health Monitoring And Nondestructive Evaluation, Zhenhua Tian

Theses and Dissertations

Damage detection and health monitoring are critical for ensuring the structural safety in various fields, such as aerospace, civil and nuclear engineering. Structural health monitoring (SHM) performs online nondestructive evaluation (NDE) and can predict the structural remaining life through appropriate diagnosis and prognosis technologies. Among various SHM/NDE technologies, guided ultrasonic waves have shown great potential for fast and large area SHM/NDE, due to their sensitivity to small defects and capability to propagate long distances. Recent advances in guided wave based SHM/NDE technologies have demonstrated the feasibility of detecting damage in simple structures such as metallic plates and pipes. However, there …

Experimental Study Of Longitudinal Sorting Of Particles Differing In Size And Density, Nabila Mahjabeen

Theses and Dissertations

Transport, deposition and erosion of sediment particles differing in size, shape and density may result in particle segregation, which in geosciences applications is generally referred to as sediment sorting. A thorough understanding of sediment sorting processes is important to describe and model a wide variety of natural processes such as the decrease in particle size and/or density in a fluvial system (downstream fining and/or lightening), the formation of economic placers, concentration of heavy minerals, chemical and metal pollutants etc. Sorting of sediment grains associated with sediment transport in the streamwise direction results in the development of longitudinal sorting patterns. Vertical …

Intercode Advanced Fuels And Cladding Comparison Using Bison, Frapcon, And Femaxi Fuel Performance Codes, Aaren Rice

Theses and Dissertations

The high density uranium-based fuels are regaining popularity as the current fleet of LWR’s are showing interest in uprating plants to increase accident tolerance and performance. Fuels such as U3Si2, UN, and UC all contain a higher uranium loading and thermal conductivity than that of UO2 making them attractive in combination with an advanced cladding type such as the ceramic SiC cladding. In addition to adding more mass uranium to the core without surpassing current enrichment limits, these advanced fuels and claddings are designed with increased accident tolerance performance in a LOCA type scenario in mind. One of the possible …

Industrial Robot Acceptance: Effects Of Workforce Demographics And Establishing A Culture Of Acceptance Within Manufacturing Industry, Melissa M. Henderson

Theses and Dissertations

Industrial applications have not been extensively researched regarding human-robot interaction. This project investigated industrial robot acceptance in the context of one manufacturing site. Acceptance was examined in relation to the workforce and conditions of acceptance were identified using mixed methodology. Quantitative (surveys) and qualitative (interviews) data was used to measure and analyze the existing state of technology acceptance and site culture. Based on this exploratory study, it was found the manufacturing facility has a weak culture but would be generally accepting of industrial robots if the technology were easy to use and useful. The identified boundary conditions to acceptance included …

In Situ Ir Spectroscopic Investigation Of Noble Metal Catalysts Related To The Reduction Of Automotive Exhaust Emissions, Zhiyong Wang

Theses and Dissertations

The reduction of automotive exhaust emissions has been one of the hottest topics in catalysis community since 1970s. Thanks to the development of three-way catalysts, main auto-exhaust pollutants, such as carbon monoxide, nitrogen oxides and unburned hydrocarbons, can be removed simultaneously. Nowadays, diesel engines and lean-engines become more and more popular due to their high fuel-efficiency and low CO2 emissions. Unfortunately, conventional three-way catalysts are not effective at reducing the NOx emissions from these engines due to the excess oxygen in the exhaust stream. Platinum catalysts were found to be highly active for selective NO reduction with hydrocarbons in excess …

Development Of Highly Active And Stable Hybrid Cathode Catalyst For Pemfcs, Won Suk Jung

Theses and Dissertations

Polymer electrolyte membrane fuel cells (PEMFCs) are attractive power sources of the future for a variety of applications including portable electronics, stationary power, and automobile application. However, sluggish cathode kinetics, high Pt cost, and durability issues inhibit the commercialization of PEMFCs. To overcome these drawbacks, research has been focused on alloying Pt with transition metals since alloy catalysts show significantly improved catalytic properties like high activity, selectivity, and durability. However, Pt-alloy catalysts synthesized using the conventional impregnation method exhibit uneven particle size and poor particle distribution resulting in poor performance and/or durability in PEMFCs. In this dissertation, a novel catalyst …

Wavelet Analysis Of Periodic Error In Heterodyne Interferometry, Chao Lu

Theses and Dissertations

Heterodyne displacement measuring interferometry provides important metrology for applications requiring high resolution and accuracy. Heterodyne Michelson interferometers use a two-frequency laser source and separate the two optical frequencies into one fixed length and one variable length path via polarization. Ideally these two beams are linearly polarized and orthogonal so that only one frequency is directed toward each path. An interference signal is obtained by recombining the light from the two paths; this results in a measurement signal at the heterodyne (split) frequency of the laser source. This measurement signal is compared to the optical reference signal. Motion in the measurement …

Supported Group Ib-Pd Bimetallic Catalysts Prepared By Electroless Deposition And Galvanic Displacement For Selective Hydrogenation Of Acetylene, Yunya Zhang

Theses and Dissertations

Ethylene is the building block for many chemical intermediates in the petrochemical industry. The current worldwide ethylene production is over 150 million tons per year and demand increases by 3-5% annually. However, ethylene produced from steam cracking of light naptha contains up to 2% acetylene which acts as a poison for the downstream ethylene polymerization catalysts. Selective hydrogenation of acetylene in the ethylene stream using supported Pd catalysts is the industrially preferred method of lowering acetylene to acceptable ppm levels (< 5 ppm). Due to inferior selectivity at high acetylene conversion and the formation of “green oil”, or ethylene/acetylene oligomers, during reaction, small amounts of Group IB metals have been added to improve the performance of current generation catalysts. However, the bimetallic effects of the above additives have not been experimentally confirmed, possibly because the conventional methods of catalyst preparation result in both monometallic and bimetallic particles with varying compositions. This in turn makes it difficult to determine the position of the two metallic components, and bimetallic interactions typically occur only when the two metals form proximal contact instead of separate particles. In this study, a series of Ag- and Au-Pd/SiO2 bimetallic catalysts were prepared by electroless deposition (ED) with incremental and controlled coverages of Ag and Au on Pd. The selectivity of acetylene to ethylene and turnover frequencies of acetylene conversion were enhanced at high coverages of Ag and Au on Pd surfaces due to the transition of acetylene adsorption modes, which was further confirmed by the kinetics of acetylene hydrogenation. The similar performance trends for Ag- and Au-Pd/SiO2 suggest that the bimetallic effect for these catalysts was likely geometric and not electronic in nature. For comparison, a series of reverse Pd-Ag/SiO2 bimetallic catalysts where variable coverages of Pd were deposited onto Ag surfaces was prepared using galvanic displacement (GD) of Ago by Pd2+ to further explore the nature of bimetallic effects for selective acetylene hydrogenation. Unlike for the earlier case for Ag on Pd surfaces using ED, for samples prepared by GD there was considerably diffusion of Pd into the Ag lattice to give greater electronic interactions between these two metals, which limited selectivity of acetylene hydrogenation to form ethylene.

Surface Modification Of Nanodiamond And Its Incorporation In Nanodiamond/Peek Nanocomposites, Zahidul Wahab

Theses and Dissertations

The continued miniaturization of electronic device components requires new lightweight polymers with high thermal stability, high thermal conductivity, low electrical conductivity, and low dielectric constant. Composites of nanodiamond (ND) and poly(ether ether ketone) (PEEK) are candidates for these applications due their unique combination of properties. The objectives of this research are to explore new routes for surface functionalization of nanodiamond (ND), develop methods for maximizing dispersion of ND as a nano-scale filler in PEEK, and characterize the effect of dispersed ND on the mechanical, thermal and dielectric properties of ND/PEEK composites. Initial attempts to disperse different kinds of commercially available, …

Impact Of Formulation And Processing Parameters On Mechanical Properties Of Magadiite/Elastomer Composites, Yating Mao

Theses and Dissertations

This work seeks a better understanding of mechanical reinforcement and energy dissipation in elastomer composites containing the layered silicate magadiite (MGD, Na2Si14O29·nH2O). We characterized the elastomer’s accessibility into MGD interlayer spaces and studied the factors that influence the composite mechanical properties. We also compare the mechanical reinforcement of MGD with montmorillonite (MMT, a layered aluminosilicate clay mineral), which is widely used as filler in other kinds of nanocomposites. The study explores the grafting chemistry, vulcanization, and reinforcement mechanism in MGD/elastomer composites, which may help us to formulate the platelet/elastomer composites with superior mechanical properties and performance in the future. We …

Preparation And Characterization Of Pt-Ru Bimetallic Catalysts Using Electroless Deposition Methods And Mechanistic Study Of Re And Cs Promoters For Ag-Based, High Selectivity Ethylene Oxide Catalysts, Weijian Diao

Theses and Dissertations

Pt-Ru bimetallic catalysts are widely used for direct methanol fuel cells, biomass upgrading and hydrocarbon refining and offer unique properties compared to Pt or Ru monometallic catalysts due to ensemble effects, electronic effects, and/or bifunctional effects. To achieve better performance, strong metal-metal interactions and true bimetallic surface are needed. Electroless deposition (ED) methods are used in our laboratory to synthesize such bimetallic catalysts. In this study, two series of Ru@Pt/C (Pt deposited on Ru surfaces) and Pt@Ru/C (Ru deposited on Pt surfaces) catalysts have been synthesized. Characterization data from temperature programmed reduction (TPR), selective chemisorption, X-ray photoelectron spectroscopy (XPS), and …

A Multiphysics Modeling Of Solid Oxide Metal-Air Redox Battery, Md Ahsan Uddin

Theses and Dissertations

Cost-effective and large scale energy storage is essential for the growth of the future’s ‘‘green energy’’ infrastructure. Among the energy storage technologies currently being used, rechargeable batteries represent a class of advanced electrical energy storage (EES) mechanisms that can be valuable for the future renewable integration and smart grid. Rechargeable batteries have innumerous advantages over the conventional pumped hydro and compressed-air energy storage system. Now days, There are various types of rechargeable batteries available to work as an energy storage device in a smart grid but it still needs many breakthroughs to become commercially viable for stationary energy storage. First …

Assessment Of Classifiers For Potential Voice-Enabled Transportation Apps, Md Majbah Uddin

Theses and Dissertations

Transportation apps are playing a positive role for today’s technology-driven users. They provide users with a convenient and flexible tool to access transportation data and services, as well as collect and manage data. In many of these apps, such as Google Maps, their operations rely on the effectiveness of the voice recognition system. For the existing and new apps to be truly effective, the built-in voice recognition system needs to be robust (i.e., being able to recognize words spoken in different pitch and tone). The goal of this study is to assess three post-processing classifiers (i.e., bag-of-sentences, support vector machine, …

Effects Of Cell Adhesion Peptides, Ph, And Matrix Shape On Maintenance Of Breast Cancer Stem Cells In An Engineered Hydrogel Matrix, Leily Daneshian

Theses and Dissertations

Metastasis, resistance to chemo- and radiotherapy, and eventual relapse has been attributed to a tumor subpopulation known as cancer stem cells (CSCs). CSCs are regulated in their tumor microenvironment by various factors. Synthetic hydrogels can be used to investigate the effects of individual environmental factors on CSCs by providing inert 3D matrices. In this thesis, poly ethylene glycol diacrylate (PEGDA) hydrogel with 5kpa modulus has been used as a culture system to study the effect of; I) integrin and heparin binding peptides, 2) pH, and 3) the shape of the microenvironment on breast CSCs maintenance and tumorsphere formation in PEGDA. …

Tool Material Degradation Due To Friction Stir Welding Of Aluminum Alloys, Corbin T. Collier

Theses and Dissertations

The purpose of this study is to investigate the friction stir welding (FSW) tool material degradation factors due variation in tool material properties and the effect of an aluminum diffusion wear mechanism on three different FSW tool material when exposed to various welding temperatures and times. The degradation factors are essential to FSW tool design due to the effect of the tool pin and shoulders on the heat generation and material flow which directly correlated to the weld quality created during the FSW process. For this investigation the three materials used are H13, TSP1, and MP159. To determine degradation factors …

Confluence Of Density Currents Over An Erodible Bed, Hassan Ismail

Theses and Dissertations

Results from laboratory experiments on conservative density current confluence are reported. Hydraulic characteristics and morphodynamic consequences of the confluence of two continuous release density currents in a horizontal, 45 degree asymmetrical junction are examined and compared to those of terrestrial river junctions. It was observed that density current confluence is markedly different than those in river junctions primarily due to the ease of the dense fluid to convect into the ambient fluid in the junction zone. Upward convection in the junction resulted in low horizontal velocity and shear stresses on the bed of the junction zone, followed by re-plunging to …

Development Of Ultra-Low Loading Of Compressive Pt Lattice Cathode Catalyst On Highly Stable Support For Pemfc Automotive Applications, Tianyuan Xie

Theses and Dissertations

The major barriers in the commercialization of the fuel cell technology for automotive applications are the cost and durability of the Pt catalyst and the support stability at high potentials. The U.S. Department of Energy (DOE) targets direct hydrogen fuel cell systems for transportation to meet 65% peak-efficiency, 5,000 hour durability with a mass production cost of $40/kW by 2020. Currently in 2015, the system can be operated at peak energy efficiency of 60% for 3,900 hours with cost of $55/kW. To meet these targets, precious metal loadings must be greatly reduced without altering the catalyst stability. The primary objective …

Bio-Inspired Design Of Mechanical Band Pass Sensor With The Ability To Scavenge Energy, Md Riaz Uddin Ahmed

Theses and Dissertations

Primary objective of this work is to introduce the multi-scale computational model for the bio-inspired acousto-ultrasonic band pass sensor that are capable of mechanically sense and/or filter wide range user defined frequencies. Selecting a particular and/or a distinct band of frequencies is essential for many applications in science engineering and technologies. For example design of sensors in chemical, biomedical and biological applications; device application for acoustic modulation by breaking the acoustic reciprocity and the sensors used in precision manufacturing applications requires sensing and/or filtering of wide range of acousto-ultrasonic frequencies. Presently, electronic devices are widely employed in commercial applications for …

Numerical And Experimental Investigations Of Dam And Levee Failure, Ezzat Youssef Elhassan Mohamed Elalfy

Theses and Dissertations

Both numerical and experimental investigations are conducted to study the failure of earthen dams and levees. Boussinesq equations describing one-dimensional unsteady flow including non-hydrostatic pressure distribution are solved numerically along with Exner equation for the sediment mass conservation to include the effects of the streamline curvature on the failure of non-cohesive earthen embankments. In addition, the effects of the steep bottom slope on the flow variables during the failure are studied by solving the Saint- Venant equations modified for steep bed slope along with the Exner equation to simulate non-cohesive earthen embankment failure due to overtopping. The Boussinesq equations are …

Dielectric Characteristics Of Microstructural Changes And Property Evolution In Engineered Materials, Jallisa Janet Clifford

Theses and Dissertations

Heterogeneous materials are increasingly used in a wide range of applications such as aerospace, civil infrastructure, fuel cells and many others. The ability to take properties from two or more materials to create a material with properties engineered to specific needs is always very attractive. Hence engineered materials are evolving into more complex formulations or heterogeneities in multiple disciplines. Design of microstructure at multiple scales controls the global functional properties of these materials and their structures. However, local microstructural changes do not directly cause a proportional change to the global properties (such as strength and stiffness). Instead, local changes follow …

Nd − Pdpa: N Dimensional Probability Density Profile Analysis, Arjang Fahim

Theses and Dissertations

Proteins are often referred as working molecule of a cell, performing many structural, functional and regulatory processes. Revealing the function of proteins still remains a challenging problem. Advancement in genomics sequence projects produces large protein sequence repository, but due to technical difficulty and cost related to structure determination, the number of identified protein structure is far behind. Novel structures identification are particularly important for a number of reasons: they generate models of similar proteins for comparison; identify evolutionary relationships; further contribute to our understanding of protein function and mechanism; and allow for the fold of other family members to be …

Thin Film Based Biocompatible Sensors For Physiological Monitoring, Yihao Zhu

Theses and Dissertations

The development and evolution of physiological sensors, from wearable to implantable, has enabled long term continuous physiological monitoring, making possible for the out-of-clinic treatment and management of many chronic illnesses, mental health issues and post-surgery recovery. This technology advance is gradually changing the definition of health care and the way it is delivered, from clinic/emergency room to patient’s own environment. In this dissertation, three general types of sensors have been proposed for physiological monitoring of blood pressure, oxygen content and electrolyte ion concentration level in human body, respectively. The study proved the device concepts and shows promising results with the …

Heat Integration Of An Aniline Production Process To Optimize Cost Savings And Reduce Energy Usage, Dillon Ashby

Senior Theses

The purpose of this project was to individually complete a heat integration optimization for my group’s senior design project, a process for the large-scale production of aniline.

New Design Of Nasogastric Decompression Tube That Incorporates A Self-Cleaning Brushing Mechanism, Nichole Abla, Lindsay Rucker, Paige Schroder

Senior Theses

Many hospitalized patients require the removal of secretions that accumulate in the stomach and must be removed by a nasogastric tube, which unfortunately clogs often. This project outlines the redesign of the nasogastric tube that will ideally prevent nasogastric tube clogging by incorporating a brush mechanism and a contracting tip mechanism, to act as preventative measures against clogging.

Project Labyrinth: Exploration Of Modulating Guitar Signals, Joseph Andrews, Andrew Patterson

Senior Theses

The overall objective of this project is to create a guitar pre-amplifier in the casing of an effects pedal. The pedal must be able to modulate amplitude and pitch. More specifically, the design for this pedal will include floating frequency filtering, phase shifting, and amplitude modulation.

Evoking History Through Sound: A Soundscape Concept For Ghosts Of The Horseshoe, Connor Patrick Bain

Senior Theses

Sound has always been treated as a second citizen in our society. Our society places so much emphasis on the visual that hearing, a sense that we cannot ever shut out from our minds, is taken for granted. This thesis argues that you can never ignore sound and proposes a design cycle for creating a soundscape for a critical interactive, then implementing that cycle for "Ghosts of the Horseshoe."

Experimental Study Of Longitudinal Sorting Of Particles Differing In Size And Density, Nabila Mahjabeen

Theses and Dissertations

Transport, deposition and erosion of sediment particles differing in size, shape and density may result in particle segregation, which in geosciences applications is generally referred to as sediment sorting. A thorough understanding of sediment sorting processes is important to describe and model a wide variety of natural processes such as the decrease in particle size and/or density in a fluvial system (downstream fining and/or lightening), the formation of economic placers, concentration of heavy minerals, chemical and metal pollutants etc. Sorting of sediment grains associated with sediment transport in the streamwise direction results in the development of longitudinal sorting patterns. Vertical …

Quantification Of The Effect Of Tool Geometric Features On Aspects Of Friction Stir Welding, Md. Reza-E-Rabby

Theses and Dissertations

In the friction stir welding (FSW) process, tool stirring and synchronized movement of the weld materials along a pre-existing seam line causes thermal gradients and severe plastic deformation resulting in the bonding of the adjacent materials. For a given set of welding parameters, tool pin geometries (dimensions, shape) and vertical/helical features that dictate the material motion also have significant effects on process response variables during FSW. Among the primary process controlling parameters in FSW, tool pin geometry and feature vary multifariously in terms of shape, dimensions, feature insertion technique depending on the weld material and application of joint. The current …

Design Of Experiments Analysis Of Non-Standard Inputs For The Optimization Of Friction Stir Welding, Ryan Widejko

Theses and Dissertations

The purpose of this study was to use non-standard Design of Experiments (DoE) inputs in Friction Stir Welding (FSW) to deduce relationships between various weld input and response variables. Typically, inputs for FSW DoE are tool rotational speed, welding speed and forge force. In this study, three different input factors were investigated: travel speed, thermal boundary conditions (TBC), and advance per revolution (APR). The experimental design included a full factorial with each factor at two levels plus two centerpoint runs. Response variables included weld temperature, microstructure, hardness, power, weld energy, and in plane forces.

An investigation of the effect of …