Engineering Commons^™

The Role Of Zinc Particle Size And Loading In Cathodic Protection Efficiency, Qiang Wang

Theses and Dissertations

Metallic additives, also known as anticorrosive pigments, can provide sacrificial cathodic protection and complement the barrier protection afforded by heterogeneous organic coatings to metallic substrates. The unique systematic study of the corrosion resistance of an epoxy coating reinforced with different sizes (80nm, 500nm, 10um) and continuous multiple pigment volume concentration (0, 2%, 10%, 20%, 45%) below global critical pigment volume concentration of zinc particles were studied. The thesis is developing the fundamental understanding to optimize corrosion protection and predicting the protection with time. The properties of these cathodic coatings were investigated by a single-frequency electrochemical impedance spectroscopy (EIS) and open …

Durability Of Reinforced Concrete Incorporating Crushed Waste Brick As Coarse Aggregate, Matthew Adamson

All Theses

Using crushed bricks as aggregates in concrete is of particular interest to preserve natural aggregate sources as well as to reduce waste, as it has been estimated that 10% to 30% of all waste in landfills in the united States comes from construction and demolition wastes. By recycling some of these wastes, the sustainability of a project can be improved. However, it is important concrete incorporating these wastes is as durable or more durable then conventional concrete, or will it have a shorter service life. Durability of concrete is its ability to resist deterioration from its external environment such as …

Study On Corrosion Activity Of Carbon Steel In Concrete Simulated Pore Solution Under Static Tensile And Compressive Stresses, Yujie Zhang

All Theses

Reinforced concrete is a structure material made up of concrete with relatively lower tensile strength containing reinforcements with higher tensile strength and better ductility, which are embedded into fresh concrete to resist tensile stress in certain regions of concrete. Steel reinforced concrete is most widely used around the world in civil engineering structures, water conservancy and highway construction due to its durability strength and reasonable cost.
However, reinforced concrete structures such as bridges and parking lots slabs inevitably experience variable loads and constant degradation from the aggressive environments, such as marine and deicing salts. Therefore, it is imperative to study …

Evaluation Of Corrosion Properties For Use Of Az31b In Bioabsorbable Stents And In Vivo Corrosion Rate Prediction Using Fea, Jared Vidales, Austin Schader, Jenna Jerman, Michael Turovskiy

Materials Engineering

AZ31B was heat treated to evoke more controlled and uniform corrosion. 1/16” diameter AZ31B wire was cut into six samples each 1” long. The samples underwent heat treatments following ASTM B661-06. Samples were weighed and placed into three different in vitro environments. In the first scenario two samples of each heat treatment were individually placed in 50 ml of saline solution at 0.9% sodium, in a static test tube at 37°C temperature. Two samples were placed in 100 ml of 0.9% saline solution in a 250 ml stirring beaker with an average whirlpool depth of 1”. Two of each sample …

Corrosion Of Stainless Steel 316l And Astm F75 Cobalt Chromium Alloy During Immersion Testing In Silver Salt Solutions, Meagan Higgins

Materials Engineering

This study evaluates the potential effects of silver salts on biocompatible metals used for prostheses during the chemical reduction process to produce a silver antimicrobial layer on the metal’s surface. Samples of two biocompatible metals were obtained: Stainless Steel 316L and ASTM F75 Cobalt Chromium Alloy. Three different silver salts were also acquired: silver nitrate, silver sulfadiazine, and silver chloride. Specimens of each metal were cut to size using a 4-1/2 inch aluminum oxide, 40 grit, cut off wheel for metal, attached to a Dewalt Angle Grinder. The biocompatible metal samples were then subject to either Solution 1, water with …

Analyzing The Corrosion Resistance Of Ni-Shield 200 Coatings At Different Temperatures When Exposed To Sulphuric Acid, Alex Hussinger

Materials Engineering

Six steel samples each were twin wire arc sprayed with Hastelloy C-276 or Nickel-Shield 200 coatings approximately 0.020″ thick. These samples were then cut into 3″ by 3″ squares. A 2″ diamond grit hole saw was used to abrade and polish to a smooth surface a ring in the middle in order to get an O-ring mechanical seal. The samples were then weighed and loaded into a jig that started from the bottom up with a stainless steel plate, then the sample, then a Viton O-ring, a ¾″ thick glass plate with a 1 3/4″ hole cut in it, another …

Evaluating Corrosion Control Alternatives For A Reverse Osmosis, Nanofiltration And Anion-Exchange Blended Water Supply, Rebecca J. Wilder

Electronic Theses and Dissertations

The research reported herein describes the study activities performed by University of Central Florida (UCF) on behalf of the Town of Jupiter Water Utilities (Town). The Town recently changed its water treatment operations from a combination of reverse osmosis (RO), lime softening (LS) and anion-exchange (IX) to a combination of RO, IX and nanofiltration (NF). Although this treatment change provided enhanced water to the surrounding community in terms of better contaminant removal and reduced DBP formation potential, integration of the NF process altered finished water quality parameters including pH, alkalinity and hardness. There was concern that these changes could result …

Rare Earth Oxide Coating With Controlled Chemistry Using Thermal Spray, Virendra Singh

Electronic Theses and Dissertations

Cerium oxide (Ceria) at nano scale has gained significant attention due to its numerous technological applications. Ceria in both doped and undoped forms are being explored as oxygen sensor, catalysis, protective coating against UV and corrosion, solid oxide fuel cell (SOFC) electrolyte and newly discovered antioxidant for biomedical applications. Therefore, there is an imminent need of a technology which can provide a cost effective, large scale manufacturing of nanoceria and its subsequent consolidation, specially using thermal spray. This dissertation aims to develop a scientific understanding towards the development of pure and doped ceria- based coating for a variety of technological …

The Effects Of Uncommon Silicides On The Oxidation Of Alloys From The Nb-Cr-Si System, Daniel Brendan Voglewede

Open Access Theses & Dissertations

Niobium based alloys are being tapped as potential successors to current nickel base superalloys in high temperature applications. In the aerospace industry, high temperature materials are constantly being pushed to higher temperature regimes in order to improve engine efficiency however current superalloys cannot be pushed further due to melting temperature limitations. Niobium, being a refractory metal, can withstand much higher temperatures than nickel however its oxidation properties are woefully inadequate.

The purpose of this study is to ascertain whether increased silicon additions can improve niobium oxidation properties by: forming ternary silicides with better oxidation properties and by preventing the formation …

Encapsulation Of High Temperature Phase Change Materials For Thermal Energy Storage, Rupa Nath

USF Tampa Graduate Theses and Dissertations

Thermal energy storage is a major contributor to bridge the gap between energy demand (consumption) and energy production (supply) by concentrating solar power. The utilization of high latent heat storage capability of phase change materials is one of the keys to an efficient way to store thermal energy. However, some of the limitations of the existing technology are the high volumetric expansion and low thermal conductivity of phase change materials (PCMs), low energy density, low operation temperatures and high cost. The present work deals with encapsulated PCM system, which operates at temperatures above 500°C and takes advantage of the heat …

Strengthening Of Reinforced Concrete Beams Pre-Damaged In Shear, Yousef Mohammed Bachar Chekfeh

Theses

Repair and strengthening of existing reinforced concrete (RC) structures has increased drastically in recent years. Shear reinforcement in RC beams is typically of a small bar diameter, and hence any shear-damage would result in a severe safety hazard and a catastrophic mode of failure especially under extreme loading events. The present work was initiated to the effectiveness of different composite strengthening systems; namely externally bonded carbon fiber reinforced polymer (EB-CFRP), and near surface mounted glass fiber reinforced polymer (NSM-GFRP) to prolong the functional service life of RC beams pre-damaged in shear. It comprised experimental testing and analytical investigation.

The experimental …