Engineering Commons^™

Thermography Detection On The Fatigue Damage, Bing Yang

Doctoral Dissertations

It has always been a great temptation in finding new methods to in-situ “watch” the material fatigue-damage processes so that in-time reparations will be possible, and failures or losses can be minimized to the maximum extent. Realizing that temperature patterns may serve as fingerprints for stress-strain behaviors of materials, a state-of-art infrared (IR) thermography camera has been used to “watch” the temperature evolutions of both crystalline and amorphous materials “cycle by cycle” during fatigue experiments in the current research.

The two-dimensional (2D) thermography technique records the surface-temperature evolutions of materials. Since all plastic deformations are related to heat dissipations, thermography …

Effects Of Environment And Frequency On The Fatigue Behavior Of The Spallation Neutron Source (Sns) Target Container Material - 316 Ln Stainless Steel, Hongbo Tian

Doctoral Dissertations

As the candidate target container material of the new Spallation Neutron Source (SNS) being designed and constructed at the Oak Ridge National Laboratory (ORNL), 316 low-carbon nitrogen-added (LN) stainless steel (SS) will operate in an aggressive environment, subjected to intense fluxes of high-energy protons and neutrons while exposed to liquid mercury. The SNS is an accelerator-based neutron source that provides pulsed beams of spallation neutrons by bombarding a mercury target with 1 GeV protons. The function of the SNS is to convert a short pulse (< 1 ms, 60 Hz, 17 kJ/pulse), high-average-power (1 MW), 1-GeV proton beam into 18 lower-energy (< 1eV), short-pulsed (~ tens of ms) neutron beams optimized for use by neutron-scattering instruments.

The current project is oriented toward materials studies regarding the effects of test environment …

Integrated Field Emission Electron Guns With Single Vertically Aligned Carbon Nanofiber Cathodes, Michael Alberto Guillorn

Doctoral Dissertations

Nanostructured carbon-based materials hold great promise as field emission (FE) cathodes for integrated FE devices. These materials display remarkable FE properties as a consequence of their unique chemical and physical properties. Among this class of materials, the vertically aligned carbon nanofiber (VACNF) is exceptional in that its synthesis can be deterministically controlled. This has enabled the characterization of the FE properties of individual VACNF grown on Si substrates. The results of these studies indicate that the VACNF is an excellent candidate for integrated FE electron sources where the generation of a focused electron beam from a microscale structure is required. …

Hot Melt Inks For Rotogravure-Formulation, Printability And Rheology, Hrishikesh Shreeram Bhide

Masters Theses

A new generation of "Hot melt inks for Rotogravure" was formulated. They melt during heating and reach printable viscosity between 75° C and 130° C, depending on formulation. After printing onto substrate, they solidify. Selections of the best formulations were done based on ink rheology, and print analysis. The formulated inks were also printed on the Moser sheet-fed proofing press .. The rheological data indicated that hot melt inks (without viscosity modifier) have viscosity in the range of 10°-10¹ Poise at 95°C. After printed on a laboratory gravure K-Proofer, the inks showed good reflective density (0.90 - Yellow, 1.30 …

Investigation Of Electrical Properties And Structure Of Vacuum Evaporated C60 Films, Angiras D. Pandya

Masters Theses

C₆₀ is an important electronic material and its properties can be tuned by thermal annealing process and solid phase crystallization process. These properties were investigated as a function of thermal annealing temperature and solid phase crystallization. However there is no systematical study on annealing effect and Solid Phase Crystallization of C₆₀ films. In this study, the effect of thermal annealing on formation of nanocrystalline C₆₀ thin films were investigated for annealed samples and solid phase crystallized samples. The C₆₀ films described here were prepared by vacuum thermal evaporation method. The structural properties of C₆₀ films …

Design Of Asphalt Concrete Mixtures For Pavement Maintenance And Rehabilitation, Mubarak Bakheet Gaith Al-Falahi

Theses

The main objective of the thesis is to develop a knowledge base for the design of asphalt concrete mixtures suiting various types and causes of pavement distress and to develop supporting guidelines for the selection of aggregate types, gradation and binder contents for desirable mixture properties.

To achieve this objective, a two-level model was developed. The upper-level is a Factorial Experimental Design Model (FEDM) for the pavement condition evaluation. It can be used as a prediction tool to estimate the Pavement Condition Index (PCI), and determine the percentages of the types of distresses (Load, Environmental, Others). The upper-level model was …

The Effect Of Non-Stoichiometry On The Structure Of La-Ni And La-Ni-Ga Alloys, Pertrice Auguste Wethey

Masters Theses

Non-stoichiometric samples of the AB₅ system defined by the formula La_1-yNi_5+2y and LaNi_5+2xGa_1-x were cast using an arc-melting furnace. The samples were then analyzed to determine their lattice parameters and phases present using XRD. They were then heat-treated to produce homogeneous compounds and quenched with the intention of retaining high temperature compositions. Following the heat-treatment, the alloys underwent XRD again as well as SEM/EDS. The XRD information was analyzed using Rietveld refinement and the elemental data derived from the EDS was used to ascertain the compositions were statistically akin to the weighed values. …

Controlled-Stress Large-Area Pulsed Laser Deposition Of Yttria Stabilized Zirconia, Paul C. Rounsavall

Theses and Dissertations

The US Air Force has need of parabolic-shaped membrane mirrors for surveillance satellites. The current polymer membrane technology has been unable to overcome shape deformation problems caused by intrinsic stresses from the membrane casting and mounting processes. One proposed solution was to coat the membrane mirrors with a stressed coating to compensate for shape deformations. Thus, the research presented in this dissertation produced controlled-stress large-area pulsed laser deposition (PLD) grown thin films on polymer substrates and investigated optical time-of-flight (TOF) sensor systems and Raman spectroscopy for control for the PLD process with respect to thin film stress. Initially, the PLD-grown …

Rheology Of Lyocell Solutions From Different Cellulosic Sources And Development Of Regenerated Cellulosic Microfibers, Zuopan Li

Doctoral Dissertations

The primary goals of the study were to develop manufactured cellulosic fibers and microfibers from wood pulps as well as from lignocellulosic agricultural by-products and to investigate alternative cellulosic sources as raw materials for lyocell solutions. A protocol was developed for the lyocell preparation from different cellulose sources. The cellulose sources included commercial dissolving pulps, commercial bleached hardwood, unbleached hardwood, bleached softwood, unbleached softwood, bleached thermomechanical pulp, unbleached thermomechanical pulp, bleached recycled newsprint, unbleached recycled newsprint, bagasse and kudzu.

The rheological behavior of solutions was characterized. Complex viscosities and effective elongational viscosities were measured and the influences of parameters such …

Effect Of Modified Clay-Zeolite Pigment On The Viscoelastic, Optical, And Printing Properties Of A Lwc Gravure Coating, Lokendra Pal

Masters Theses

This study investigates the influence of modified clay- zeolite pigment on the viscoelastic, optical, and printing properties of a LWC coating. Currently, lightweight, coated papers have experienced problems with mottle, distortion, fiber puffing and poor print quality when printed with water-based inks. However, water-based inks represent a proven solution to reducing volatile organic compound (VOCs) emissions. Poor wetting and ink spreading on the paper surface constitute the majority of print quality issues associated with the water-based printing of LWC papers.

Similar problems are encountered during the printing of ink jet papers due to high percentage of water contained in these …

The Localized Corrosion Behavior Of 6% Mo And 316l Stainless Steels In Chloride Media And The Effect Of Applied Mechanical Stress, Houssam El-Din Sabry Ahmed

Archived Theses and Dissertations

Electrochemical techniques were applied to study the crevice corrosion resistance of two types of stainless steel alloys namely, conventional 316L and super austenitic 6% Mo in acidified 3% NaCl solution at room temperature. Potentiodynamic results showed that 6% Mo alloy possessed a remarkable resistance to crevice corrosion compared to 316L alloy when tested in the same solution. The breakdown potential at which passivity broke down for 316L alloy was 0.00 m V, SCE, the corresponding value for 6% Mo alloy could not be reached up to the potential value of 700 m V, SCE. 316L alloy suffered extremely from crevice …

Assessment Of The Readiness Of Egyptian Companies To Implement Business Process Reengineering Programs, Hany Waguih Shoukry

Archived Theses and Dissertations

Business Process Reengineering (BPR) emerged as a performance improvement methodology in 1990. Its objective of radical process redesign to achieve dramatic performance improvements makes it a potential candidate to be applied in most Egyptian companies, especially in the Egyptian private sector that is struggling to upgrade its performance in the new global economy. Although the main problem of BPR is its high probability of failure, which is due to the failure of companies to fulfill all BPR prerequisites, very limited research exists on how to measure the readiness of a company to implement successful BPR programs. The current research addresses …

The Effectiveness Of Sacp In Controlling Of Concrete Steel Reinforcement In Aggressive Environments, Hassan Ali Abubaker Al Jafri

Theses

The Arabian Gulf is considered to be one of the world's most aggressive environments for reinforced concrete. Traditional methods of corrosion protection may not be enough to provide the required level of corrosion control for the design life of concrete structures in such environments.

Cathodic protection has been found as a viable technique of inhibiting chloride induced corrosion of steel in concrete structures. As an alternative to impressed current cathodic protection ICCP a remarkable developments recently have been made in the application of sacrificial anode cathodic protection as a means of enhancing the performance of patch repair.

The main objective …

Paints And Their Environmental Impacts On Human Health In The U.A.E, Masara Y. Al-Ameri

Theses

This thesis records the findings of a research program related to "Paints and Their Environmental Impacts on Human Health in the U.A.E". The study recommends attempt to find out what paint types are of a less harmful influence on human health within different building types in United Arab Emirates due to environmental conditions.

According to Larry W. Canter (1997) "Environmental Impact Assessment" can be defined as "the systematic identification and evaluation of the potential impact (effects) of proposed projects, plans, programs, or legislative actions relative to the physical- chemical, biological, cultural, and socioeconomic components of the total environment. The primary …

Assessment Of The Performance Of Shape Memory Alloys As Implant Devices, Noura Ali Al-Khalifi

Theses

Shape memory alloys are one class of the family of smart materials. They are considered as biomaterials, since they are well accepted by the human body. One special feature of shape memory alloys (SMA) is their ability to revert to their previous shape. This material is deformed at low temperature and when it is heated, it returns (remember) to its original form. Although, the implant binary NiTi SMA is particularly successful as a biomaterial, our NiTi SMA consist of more that 50% (55.7%) of nickel. The main purpose of this thesis was to evaluate the biological response of the shape …

Effects Of Implementation Of Decaborane Ions In Silicon, Cheng Li

Dissertations

The next generations of Si microelectronic devices will require ultra shallow p-type junctions formed by implantation of B ions with energies below 1 keV, at which available beam currents are severely limited by space charge effects. To solve this problem, decaborane (B₁₀H₁₄) cluster ion implantation has been suggested as an attractive alternative to conventional B implants, because one decaborane ion implants ten B atoms simultaneously and each of the B atoms only carries approximately 1/11 of the total ion energy. Thus the same implantation depth and dose as with monomer B ions can be obtained using …

Process-Structure-Property Relationship Of A Mesogenic Bioerodible Polyarylate, Seung Uk Yoo

Theses

Polymeric biomaterials are artificially synthesized polymers designed for in-vivo use. The material must be characterized and should satisfy the requirements suitable in human bodies.

For the proper characterization of materials, it is essential to apply specific processes, analyze thermal and mechanical properties, and understand the process effect and the morphology. Thermal analysis is one of the most sophisticated and well developed techniques for polymer characterization. Turi [ 1 ] has explained about the thermal characterization of polymeric materials. Jaffe et al [2], in the chapters of characterization of fibers and films, emphasized the effect of the process history of a …

Effects Of Diabetes And Aging On Posture And Acceleration Thresholds During Lateral Translations, Samantha Jean Richerson

Doctoral Dissertations

Research objectives. One source of falls in the elderly may be an inability to sufficiently adjust to transient postural perturbations or slips. Identifying useful predictors of fall potential, as well as factors that affect the ability of an individual to detect a movement of the standing support surface may provide insight into postural stability and methods to increase stability in elders. To do this, acceleration thresholds to short, precise, lateral platform translations and the resultant psychophysical responses of adults with early Type 2 diabetes to age-matched controls and young adults were measured.

Methods. Using an innovative SLIP-FALLS platform, …

Dynamics Of Phase Transitions On Low-Index Metal Surfaces, Bo Lin

Electrical & Computer Engineering Theses & Dissertations

The surface superheating and phase transitions at the low-index surface of metal were investigated using conventional continuous and 100-ps time-resolved reflection high-energy electron diffraction. Three metal surfaces, In(111), Au(110) and Pb(111), have been investigated in this work. The high temperature behavior of the In(111) surface was investigated using reflection high-energy electron diffraction with 100-ps temporal resolution. The change of surface vacancy density on In(111) is observed from 300 K to near the bulk melting point. The vacancy-formation energy of In(111) surface is estimated from experimental results. The surface vacancy density is observed to increase with temperature; however, the average random …

Field Emission Based Sensors Using Carbon Nanotubes, Changkun Dong

Physics Theses & Dissertations

A number of sensitive applications would be greatly benefited by the development of better cold cathodes that employ the electron field emission process. Among the many kinds of field emitters that could be tried, carbon nanotubes (CNT) have a number of distinct advantages because of their unique geometrical structure, chemical inertness, mechanical stiffness, and high thermal and electrical conductivities. This dissertation describes research in which CNT cathodes were fabricated and their emission characteristics were measured.

Multi-walled carbon nanotubes (MWNT) were grown by chemical vapor deposition (CVD) on various substrates: Ni and Hastelloy gauze, 304 stainless steel (SS) plates, and Ni-coated …

Electrical Activation Studies Of Silicon Implanted Alx Gal-X N And Coimplanted Gan, Elizabeth A. Chitwood

Theses and Dissertations

A comprehensive study of the electrical activation of silicon implanted Al_xGa_1-xN was performed as a function ion dose, anneal temperature, and aluminum mole fraction, Also, GaN coimplanted with silicon and nitrogen was investigated. Room temperature Hall effect measurements were used to determine carrier concentration and mobility. All the samples had a 500 Å encapsulant of AlN, and were implanted at room temperature with 200 keV silicon ions at doses ranging from 1x10¹³ to 1x10¹⁵ /sq cm. The GaN was also implanted with nitrogen under the same conditions in doses of 9x10¹² to 9x10 …

Luminescence Studies Of Ion-Implanted Gallium Nitride And Aluminum Gallium Nitride, Erin N. Claunch

Theses and Dissertations

Recently, research on the wide bandgap semiconductors such as GaN and Al(x)Ga(1-x)N became very popular for their applications on various devices. Therefore comprehensive and systematic luminescence studies of Si implanted Al_xGa_1-xN, Mg doped GaN, and Si+N implanted GaN grown on sapphire substrates by molecular beam epitaxial method have been made as a function of ion dose and anneal temperature.

A Feasibility Study Of A Surface Modification Method For Polyolefin Plastics Formed By Injection Molding, David Brian Naughton

Master's Theses and Doctoral Dissertations

Polyolefin plastic (i.e. polypropylene, polyethylene, thermoplastic olefin i.e. TPO and blends) articles formed by injection molding have been found to have many useful applications. Many costly and/or hazardous methods are employed to increase the surface energy to a level that promotes the ability of a coating or adhesive to make intimate contact and thereby bond to the molded surface. The method described herein refers to a process that could eliminate the need for a post molding process such as solvent or waterborne adhesion promoting primers or expensive, hazardous surface treatment equipment by modifying the plastic surface during the injection molding …

Characterization And Corrosion Of Bcc-Tantalum Coating Deposited On Aluminum And Steel Substrate By Dc Magnetron Sputtering, Chirag Joshi

Theses

Tantalum is one of the most versatile highly refractory corrosion-resistant metals. Tantalum coating can be used as an effective corrosion barrier if it is continuous, free from defects and it adheres well to the substrate. A DC magnetron sputtering technique was used to deposit tantalum on aluminum and steel. X-ray diffraction measurements revealed that the tantalum films produced by sputtering had two crystallographic structures: a body centered cubic α-phase and a metastable tetragonal β-phase. Tough and ductile alpha phase tantalum is preferred over the hard and brittle beta phase tantalum, as a protective coating. Alpha phase coatings were successfully deposited …

In Situ Laser Etch-Depth Monitoring Of The Deep Reactive Ion Etching Process, Yuki Imura

Theses

A laser-based method for measuring feature thickness during the deep reactive ion etching process is investigated. Interference occurs between laser beam reflections from the mask surface, the mask/silicon interface, and the exposed silicon surface of a process wafer. Information from this interference signal allows the etch process to be characterized. Three methods are investigated: laser-on-SiO₂, laser-on-photoresist, and laser-on-both SiO₂ and silicon at a mask edge.

The measured data from these experiments are found to be in good agreement with theoretical calculations. Differences in reflected beam amplitude and interference fringe frequency represent well the differences SiO₂ and …

Reaction Control In Quiescent Systems Of Free-Radical Retrograde-Precipitation Polymerization, Vijaya Raghavan Tirumala

Dissertations, Master's Theses and Master's Reports - Open

Free-radical retrograde-precipitation polymerization, FRRPP in short, is a novel polymerization process discovered by Dr. Gerard Caneba in the late 1980s. The current study is aimed at gaining a better understanding of the reaction mechanism of the FRRPP and its thermodynamically-driven features that are predominant in controlling the chain reaction.

A previously developed mathematical model to represent free radical polymerization kinetics was used to simulate a classic bulk polymerization system from the literature. Unlike other existing models, such a sparse-matrix-based representation allows one to explicitly accommodate the chain length dependent kinetic parameters.

Extrapolating from the past results, mixing was experimentally shown …

Chemical Bonding In Hard And Elastic Amorphous Carbon-Nitride Films, W. Jason Gammon

Dissertations, Theses, and Masters Projects

In this study, the chemical bonding in hard and elastic amorphous carbon nitride (a-CNx) films is investigated with x-ray photoelectron spectroscopy (XPS) and 15N, 13C, and 1H nuclear magnetic resonance (NMR) spectroscopy. The films were deposited by DC Magnetron sputtering in a pure nitrogen discharge on Si(001) substrates at 300--400??C. Nanoindentation measurements reveal an elastic modulus of ∼50 GPa and a hardness of ∼5 GPa, thus confirming our films are highly elastic but resist plastic deformation.;Our 13C NMR study demonstrates the absence of sp 3-bonded carbon in this material. Collectively, our N(1s) XPS, 13C NMR, and 15N NMR data suggest …

Thermal Assessment Of Silicon-Based Composite Materials Used In Photovoltaics, Pavlos K. Bataglannis

Theses

Photovoltaics are devices that convert sunlight directly to electricity. It is well established that the conversion efficiency of mono and poly-crystalline silicon-based photovoltaic modules is inversely related to their temperature. Substantial improvements in operational performance can thus be achieved if the thermal energy accumulating in the material can be effectively dissipated.

Accurate modelling of modules would allow possible methods of thermal dissipation to be evaluated, and as a crucial component of the model, the thermal properties of the constituent materials of PV modules needed to be known. Special consideration needed to be given to the interfaces between dissimilar materials and …