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Tailoring Optical And Plasmon Resonances In Core-Shell And Core-Multishell Nanowires, Sarath Ramadurgam
Tailoring Optical And Plasmon Resonances In Core-Shell And Core-Multishell Nanowires, Sarath Ramadurgam
Open Access Dissertations
Semiconductor nanowires (NWs) are sub-wavelength structures which exhibit strong optical (Mie) resonances in the visible range. In addition to such optical resonances, the localized surface plasmon resonances (LSPR) in metal and semiconductor (or dielectric) based core-shell (CS) and core-multishell (CMS) NWs can be tailored to achieve novel negative-index metamaterials (NIM), extreme absorbers, invisibility cloaks and sensors. Particularly, in this dissertation, the versatility of CS and CMS NWs for the design of negative-index metamaterials in the visible range and, plasmonic light harvesting in ultrathin photocatalyst layers for water splitting are studied.
Utilizing the LSPR in the metal layer and the magnetic …
Preparation Of Mesoporous Silica Supported Ruthenium Oxides And The Application And Kinetic Study In The Catalysis Of Water Oxidation, Yang Zhang
Open Access Dissertations
Photo-induced water splitting of water into H2 and O2 has been a major focus in the development of clean and renewable energy. The development of viable and efficient catalysts that facilitates O2 production remains the major challenge in the study of the corresponding half-reaction of water oxidation. There are plenty of metal oxides reported active in the catalysis of water oxidation. However, several important performance bench marks of those materials, such as the non-stoichiometric production of O2, slow reaction rate and/or low quantum efficiency, remain to be improved.
Ruthenium oxide (RuO2) has long been known as one of the most …