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Hydraulic And Electrokinetic Delivery Of Remediants For In-Situ Remediation, Ahmed I. A. Chowdhury
Hydraulic And Electrokinetic Delivery Of Remediants For In-Situ Remediation, Ahmed I. A. Chowdhury
Electronic Thesis and Dissertation Repository
Nano-scale zero valent iron (nZVI) has shown promising mobility and in-situ reactivity with chlorinated volatile organic compounds when injected into saturated porous media. The current study evaluated nZVI mobility and subsequent reactivity with in-situ contaminants in a variably saturated porous media. The nZVI particles, synthesized onsite at subzero temperatures, demonstrated complete trichloroethene (TCE) degradation within the target area. Furthermore, a three dimensional finite difference model (CompSim) was utilized to investigate nZVI mobility in variably saturated zones. Model predicted well head data were in very good agreement with field observations. Simulation results showed that the injected slurry migrated radially outward from …
Field Scale Application Of Nanoscale Zero Valent Iron: Mobility, Contaminant Degradation, And Impact On Microbial Communities, Chris M.D. Kocur
Field Scale Application Of Nanoscale Zero Valent Iron: Mobility, Contaminant Degradation, And Impact On Microbial Communities, Chris M.D. Kocur
Electronic Thesis and Dissertation Repository
This thesis began by verifying that nanoscale zero valent iron (nZVI) synthesis methods could be scaled up and implemented at the field scale in a safe manner. This led to successful demonstration of nZVI injection and mobility under constant head gravity injection into a contaminated utility corridor in Sarnia, Ontario. Where field studies have fallen short in the past was linking the somewhat qualitative field geochemical parameters to other evidence of nZVI transport. Definitive nZVI detection was elusive in previous field studies due to the highly reactive nature of the particles caused by their high surface area. nZVI was detected …