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Optically Driven Ph Gradient Generator Based On Self-Assembled Proton Pumps For Activating Hydrogel Microactuators, Khaled M. Al-Aribe

Electronic Thesis and Dissertation Repository

This dissertation presents a new approach for developing a biologically inspired photo-electro-chemo-mechanical microactuator by exploiting the ion pumping characteristics of bacteriorhodopsin (bR) proton pumps and the pH sensitivity of smart hydrogels. The ultimate goal of this project is to prove the viability of integrating bR monolayer into novel actuation applications using molecular level architectures. To accomplish this, the bR proton pumps are molecularly labelled, organized, and directionally immobilized on Au-coated substrate, and then integrated with pH sensitive hydrogel. When responding to an incident light beams, the internal proton pumping mechanism is mathematically modeled for quantifying the processing of the photonic …