Engineering Commons^™

Doping Plasmon-Enhanced Tio2 With Zirconia To Improve Solar Energy Harvesting In Dye-Sensitized Solar Cells, Anastasia Pasche

Electronic Thesis and Dissertation Repository

Solar energy is a promising solution towards meeting the world’s ever-growing energy demand. Dye-sensitized solar cells (DSSCs) are hybrid organic-inorganic solar cells with potential for commercial application, but are plagued by inefficiency due to their poor sunlight absorption. Silver nanoparticles have been shown to enhance the absorptive properties of DSSCs, but their plasmonic resonance causes local hot spots, resulting in cell deterioration. This thesis studies the mitigation of thermal energy loss of plasmon-enhanced DSSCs by the co-incorporation of zirconia, a well-known thermostabilizer, into the cell’s photoactive material. TiO2 was also synthesized using green bio-sourced solvents in supercritical CO2 to compare …

Inkjet Printed Thin Film Electrodes For Lithium-Ion Batteries, Stephen D. Lawes

Electronic Thesis and Dissertation Repository

With the miniaturization of wireless electronics, the demand for ever-smaller energy storage devices has increased. Thin film batteries can meet this need by providing higher energy densities at smaller scales than conventional lithium-ion batteries. However, the fabrication of thin films batteries by vapor deposition methods typically involves expensive equipment and high temperatures, which limits their commercial application. This thesis reports the development of an inexpensive inkjet printing method of fabricating thin film electrodes for thin film lithium-ion batteries. Inks containing various electrode materials were first developed and optimized in terms of physical properties to ensure ideal jetting conditions. Then, thin …

Application Of 3d Printing Technology In Porous Anode Fabrication For Enhanced Power Output Of Microbial Fuel Cells, Bin Bian

Electronic Thesis and Dissertation Repository

Microbial fuel cells (MFCs) are widely researched for application in wastewater treatment. However, the current anodes used in MFCs often suffer from high fabrication cost and uncontrollable pore sizes. In this thesis, three-dimensional printing technique was utilized to fabricate anodes with different micro pore sizes for MFCs. Copper coating and carbonization were applied to the printed polymer anodes to increase the conductivity and specific surface area. Voltages of MFCs with various anodes were measured as well as other electrochemical tests such as linear sweep voltammetry and electrochemical impedance spectroscopy. 3D copper porous anode produced higher maximum voltages and power densities …

Thermal Kinetics Of Ion Irradiation Hardening In Selected Alloys For The Canadian Gen. Iv Nuclear Reactor Concept, Heygaan Rajakumar

Electronic Thesis and Dissertation Repository

Canada is designing supercritical water fission reactors (SCWR) to increase the thermal efficiency of nuclear power generation from ~34% to ~48%. The temperature and pressure of a supercritical water reactor core is very high compared to a CANDU reactor. This thesis examines irradiation hardening and thermal recovery of two candidate alloys, AISI 310 and Inconel 800H, for the Canadian SCWR.

Samples of both alloys are mechanically ground and polished, then irradiated using 8.0 MeV Fe ions. The use of ion irradiation safely and quickly simulates neutron damage. The change in the hardness of the samples is then studied during a …

Application Of Polyurethane Products In Accelerated Construction Of Innovative Noise Barrier, Bahman Daee

Electronic Thesis and Dissertation Repository

Noise barriers (sound walls) are usually constructed along roadways to mitigate the airborne noise emanating from vehicles. They are currently built using various materials including precast concrete panels, masonry, wood and transparent sheets. The main challenge in roadside construction is the obstruction of roadways during the construction, which may result in traffic congestion, public dissatisfaction, car collision and subsequently fatalities. In order to decrease the risk of roadside construction, accelerated and non-obstructive methods are highly preferred by transportation authorities.

An innovative wall system comprised of polyurethane products is proposed, developed and investigated for application in accelerated construction of noise barriers. …

Exploring The Chemistry Of Phosphorus For Photopolymer Applications, Ryan Guterman

Electronic Thesis and Dissertation Repository

Prior to this thesis, phosphorus-containing polymers and photopolymerization represented two distinct, non-overlapping fields of study. This thesis examined the prospect of combining these two approaches to create a system possessing the benefits of both techniques. By exploiting the chemistry of phosphorus, and using photopolymerization as a fabrication method, new materials were developed and assessed for their use in various applications.

Among the many phosphorus compounds that may be used in polymer science, phosphonium salts and primary phosphines were of specific focus. First, highly fluorinated phosphonium monomers were developed to create photopolymerized hydrophobic surfaces. A structure-activity relationship was established, as both …

Synthesis, Characterization And Applications Of Lignin-Based Epoxy Resins, Fatemeh Ferdosian

Electronic Thesis and Dissertation Repository

Epoxy resin is one of the most versatile thermosetting polymers with diverse applications. Epoxy resins are mainly produced from the reaction of bisphenol-A (BPA) and epichlorohydrin. The consumption of bisphenol-A is facing growing concerns over its carcinogenic effects and its sustainability. Lignin can be a promising renewable substitute of bisphenol-A in the synthesis of epoxy resins.

In this thesis work, a novel method has been developed for the synthesis of bio-based epoxy resins with reduced side reactions, employing de-polymerized lignin from organosolv lignin (DOL), kraft lignin (DKL) and hydrolysis lignin (DHL) under alkaline condition in the presence of a phase …

The Effect Of Cutting Blade Geometry And Material On Carbon Fiber Severing As Used In High-Volume Production Of Composites, Michael Francis Anthony Adamovsky

Electronic Thesis and Dissertation Repository

Automotive manufacturers have started to actively look into weight savings options for mass production of vehicles that meet new government regulations. Falling prices of carbon fibers have made carbon fiber composites a promising material to be used. The study has focused on the fiber-severing unit incorporated in a high-volume composite production line in an attempt to better define the impact of blade geometry and material on the wear as experienced while cutting carbon fiber. A method to quantify the effect of usage on the cutting ability of a blade has been developed, as well as methods to measure blade wear. …

Characterization Of High-Pressure-Die-Cast Magnesium Alloy Am60, Hooman Baghaei Anaraki

Electronic Thesis and Dissertation Repository

The primary goal of this study is the characterization of high pressure die cast magnesium alloys AM60 so that the failure model which is proposed by J.Weiler can be validated for two new castings. The input variables of failure model can be determined by characterization of different regions within the castings. Based on the location of gate system, the desired regions are identified across both castings and tensile specimens are extracted from various regions. Therefore the local mechanical properties are determined, and fracture strain of samples ranges from 1.2 to 9.5%. The area fraction of porosities and skin fraction of …