Engineering Commons^™

Stress Relaxation Cracking In 347h Austenitic Steel Weldments Under Various Heat Treatments: Experiments And Modeling, Yi Yang

Doctoral Dissertations

347H austenitic stainless steel exhibits exceptional creep and corrosion resistance, rendering it an exemplary candidate for pipeline materials, particularly in mid- to high-temperature working conditions. However, due to constraints in component dimensions, welding has been chosen as the preferred method for joining pipeline systems extensively employed in nuclear power plants, fossil fuel plants, and petrochemical companies. The welding process entails the accumulation of residual stress during the cooling stage, along with the introduction of microstructure evolution. Moreover, the residual stress field and microstructure continuously evolve under service conditions, thereby intensifying the susceptibility of crack initiation and propagation. The initial residual …

Atomic-Level Mechanisms Of Fast Relaxation In Metallic Glasses, Leo W. Zella

Doctoral Dissertations

Glasses are ubiquitous in daily life and have unique properties which are a consequence of the underlying disordered structure. By understanding the fundamental processes that govern these properties, we can modify glasses for desired applications. Key to understanding the structure-dynamics relationship in glasses is the variety of relaxation processes that exist below the glass transition temperature. Though these relaxations are well characterized with macroscopic experimental techniques, the microscopic nature of these relaxations is difficult to elucidate with experimental tools due to the requirements of timescale and spatial resolution. There remain many questions regarding the microscopic nature of relaxation in glass …

3d Experimental Studies Of Temperature And Crystallographic Effects On Creep And Strength In Rock Salt, Amirsalar Moslehy

Doctoral Dissertations

Salt domes utilization as storage reservoirs in the energy sector has led to extensive studies on rock salt’s mechanical and geothermal behavior. These important facilities’ safety and serviceability rely on understanding rock salt’s compressive strength and creep behavior under various loading directions, water contents, in-situ stresses, and temperatures. Despite numerous studies on rock salt’s mechanical behavior in the literature, there are still many unanswered questions about rock salt’s behavior. This dissertation was aimed at utilizing state-of-the-art experimental techniques such as 3D synchrotron micro-computed tomography (SMT) and 3D x-ray diffraction (3DXRD) along with hundreds of compression and creep experiments to enhance …

Additive Manufacturing Of Magnetic Materials For Electric Motor And Generator Applications, Haobo Wang

Doctoral Dissertations

This work details the research into the 3D Printing, also known as Additive Manufacturing (AM), of both impermanent and permanent magnets. This work also details the research in enabling such AM magnets in electrical machine applications, primarily motors and generators. The AM processes of many types of magnets are described in detail. The material properties of such AM magnets are also described. The two main types of AM magnets that are discussed in detail are AM NdFeB, and AM Silicon Steel. The implementation of AM NdFeB as rotor magnets, and the implementation of AM Silicon Steel as rotor and stator …

Characterizing The Structure And Radiation Resistance Of Weberite-Type Complex Oxides, Igor M. Gussev

Doctoral Dissertations

Weberite-type A₃BO₇ oxides, where A is a trivalent rare earth and B is a pentavalent element like Ta, have been a focus of research due to the discovery of the weberite-type local atomic arrangement in ceramics with a defect-fluorite structure. Earlier studies primarily examined their long-range structures, leaving gaps in understanding their short-range atomic behavior. This thesis investigates various weberite-type tantalates across all structural scales. There has been debate over the long-range structure of Y₃TaO₇, a medium-sized rare earth tantalate oxide, particularly regarding its spacegroup symmetry. This work identifies Y₃TaO_{7 …}

Modular Composite Sandwich Structures For Thermal And Structural Retrofitting Of Existing Buildings, Marc Al Ghazal

Masters Theses

Around 40% of global energy consumption and 30% of worldwide carbon dioxide (CO2) emissions are attributed to buildings. Most of this consumption is dedicated to ensuring thermal comfort. The goal of this research was to develop and field validate retrofit solutions to improve the energy efficiency of buildings. Exterior cladding panels were designed and tested to ensure adequate thermal and structural performance. Sandwich panels (glass fibers reinforced polymer (GFRP) skins and polymeric foam cores) were fabricated using the vacuum assisted resin transfer molding (VARTM) process. Extruded polystyrene (XPS) and polyurethane (PU) foams were compared as core materials through a series …

Characterization Of Residual Stress And Precipitate Evolution In Aluminum 2xxx Self-Reacting Friction Stir Welds, Benjamin Joe Wing

Doctoral Dissertations

2xxx series aluminum alloys possess attractive properties for structural aerospace applications including high strength to weight ratio, corrosion resistance, and stable cryogenic performance. Solid state joining processes are often employed to reduce weld defects and improve weld performance/consistency as many alloys of this range have poor weldability for traditional fusion based joining techniques. One such process, self-reacting friction stir welding (SRFSW) allows for consistent high-quality, welding of large and curved articles is often used in the construction of large structures such as launch vehicle liquid propellant tanks.

Despite the merits of this process, joint softening (a decrease in mechanical properties …

Evaluation Of Biomass As Bio-Additive In 3d Printing, Shuyang Zhang

Doctoral Dissertations

The petrol-based polymer has been widely applied in current daily life. The end-of-life of polymeric products has drawn environmental concerns. One of the solutions to such issues is to use bio-renewable materials to replace or reduce the use of petrol-based materials. Lignocellulosic materials are one of the potential candidates. Along with the features of 3D printing and the unique properties of biomass, 3D-printed biomass-based materials could be promising in preparing sustainable alternatives.

In this dissertation, lignin and other biomass were applied to various 3D printing techniques for sustainable composites. Stereolithography (SLA) was first used, and the kraft softwood lignin was …

The Synthesis And Optimization Of Sulfide And Halide Solid Electrolytes For All Solid-State Batteries, Teerth Brahmbhatt

Doctoral Dissertations

Countries and organizations around the world have established ambitious targets to transition away from fossil fuel-based energy sources and devices. The transition is focused on cleaning up power generation by converting coal, natural gas, and oil-based power generation to renewables and nuclear energy. Decarbonizing other sectors of energy use, transportation for example, will require broader electrification. To drive this move away from fossil fuel powered transportation will require portable energy storage devices. Conventional lithium-ion batteries are a popular candidate to lead this shift. However, these batteries often rely on flammable liquid electrolytes and carbon anodes that suffer from low energy …

Investigation Of Microstructure And Mechanical Behavior Of Novel Powder-Extruded Al-Ce-Mg Alloys, Mairym Vazquez

Doctoral Dissertations

Pursuing advanced structural materials with enhanced performance, reduced weight, and lower costs is a constant endeavor in the aerospace and automotive industries. Conventional structural alloys, such as cast irons, carbon steels, and titanium alloys, have strength, weight, and cost limitations. Aluminum-based alloys, known for their lightweight and high strength, have gained popularity in these industries. This dissertation focuses on investigating microstructure and mechanical behavior of novel powder-extruded Al-Ce-Mg alloys as potential candidates for high-performance structural materials.

This research explores using powder extrusion, a well-established forging methodology in the steel industry, to produce Al-Ce-Mg alloys with improved properties and aims to …

Refractory High-Entropy Alloys: Design, Fabrication, Characterization, And Nanoparticle Synthesis, John Hutson Whitlow

Masters Theses

High-Entropy Alloys have been a highly researched area of metals ever since their introduction in 2004 by Brian Cantor and Jien-Weh Yeh. In the continued research of High-Entropy Alloys (HEAs), a specific area concerning Refractory High-Entropy Alloys (RHEAs) has emerged for their high-temperature applications. Although RHEAs have maintained high strength and toughness at high temperatures, their low ductility still needs to be addressed. A dataset was created to find correlations between various characteristics of RHEAs and their composition. A set of seven compositions were selected and fabricated. Mechanical tests were run on the seven compositions, and a proposal was written …

A Study Of The Effect Of Machine Parameters On Defects Produced In Eos Additive Manufacturing Builds, Tina White Malone

Doctoral Dissertations

⁵Additive Manufacturing (AM) is defined in the American Society for Testing and Materials (ASTM) standard F2792 as “a process of joining materials to make objects from 3D model data, usually layer upon layer, as opposed to subtractive manufacturing methodologies. It provides an advanced method for building complex geometries and parts for high performance with a significant cost savings. ⁵⁵It’s advantages include the reduced need for tools and molds commonly used in manufacturing, a large reduction in wasted material, much shorter manufacturing cycles for the building of hardware, and its uniquely inherent ability to produce much more complex shapes. …

Al-Ce-Mn Solidification Phase Selection And Solid-State Phase Transformations, Kevin Dean Sisco

Doctoral Dissertations

The design of Al alloys has become an important topic in Additive Manufacturing (AM). The adoption of Al alloys to AM has been difficult because traditional alloys are prone to processing related defects such as solidification cracking. The Al-10Si-Mg alloy was initially adopted because of its resistance to solidification cracking. However, the Al-10Si-Mg alloy has reduced tensile properties especially at high temperatures, where the silicon phase coarsens readily. Therefore, efforts have been made to design new Al alloys that can take advantage of the AM processing. The goal of new alloys is to optimize based on rapid solidification conditions, while …

Non-Collinear Magnetic Textures Studied By Neutron Scattering, Nan Tang

Doctoral Dissertations

Non-collinear magnetic structures, where the magnetic moments do not align along a single axis, can lead to interesting physical phenomena and potential device applications. In this dissertation, two specific non-collinear magnetic textures are studied which includes soft/hard bilayer and skyrmions. Soft/hard magnetic bilayer thin films have been widely used in data storage technologies and permanent magnet applications. Here, we use polarized neutron reflectometry (PNR) to study magnetic configuration in soft-hard bilayer heterostructure thin films designed with different sample geometry and material properties under a range of temperatures and fields. Comparing the PNR results to the micromagnetic simulations reveals that the …

Comparative Analysis On Low Cost Continuous Carbon Fiber Polypropylene Composite Using Compression Molding And Automated Tape Placement, Benjamin U. Schwartz

Masters Theses

Carbon fiber reinforced plastics (CFRP) are widely used throughout the aerospace industry where a weight reduction remains the highest priority with less emphasis on cost. Textile grade carbon fiber (TCF) and other low cost carbon fiber (LCCF) alternatives have recently emerged for use in the automotive market where emissions regulations have pushed automotive manufacturers and research institutions to look for cost effective light weight materials. Fiber reinforced thermoplastics provide an effective solution that align with automotive design including low cost, high processing rates, high impact toughness, unlimited shelf life, and recyclability.

TCF and Zoltek_PX35 fibers are two LCCF aimed at …

Correlating Large-Format Additive Manufacturing Processing Parameters To Fiber Length And The Mechanical Performance Of Reinforced Polymer Composites, Andrew Phillip Rhodes

Masters Theses

The Big Area Additive Manufacturing (BAAM) system at Oak Ridge National Laboratory has been used to produce carbon fiber reinforced structures for several years, including vehicles, building constituents, composite tooling, etc. While the development of a large-format polymer additive manufacturing (AM) system has moved quickly, the impact of the BAAM’s extruder on the length of carbon fiber feedstock has not been systematically studied. Numerous studies in processing fiber reinforced thermoplastics in plasticizing and injection molding systems have shown that fibers are subjected to significant shear as they are processed, which can cause a drastic reduction in fiber length which negatively …

Surface Corrosion Response Of Al Alloys A383 And Aural 2 With Ce Additions In Aqueous Nacl And Salt-Fog Environments, Michael James Thompson

Masters Theses

Copper is commonly used in aluminum alloys to increase its strength by solid solution and precipitation strengthening, however, the corrosion resistance is inversely related to the amount of copper in the alloy. Over 70 percent of material used to produce aluminum alloys in the US come from recycled (secondary) alloys, many of which have a copper content of more than one percent by weight. Alloys with tightly controlled tolerances, where copper is seen as an impurity, are unable to utilize many of the recycling feedstock without adding newly processed (primary) aluminum to dilute impurities to within specifications. Primary aluminum is …

A Study On Early Age Properties Of Concrete For Precast And 3d Printing, Debalina Ghosh

Doctoral Dissertations

Concrete is the second-most consumed material, leading the global Portland cement production of 4.1 billion tons in 2020 and 5-8% of global Carbon dioxide (CO₂) emission annually. As with any other material and practice, the construction industry is also ever-changing to meet market demand, evolving technology, and resource limitation. In the case of concrete construction, one of the main concerns is the lack of automation. In the last few decades, some new construction methods have risen to address this concern. Some of these economic and successful practices are precast construction, self-compacting concrete (SCC), and 3D printing of concrete(3DPC). …

Compositional Effects On The Mechanical Properties And Deformation Mechanisms Of Face-Centered Cubic High-Entropy Alloys, Joshua L. Cicotte

Doctoral Dissertations

High entropy alloys, HEAs, have expanded the compositional spaces of modern metallurgy into highly concentrated and chemically complex alloys, previously believed to be unproductive. With this newfound compositional freedom, comes additional control, allowing for new investigations into previously established mechanisms. To discover new and potentially useful alloys, the HEA field is continually expanding away from the equiatomic solid solutions that dominated early work. The work presented in this dissertation utilizes two, intuitive, pseudo-binary HEA systems to investigate compositional effects on solid solution strengthening in highly concentrated alloys and twinning and transformation induced plasticity. It furthers the understanding of the mechanical …

Fabrication, Thermophysical, And Mechanical Properties Of Cermet And Cercer Fuel Composites For Nuclear Thermal Propulsion, Neal D. Gaffin

Doctoral Dissertations

Nuclear thermal propulsion (NTP) utilizes nuclear fission to double the efficiency of
in-space propulsion systems compared with traditional combustion rocket systems.
NTP systems are limited primarily by the fuel material choice, due to the extreme
conditions they will need to endure, including temperatures up to 3000 K, multiple
thermal cycles with rapid heating and cooling, exposure to hot flowing hydrogen,
large thermal gradients, and high neutron flux. Particle based fuels, namely ceramic-
metallic (cermet) and ceramic-ceramic (cercer) composites are both promising fuel
element material candidates for NTP. Given the high temperature nature, these
materials are difficult to fabricate and very …

Optimized 3d-Printing Of Carbon Fiber-Reinforced Polyether-Ether-Ketone (Cfr-Peek) For Use In Overmolded Lattice Composite, Ryan C. Ogle

Masters Theses

Current orthopedic implants are overwhelmingly composed from metallic materials. These implants show superior mechanical properties, but this can additionally result in stress shielding due to a modulus mismatch between the bone tissue and implanted device. Polymeric implants reduce this stress shielding effect but have much lower mechanical properties, limiting their use. Polylactic acid (PLA) is a widely used biodegradable thermoplastic polymer, however, its use has been limited by the polymer’s mechanical properties and rapid loss of strength during degradation in vivo. Polyether-ether-ketone (PEEK) is another common biocompatible polymer , with chemical and mechanical properties which make it a popular alternative …

Iron Nanoparticles For Magnetic Imaging Applications, Aleia Williams

Masters Theses

Extensive research on iron oxide nanoparticles for various applications including nanomedicine, energy applications, environmental remediation, and magnetic imaging have previously been performed. Many are currently FDA approved as magnetic resonance imaging contrast agents and tracers for magnetic particle imaging applications. Magnetic properties of such materials are crucial to obtain good contrast and resolution. However, studies have shown the magnetic properties of iron oxide nanoparticles are less in comparison to those found in pure iron nanoparticle.

This research involves the synthesis and characterization of iron nanoparticles for applications in magnetic resonance imaging contrast agents, magnetic particle imaging tracers, and therapeutic agents …

Fundamental Understanding Of The Transient Melt Pool Dynamics, Solidification Kinetics And Build Texture In Spot-Melt Additive Manufacturing Of Ti-6al-4v, Rakesh Rajaram Kamath

Doctoral Dissertations

The overarching goal of this dissertation is to better understand the underlying process-structure relationships in play during the implementation of a spot melt strategy for metal additive manufacturing, which has become a popular alternative to the conventional raster melt strategy for site-specific microstructure control. In the first part of this dissertation, the effect of a spot melt strategy on the solidification texture, variant selection, phase fraction, and their variations along the build height of an E-PBF Ti-6Al-4V is investigated in comparison to a conventional linear melt strategy using high-energy synchrotron x-ray diffraction. In spite of the thermal excursions involved, the …

Functional Bottlebrush Polymer Additives For Thin Films And Coatings, Travis S. Laws

Doctoral Dissertations

Bottlebrush polymers are a class of highly branched polymers consisting of polymeric side chains that are densely grafted to a linear backbone. Their highly branched architecture results in surface enrichment across a broad range of materials. The goal of my research has been centered around the design of functional bottlebrush polymers and their use as surface active additives in blend films and coatings.

In the first chapter, we examine the segregation behavior of polystyrene bottlebrushes that are blended with linear polystyrene. We systematically vary the lengths of the bottlebrush backbone (Nb), side-chain (Nsc), and the linear matrix (Nm) in order …

Computational Investigation Of Planar Fault Structures In Ni-Based Concentrated Alloys, Liubin Xu

Doctoral Dissertations

The Nickel-based Cantor-type concentrated alloys have drawn tremendous research interest as they exhibit great potential for advanced structural materials. The origins of their mechanical performances have been largely associated with planar fault structures, such as stacking faults and deformation twins, as well as their interplay with other defects. Therefore, it is essential to investigate the energetics and the evolution of the planar faults during the deformation processes of the materials.

In the first part of this dissertation, we compute the stacking fault energies (SFEs) in the Ni-based concentrated binary and ternary alloys at both density functional theory (DFT) and atomistic …

How Dynamic Bond Results In The Unique Viscoelastic Behavior Of The Associating Polymers, Sirui Ge

Doctoral Dissertations

Associating polymer is a special kind of polymer possessing transient reversible bonds in addition to the conventional covalent bonds. The reversible bonds provide unique dynamics and fascinating viscoelastic properties, resulting in attractive applications for these polymers, such as self-healing and shape memory materials. Despite many years of studies, the understanding of dynamics of polymers with reversible bonds, especially on molecular level, is still in the rudimentary stage, preventing the rational design of the potential novel functional materials based on associating polymers. In this dissertation, we provide a detailed and quantitative understanding of the dynamics and viscoelastic properties of associating polymers. …

Development Of Metal Halide Perovskites For Radiation Detection, Ryan Tan

Doctoral Dissertations

Metal halide perovskite (MHP) semiconductors have attracted significant interest in recent years within photovoltaic and radiation detection communities due to their inexpensive solution growths, high effective atomic number for gamma and X-ray sensing, suitable bandgap, large resistivity, and moderate mobility-lifetime products. The MHP stoichiometry can also be tuned as needed to achieve desired physical and electronic properties. Moreover, the hybrid or organometallic halide perovskite (OMHP) variants contain a large atomic fraction of hydrogen for fast neutron sensing. These qualities make MHPs an attractive low-cost option for meeting detector needs within nuclear security and imaging applications. This work presents the development …

Direct Calculation Of Configurational Entropy: Pair Correlation Functions And Disorder, Clifton C. Sluss

Doctoral Dissertations

Techniques such as classical molecular dynamics [MD] simulation provide ready access to the thermodynamic data of model material systems. However, the calculation of the Helmholtz and Gibbs free energies remains a difficult task due to the tedious nature of extracting accurate values of the excess entropy from MD simulation data. Thermodynamic integration, a common technique for the calculation of entropy requires numerous simulations across a range of temperatures. Alternative approaches to the direct calculation of entropy based on functionals of pair correlation functions [PCF] have been developed over the years. This work builds upon the functional approach tradition by extending …

Brain Inspired Organic Electronic Devices And Systems For Adaptive Signal Processing, Memory, And Learning., Subhadeep Koner

Doctoral Dissertations

A new class of electronic device has emerged which bear the potential for low powered brain like adaptive signal processing, memory, and learning. It is a non-linear resistor with memory coined as memristor. A memristor is a two-terminal electrical device which simultaneously changes its resistance (processing information) and store the resistance state pertaining to the applied power (memory). Therefore, it can collocate memory and processing much like our brain synapse which can save time and energy for information processing. Leveraging stored memory, it can thereby help future engineered systems to learn autonomously from past experiences. There has been a growing …

Polynorbornenes For Advanced Applications And Processes, Xinyi Wang

Doctoral Dissertations

Polynorbornenes have dramatically different properties and various applications depending on their chemical structures. The modular nature of norbornene-based systems provides a facile route toward synthesizing diverse polymeric materials, thus making them ideal materials for systematic structure-property investigations. Herein, their application as gas separation membranes and the correlation between their gas-transport properties and polymer structures will be investigated. Though many valuable correlations between gas-permeability and polynorbornene structure have been studied previously, many of these efforts have focused heavily on designing materials with various chemical structures to achieve high permeabilities. In contrast, the influence of molecular structure on: a) polynorbornene chain packing …