Engineering Commons^™

Fate And Transport Of Emerging Contaminants Entering, Leaving, And Flowing Past Wastewater Treatment Plants In Central Kentucky, Kyra Sigler

Theses and Dissertations--Biosystems and Agricultural Engineering

Per- and polyfluoroalkyl substances (PFAS) and neonicotinoid insecticides are two classes of emerging contaminants that have been recently detected in many environmental compartments. Both have been associated with negative impacts on humans and the environment. Wastewater treatment plants (WWTPs) have been identified as likely hotspots for introduction of these contaminants into the environment. Thus, the aim of this study was to investigate the occurrence of PFAS and neonicotinoids in two WWTPs in Central Kentucky. Polar organic chemical integrative samplers (POCIS) were deployed in WWTP influent and effluent and placed upstream and downstream of the effluent mixing zone (EMZ) for two …

Fate And Transport Of Nanopesticides In Agricultural Field Plots In Central Kentucky, William D. Rud

Theses and Dissertations--Biosystems and Agricultural Engineering

Due to a growing world population, pesticide applications are necessary part to increasing agricultural production on the same arable land, but this has created environmental contamination, human toxicity, and endangerment to non-target species (i.e, honeybees, monarch butterflies) from bulk pesticide application. Nanoengineered particles or ENP are a potential solution with increased efficiency, longer duration, and enhanced stability of pesticides due to their unique formulations at smaller sizes. However, the potential long-term impact to agroecosystems is still unknown. Therefore, the goal of this project was to evaluate the fate, transport, impact, and persistence of two commercially available nanopesticides (copper hydroxide and …

Life Cycle Assessment Of Air Classification As A Sulfur Mitigation Technology In Pine Residue Feedstocks, Ashlee Edmonson

Theses and Dissertations--Biosystems and Agricultural Engineering

Sulfur accumulation during biofuel production is pollutive, toxic to conversion catalysts, and causes the premature breakdown of processing equipment. Air classification is an effective preprocessing technology for ash and sulfur removal from biomass feedstocks. A life cycle assessment (LCA) sought to understand the environmental impacts of implementing air classification as a sulfur-mitigation technique for pine residues. Energy demand and material balance for preprocessing were simulated using SimaPro and the Argonne National Laboratory’s GREET model, specifically focusing on comparing the global warming potential (GWP) of grid electricity versus bioelectricity scenarios. Overall, the grid electricity scenario had a GWP impact over 7 …

Improving Indoor Arenas For The Equine Industry, Staci Mcgill

Theses and Dissertations--Biosystems and Agricultural Engineering

Equine indoor arenas are a unique infrastructure investment found at equine farms and facilities. They are semi-indoor structures for exercising horses, exhibiting skills during competitive events, and other equine related activities. These spaces do not always include mechanical ventilation or stirring fans and occupancy by horses and humans can be sporadic and inconsistent, which creates a challenging space for understanding and predicting airflow. Typically, indoor arenas have a sand-based footing over which the horse travels. The impact of the hooves can cause dust to become a concern within the facilities. Environmental concerns within these facilities (temperature, respirable dust, moisture, and …

Unmanned Aircraft Systems For Precision Meteorology: An Analysis Of Gnss Position Measurement Error And Embedded Sensor Development, Karla S. Ladino

Theses and Dissertations--Biosystems and Agricultural Engineering

The overarching objective of this research was to enhance our comprehension of the three-dimensional precision of meteorological measurements obtained using small unmanned aircraft systems (UAS). Two complimentary experiments were conducted to achieve this objective.

The first experiment entailed the development and implementation of a system to determine the global navigation satellite system (GNSS) position accuracy on a UAS platform. This system was utilized to assess the static and dynamic accuracy of L1 and L1/L2 GNSS receivers in real-time kinematic (RTK) and non-RTK fix modes. Adjusted two-sample t-tests revealed significant differences in horizontal and vertical error between RTK and non-RTK receivers …

A Process Intensification Approach To Improve Volatile Fatty Acids Production, Extraction, And Valorization, Can Liu

Theses and Dissertations--Biosystems and Agricultural Engineering

Anaerobic digestion (AD) is a widely used biowaste conversion method. Recent studies have explored arrested methanogenesis as an alternative approach to leverage existing AD facilities and produce volatile fatty acids (VFAs) instead of biogas. VFAs have been recognized as precursors for a range of value-added chemicals and bioproducts. Arrested methanogenesis involves inducing acidic fermentation by halting the AD process before methanogenesis. It has been found that higher organic loading and thermophilic conditions enhance VFA accumulation and stabilize the acidic fermentation (AF) system.

Brewer's spent grain (BSG), a significant by-product of the brewing industry, was employed as the feedstock for VFA …

Densification Of Hemp Floral Biomass Pre And Post-Extraction: Determination Of Pellet Physical Characteristics, Gary Lopez

Theses and Dissertations--Biosystems and Agricultural Engineering

The production of cannabidiol (CBD) from the floral material of Cannabis sativa L.is of great interest to the hemp industry. The low bulk density oh hemp floral material presents challenges in terms of storage and handling. To improve handling and storage characteristics, both intact (pre-extraction) and supercritical CO₂ extracted hemp floral materials were pelletized. Intact floral material (BaOx) was passed through a hammer mill with a 5 mm screen; while, extracted floral material (Hawaiian Haze) was ball milled through a 60 mesh (250 microns) prior to extraction. Pelletization was conducted using a 3.7 kW pilot scale flat ring …

Impact Of Physicochemical Characteristics And Distillation Parameters On The Biomethane Potential Of Bourbon Stillage, Danielle Hockensmith

Theses and Dissertations--Biosystems and Agricultural Engineering

Bourbon, or whiskey, production in Kentucky has been estimated to double within the next five years and an increase in the main by-product from bourbon distillation, stillage. Stillage is composed mostly of water along with the fermented grains after distillation. Stillage is expensive to dispose of and difficult to store due to the high biodegradability, posing a risk to the environment given the low pH and high chemical oxygen demand (COD). Anaerobic digestion has been identified as a potential solution for stillage valorization, but little research has been performed. Stillage from different mash bills has varying physicochemical properties, total solids …

Nanopesticide Influence On Nitrogen Cycling In Soils, Jacob Richardson

Theses and Dissertations--Biosystems and Agricultural Engineering

Nanotechnology has several applications in the agricultural industry, as the small size of nanoparticles and high reactivity enables targeted delivery of pesticides and fertilizers to the intended crop. Copper-based nanopesticides such as Kocide, are proposed as a more efficient method for targeted pest control. Despite the potential benefits of nanopesticides, little is known regarding the transport and implications of nanopesticides under long-term inundation conditions often found in downstream wetlands. Specifically, the impact of nanopesticides on microbial nitrogen processes in wetland environments remains unknown. Therefore, this thesis explores the impact of nanopesticides, specifically Kocide, on microbial nitrogen cycles in agricultural and …

Microalgae Immobilization With Filamentous Fungi: Process Development For Sustainable Food Systems, Suvro Talukdar

Theses and Dissertations--Biosystems and Agricultural Engineering

Demand for sustainable food sources has increased because of the rapid growth of the world's population.  In this study, microalgae cells of Haematococcus pluvialis were immobilized using the edible fungal strain Aspergillus awamori for potential food applications. The study investigated the impact of fungal loading, pellet geometry, and initial microalgae cell concentration on the immobilization performance and product characteristics. It was found that higher fungal loading and larger fungal pellets contributed to increased immobilization performance while increased initial microalgae concentration inhibited the process. Larger fungal pellets had decreased biomass density, which led to decreased surface concentration of immobilized microalgae but …

Applying Hermetic Storage And Multiple Abiotic-Stressed Germinations To Actuate Desirable Effects In Wheat Phytochemistry, Food, And Biological Functionalities, Bababode Kehinde

Theses and Dissertations--Biosystems and Agricultural Engineering

Wheat is one of the most widely consumed staple foods in the world, supplying both nutritional and caloric requirements for billions of people. The rising global population and increased food demand behooves all stakeholders across the wheat supply chain to significantly increase their output and efficiency. Beyond the target for increased farm yields, dietary, nutritional, and health requirements along with their continuous supply must be satisfied with improved storage and processing schemes. Post-harvest changes in wheat can result in a significant reduction in its quality. Such losses could be qualitative and/or quantitative, impacting its physical, physiological, organoleptic, and nutritional attributes. …

Using Stream Restoration To Mitigate Stormwater Runoff In An Urban Watershed: A Case Study, Jonathan M. Brantley

Theses and Dissertations--Biosystems and Agricultural Engineering

The goal of this case study was to evaluate the effectiveness a 275 m regenerative stream restoration design to mitigate stormwater runoff in a highly urbanized watershed. The restoration resulted in a wide, wetland-like floodplain, comprised of a rock base that was overtopped with a filtration media (approximately 30% woodchips and 70% topsoil). The creation of the floodplain-wetland complex in tandem with filtration media lead to increased storage capacity and an increase in hyporheic exchange within the system. Significant reductions were found for the storm hydrograph parameters volume, peak discharge, and time to peak. Reductions in baseflows were also noted …

Lignin Valorization Via Reductive Depolymerization Using Promoted Nickel Catalysts And Sub- And Supercritical Methanol, Julia Parker

Theses and Dissertations--Biosystems and Agricultural Engineering

While lignin has been regarded as the most promising renewable feedstock for the sustainable manufacture of aromatic compounds, lignin valorization is necessary to improve the economic viability of biorefineries. Reductive catalytic fractionation (RCF), which combines delignification and lignin depolymerization into a single stage while maintaining the structure and integrity of the cellulose component, has evolved as an effective method for processing biomass. The ability of Cu and Fe to promote the performance of a 20% Ni/alumina catalyst when converting native lignin to alkylphenols by RCF in sub- and supercritical methanol was tested. The effectiveness of lignin extraction as measured by …

Implications To Tap And Stream Water Chemistry Due To Variations In Sampling Locations And Watershed Land Use, Dayana Rodriguez

Theses and Dissertations--Biosystems and Agricultural Engineering

The Kentucky River Basin, which is in the Eastern Kentucky Coal Field region, is a rural region with sparse population distribution and a history of water quality impairments. The long history of mining activity in the Commonwealth has not only left a mark on the area’s economy, but it has also shaped the environment. Changes in land use from forested areas to surface mining have been shown to significantly change water chemistry and hydrology. To date, there is limited information regarding the potential exposure and introduction of heavy metals and sulfate entering rural water treatment plants, resulting in a notable …

Sediment Nitrogen Dynamics In Backwater Wetland Confluences Of A Regulated River, Gina Degraves

Theses and Dissertations--Biosystems and Agricultural Engineering

As harmful algal blooms in regulated river systems have increased in the past decade, the importance of understanding sediment nutrients has also increased. Research linking nutrient processes and fine sediment dynamics to harmful algal blooms in confluence wetlands along regulated rivers has recently become apparent. However, the relationship between sediment nutrient dynamics in confluence wetlands has been understudied. Utilization of sediment fingerprinting, high-frequency water quality monitoring, and tracer unmixing mass-balance modeling, was able to suggest sediment N mineralization in Appalachia confluence riparian wetland was not a dominate source of nitrate downstream. Further measures of supplementary tracers and additional sediment sources …

Nondestructive Multivariate Classification Of Codling Moth Infested Apples Using Machine Learning And Sensor Fusion, Nader Ekramirad

Theses and Dissertations--Biosystems and Agricultural Engineering

Apple is the number one on the list of the most consumed fruits in the United States. The increasing market demand for high quality apples and the need for fast, and effective quality evaluation techniques have prompted research into the development of nondestructive evaluation methods. Codling moth (CM), Cydia pomonella L. (Lepidoptera: Tortricidae), is the most devastating pest of apples. Therefore, this dissertation is focused on the development of nondestructive methods for the detection and classification of CM-infested apples. The objective one in this study was aimed to identify and characterize the source of detectable vibro-acoustic signals coming from CM-infested …

The Response Of Beef Cattle To Disturbances From Unmanned Aerial Vehicles (Uavs), Gabriel Abdulai

Theses and Dissertations--Biosystems and Agricultural Engineering

Unmanned aerial vehicles (UAVs) are increasingly becoming common in animal agriculture. However, research regarding the impact of UAV disturbance on animal wellbeing is lacking or limited. The goal of this study was to investigate the effect of UAV flights on beef cattle by measuring cattle heart and movement rate when introduced to single or multiple UAV flights. A total of 16 -18 crossbred beef heifers were introduced to different flights patterns at between 5 and 9 m above ground level (AGL) at approximately 1 to 2 m/s horizontal velocity for 4 weeks with flights repeated 3 days per week. Results …

Exploration Of Lignin-Based Superabsorbent Polymers (Hydrogels) For Soil Water Management And As A Carrier For Delivering Rhizobium Spp., Toby Adjuik

Theses and Dissertations--Biosystems and Agricultural Engineering

Superabsorbent polymers (hydrogels) as soil amendments may improve soil hydraulic properties and act as carrier materials beneficial to soil microorganisms. Researchers have mostly explored synthetic hydrogels which may not be environmentally sustainable. This dissertation focused on the development and application of lignin-based hydrogels as sustainable soil amendments. This dissertation also explores the development of pedotransfer transfer functions (PTFs) for predicting saturated hydraulic conductivity using statistical and machine learning methods with a publicly available large data set. A lignin-based hydrogel was synthesized, and its impact on soil water retention was determined in silt loam and loamy fine sand soils. Hydrogel treatment …

Classifying And Mapping Aquatic Vegetation In Heterogeneous Stream Ecosystems Using Visible And Multispectral Uav Imagery, Rozalia Agioutanti

Theses and Dissertations--Biosystems and Agricultural Engineering

The need for assessment and management of aquatic vegetation in stream ecosystems is recognized given the importance in impacting water quality, hydrodynamics, and aquatic biota. However, existing approaches to monitor are laborious and its currently not feasible to track spatial and temporal differences at broad scales. The objective of this study was therefore to map and classify aquatic vegetation of a shallow stream with heterogenous mixtures of emergent and submerged aquatic vegetation. Data was collected in the Camden Creek watershed within the Inner Bluegrass Region of central Kentucky. The use of unmanned aerial vehicles (UAVs) was employed and both visible …

Assessing Machine Learning Utility In Predicting Hydrologic And Nitrate Dynamics In Karst Agroecosystems, Timothy Mcgill

Theses and Dissertations--Biosystems and Agricultural Engineering

Seasonal hypoxia in the Gulf of Mexico and harmful algal blooms experienced in many inland freshwater bodies is partially driven due to excessive nitrogen loading seen from agricultural watersheds. Within the Mississippi/Atchafalaya River Basin, many areas are underlain with karst features, and efforts to reduce nitrogen contributions from these areas have had varying success, due to lacking a complete understanding of nutrient dynamics in karst agricultural systems. To improve the understanding of nitrogen cycling in these systems, 35 months of high resolution in situ water quality and atmospheric data were collected and fed into a two-hidden layer extreme learning machine …

Extraction Of Micro- And Nano-Plastic Particles From Water Using Hydrophobic Natural Deep Eutectic Solvents, Jameson R. Hunter

Theses and Dissertations--Biosystems and Agricultural Engineering

The production of plastic and the amount of waste plastic that enters the environment increases every year. Synthetic polymers will gradually break down into particles on the micro- and nano-scale. The micro- and nano-plastics pose a significant ecological harm by transporting toxic chemicals and causing inflammation and cellular damage when ingested. Two common plastics are polyethylene terephthalate (PET) and Polystyrene (PS), and a newer bioplastic polylactic acid (PLA) that has become a popular alternative. Deep eutectic solvents are a recently discovered solvent composed of a hydrogen bond donor and hydrogen bond acceptor and have been proposed as a cheaper alternative …

Comparing Beopt (Energyplus) Energy Predictions To Measured Circuit Level Energy Consumption Of 12 Similar Small Energy-Efficient Single-Family Residences, Braydi Mcpherson-Hathaway

Theses and Dissertations--Biosystems and Agricultural Engineering

Residential energy usage patterns change as a result of new building codes, renewable technologies, household electronics, and changes in occupancy habits. Building simulations have used end-use energy studies to inform occupancy profiles and overall usage characteristics for the building simulations. Building simulations allow designers, engineers, policymakers, code developers, and building owners to model proposed designs to new and existing buildings, thus it is imperative that the energy profiles used in the models are accurate. In this study, the building simulation engine BEopt is used to model energy-efficient homes recently constructed in Southern Kentucky. The homes have well defined building characteristics …

Assessing The Use Of Lidar And Uav Technology For Monitoring Growing Alfalfa, Stuart Tucker Sheffield

Theses and Dissertations--Biosystems and Agricultural Engineering

Alfalfa is a popularly grown crop because of its value as a nutritious feed source for livestock. The efficient production of an alfalfa crop relies on the monitoring of certain parameters, like height, quality, and yield. Traditionally, producers have used manual measurements of alfalfa plant height to estimate the nutritive quality and yield of a growing alfalfa crop. Manual measurements of plant height are often labor intensive and provide low resolution data that is not acceptable for full field scale assessment of growing alfalfa. The two studies presented in this thesis offer detailed insight into the rapid and accurate monitoring …

Characterization And Upgrade Of Endocarp Biomass Derived Lignin To Value Added Products, Makua Vin-Nnajiofor

Theses and Dissertations--Biosystems and Agricultural Engineering

Lignin is an abundant biopolymer and a promising source of feedstock for high-value chemicals and energy materials, however, application methods of lignin into valuable products is yet to be fully explored. This study explores the valorization of lignin derived from lignin-rich endocarp biomass through the development of lignin-derived electrode materials. The chemical composition and cellular structure of the endocarps were characterized using HPLC and scanning electron microscopy (SEM) imaging. Mechanical properties of walnut and peach endocarps and preprocessing requirements were investigated using nanoindentation and specific energy consumption during grinding. Next, lignin was extracted from endocarps using deep eutectic solvent and …

Evaluating The Biotic Condition Of Restored Streams In Kentucky’S Inner Bluegrass Region, Charles Cole Crankshaw

Theses and Dissertations--Biosystems and Agricultural Engineering

Numerous stream restoration projects have been implemented in Kentucky’s Inner Bluegrass region to offset anthropogenic impacts. These projects range from full channel realignments to volunteer-led riparian installations. To assess the ability of said projects to restore stream habitat and biota, full restoration (n=12) and riparian (n=6) sites were compared to reference (n=6) and disturbed (n=12) sites using RBP and SVAP protocols, macroinvertebrate samples, and geomorphology. General trends for SVAP, RBP, and BI scores, starting with highest habitat or biotic quality, were reference sites, full and riparian restoration sites, then disturbed sites. The number of EPT taxa, another indicator of biological …

Impact Of Preferential Flow, Source Water Connectivity, And Agricultural Management Practices On Sediment And Particulate Phosphorus Dynamics In Midwestern Tile-Drained Landscapes, Saeid Nazari

Theses and Dissertations--Biosystems and Agricultural Engineering

Tile drainage is recognized as a significant transporter of sediment and particulate phosphorus (PP) in the Midwestern U.S., leading to proliferation of Harmful Algal Blooms (HABs). Numerous studies have focused on Dissolved Reactive Phosphorus (DRP) and Nitrogen (N) flux dynamics in tile-drained landscapes; however, the impact of preferential flow and agricultural management practices on fate and transport of sediment and PP has remained poorly understood. The overarching objective of this study was to improve understanding of sediment P delivery in tile-drained landscapes. This dissertation focuses on four studies. In the first study, forms and flow pathway dynamics of total phosphorus …

Quantifying The Source And Pathway Of Dissolved Reactive Phosphate In Karst Drainage Of The Inner-Bluegrass, Cory Radcliff

Theses and Dissertations--Biosystems and Agricultural Engineering

In the Midwestern U.S. seasonal hypoxia experienced in the Gulf of Mexico and harmful algal blooms in inland freshwater ponds, lakes, and rivers are partly fueled by dissolved orthophosphate loadings from disturbed landscapes. Efforts to reduce dissolved reactive phosphate (DRP) loadings have had varying levels of success and have led to insufficient water quality improvements. Inefficiencies in conservation strategies can stem from poor understanding of phosphate source and flow pathway dynamics. This study focused on monitoring sources and flow pathways of dissolved reactive P in a karst agroecosystem with phosphatic limestone. We collected event water samples at the Camden Creek …

Modeling Energy Flows In Floating In-Pond Raceways Utilizing Solar Power Back-Up, Bo Smith

Theses and Dissertations--Biosystems and Agricultural Engineering

The In-pond Raceway (IPR) is a novel option for production aquaculture, depending on water moving devices to provide constant flow. Device failure may result in catastrophic fish loss, requiring power backup systems to mitigate risk in case of power outages. Because these systems must be dependable and many suitable locations are remote, off-grid solar photovoltaic (PV) systems with battery storage have been considered since they eliminate need for utility power. Such systems can be hard to size and expensive. This study modeled system requirements using an energy balance to determine whether systems could withstand varying loads based on climatological conditions. …

Fourier Transform Infrared Spectroscopy (As A Rapid Method) Coupled With Machine Learning Approaches For Detection And Quantification Of Gluten Contaminations In Grain-Based Foods, Abuchi Godswill Okeke

Theses and Dissertations--Biosystems and Agricultural Engineering

Cross-contamination between food grains during harvesting, transportation, and/or food processing is still a major issue in the food industry. Due to cross-contact with gluten-rich grains (wheat, barley, and rye grains), gluten can get into food that’s naturally free from gluten and thus may not be safe for consumption for people susceptible to gluten-related disorders such as celiac disease, wheat allergy, gluten intolerance or sensitivity. The conventional method of gluten detection is cumbersome, time-consuming, and requires well-trained personnel. Therefore, there is a need for a rapid and equally effective technique to authenticate gluten contamination in foods. This research work explored the …

Quantifying Nitrogen Fate In Karst Agroecosystem Streams Of Central Kentucky: Development And Application Of Numerical Modeling And Insight From High-Resolution Sensors, Nolan Lewis Bunnell

Theses and Dissertations--Biosystems and Agricultural Engineering

In-stream fate of nutrients in karst agroecosystems remains poorly understood, despite the known impact of karst on water resources at local to global scales. In the Inner-Bluegrass region of central Kentucky, heterogeneity of karst maturity, flow pathways, and nutrient sources adds to the complexity of quantifying nutrient dynamics, thus requiring novel monitoring and modeling approaches. The significance of these streams is recognized given spring/surface water confluences have been identified as hotspots for biogeochemical transformations. In slow-moving streams high in dissolved inorganic nutrients (particularly dissolved inorganic nitrogen (DIN) and dissolved reactive phosphorus (DRP)), benthic and floating aquatic macrophytes are recognized to …