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Full-Text Articles in Engineering
Co-Planar Waveguides For Microwave Atom Chips, Morgan Logsdon
Co-Planar Waveguides For Microwave Atom Chips, Morgan Logsdon
Undergraduate Honors Theses
This thesis describes research to develop co-planar waveguides (CPW) for coupling microwaves from mm-scale coaxial cables into 50 μm-scale microstrip transmission lines of a microwave atom chip. This new atom chip confines and manipulates atoms using spin-specific microwave AC Zeeman potentials and is particularly well suited for trapped atom interferometry. The coaxial-to-microstrip coupler scheme uses a focused CPW (FCPW) that shrinks the microwave field mode while maintaining a constant 50 Ω impedance for optimal power coupling. The FCPW development includes the simulation, design, fabrication, and testing of multiple CPW and microstrip prototypes using aluminum nitride substrates. Notably, the FCPW approach …
Magneto-Optics And Magneto-Transport Studies On Thin Films For Sensor Applications, Kaida Yang
Magneto-Optics And Magneto-Transport Studies On Thin Films For Sensor Applications, Kaida Yang
Dissertations, Theses, and Masters Projects
Recent progress and interest have bought considerable effort to bear on the synthesis and opportunities of magnetic thin films in different fields. There are applications in many fields, including remote sensing, waveguide applications, hard drive applications, etc. at the College of William and Mary, we have focused on utilizing magnetic thin films in some of these applications and are deeply involved in the optimization process of the thin films.
Superconducting Thin Films For Srf Cavity Applications: A Route To Higher Field Gradient Linacs, Wiliam Michael Roach
Superconducting Thin Films For Srf Cavity Applications: A Route To Higher Field Gradient Linacs, Wiliam Michael Roach
Dissertations, Theses, and Masters Projects
Many linear accelerator (linac) applications rely on the use of superconducting radio frequency (SRF) cavities. In order to overcome the current field gradient limits imposed by the use of bulk niobium, a model involving the deposition of alternating superconducting-insulating-superconducting (SIS) thin films onto the interior surface of SRF cavities has been proposed. Since SRF performance is a surface phenomenon, the critical surface of these cavities is less than 1 micron thick, thus enabling the use of thin films. Before such approach can successfully be implemented fundamental studies correlating the microstructure and superconducting properties of thin films are needed. to this …
Nonlinear Optical Studies Of Photoelastic Effect And Magneto-Plasmonics, Wei Zheng
Nonlinear Optical Studies Of Photoelastic Effect And Magneto-Plasmonics, Wei Zheng
Dissertations, Theses, and Masters Projects
Nonlinear optical (NLO) processes are optical phenomena involving a nonlinear response to an applied light field. Two kinds of nonlinearities are studied in this dissertation: magnetic-induced second-harmonic generation (MSHG) interacting with surface plasmon, called "nonlinear magnetoplasmonics" (NMP), and the nonlinear index induced by a strong pump beam in Titanium doped sapphire crystal, referred to as population-induced nonlinear index effect.;The fundamentals of the major effects involved are discussed, which include: surface plasmon and its field enhancement effect, MSHG technique and phenomenological calculations, the contrast ratio of magnetic switching, the calculation of lensing effects, population induced strain, and photoelastic effect. Furthermore, the …
Optical Characterization Of Magnetism In Magnetic/Nonmagnetic Heterostructures, Yichun Fan
Optical Characterization Of Magnetism In Magnetic/Nonmagnetic Heterostructures, Yichun Fan
Dissertations, Theses, and Masters Projects
This thesis focuses on the study of the static and dynamic magnetic interactions in ferromagnetic/nonmagnetic heterostructures using interface-specific and time-resolved optical techniques. The goal of this thesis is to elucidate the interface exchange coupling, magnetic anisotropy, and coherent spin dynamics in these advanced material systems, crucial to the realization of high performance spintronic devices.;First, a pronounced exchange bias (EB) phenomenon is observed in Fe/MgO (001) by magnetic second harmonic generation. The bulk magnetization does not, in marked contrast to typical systems where EB is manifested only in the net magnetization. The magnitude of the exchange bias varies with interface oxygen …
Surface Impedance Of Superconducting Radio Frequency (Srf) Materials, Binping Xiao
Surface Impedance Of Superconducting Radio Frequency (Srf) Materials, Binping Xiao
Dissertations, Theses, and Masters Projects
Superconducting radio frequency (SRF) technology is widely adopted in particle accelerators. There remain many open questions, however, in developing a systematic understanding of the fundamental behavior of SRF materials, including niobium treated in different ways and various other bulk/thin film materials that are fabricated with different methods under assorted conditions. A facility that can measure the SRF properties of small samples in a range of 2∼40 K temperature is needed in order to fully answer these questions. The Jefferson Lab surface impedance characterization (SIC) system has been designed to attempt to meet this requirement. It consists of a sapphire-loaded cylindrical …
Microscopic Dynamics And Transport Of Hydrogen In Proton Conducting Oxides, Erik J. Spahr
Microscopic Dynamics And Transport Of Hydrogen In Proton Conducting Oxides, Erik J. Spahr
Dissertations, Theses, and Masters Projects
The microscopic motion of hydrogen in solid oxides plays an important role in defect migration and reaction processes. Understanding the vibrational dynamics associated with both hydrogen-oxygen (O-H) bonds and the surrounding ionic environment allows one to better characterize these fundamental interactions. This thesis presents a comprehensive investigation into the vibrational decay dynamics of O-H and O-D stretch modes in crystalline oxides using time-resolved infrared pump-probe spectroscopy.;Measurements of the vibrational lifetimes of hydrogen related local modes in potassium tantalate (KTaO3) and titanium dioxide (TiO2 ) show that the localized O-H vibration is very closely tied to proton transport. In KTaO3 we …
Thin Film And Chemical Ordering Effects On The Magnetic Anisotropy In Binary Alloys, Jonathan Ronald Skuza
Thin Film And Chemical Ordering Effects On The Magnetic Anisotropy In Binary Alloys, Jonathan Ronald Skuza
Dissertations, Theses, and Masters Projects
This dissertation presents various investigations into the structure-property correlations in highly anisotropic FePt and FePd thin films and nanostructures. These binary alloy thin films may exhibit long-range chemical ordering (e.g. L10), which induces a strong uniaxial magnetic anisotropy whose orientation is dependent on the ordering direction in the thin film. The chemical ordering, and hence the magnetic anisotropy, in these thin films can be controlled and tailored through sputter deposition and ion implantation conditions followed by subsequent processing. Two novel fabrication methods, x-ray rapid thermal annealing (XRTA) and heavy ion implantation, successfully demonstrate the ability to obtain highly anisotropic nanometer-sized …
Enhanced Field Emission From Vertically Oriented Graphene By Thin Solid Film Coatings, Michael Bagge-Hansen
Enhanced Field Emission From Vertically Oriented Graphene By Thin Solid Film Coatings, Michael Bagge-Hansen
Dissertations, Theses, and Masters Projects
Recent progress and a coordinated national research program have brought considerable effort to bear on the synthesis and application of carbon nanostructures for field emission. at the College of William and Mary, we have developed field emission arrays of vertically oriented graphene (carbon nanosheets, CNS) that have demonstrated promising cathode performance, delivering emission current densities up to 2 mA/mm2 and cathode lifetime > 800 hours. The work function ( & phis;) of CNS and other carbonaceous cathode materials has been reported to be &phis;∼4.5-5.1 eV. The application of low work function thin films can achieve several orders of magnitude enhancement of …
First-Principles Calculations Of Nuclear Magnetic Resonance Chemical Shielding Tensors In Complex Ferroelectric Perovskites, Daniel Lawrence Pechkis
First-Principles Calculations Of Nuclear Magnetic Resonance Chemical Shielding Tensors In Complex Ferroelectric Perovskites, Daniel Lawrence Pechkis
Dissertations, Theses, and Masters Projects
Nuclear magnetic resonance (NMR) spectroscopy is one of the most important experimental probes of local atomistic structure, chemical ordering, and dynamics. Recently, NMR has increasingly been used to study complex ferroelectric perovskite alloys, where spectra can be difficult to interpret. First-principles calculations of NMR spectra can greatly assist in this task. In this work, oxygen, titanium, and niobium NMR chemical shielding tensors, s&d4; , were calculated with first-principles methods for ferroelectric transition metal prototypical ABO3 perovskites [SrTiO3, BaTiO 3, PbTiO3 and PbZrO3] and A(B,B')O3 perovskite alloys Pb(Zr1/2Ti1/2)O3 (PZT) and Pb(Mg1/3Nb2/3)O3 (PMN). The principal findings are 1) a large anisotropy between …
Applications Of Pattern Classification To Time-Domain Signals, Crystal Ann Bertoncini
Applications Of Pattern Classification To Time-Domain Signals, Crystal Ann Bertoncini
Dissertations, Theses, and Masters Projects
Many different kinds of physics are used in sensors that produce time-domain signals, such as ultrasonics, acoustics, seismology, and electromagnetics. The waveforms generated by these sensors are used to measure events or detect flaws in applications ranging from industrial to medical and defense-related domains. Interpreting the signals is challenging because of the complicated physics of the interaction of the fields with the materials and structures under study. often the method of interpreting the signal varies by the application, but automatic detection of events in signals is always useful in order to attain results quickly with less human error. One method …
Advancements In Dual-Pump Broadband Cars For Supersonic Combustion Measurements, Sarah Augusta. Tedder
Advancements In Dual-Pump Broadband Cars For Supersonic Combustion Measurements, Sarah Augusta. Tedder
Dissertations, Theses, and Masters Projects
Space- and time-resolved measurements of temperature and species mole fractions of nitrogen, oxygen, and hydrogen were obtained with a dual-pump coherent anti-Stokes Raman spectroscopy (CARS) system in hydrogen-fueled supersonic combustion free jet flows. These measurements were taken to provide time-resolved fluid properties of turbulent supersonic combustion for use in the creation and verification of computational fluid dynamic (CFD) models. CFD models of turbulent supersonic combustion flow currently facilitate the design of air- breathing supersonic combustion ramjet (scramjet) engines. Measurements were made in supersonic axi-symmetric free jets of two scales. First, the measurement system was tested in a laboratory environment using …
Optical Control Of Ultrafast Spin -Wave Relaxation By Magnetic Anisotropy In A Ferromagnet, Kevin James Smith
Optical Control Of Ultrafast Spin -Wave Relaxation By Magnetic Anisotropy In A Ferromagnet, Kevin James Smith
Dissertations, Theses, and Masters Projects
This thesis presents an investigation of the damping of spin waves in ferromagnetic Au(3 nm)/Ni(10 nm)/MgO(001) thin films using the time-resolved Magneto-optical Kerr Effect (TR-MOKE) and ferromagnetic resonance (FMR) techniques. In the optical measurements, a 150 fs, 800 nm laser beam pulse is split into pump and probe components. The pump pulse, containing most of the beam energy, thermally excites coherent spin precession. The weaker probe pulse, time-delayed by a variable beam path, captures the magnetization dynamics via the polar MOKE effect, and oscillations are observed as a function of external field amplitude and direction. The extracted precession frequency is …
The Functionalization Of Carbon Nanosheets, Ronald A. Quinlan
The Functionalization Of Carbon Nanosheets, Ronald A. Quinlan
Dissertations, Theses, and Masters Projects
Carbon nanosheets are a novel two-dimensional nanostructure made up of 2-20 graphene atomic planes oriented with their in-plane axis perpendicular to the growth substrate. Previous efforts in developing nanosheet technology have focused on the characterization of the system and their development as an electron source due to the high atomic enhancement factor (beta) and low turn on field. Further investigation of nanosheets as high surface area electrodes revealed poor wetting by polymeric material and extreme hydrophobic behavior.;Because nanosheet technology has promise as a high surface area electrode material, this thesis research has focused on three areas of interest: the enhancement …
Time-Resolved Magnetic Flux And Ac-Current Distributions In Superconducting Yttrium Barium Copper Oxide Thin Films And Multifilaments, Ran Yang
Dissertations, Theses, and Masters Projects
Time-resolved magneto-optical imaging (TRMOI) technique allows dynamic ac transport measurements on superconductors. The high time and spatial resolutions of the measurements also offer good quantitative data analysis of the MO images. YBa2Cu 3O7-delta (YBCO) was discovered as a high-temperature superconductor (HTSC) which has wide applications due to its high critical temperature of Tc = 91 K, and high critical current density Jc in the order of 106-7 Acm-2. Many of the applications require high ac current load and a high magnetic field. We study the interaction behavior of YBCO thin films in an ac transport current and a dc magnetic …
Synthesis And Field Emission Properties Of Carbon Nanostructures, Kun Hou
Synthesis And Field Emission Properties Of Carbon Nanostructures, Kun Hou
Dissertations, Theses, and Masters Projects
This dissertation focuses on developing carbon nanostructures for application as the electron emissive material in novel back-gated triode field emission devices. The synthesis, characterization, and field emission properties of carbon nanostructures, including 1-D carbon nanofibers (CNF), 2-D carbon nanosheets (CNS), and chromium oxide coated carbon nanosheets (CrOx-CNS), are presented in this work.;First, we have fabricated aligned carbon nanofiber based back-gated triode field emission devices and confirmed the operation of these devices. 1-D carbon nanofibers were directly synthesized on blank TiW substrates using direct current plasma enhanced chemical vapor deposition. It was found that the morphology of carbon nanofibers could be …
Fluorescence Imaging Study Of Free And Impinging Supersonic Jets: Jet Structure And Turbulent Transition, Jennifer Ann Inman
Fluorescence Imaging Study Of Free And Impinging Supersonic Jets: Jet Structure And Turbulent Transition, Jennifer Ann Inman
Dissertations, Theses, and Masters Projects
A series of experiments into the behavior of underexpanded jet flows has been conducted at NASA Langley Research Center. This work was conducted in support of the Return to Flight effort following the loss of the Columbia. The tests involved simulating flow through a hypothetical breach in the leading edge of the Space Shuttle Orbiter along its reentry trajectory, with the goal of generating a data set with which other researchers can test and validate computational modeling tools. Two nozzles supplied with high-pressure gas were used to generate axisymmetric underexpanded jets exhausting into a low-pressure chamber. These nozzles had exit …
Optical Characterization Of Ferromagnetic Heterostructure *Interfaces And Thin Films, Haibin Zhao
Optical Characterization Of Ferromagnetic Heterostructure *Interfaces And Thin Films, Haibin Zhao
Dissertations, Theses, and Masters Projects
This thesis presents optical characterizations of interfaces in ferromagnetic heterostructures and thin films used for spin polarized electronic devices. In these experiments, femtosecond laser spectroscopies are exploited to investigate the interface magnetization reversal, spin precession, and band offset, which are crucial in determining the performances of spintronic devices.;First, magnetization-induced second-harmonic-generation (MSHG) is applied to study interface magnetism in a hybrid structure containing a noncentrosymmetric semiconductor---Fe/AlGaAs. The reversal process of Fe interface layer magnetization is compared with the bulk magnetization reversal. In Fe/AlGaAs (001), the interface magnetization is found to be decoupled from the bulk magnetization based on the different switching …
Ultrafast Laser Spectroscopy Of Half -Metallic Chromium Dioxide, Hailong Huang
Ultrafast Laser Spectroscopy Of Half -Metallic Chromium Dioxide, Hailong Huang
Dissertations, Theses, and Masters Projects
This thesis presents ultrafast laser pump-probe differential transmission experiments on epitaxial CrO2 (110). The experiments were conducted at the wavelengths of 600 nm, 800 nm and 1200 nm, corresponding to the transition energies of 2 eV, 1.5 eV and 1 eV respectively. The wavelength dependent results, comparing with linear optical absorption, revealed the electronic structure of the material. The experimental results also showed polarization dependence of the probe beams. This is attributed to the electronic orbital anisotropy.;Temperature dependence was observed in the pump-probe experiments. The ultrafast transmission data show similar temperature dependence as ultrafast MOKE (Magneto-Optical Kerr Effect) data. A …
Vibrational Lifetimes Of Hydrogen And Oxygen Defects In Semiconductors, Baozhou Sun
Vibrational Lifetimes Of Hydrogen And Oxygen Defects In Semiconductors, Baozhou Sun
Dissertations, Theses, and Masters Projects
Characterization of defect and impurity reactions, dissociation, and migration in semiconductors requires a detailed understanding of the rates and pathways of vibrational energy flow and of the coupling mechanisms between local modes and the phonon bath of the host material. Information on the inelastic microscopic interaction can be obtained by measuring the lifetime of local vibrational modes. This dissertation presents lifetime measurements of hydrogen and oxygen defects in semiconductors by means of time-resolved infrared pump-probe spectroscopy.;First, we measured the vibrational lifetime of H- and D-related bending modes in Si and other semiconductors. Time-resolved pump-probe and linewidth measurements reveal that the …
Solid State Nmr Characterization Of Conductive Polyanilines, Yanina Anatolievna Goddard
Solid State Nmr Characterization Of Conductive Polyanilines, Yanina Anatolievna Goddard
Dissertations, Theses, and Masters Projects
Different forms of ring deuterated polyaniline with different conductivity have been characterized by solid state deuteron nuclear magnetic resonance.;Quadrupole echo (QE) spectra of all forms of polyaniline consist of a superposition of lineshapes for nearly rigid aromatic rings and a small fraction of rings which undergo fast 180?? flips. The intensity of the fast flipping component is temperature dependent and different for conductive emeraldine salt (ES) and non-conductive emeraldine base (EB). This is a manifestation of the different structure and morphology of these polymers.;Simultaneous measurements of QE lineshapes and the relaxation time anisotropies allowed an accurate description of motion in …
Dual Energy Scanning Beam X -Radiography, Randolph Frank Wojcik
Dual Energy Scanning Beam X -Radiography, Randolph Frank Wojcik
Dissertations, Theses, and Masters Projects
Dual energy X-radiography is a method first developed in the mid-1970's by which one uses the information contained in the energy spectrum of the transmitted X-ray flux through an object. With this information one can distinguish the types of materials present in a radiograph and thus allow a computer to subtract them from the image enhancing the contrast of the remaining materials. Using this method, one can see details, which would have been hidden by overlying structures of other materials such as seen in radiographs of parts, made up of mixtures of metals and composites. There is also great interest …
Chemical Bonding In Hard And Elastic Amorphous Carbon-Nitride Films, W. Jason Gammon
Chemical Bonding In Hard And Elastic Amorphous Carbon-Nitride Films, W. Jason Gammon
Dissertations, Theses, and Masters Projects
In this study, the chemical bonding in hard and elastic amorphous carbon nitride (a-CNx) films is investigated with x-ray photoelectron spectroscopy (XPS) and 15N, 13C, and 1H nuclear magnetic resonance (NMR) spectroscopy. The films were deposited by DC Magnetron sputtering in a pure nitrogen discharge on Si(001) substrates at 300--400??C. Nanoindentation measurements reveal an elastic modulus of ∼50 GPa and a hardness of ∼5 GPa, thus confirming our films are highly elastic but resist plastic deformation.;Our 13C NMR study demonstrates the absence of sp 3-bonded carbon in this material. Collectively, our N(1s) XPS, 13C NMR, and 15N NMR data suggest …
Theoretical And Experimental Study Of Generation Mechanisms For Laser Ultrasound In Woven Graphite /Epoxy Composites With Translaminar Stitching, Adam D. Friedman
Theoretical And Experimental Study Of Generation Mechanisms For Laser Ultrasound In Woven Graphite /Epoxy Composites With Translaminar Stitching, Adam D. Friedman
Dissertations, Theses, and Masters Projects
The aerospace industry is beginning to use advanced composite materials for primary load bearing structures and their failure mechanisms must be better understood to predict their behavior in service. The Combined Loads Tests (COLTS) facility is being constructed at the NASA Langley Research Center to characterize these failure mechanisms. Laser based ultrasonic NDE can monitor the samples during dynamic loading without interfering with the structural tests. However, the constraints of implementing laser ultrasound in a structures laboratory reduces the efficiency of the technique. The system has to be "eye-safe" because many people will be present during the structural tests. Consequently, …
Plasma Source Ion Implantation Of High Voltage Electrodes, Thomas Joseph Venhaus
Plasma Source Ion Implantation Of High Voltage Electrodes, Thomas Joseph Venhaus
Dissertations, Theses, and Masters Projects
Field emission and breakdown characteristics of high voltage, large area electrodes determine the performance of many vacuum-based electron sources. A corroborative project with the Thomas Jefferson National Accelerator Facility involves studying the behavior of such electrodes after nitrogen ion implantation. A Plasma Source Ion Implantation (PSII) facility is designed and constructed at William and Mary, and used to treat stainless steel electrodes. PSII is a novel implantation technique developed at the University of Wisconsin-Madison. A workpiece is submerged in a quiescent plasma of the species to be implanted. A series of high, negative voltages (30--100 kV) is applied to the …
Low Damage Processing And Process Characterization, Xianmin Tang
Low Damage Processing And Process Characterization, Xianmin Tang
Dissertations, Theses, and Masters Projects
Two novel plasma sources (one neutral source and one pulsed inductively coupled plasma source) and ashing process characterization were investigated. The primary goal was to characterize these source properties and develop corresponding applications. The study includes process damage assessment with these two sources and another continuous wave (13.56MHz) plasma source. A global average simulation of the pulsed discharges was also included.;The transient plasma density and electron temperature from the double probe analysis were compared with single Langmuir probe results with sheath displacement corrections in pulsed discharges (200Hz--10kHz). The equivalent resistance method can be used effectively to analyze these double probe …
Surface Processing By Rfi Pecvd And Rfi Psii, Lingling Wu
Surface Processing By Rfi Pecvd And Rfi Psii, Lingling Wu
Dissertations, Theses, and Masters Projects
An RFI plasma enhanced chemical vapor deposition (PECVD) system and a large-scale RF plasma source immersion ion implantation (PSII) system were designed and built to study two forms of 3-D surface processing, PECVD and PSII. Using the RFI PECVD system, Ti-6Al-4V substrates were coated with diamond-like carbon films with excellent tribological and optical properties. as an innovation, variable angle spectroscopic ellipsometry (VASE) was successfully applied for non-destructive, 3-D, large-area tribological coatings quality investigation.;Based on the experience with the RFI PECVD system, a large-scale RFICP source was designed and built for the PSIL Langmuir probe and optical emission spectroscopy studies indicated …
Thermoelastic And Photoelastic Full-Field Stress Measurement, Deonna Faye Woolard
Thermoelastic And Photoelastic Full-Field Stress Measurement, Deonna Faye Woolard
Dissertations, Theses, and Masters Projects
Photoelasticity is an optical technique that measures the difference of the principal stresses plus the principal stress direction. A complementary technique is thermoelasticity which measures the sum of the principal stresses. Combining these two full-field, non-contact nondestructive evaluation techniques allows the individual stress components to be measured. One of the main difficulties in merging these two measurement systems is in identifying an appropriate surface coating. Thermoelasticity demands a highly emissive surface, while photoelasticity requires a thick, stress-birefringent, transparent coating with a retro-reflective backing. Two coatings have been identified that can be used for combined thermoelastic and photoelastic stress measurements: PMMA …
The Role Of Adsorbed Oxygen In Secondary Emission From Metallic Substrates, Scott Gregory Walton
The Role Of Adsorbed Oxygen In Secondary Emission From Metallic Substrates, Scott Gregory Walton
Dissertations, Theses, and Masters Projects
Low energy, ion- and photon-induced secondary electron and anion emission from metallic substrates has been investigated as a function of adsorbate coverage. Sodium positive ions (Na+), with kinetic energies up to 500 eV, and photons, with energies up to 23 eV, are utilized to initiate secondary emission. The principal adsorbate is oxygen with coverages ranging from none to a few monolayers.;For ion-induced emission, the secondary electron and negative ion absolute and relative yields from 302 stainless steel and polycrystalline tungsten (W) have been measured as a function of both impact energy and oxygen coverage. Additionally, the yields from a "technical" …
On-Line System Identification For Control System Applications In Particle Accelerators, Mahesh Chowdhary
On-Line System Identification For Control System Applications In Particle Accelerators, Mahesh Chowdhary
Dissertations, Theses, and Masters Projects
Particle accelerators require a number of feedback systems in order to stabilize a variety of parameters. The Continuous Electron Beam Accelerator at Thomas Jefferson National Accelerator Facility presents a unique set of control and identification problems. This accelerator produces a continuous electron beam with energies between 0.5 and 4.0 GeV to be delivered to the experimental halls. In order to meet stringent beam quality requirements specified by the experimental halls, the position and the energy of the electron beam needs to stabilized at various locations in the accelerator.;A number of noise measurement tests were conducted at various locations in the …