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Full-Text Articles in Engineering

Raman Spectroscopic Investigation Of The Speciation Of Uranyl (Vi) And Thorium (Iv) Ions In Chloride-Bearing Aqueous Solutions Under Hydrothermal Conditions, Nadib Akram Dec 2020

Raman Spectroscopic Investigation Of The Speciation Of Uranyl (Vi) And Thorium (Iv) Ions In Chloride-Bearing Aqueous Solutions Under Hydrothermal Conditions, Nadib Akram

MSU Graduate Theses

Raman spectra were acquired for a uranyl chloride aqueous solution at temperatures ranging from 25°C to 500°C at the chloride concentration of 6M and uranium (vi) concentration of 0.05M. The measurements were taken by sealing the sample in a hydrothermal diamond anvil cell (HDAC) which enabled spectra acquisition at non-ambient conditions. The pressure inside the cell was measured by estimating the liquid-vapor homogenization temperature (TH) and using the isochoric equation of state diagram of water. The acquired spectra were then fitted to determine the speciation distribution of the various uranyl chloride species for the mentioned concentration. The developed …


Assessing Grassed Waterway Implementation Using Acpf And Swat Models, Kirsten Schaefer Dec 2020

Assessing Grassed Waterway Implementation Using Acpf And Swat Models, Kirsten Schaefer

MSU Graduate Theses

Agriculture is the most significant contributor of nonpoint source pollutants in US waterways, with sediment being the most prevalent cause of impairments. Sediment loss mitigation occurs through Best Management Practices (BMPs), such as grassed waterways. Federal and state agencies incentivize the implementation of BMPs through cost-share programs for farmers. The investment of public funds has increased pressure to demonstrate the effectiveness and value of individual projects, necessitating the development of strategies for prioritizing projects based on the sensitivity of sites to sediment erosion and optimal locations for implementation. This study has three primary objectives: (i) document existing locations of grassed …


An In-Situ Study Of The Aqueous Speciation Of Uranium (Vi) Under Hydrothermal Conditions, Diwash Dhakal May 2019

An In-Situ Study Of The Aqueous Speciation Of Uranium (Vi) Under Hydrothermal Conditions, Diwash Dhakal

MSU Graduate Theses

Rigorous study of the speciation distribution of uranyl-chloride bearing solutions under hydrothermal conditions is important to understand the transport mechanism of uranium underground, which is of uttermost interest to parties studying the geological uranium deposits and those studying the possibilities of geological repositories for spent nuclear waste. I report an in-situ Raman spectroscopic study of the speciation distribution of aqueous uranyl-chloride complexes upto 500°C conducted using a HDAC as the high PT spectroscopic cell. The samples studied contained the species UO22+, UO2Cl+, UO2Cl20 and UO2Cl3- …


Gravity And Magnetic Investigations Into Possible Economic Mineral Deposits Within The Northwest St. Francois Terrane, Southeastern Missouri, Brandon Todd Ives Jan 2015

Gravity And Magnetic Investigations Into Possible Economic Mineral Deposits Within The Northwest St. Francois Terrane, Southeastern Missouri, Brandon Todd Ives

MSU Graduate Theses

The exposed Precambrian St. Francois Mountains in southeast Missouri are a well-studied terrane of rhyolites, granites, and basaltic dikes, but much of the buried basement lithology west of the exposed region is still poorly delineated. The western St. Francois is host to large hydrothermal Pb-Zn and Fe-oxide ore deposits, some of which were located with previous geophysical investigations. The economic ore deposits specifically in the Pea Ridge Mine in Washington County contain known economic minerals and rare earth element deposits. In order to further investigate the Precambrian basement lithologies and the possible locations of additional economic ore deposits, a gravity …


Spatial Patterns And Floodplain Contributions Of Mining-Related Contaminants In Chat Creek Watershed, Southwest Missouri, Jimmy Trimble Jan 2001

Spatial Patterns And Floodplain Contributions Of Mining-Related Contaminants In Chat Creek Watershed, Southwest Missouri, Jimmy Trimble

MSU Graduate Theses

Past mining activities have left a legacy of water quality problems in the Tri-State Mining District. Contemporary environmental risks stem from the release of lead and zinc from mine tailings previously dispersed far downstream in alluvial deposits as well as abandoned tailings piles. This study examines mining-related heavy metal contamination in the Chat Creek Watershed. Chat Creek drains the area near Aurora, Missouri on the eastern edge of the Tri-State District where mining occurred from 1886 to about 1930. This study identifies the spatial distribution of metal contamination in fluvial sediments and quantifies the role of bank erosion as a …