Removel Of Polluntants From Aqueous Solution Via Graphene Oxide/Magnesium Oxide Nanocomposites, Mahdi Heidarizad

Civil and Environmental Engineering Theses and Dissertations

In this study, a series of graphene oxide/magnesium oxide nanocomposites (GO/MgO NCs) were synthesized and applied for the removal of Methylene Blue (MB) from aqueous solutions. The prepared NCs were characterized using scanning electron microscopy, transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and thermogravimetric analysis. The results showed that MgO particles were successfully layered on GO. The impacts of different experimental variables on the removal of MB including GO/MgO NCs dosage, pH, contact time, and initial MB concentration were investigated.

Thereafter, we investigate the mechanism and kinetics of ozonation processes in the presence of GO/MgO NCs as a catalyst …

Evaluation Of The Mechanisms And Effectiveness Of Nano-Hydroxides, Wood And Dairy Manure-Derived Biochars To Remove Fluoride And Heavy Metals From Water, Anna Rose Wallace, Wenjie Sun Dr, Chunming Su Dr

Civil and Environmental Engineering Theses and Dissertations

The development of effective treatment processes for the removal contaminants, such as fluoride and heavy metals, from polluted water have been urgently needed due to serious environmental health and safety concerns. In this dissertation, a variety of materials including various (hydro)oxide nanomaterials, biochars and surface modified biochar were studied to evaluate their effectiveness and mechanism on removing fluoride or mixed heavy metals from water.

In the Chapter 2, this study investigated the adsorptive removal of fluoride from water using various (hydro)oxide nanomaterials, focusing on ferrihydrite, hydroxyapatite (HAP) and brucite, which have the potential to be used as sorbents for surface …

Utilization Of Low-Lime Calcium Silicate In Hydrated And Carbonated Cementitious Materials, Mohammad Rakibul Islam Khan

Electronic Theses and Dissertations

This study investigated the potential application of wollastonite as a cementitious material in both hydrated and carbonated binder systems. Wollastonite is naturally occurring low-lime calcium silicate (CaO.SiO₂) mineral with a substantially lower carbon footprint compared to the ordinary Portland cement (OPC). The first part of this work presented the application of wollastonite as partial replacement of OPC in traditional hydrated cement-concrete system. Second part of this work evaluated the properties of carbonation activated binder produced using wollastonite as the primary ingredient.

For the first part of the thesis, ground wollastonite with 3.5 µm and 9 µm mean particle …

An Investigation On The Effects Of Cellulose Nanofibrils On The Performance Of Cement Based Composites, Hosain Haddad Kolour

Electronic Theses and Dissertations

Cellulose nanofibrils (CNFs) are hydrophilic biodegradable nanoparticles (typically, less than 0.2 mm in length and 20-50 nm in width) that can be extracted from various plants, trees, and recycled paper stock. Their low density, low toxicity, relatively low cost, high aspect ratio, and high specific surface enable functionalization. In this work, the effects of CNFs on selected properties of cement paste, mortar, and concrete were investigated. For the cement pastes, rheology tests using a simple rheometer showed a reduction in workability as CNF dosage increased. Free shrinkage tests showed an increase in shrinkage at high w/c ratios but a decrease …

A Laboratory Investigation Of Cement Based Materials With Cellulose Nanofibers, Parivash Takasi

Electronic Theses and Dissertations

Cellulose Nanofibers (CNFs) are used as additives in cement-based products to modify their properties. Recent studies about the effects of CNFs on cement paste showed inconsistent results for several different important properties, including compressive strength and free shrinkage. There is reason to believe that the unsystematic results of the compressive strengths were affected by the lack of uniform dispersion of CNFs. As a potential remedy, two different mixing methods were applied. The first method used a basic mixer, but aggregates were added to the cement paste mixture to improve the blending process. The second method utilized a high-speed shear mixer …

Two Clamped Pipe Support Connections For Oil And Gas Brownfield Projects, Helen M. Claycomb

University of New Orleans Theses and Dissertations

In the oil and gas industry, brownfield projects focus on the modification of or addition to an existing production facility that is fully operational and operating. Welding is typically avoided on these projects. The drilling of holes in existing primary structural elements is also prohibited. Clamped connections are often used when adding additional services in a brownfield project. There are different types of clamped connections utilized when a new structural support must be attached to an existing vertical structural pipe. The short bolt clamped connection is a well-established connection and typically used on offshore projects. The U-bolt clamped connection is …

Effect Of Recycled Concrete Aggregates On The Long-Term, Elastic, Total Deflection And Strength Of Precast Prestressed Hollow Core Concrete Slabs, Lizeth Marisol Gomez Santana

Civil Engineering Theses

Concrete constitutes the largest portion of construction and demolition waste generated each year in the United States. The Environmental Protection Agency (EPA) estimates that the total production of construction and demolition of concrete waste during 2015 was 381.8 million tons. In order to reduce the economic and environmental effects of waste concrete, researchers have begun to incorporate it into concrete mixtures. However, the inherent variability in mechanical properties between RCA sources makes it difficult to quantify the maximum permissible replacement of natural aggregate and the end-result properties of concrete. This project investigates the use of recycled concrete aggregates (RCA) obtained …

Concentrations, Sources, And Health Risks Of Particulate Matter In Southeast Us.: Current Status And Future Changes, Fenglin Han

LSU Doctoral Dissertations

Evaluation of long-term air quality trends and prediction of future air quality may help to design and demonstrate effectiveness of control strategies and guide future air quality management. As one of the six criteria air pollutants (CAPs) regulated by the US Environmental Protection Agency (EPA), particulate matter with aerodynamic diameter of 2.5 µm or less (PM_2.5) is of great interests since it has adverse effects on human health, visibility and climate. This study aims to understand the current status and future changes in concentrations, sources, and health risks of PM_2.5 in Southeast US. Firstly, observations were analyzed …

Self-Healing Of Concrete Under Diverse Environmental Exposure, Ahmed Ramadan Suleiman

Electronic Thesis and Dissertation Repository

Self-healing efficiency of cement-based materials has so far been evaluated mostly through the healing of surface cracks, without adequately capturing the dominant effects of environmental exposure or accurately quantifying the volume of cracks healed. In addition, the effects of diverse additions such as silica-based materials, swelling agents, superabsorbent polymers, and carbonating minerals on self-healing performance under different environmental exposure, remain largely unexplored.

In this dissertation, multiple test methods were used to investigate self-healing of cracks in cement mortar incorporating metakaolin, bentonite, fly ash, superabsorbent polymers, and calcium carbonate microfiller under different environmental exposure (i.e. cold and hot temperatures, high and …

Role Of Groundwater-Lake Interactions On The Behavior Of Chemicals In A Nearshore Aquifer, Sabina Rakhimbekova

Electronic Thesis and Dissertation Repository

It is well recognized that groundwater-surface water interactions play an important role in controlling the flux of groundwater-derived inorganic chemicals to surface waters. While these interactions have been well-studied in marine, and river and stream settings, the influence of these interactions on chemical fluxes to large lakes is poorly understood. Nearshore aquifers adjacent to inland coastal waters, such as the Great Lakes, are characterized by dynamic flow patterns and the mixing of groundwater and lake water, which have distinct chemical compositions. This sets up an important reaction zone in the nearshore aquifer that may modify the fate of groundwater-derived chemicals …

Partial Nitritation Anammox Process For Sidestream Wastewater Treatment In Mabr Technology, Panagiota Stamatopoulou

Electronic Thesis and Dissertation Repository

There has been an increased interest in alternative wastewater treatment systems to improve nutrients removal and energy consumptions while achieving acceptable discharge limits. Wastewater treatment plants (WWTP) have shifted their interest in treating the sidestream wastewater; a reject liquid post anaerobic digestion, rich in ammonium-nitrogen. A dedicated sidestream wastewater treatment unit has become an attractive option with the finding of a relatively new species of bacteria, anaerobic ammonium oxidizers (anammox), able to convert ammonium and nitrite into nitrogen gas. However, anammox bacteria are sensitive in environmental changes, and in combination with their low growth rate, it is challenging to establish …

Human-Infrastructure Interfaces (Hii) Enabled Using Augmented Reality (Ar), Dilendra Maharjan

Civil Engineering ETDs

The modern industrial society is built upon the productivity of advanced computing and agile machines assisting the human workforce to perform their tasks more effectively, accurately and efficiently. The industrial revolution termed as "Industry 4.0" is based on the intelligence of machines working with humans in a collaborative work-space. Contrarily, infrastructure management has relied on the human for making day to day decisions. New emerging technologies can assist during infrastructure inspections, to quantify structural condition with more objective data. However, today's’ owners agree in trusting the inspector's decision in the field over data collected with sensors. If data collected in …

Miniature Cone Penetration Tests With Shear Wave Velocity And Electrical Resistivity Measurements In Characterization Of Silica Sand, Ronit Ganguly

Electronic Thesis and Dissertation Repository

Geotechnical engineering design and analysis require sound identification and characterization of in-situ soil. To characterize is to gather information about the engineering properties of a particular soil which will affect the performance of any structure built on it. As a result of complications associated with the retrieving of undisturbed samples of cohesionless soils, calibration chamber-based experiments under controlled laboratory settings are used for the determination of several geotechnical engineering parameters. The capability of a reduced-scale calibration chamber-based cone penetration testing system along with shear wave velocity and electrical resistivity measurements, to better characterize in-situ soil is examined in this study. …

Anaerobic Digestion Modeling Of A High Rate Acidification Pre-Treatment Technology, Connor Pritty

Electronic Thesis and Dissertation Repository

Through the application of a computerized model (BioWin), anaerobic co-digestion (AcoD) of source separated organics (SSO) and a high rate acidification technology (pretreatment) for a conventional wastewater treatment plant was reviewed. Through this combined approach of high rate acidification, and co-digestion techniques it was found that the experimental modeling scenarios offered increases when compared to the existing base scenario production levels. With the addition of the high rate acidification technology and application of source separated organics the maximum increases in biogas production came when an OLR of 5.24 kg-COD/m³/day and 97g COD/L/d was experimentally modeled. It is therefore, recommended that …

Evaluation Of A Novel Remote Displacement Sensor Prototype Using Video And Laser-Based Technology For Civil Infrastructure Applications, Nicholas J. Brown

Civil and Environmental Engineering Master's Project Reports

Deflection measurements on structures, especially with regards to long-term monitoring, continues to be a challenge with current sensor technologies. Material degradation and changes in the mechanical properties due to aging (for example, creep and shrinkage in concrete bridges) directly impact the deflections exhibited by a structure. In this article we introduce and discuss the evaluation of a novel laser and video-based displacement sensor prototype to monitor displacements and rotations in structures remotely. The sensor is both inexpensive, using off-the shelf components, but also accurate and practical for situations that do not allow the use of conventional displacement sensors, which require …

Flood Dynamics In The Portland Metropolitan Area, Past, Present, And Future, Lumas Terence Helaire

Dissertations and Theses

The Portland area has an extensive flood history since it was founded in 1845. In the late 19th century, the Portland area was prone to flooding from snowmelt freshets (3-6 months duration) and brief winter rain or rain-on-snow events. Since that time the magnitude of spring freshets has been curtailed by 45% due to climate change, flow diversions, and reservoir management. Along with changes in hydrology, the bathymetry of the Lower Columbia River has been altered by the dredging of the navigation channel, diking, and land reclamation. To understand how these changes in hydrology and bathymetry have affected tidal and …

Galena Creek Bridge Structural Health Monitoring Instrumentation And Modeling, Leopold Falkensammer

UNLV Theses, Dissertations, Professional Papers, and Capstones

Structural health monitoring (SHM) of an instrumented structure provides numerous benefits when assessing the long-term condition of the structure against degradation, or the short-term condition after an extreme event, such as an earthquake. The Nevada Department of Transportation (NDOT) has an interest in expanding the use of SHM for such assessments. Accordingly, the objective of the current study is to develop and implement a permanent SHM system for the Galena Creek Bridge, the largest concrete cathedral arch bridge in the world, to monitor its response to routine traffic and seismic activity. Completed in 2012, the bridge connects Reno and Carson …

Treatment Of Perchlorate And Multiple Oxyanions: Chemical And Biological Investigations, Mark Elkouz

UNLV Theses, Dissertations, Professional Papers, and Capstones

Groundwater contamination with oxyanions is an issue that must be addressed for environmental, ecological and societal reasons. Chemical and biological treatment methods of reduction are already known and practiced, but the simultaneous presence of multiple oxyanions can add complicating effects to treatment sequence and efficacy. This research was concerned with the investigation of the chemical reductive treatment of Cr(VI) using both calcium polysulfide (CaSx) and ferrous sulfate (FeSO4), and the biological reductive treatment of chlorate, Cr(VI), nitrate and perchlorate using multiple organic substrates. The chemical treatment phase consisted of initial jar tests, using CaSx and FeSO4, followed by a laboratory …

Alkali-Silica Reactivity Of Mortars Containing Natural Pozzolan, Arash Kian

UNLV Theses, Dissertations, Professional Papers, and Capstones

Alkali-silica reactivity is one of the most recognized deleterious phenomena in Portland cement concrete resulting in cracks, spalling, and other deleterious mechanisms.

The aim of this study was (i) to assess the extent of reactivity of the aggregates, quarried from seven different sources, suspected of being conducive to ASR, and (ii) to compare the effectiveness of industrial (Class F fly ash) and natural pozzolans in mitigation of alkali-silica reactivity of the studied aggregates. To this end, seven aggregate sources, four natural pozzolan sources, and one source of Class F fly ash were used. ASTM Type V Portland cement was replaced …

Development Of Natural Perlite Based Concrete For Sustainable Construction, Seyedmahmoud Motaharikarein

UNLV Theses, Dissertations, Professional Papers, and Capstones

This study aimed to partially replace Portland Cement (PC) with environmentally friendly binders capable of improving the longevity of concrete. The new binders consisted of different proportions of natural pozzolan (perlite) with various fineness and particle size distributions. A step-by-step research program was designed to: (1) discover the optimum fineness of perlite powder and its optimum replacement level with cement; (2) investigate the rheological properties of the perlite-containing mixtures, and examine whether this binder can be used in selfconsolidating concrete; and (3) assess the weaknesses of the new binder, and improve its deficiencies by using nanomaterials such as nano-silica. The …

Design Of Efficient Carbon-Based Adsorbents For The Removal Of Organic And Inorganic Water Contaminants, Sayedeh Soroosh Mortazavian Dehkordi

UNLV Theses, Dissertations, Professional Papers, and Capstones

Granular activated carbon (AC) and biochar (BC) are two carbon-based adsorbents commonly used for water and wastewater treatment. However, these adsorbents have drawbacks that suppress their aqueous contaminants removal efficiency. Their major disadvantages are that AC has low selectivity and reusability potential, and BC has a hydrophobic nature.

The scope of this dissertation is to enhance the performance of commonly-used carbon-based adsorbents for the removal of organic and inorganic water contaminants and to understand the interactive mechanism of contaminants’ ions/molecules with adsorbents. Hexavalent chromium (Cr(VI)) and trichloroethylene (TCE) are two types of inorganic and organic water contaminants, respectively, which are …

Impact Of Design Cost Percentage On Cost Growth, Schedule Growth, And Construction Intensity Of Road Construction Projects, Elina Prajapati

UNLV Theses, Dissertations, Professional Papers, and Capstones

The performance of construction projects is measured in terms of cost and schedule variation. Studies have identified that such variations are mainly due to design changes, which are more frequent on projects executed through the design-bid-build (DBB) delivery method. Thus, the design factor is identified as one of the major parameters affecting the performance of DBB projects. Despite the majority of road projects being constructed following the DBB method, the impact of design cost on the performance of road projects has not been sufficiently studied yet. Therefore, this study focuses on determining the effect of design cost on the performance …

Sizing A New Bike Sharing System For The University Of Nevada, Las Vegas, Nesley Orochena

UNLV Theses, Dissertations, Professional Papers, and Capstones

The strategic planning objectives for a novel Bike Sharing Systems (BSS) are to locate the BSS stations, size the stations, and determine the bicycle fleet size, among others. Current guidelines to design BSS programs are tailored to city centers with large coverage areas and high bicycle to population ratios, and thus not directly transferable to a university setting. An ordered probit model was created using data from a university online stated preference survey to determine the key factors that affect the uptake rates for the UNLV BSS program and to estimate the potential demand. The demand analysis was incorporated into …

Carbon Management And Volatile Fatty Acid Production In Primary Clarifiers At A Wastewater Treatment Plant, Brittany Nicole Radke

UNLV Theses, Dissertations, Professional Papers, and Capstones

An increasing number of treatment plants are required to remove nutrients from domestic wastewater to lessen the impact of nutrient loading to water bodies. Enhanced Biological Phosphorus Removal (EBPR) is one of the processes commonly used to remove phosphorus from domestic wastewater. The presence of an adequate quantity of volatile fatty acids (VFA) in the wastewater influent to EBPR is important for process efficiency and stability. The objective of this research was to investigate the production of VFAs through fermentation of sludge in primary clarifiers as it related to improving nutrient removal, primarily targeting phosphorus.

The research tested, in full-scale, …

Application Of Data-Driven And Process-Based Modeling Approaches For Water Quality Simulation In Lakes And Freshwater Reservoirs, Ali Saber Sichani

UNLV Theses, Dissertations, Professional Papers, and Capstones

Lakes and freshwater reservoirs often serve as the primary drinking and irrigation water sources for surrounding communities. They provide recreational and tourism opportunities, thereby promoting the prosperity of neighboring communities. Reliable estimates of water quality in lakes and reservoirs can improve management practices to protect water resources.

Seasonal water temperature and solar shortwave radiation variations, and their subsequent interactions with water column aquatic life, combined with seasonal variations of mixing intensity throughout the water column, result in variations of water quality constituents with depth during the annual cycle. The complexity of these variations entails the use of advanced water quality …

Evaluation Of Titanosilicate Materials For The Sorption Of Cesium And Strontium From High Level Wastes, Matheus Tolentino Lauar

UNLV Theses, Dissertations, Professional Papers, and Capstones

Treatment of high-level waste (HLW) stored in the U.S. Department of Energy (U.S. DOE) sites of Hanford and Savannah River involves the separation of radioactive cesium (137Cs) and strontium (90Sr). Challenges in treating the liquid HLW includes high alkalinity or acidity, and high salt content, many orders of magnitude above Cs and Sr concentrations. Ion exchange is the preferred process for removing these compounds, due to the availability of selective media and large volume-processing capacity by column operations. The crystalline silicotitanate (Na2Ti2O3SiO4·2H2O), i.e. CST, which structure is analog to the mineral sitinakite, is considered the reference material for this application. …

Contemporary Problems In Aerosol Aggregation And Gelation, Pai Liu

McKelvey School of Engineering Theses & Dissertations

Aggregation of nanoparticles in aerosols is a fundamental phenomenon with important implications to diverse fields ranging from material synthesis to pollutant control. The past few decades have witnessed extensive research on investigating the structure and growth mechanism of aerosol aggregates with sizes spanning across several orders of magnitude. This dissertation focuses on some contemporary problems that remain unaddressed in this topical area. Aerosol aggregates in sub-micron regimes, which are formed via the irreversible collision and aggregation of solid nanoparticle monomers, are fractal-like in their morphology. A mathematical description of this seemingly random structure dates to the seminal works by Forest …

Utility Of Bench Scale Sand Tank Experiments At Assessing Permeable Reactive Barrier Design, Brandon Meier

UNLV Theses, Dissertations, Professional Papers, and Capstones

The objective of this work was to evaluate the utility of bench scale sand tank experiments at assessing permeable reactive barrier (PRB) design. Our criteria for meeting this goal was that differences between PRB designs could be identified solely by measuring concentration in outflow from the sand tank models. For our PRB designs (funnel-and-gate, staggered wells, and parallel bars), numerical simulations clearly showed that PRB design had a quantifiable effect on outflow concentration, provided that the solute reacted with the PRB materials. Conversely, use of a conservative (non-reactive) solute did not allow us to discern between PRB design alternatives. Employing …

Examining The Effectiveness Of A 4d Schedule And A Virtual Reality Model On A Modular Project: Unlv Solar Decathlon Case, Rajarshi Ghimire

UNLV Theses, Dissertations, Professional Papers, and Capstones

The use of a 4D schedule as technological advancement has brought significant improvement to the planning and execution of construction projects, through visualizing stepwise construction progress, following a sequence of pre-planned activities, and finalizing a baseline schedule with necessary changes. Moreover, the application of virtual reality (VR) to create interactive 3D models of a planned structure has made it possible to make a detailed planning of any construction project. Because of these benefits, the use of 4D schedules and VR in the construction industry has increased drastically, leading to improved planning and execution. However, past studies have given little attention …

Retrofit Of Corroded Corrugated Metal Culverts Using Gfrp Slip-Liner, Rahulreddy Chennareddy

Civil Engineering ETDs

Culverts are water conveyance structures, typically used to allow water flow and maintain a balance between the flow streams without interrupting structures such as highways and bridges. Corrugated metal pipes (CMPs) have been used as culverts in North America since the 1950s because of their low cost and simple construction method. Today, the corrosion of CMPs is a major problem faced by all U.S. Departments of Transportation. There is an urgent need to provide an efficient solution, one that is corrosion-resistant, to retrofit thousands of corroded CMPs across the country. High specific strength, high strength to weight ratio, corrosion resistance, …