Engineering Commons^™

Sugarcane Bagasse Hydrolysis Enhancement Using Bsa, Antonio Carlos Freitas Dos Santos

Open Access Theses

Lignocellulose is composed of polysaccharides linked to lignin and other aromatic compounds, making the sugars not readily available to fermentation. This entails that biomass must go through the unit operations of pretreatment and enzyme hydrolysis. Pretreatment opens the structure to allow the enzymes to act on and hydrolyze cellulose and hemicellulose to glucose and/or xylose which in turn are fermented to ethanol. Concomitantly, the enzymes interact with soluble phenols and insoluble solids derived from lignin that inhibit hydrolysis. This leads to high enzyme loadings and higher production costs. Soluble phenols can be eliminated through washing. Insoluble lignin, however, demands another …

Design And Plan Of A Modified Hydroponic Shipping Container For Research, John A. Houtman

Open Access Theses

As the world’s population continues to increase, food production will need to increase in order to meet the predicted rise in food demand. However, with increased pressure on cropland available from environmental effects and urbanization, new innovative methods of crop production need to be researched in order to increase agricultural production with limited land. This research focuses on the design of a single form of urban agriculture that is considered Zfarming and has the potential to produce quality urban agricultural produce through ground-based measures. This project produced detailed step-by-step analysis of the design process, develop variability within the modified hydroponic …

Exploring The Cause Of Injury Or Death In Grain Entrapment, Engulfment And Extrication, Salah F. Issa

Open Access Dissertations

Grain entrapments and engulfments are one of most common hazards associated with grain storage facilities. Since the 1970’s over 1,880 incidents have been documented in agricultural confined spaces of which 65% of all recorded incidents were grain entrapments and engulfments. There have been several studies conducted on the contributing factors behind these incidents; however, there have been very few attempts to understand the environmental, physiological or psychological factors the victims experience while entrapped, engulfed, or extricated. This includes understanding how secondary injuries are caused by grain or during extrication by first responders. The research effort was divided into three segments. …

Investigation Of Methods For Reducing Aflatoxin Contamination In Distillers Grains, Hu Shi

Open Access Dissertations

The overall goal of this project was to reduce the aflatoxin level in the final coproduct of ethanol bioprocessing--DDGS. This was pursued by examining the effects of reduction of aflatoxin in the incoming corn prior to bioprocessing, the degradation of aflatoxin in the intermediate products, namely DWG and CDS, during processing, and aflatoxin degradation in the DDGS. Segregation techniques (size screening and density sorting) and detoxification methods (conventional and microwave heating, food additives, and high voltage atmospheric cold plasma) were evaluated for their effectiveness in aflatoxin reduction.

Effectiveness of physical segregation of aflatoxin contaminated corn was investigated by size screening …

Organizing Historical Agricultural Data And Identifying Data Integrity Zones To Assess Agricultural Data Quality, Elizabeth Marie Hawkins

Open Access Dissertations

As precision agriculture transitions into decision agriculture, data driven decision- making has become the focus of the industry and data quality will be increasingly important. Traditionally, yield data cleaning techniques have removed individual data points based on criteria primarily focused on the yield values. However, when these methods are used, the underlying causes of the errors are often overlooked and as a result, these techniques may fail to remove all of the inaccurate data or remove “good” data. As part of this research, an alternative to data cleaning was developed. Data integrity zones (DIZ) within each field were identified by …

Design And Analysis Of A High Performance Valve, Jordan M. Garrity

Open Access Theses

Most valves available in the fluid power industry today are capable of achieving either a large flow rate or a quick response time; however, often they are unable to deliver both simultaneously. Commercially available valves that can produce both at the same time require complex geometries with multiple actuation stages and piloting pressures, making them expensive components. To establish their active usage in applications across the fluid power industry, a reduction in price for these components is paramount. The Energy Coupling Actuated Valve (ECAV) is capable of solving the large flow rates with fast actuation speeds trade-off by utilizing a …

Simulation Of Flow And Water Quality From Tile Drains At The Watershed And Field Scale, Colleen Moloney

Open Access Theses

Simulation models such as the Soil and Water Assessment Tool (SWAT) have become widely used in determining the water quality impacts of various management practices. Ensuring that the algorithms accurately represent the processes simulated has become an important goal. Tile drainage is a standard practice in the Midwest, US in order to reduce risk of yield loss due to excess water. Multiple tile drainage and water table algorithms have been available in the SWAT model between the initial SWAT release and revision 638 used in this study. Testing of those algorithms is often limited. Furthermore, algorithms in the current version …

Mapping And Analyzing Energy Use And Efficiency In A Modified Hydroponic Shipping Container, Rachel E. Sparks

Open Access Theses

In urban centers today, vertical farming is becoming a popular alternative to conventional agriculture in an effort to increase local food production and improve urban food security by growing crops using hydroponic methods in controlled environment spaces. More specifically, one vertical method involves growing crops inside refurbished shipping containers, or a “farm-in-a-box” concept, which offers a flexible, mobile, and scalable means of year-round food production in a variety of climates. Despite benefits of producing food locally, some of the concerns associated with these vertical farming systems include high energy consumption from climate control and electric lighting systems as well as …

Enzymatic Liquefaction Of Untreated Corn Stover, Neal N. Hengge

Open Access Theses

There is an ever increasing need for renewable alternatives to fossil fuels derived from petroleum. This makes feedstocks in the form of lignocellulosic biomass attractive substrates for the production of ethanol and value added chemicals. However, the economics of converting lignocellulosic materials involve high processing costs attributed with pretreatment of the biomass and the use of enzymes for saccharification. Corn stover was obtained for the examination of an upstream processing step to transform the material into a pumpable slurry for subsequent pretreatment and saccharification. Biomass liquefaction was carried out using the enzyme Depol 692L (Biocatalysts, Wales, UK) at 50°C with …

Investigation Of Climate Variability And Climate Change Impacts On Corn Yield In The Eastern Corn Belt, Usa, Ruoyu Wang

Open Access Dissertations

The increasing demand for both food and biofuels requires more corn production at global scale. However, current corn yield is not able to meet bio-ethanol demand without jeopardizing food security or intensifying and expanding corn cultivation. An alternative solution is to utilize cellulose and hemi-cellulose from perennial grasses to fulfill the increasing demand for biofuel energy. A watershed level scenario analysis is often applied to figure out a sustainable way to strike the balance between food and fuel demands, and maintain environment integrity. However, a solid modeling application requires a clear understanding of crop responses under various climate stresses. This …

Simulation Of Conservation Practice Effects On Water Quality Under Current And Future Climate Scenarios, Carlington W. Wallace

Open Access Dissertations

Analysis of the effects of implementing different conservation practices, as well as increased levels of conservation practices under existing and projected future climate, will determine if current conservation practice recommendations will be sufficient to maintain soil and water resources. The Soil and Water Assessment Tool (SWAT) was used to study four watersheds of different sizes (CCW = 680 km2, F34 = 183 km2, AXL = 42 km 2 and ALG = 20 km2) located in Northeastern Indiana. The overarching goal of this study was to evaluate the effect of various agricultural practices on runoff and agricultural chemical losses under current …

Effect Of Bioenergy Crops And Fast Growing Trees On Hydrology And Water Quality In The Little Vermilion River Watershed, Tian Guo

Open Access Dissertations

Energy security and sustainability require a suite of biomass crops, including woody species. Short rotation woody crops (SRWCs) such as Populus have great potential as biofuel feedstocks. Quantifying biomass yields of bioenergy crop and hydrologic and water quality responses to growth is important should it be widely planted in the Midwestern U.S. Subsurface tile drainage systems enable the Midwest area to become highly productive agricultural lands, but also create environmental problems like nitrate-N contamination of the water it drains. The Soil and Water Assessment Tool (SWAT) has been used to model watersheds with tile drainage, but the new tile drainage …

Investigating U.S. Resident Perceptions Of Corporate Social Responsibility In Food And Agriculture, Carissa Jae Morgan

Open Access Theses

Corporations are prioritizing corporate social responsibility (CSR) activities by investing in and actively promoting their social practices. In the U.S. of the modern food supply chain creates a unique challenge for corporations to address concerns about social issues of consumers and non-consumers alike. This study is motivated by the need to better understand individuals’ perceptions of CSR as it pertains to the food supply chain. In April 2015 an online survey collected information from 1,201 U.S. residents with the objective of investigating individuals’ perceptions of relative importance of eight prominent CSR areas relevant to food and agriculture. Demographic, household consumption, …

Enhancing Bioethanol Fermentation Through Removal Of Acetic Acid Using Liquid-Liquid Extraction, Mahdieh Aghazadeh

Open Access Dissertations

The concern for the ever growing human population as well as the depletion of fossil fuel resources and their impact on global warming have long been motivations for the researchers to investigate means for sustainable producing carbon-neutral energy. Second-generation biofuel refers to liquid fuels that are produced from non-food resources and reduce the total greenhouse gas emission by at least 60 %. Acetic acid has been shown to be one of the most ubiquitous fermentation inhibitors in a bioethanol production facility which slows down the bioethanol production and reduces its yield through inhibition of the ethanol producing microorganisms. The use …

Development And Evaluation Of A Watershed-Scale Hybrid Hydrologic Model, Younghyun Cho

Open Access Dissertations

A watershed-scale hybrid hydrologic model (Distributed-Clark), which is a lumped conceptual and distributed feature model, was developed to predict spatially distributed short- and long-term rainfall runoff generation and routing using relatively simple methodologies and state-of-the-art spatial data in a GIS environment. In Distributed-Clark, spatially distributed excess rainfall estimated with the SCS curve number method and a GIS-based set of separated unit hydrographs (spatially distributed unit hydrograph) are utilized to calculate a direct runoff flow hydrograph, and time-varied SCS CN values and conditional unit hydrograph approach for different runoff depth-based flow convolution are also used to compute long-term rainfall-runoff flow hydrographs. …

Rearward Visibility Issues Related To Agricultural Machinery: Contributing Factors, Potential Solutions, Shawn Gregory Ehlers

Open Access Dissertations

As the size, complexity, and speed of tractors and other agricultural self-propelled machinery have increased, so have the visibility-related issues, placing significant importance on the visual skills, alertness, and reactive abilities of the operator. Rearward movement of large agricultural equipment has been identified in the literature as causing not only damage to both machine and stationary objects, but also injuries (even fatalities) to bystanders not visible to the operator. Fortunately, monitoring assistance, while not a new concept, has advanced significantly, offering operators today more options for increasing awareness of the area surrounding their machines. In this research, an attempt is …

Hydrologic And Water Quality Impacts From Perennial Crop Production On Marginal Lands, Qingyu Feng

Open Access Dissertations

Marginal lands are proposed as a viable option for producing biofeedstocks as these lands are not heavily engaged in agricultural production or may not be suitable for intensive row-crop food/feed production. However, meeting biofeedstock production goals will require large amount of marginal lands and the unintended consequences of producing biofeedstocks on marginal lands are not fully clear. The overall goal of this study was to evaluate the productivity of biofeedstocks on marginal lands and the potential impacts on hydrologic and water quality processes from the land use conversion.

This study was conducted in the Upper Mississippi River Basin (UMRB). First, …

Estimating The Water Quality Condition Of River And Lake Water In The Midwestern United States From Its Spectral Characteristics, Jing Tan

Open Access Dissertations

This study focuses on developing/calibrating remote sensing algorithms for water quality retrieval in Midwestern rivers and lakes. In the first part of this study, the spectral measurements collected using a hand-held spectrometer as well as water quality observations for the Wabash River and its tributary the Tippecanoe River in Indiana were used to develop empirical models for the retrieval of chlorophyll (chl) and total suspended solids (TSS). A method for removing sky and sun glint from field spectra for turbid inland waters was developed and tested. Empirical models were then developed using a subset of the field measurements with the …

Effect Of Maleic Acid On The Selectivity Of Glucose And Fructose Dehydration And Degradation, Ximing Zhang

Open Access Dissertations

5-Hydroxymethyfurfural (HMF), a platform chemical can upgrade to a variety of fuels and polymers, can be manufactured from lignocellulose. This study focuses on the Lewis and Brønsted acid effect on hexose dehydration for HMF production. We report the positive effect of maleic acid, a dicarboxylic acid used as Brønsted acid, on the selectivity of hexose dehydration to 5-hydroxymethyfurfural (HMF), and subsequent hydrolysis to levulinic and formic acids. We also describe the kinetic analysis of a Lewis acid (AlCl ₃) alone and in combination with HCl or maleic acid to catalyze the isomerization of glucose to fructose, dehydration of fructose …

Development And Application Of Quantitative Methods For Ecosystem Services, Rebecca A. Logsdon

Open Access Dissertations

Ecosystem services are benefits that people receive from the environment. Despite recent exponential increases in ecosystem service research, the ecosystem service framework has made little impact on policy and land management decisions, especially in the United States. Two of the main limitations for a lack of ecosystem service considerations in both policy and land management decisions are a need for more advanced quantification methods and the lack of engagement of key stakeholders who are responsible for making land management decisions. This research seeks to address these two limitations by testing and improving quantification methods of ecosystem services and by evaluating …

A Nearly Autonomous, Platform-Independent Mobile App For Manure Application Records, Matthew R. Koester

Open Access Theses

A major part of modern manure management is accurate application records; a key to their creation and maintenance is ease. This project involved the integration of existing technologies (smartphones, Bluetooth tags) in mobile web and native Android applications (apps) which enable the autogenic creation and upkeep of manure hauling records. This approach greatly improves the efficiency of the recording process which should help to improve the management of applied nutrients. Features of the app include: computation of a suggested travel speed to ensure target nutrient application (based on desired application rate and spreading width); minimized keystrokes/screen taps to accurately capture …

Kernel And Bulk Density Changes Due To Moisture Content, Mechanical Damage, And Insect Damage, Danping Guo

Open Access Theses

Corn (Zea Mays), is one of the major grain crops in the world and moisture content, mechanical damage and insect damage are three factors that affect its quality. The primary goal of this thesis was to investigate the effects of moisture content, mechanical damage and insect damage on kernel and bulk density of corn. The study was conducted using two corn hybrids, Pioneer 1352 and Pioneer 1221, that were grown on Purdue Agronomy Farm for Research and Education (ACRE), manually picked and shelled. In Objective 1, the effect of three different moisture conditioning processes (drying from harvest moisture, …

Smart V-Belt, Kyle J. Mosier

Open Access Theses

The purpose of this research was to develop a method for detecting premature failure in a v-belt using capacitance and resistance readings. Another goal of the research was to detect tension values on the belt using the same readings. Materials of current belts and possible materials for a prototype belt were tested. Materials were chosen, and prototype belts were built. Pulley system configurations were developed and built. Sections of the belt designs were tested for capacitance and resistance before and after various methods of damage. Capacitance was chosen as the better sensing method. Certain layered belt configurations and sheave configurations …

Improvement Of Simulating Bmps And Lid Practices In L-Thia-Lid Model, Yaoze Liu

Open Access Dissertations

Best management practices (BMPs) and low impact development (LID) practices are popular approaches used to reduce the negative impacts of urbanization on hydrology and water quality. To assist planners and decision-makers in urban development projects, user-friendly tools are needed to assess the effectiveness of BMPs and LID practices on water quantity and quality. To address this need, the Long-Term Hydrologic Impact Assessment-LID (L-THIA-LID) model was enhanced with additional commonly used BMPs and LID practices represented in the model, improved approaches to estimate hydrology and water quality, and representation of practices in series. The tool was used to evaluate the performance …

Climate Change Impact Assessments Using The Water Erosion Prediction Project Model, Joseph Trotochaud

Open Access Theses

This study was conducted to develop a simplified method of obtaining future climate data inputs for natural resource models and apply that method to three locations within the continental United States to assess the effect of climate change on soil erosion, runoff, and fire risk. A method was developed for quickly obtaining future climate data over a wide range of scenarios, General Circulation Models (GCMs), and timescales from the Intergovernmental Panel on Climate Change (IPCC) Fourth Assessment Report (AR4) and Fifth Assessment Report (AR5) model families using the MarkSim^® DSSAT Weather Generator and a Microsoft Excel VBA Macro, the …

Watershed Delineation In The Field: A New Approach For Mobile Applications Using Lidar Elevation Data, Samuel Adam Noel

Open Access Theses

With the advancement of mobile devices, opportunities to take watershed management tasks out of the office and into the field can be realized. In turn, field workers can utilize these technologies to expedite the decision-making process so that they may focus on meeting with clients and addressing agricultural watershed management issues. High-resolution (∼1.5 m postspacing) elevation data gathered by light detection and ranging (LiDAR) provides the topographic detail necessary to model hydrology at the field-scale (∼1 km2).

Non-artifactual surface depressions lead to erroneous surface flow patterns when using existing algorithms. So a sequential depression-filling algorithm (SDFA) has been developed to …

Using Energy-Efficient Technologies To Produce Bedding Plants And Microgreens In Protected And Controlled Environments, Joshua R. Gerovac

Open Access Theses

Gerovac, Joshua R. M.S., Purdue University, December 2014. Using Energy-Efficient Technologies to Produce Bedding Plants and Microgreens in Protected and Controlled Environments. Major Professor: Roberto G. Lopez. Production of bedding plants in commercial greenhouses (GHs) located in northern latitudes begins in late winter and continues through late spring when low outdoor temperatures generally necessitate active heating to maintain temperatures suitable for growth and development. Meanwhile, year-round production of microgreens using multi-layer systems requires sole-source (SS) photosynthetic lighting for production. Energy used to provide active heating in commercial GHs or SS lighting in multi-layer systems is second only to labor as …

Differences In Carbon Dioxide Evolution From Samples Of Shelled Corn Subjected To Various Storage Treatments, Cininta Alp Pertiwi

Open Access Theses

Shelled corn was collected from two sources - commercial grain elevators and corn harvested from Purdue University farms and then frozen until tested. Using a carbon dioxide (CO₂) test kit manufactured by Woods End Laboratories, CO₂ evolution measurements were conducted on shelled corn from both sources, after the samples were re-wetted to approximately 21% moisture content, placed in a 473 ml glass jar, and incubated at room temperature for 72 hours. The CO₂ test kit uses a gel that changes color in response to a change in the level of CO₂ in the surrounding air. …

Solvent System Selection For Xylooligosaccharides Separation By Centrifugal Partition Chromatography Using Conductor-Like Screening Model For Real Solvents, He Zhang

Open Access Theses

The production of value-added, bio-based industrial commodity chemicals is an important area in science right now and this study provides an initial step in the recovery of bio-based chemicals from hemicellulose. Hemicellulose is a long chain polymer mostly consisting of xylose, which is a five-carbon sugar, and a variety of other compounds that are ubiquitous in plant life. The hemicellulose polymer chain can be depolymerized into smaller components, called xylooligosaccharides (XOS) with different chain lengths of xylose linked by beta-1-4 glycosidic bonds, using either hot water, or dilute sulfuric acid. The xylooligosaccharides can then be purified from one another from …

Physical And Chemical Attributes Of A Genetically Modified Fruit Pectin, Carl Patrick Littrell

Open Access Theses

Pectin is an important polymer used in the food industry as a thickening and gelling agent. Though pectin is ubiquitous in plants, chemical and structural differences among pectin molecules prevent most from being viable for industrial use. Enzymes found naturally in fruit cell walls during the ripening process impair many desirable attributes of fruit pectins, rendering them unsuitable for industrial applications. Pectin methylesterase (PME) is one such enzyme whose expression can be altered during ripening through the use of recombinant genetic engineering. Reduction in levels of PME results in increased degree of methylation and molecular size of pectin, greatly increasing …