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Materials Science and Engineering Faculty Research & Creative Works

2001

Articles 1 - 8 of 8

Full-Text Articles in Engineering

Size-Induced Lattice Relaxation In Ceo₂ Nanoparticles, X.-D. Zhou, Wayne Huebner Nov 2001

Size-Induced Lattice Relaxation In Ceo₂ Nanoparticles, X.-D. Zhou, Wayne Huebner

Materials Science and Engineering Faculty Research & Creative Works

Size-induced lattice relaxation was observed for nanoscale CeO2 single crystals with an average size from 4 to 60 nm. Results showed the finest crystallites exhibited no strain-induced line broadening, while high temperature annealing resulted in larger grain sizes and significant strains. The observed shift in the x-ray diffraction lattice parameters was assumed to be due to the formation of defects on the lattice, specifically oxygen vacancies. Modeling revealed that the oxygen vacancy concentration ([V••O]) was found to be ≈4 x 1020/cm3 for the 4 nm crystallites, and decreased two orders of magnitude for …

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Ultrasonic Characterization Of Poling In Lead Zirconate Titanate Ceramics, James R. Friend, Eric Jamieson, Marvin Pennell, Wayne Huebner Oct 2001

Ultrasonic Characterization Of Poling In Lead Zirconate Titanate Ceramics, James R. Friend, Eric Jamieson, Marvin Pennell, Wayne Huebner

Materials Science and Engineering Faculty Research & Creative Works

A method for measuring the spatial variation of the macroscopic poling state of a piezoelectric material using an ultrasonic transducer is described. The relatively simple method clearly indicates the distribution of poling within the material, demonstrated by the testing of a collection of partially poled lead zirconate titanate samples.

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Ni-Induced Local Distortions In La₁.₈₅Sr₀.₁₅Cu1-YNiYO₄ And Their Relevance To Tc Suppression, Daniel Haskel, Edward A. Stern, Victor Polinger, Fatih Dogan Aug 2001

Ni-Induced Local Distortions In La₁.₈₅Sr₀.₁₅Cu1-YNiYO₄ And Their Relevance To Tc Suppression, Daniel Haskel, Edward A. Stern, Victor Polinger, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

We present results from angular-resolved x-ray-absorption fine-structure (XAFS) measurements at the Ni, La, and Sr K edges of oriented powders of La1.85Sr0.15Cu1-yNiyO4, with y=0.01, 0.03, 0.06. A special magnetic alignment procedure allowed us to measure pure ĉ- and ab-oriented XAFS at the Ni K edge in identical fluorescence geometries. Both the x-ray-absorption near-edge structure and the XAFS unequivocally show that the NiO6 octahedra are contracted along the c axis by ≈0.32Å relative to CuO6 octahedra while the in-plane distances of NiO6 and CuO6 octahedra are the same within 0.01Å. The NiO6 octahedral contraction drives the average ĉ axis contraction measured …

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Observation Of Magnetic Moments In The Superconducting State Of Yba₂Cu₃O₆.₆, Herbert A. Mook, Pengcheng Dai, Fatih Dogan May 2001

Observation Of Magnetic Moments In The Superconducting State Of Yba₂Cu₃O₆.₆, Herbert A. Mook, Pengcheng Dai, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

Neutron scattering measurements for YBa2Cu3O6.6 have identified small magnetic moments that increase in strength as the temperature is reduced below T* and further increase below Tc. An analysis of the data shows the moments are antiferromagnetic between the Cu-O planes with a correlation length of longer than 195 Å in the a-b plane and about 35 Å along the c axis. The origin of the moments is unknown, and their properties are discusssed both in terms of Cu spin magnetism and orbital bond currents.

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Dopant Structural Distortions In High-Temperature Superconductors: An Active Or A Passive Role?, Daniel Haskel, Edward A. Stern, Fatih Dogan, Arnie R. Moodenbaugh Mar 2001

Dopant Structural Distortions In High-Temperature Superconductors: An Active Or A Passive Role?, Daniel Haskel, Edward A. Stern, Fatih Dogan, Arnie R. Moodenbaugh

Materials Science and Engineering Faculty Research & Creative Works

The parent compounds of high-temperature superconductors, such as YBa2Cu3O6 and La2CuO4, are strongly interacting electron systems, rendering them insulators with Mott-Hubbard gaps of a few electronvolts. Charge carriers (holes) are introduced by chemical doping, causing an insulator-metal (IM) transition and, at low temperatures, superconductivity. the role of dopants is widely seen as limited to the introduction of holes into the CuO2 planes (i.e. occupying electronic states derived from Cu and O 2px,y atomic orbitals). Most theories of high-Tc superconductivity deal with pairing interactions between these planar holes. Local distortions around dopants are poorly understood, because of the experimental difficulty in …

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Agglomerated Die Casting Lubricant, Mary R. Reidmeyer Jan 2001

Agglomerated Die Casting Lubricant, Mary R. Reidmeyer

Materials Science and Engineering Faculty Research & Creative Works

A lubricant for use in lubricating the shot sleeve of a machine for die casting molten metals is in the form of agglomerated particles. The particles have an inorganic high pressure lubricant agglomerated, with a binder material and with an organic material. The solid lubricant is resistant to dusting, caking and breakage, can be fed through an automatic dispensing machine, and combines inorganic and organic materials to achieve excellent lubrication properties. The product has low flash and low smoke release into the environment.

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Chemical Plating Method, Electrolytic Cell And Automotive Oxygen Sensor Using It, Mary R. Reidmeyer, Matthew J. Donelon, Robert F. Killion Jan 2001

Chemical Plating Method, Electrolytic Cell And Automotive Oxygen Sensor Using It, Mary R. Reidmeyer, Matthew J. Donelon, Robert F. Killion

Materials Science and Engineering Faculty Research & Creative Works

An automotive lambda oxygen sensor is formed by electroless plating of a thin, catalytically active, conductive electrode uniformly on the outer surface of a zirconia thimble. The process includes forming a pristine zirconia solid electrolyte thimble and drilling out a cylindrical cavity in it. A porous outer surface suitable for producing crystallization sites is formed by dipping the unfired thimble in a zirconia slurry containing spray-dried microspheres and firing the coated thimble to densify the thimble and the microspheres and to produce cavities on the surface of the thimble. An inner platinum electrode is formed by conventional conductive ink painting …

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Evolution Of The Resonance And Incommensurate Spin Fluctuations In Superconducting Yba₂Cu₃O₆₊ₓ, Pengcheng Dai, Herbert A. Mook, Rodney Dale Hunt, Fatih Dogan Jan 2001

Evolution Of The Resonance And Incommensurate Spin Fluctuations In Superconducting Yba₂Cu₃O₆₊ₓ, Pengcheng Dai, Herbert A. Mook, Rodney Dale Hunt, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

Polarized and unpolarized neutron triple-axis spectrometry was used to study the dynamical magnetic susceptibility Χ″(q, ω) as a function of energy (ℏ ω) and wave vector (q) in a wide temperature range for the bilayer superconductor YBa2Cu3O6+x with oxygen concentrations, x, of 0.45, 0.5, 0.6, 0.7, 0.8, 0.93, and 0.95. The most prominent features in the magnetic spectra include a spin gap in the superconducting state, a pseudogap in the normal state, the much-discussed resonance, and incommensurate spin fluctuations below the resonance. We establish the doping dependence of the spin gap in the superconducting state, …

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