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Full-Text Articles in Engineering

From Waste To Energy: The Electrochemical Reduction Of Co2 Using Recycled Nanostructured Catalysts, Ibrahim Badawy Jul 2023

From Waste To Energy: The Electrochemical Reduction Of Co2 Using Recycled Nanostructured Catalysts, Ibrahim Badawy

Theses and Dissertations

The reduction of carbon dioxide (CO2RR) using electrochemistry is a promising solution for the burgeoning global energy crisis. The overall vision of its implementation relies on renewable energy sources to power the reaction creating carbon neutral products and effectively closing the carbon cycle. Research in this field has come a long way since its inception in the mid-1900s. However, there remain significant hurdles and important considerations to overcome in order to reach full commercialization. Most electrocatalysts tested for CO2RR have been designed solely for maximum performance while ignoring the environmental consequences if such a material were …


Towards Structured Planning And Learning At The State Fisheries Agency Scale, Caleb A. Aldridge Dec 2022

Towards Structured Planning And Learning At The State Fisheries Agency Scale, Caleb A. Aldridge

Theses and Dissertations

Inland recreational fisheries has grown philosophically and scientifically to consider economic and sociopolitical aspects (non-biological) in addition to the biological. However, integrating biological and non-biological aspects of inland fisheries has been challenging. Thus, an opportunity exists to develop approaches and tools which operationalize planning and decision-making processes which include biological and non-biological aspects of a fishery. This dissertation expands the idea that a core set of goals and objectives is shared among and within inland fisheries agencies; that many routine operations of inland fisheries managers can be regimented or standardized; and the novel concept that current information and operations can …


Tree Ring Reconstructions Of Streamflow For The Lower Rio Grande Valley Of Texas, Adedolapo Mutiyat Adeyanju Aug 2022

Tree Ring Reconstructions Of Streamflow For The Lower Rio Grande Valley Of Texas, Adedolapo Mutiyat Adeyanju

Theses and Dissertations

The Rio Grande River is a major water source for people living within the USA-Mexico border. The Rio Grande River has its headwaters in the San Juan Mountains in Colorado and the Sierra Madre Occidental in Mexico before flowing into Texas through El-Paso. The water supply issues facing the Lower Rio Grande Basin (LRGB) are extremely complex from international restrictions to severe climate change. The river shares its flow between the U.S.A and Mexico based on the provisions of the 1944 treaty between the U.S.A and Mexico. The LRGB flow is regulated by releases from Falcon and Amistad Reservoirs managed …


Impact Of Climate Oscillations/Indices On Hydrological Variables In The Mississippi River Valley Alluvial Aquifer., Meena Raju May 2022

Impact Of Climate Oscillations/Indices On Hydrological Variables In The Mississippi River Valley Alluvial Aquifer., Meena Raju

Theses and Dissertations

The Mississippi River Valley Alluvial Aquifer (MRVAA) is one of the most productive agricultural regions in the United States. The main objectives of this research are to identify long term trends and change points in hydrological variables (streamflow and rainfall), to assess the relationship between hydrological variables, and to evaluate the influence of global climate indices on hydrological variables. Non-parametric tests, MMK and Pettitt’s tests were used to analyze trend and change points. PCC and Streamflow elasticity analysis were used to analyze the relationship between streamflow and rainfall and the sensitivity of streamflow to rainfall changes. PCC and MLR analysis …


Photocatalytic Degradation Of Organic Contaminants By Titania Particles Produced By Flame Spray Pyrolysis, Noah Babik May 2022

Photocatalytic Degradation Of Organic Contaminants By Titania Particles Produced By Flame Spray Pyrolysis, Noah Babik

Theses and Dissertations

Advanced oxidation of organic pollutants with TiO2 photocatalysts is limited due to the wide bandgap of TiO2, 3.2 eV, which requires ultraviolet (UV) radiation. When nanosized TiO2 is modified by carbon doping, charge recombination is inhibited and the bandgap is narrowed, allowing for efficient photodegradation under visible light. Here, we propose a flame spray pyrolysis (FSP) technique to create TiO2. The facile process of FSP has been successful in preparing highly crystalline TiO2 nanoparticles. Using the same procedure to deposit TiO2 onto biochar, the photocatalyst was doped by the carbonaceous material. The morphology, crystalline and electronic structure of the FSP …


Investigation Of A Simultaneaous Direct And Indirect Contact Dehumidifier Using Parallel Strings For Hdh Desalination, Josue Perez Perez May 2022

Investigation Of A Simultaneaous Direct And Indirect Contact Dehumidifier Using Parallel Strings For Hdh Desalination, Josue Perez Perez

Theses and Dissertations

Freshwater is a limited and precious resource. Currently, half a billion people in the world face sever water scarcity all year round. Humidification dehumidification (HDH) systems have received special attention among the variety of small-scale desalination technologies due to its potential to create affordable and sustainable seawater desalination, especially when combined with natural power sources such as waves, wind, and solar rays. Improvements in the development of HDH desalination systems have been achieved in recent years. Nonetheless, the improvements that have received most attention focus on solar heaters and humidifiers. Dehumidification systems have often been adapted from air conditioning condensation …


Hydrologic Modeling Study To Determine Hydrologic Impact Of Resacas On The Lower Laguna Madre Watershed, Antonio L. Reyna May 2022

Hydrologic Modeling Study To Determine Hydrologic Impact Of Resacas On The Lower Laguna Madre Watershed, Antonio L. Reyna

Theses and Dissertations

During a high intensity storm events, a series of catastrophic events occur. These catastrophic events include flooding and destruction of infrastructure. Engineers have determined a method to design for high intensity storms based off hydrologic analysis of previous storms. With this data engineers can determine the outflow of major rivers and streams that may impact infrastructure. By determining the watershed engineers can predict the flow of the water and as well as the location of the outfall. In the Rio Grande Valley, water quality is very important because after rain events stormwater from cities is carried out towards the Laguna …


Water Quality Monitoring To Assess Pollutant Loadings In Brownsville Ship Channel Watershed, Ivan Rene Santos Chavez May 2022

Water Quality Monitoring To Assess Pollutant Loadings In Brownsville Ship Channel Watershed, Ivan Rene Santos Chavez

Theses and Dissertations

The Brownsville Ship Channel (BSC) was listed as an impaired waterway from 2010 to 2018 due to screening levels of bacteria concentration. This study aims to address water quality at the three main tributary ditches draining into Brownsville Ship Channel to model present along with future pollutant loads within Brownsville Ship Channel Watershed. Load Duration Curves (LDCs) and Spatial Explicit Load Enrichment Calculation Tool (SELECT) models were developed to determine if current pollutant loads meet water quality standards stablished by the Texas Commission on Environmental Quality (TCEQ), and to estimate average daily potential E. Coli loading contribution from sub-watersheds within …


Efficiency Mapping And Determination Of Reliability, Resiliency And Vulnerability Of Atmospheric Water Generators In The United States, Erica F. Sadowski Mar 2022

Efficiency Mapping And Determination Of Reliability, Resiliency And Vulnerability Of Atmospheric Water Generators In The United States, Erica F. Sadowski

Theses and Dissertations

Atmospheric Water Generators (AWG) extract water from the air using one of three available technologies: refrigeration, sorption, and fog harvesting. A refrigeration device works like a dehumidifier and works best in conditions above 60% relative humidity. A sorption device utilizes a desiccant to extract the water vapor from the air and works in very low humidity levels. A fog harvesting device utilizes a mesh to capture the water vapor from the air and requires 100% relative humidity. In this research, I analyze two refrigeration-based devices and one sorption-based device and their efficacy in providing supplemental water supply. Due to climatological …


Persistence And Mitigation Of Pfas Within Concrete Stormwater Drainage Infrastructure, Jason R. Mcdonald Mar 2022

Persistence And Mitigation Of Pfas Within Concrete Stormwater Drainage Infrastructure, Jason R. Mcdonald

Theses and Dissertations

The persistence, fate, and transport of per- and poly-fluoroalkyl substances, which have been shown to have adverse effects on human health, have been previously studied in environmental media such as soils and groundwater. This study investigates concrete, a medium that is rarely studied but frequently present in instances where PFAS originating from AFFF releases and spills have occurred. Used heavily throughout aviation firefighting, AFFF poses environmental hazards due to the length of PFAS degradation and toxicological implications, thus its classification as a forever chemical. From the very limited reports to date, studies have suggested very slow release from concrete, potentially …


Design And Fabrication Of Nanostructured Electrodes For Complementary Electrochemical And Photoelectrochemical Water Splitting, Kholoud El Sayed Abousalem Jan 2022

Design And Fabrication Of Nanostructured Electrodes For Complementary Electrochemical And Photoelectrochemical Water Splitting, Kholoud El Sayed Abousalem

Theses and Dissertations

Designing highly active, durable, and nonprecious electrodes for overall water splitting is of urgent scientific importance to realize sustainable hydrogen production. Accordingly, the need to search efficient energy production systems is of crucial necessity. In this thesis, two various systems for sustainable hydrogen production have been reported using electrochemical and photoelectrochemical pathways. In the first part of the thesis, electrochemical water splitting involving both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) has been established. To this end, an innovative approach is demonstrated to synthesize flower-like 3D homogenous trimetallic Mn, Ni, Co phosphide catalysts directly on nickel foam via …


Development Of A Cyberinfrastructure For Assessment Of The Lower Rio Grande Valley North And Central Watersheds Characteristics, Linda Isabel Navarro Navarro May 2021

Development Of A Cyberinfrastructure For Assessment Of The Lower Rio Grande Valley North And Central Watersheds Characteristics, Linda Isabel Navarro Navarro

Theses and Dissertations

Due to an increase in urbanization in the Lower Rio Grande Valley (LRGV), there have been substantial modifications to hydrology causing a decline in water quality to the Laguna Madre watershed. The major concern is the inflow of freshwater from the North and Central waterways released to the Lower Laguna Madre which is designated as an impaired watershed for high concentrations of bacteria and low dissolved oxygen. The objective of this study is to perform a watershed characterization to determine potential pollution sources of each watershed by developing a cyberinfrastructure and collect a wide inventory of data. The objective will …


Application Of Deep Learning For Imaging-Based Stream Gaging, Ryan Lee Vanden Boomen May 2021

Application Of Deep Learning For Imaging-Based Stream Gaging, Ryan Lee Vanden Boomen

Theses and Dissertations

In the field of water resources management, one vital instrument utilized is the stream gage. Stream gages monitor and record flow and water height within some water body. The United States Geological Survey maintains a network of stream gages at many locations across the country. Many of these sites are also equipped with webcams monitoring the state of the water body at the moment of measurement. Previous studies have outlined methods to approximate stream gage data remotely with limitations such as the requirement of detailed depth information for each site. This study seeks to create a process for training a …


Fluid Dynamics Modeling For Per- And Polyfluoroalkyl Substances Removal In Legacy Fire Suppression Systems, Jacob G. Spaulding Mar 2021

Fluid Dynamics Modeling For Per- And Polyfluoroalkyl Substances Removal In Legacy Fire Suppression Systems, Jacob G. Spaulding

Theses and Dissertations

Legacy per- and polyfluoroalkyl substances (PFASs) exist in the form of aqueous film-forming foams within hangar fire suppression systems throughout the country, posing a threat to both surrounding environments as well as local populations. The United States (US) Department of Defense (DoD), in conjunction with the US Environmental Protection Agency (EPA), is investigating best practices to flush out existing contaminants prior to disposal and replacement with a less environmentally harmful replacement. While current procedures dictate a triple rinse of the entire system to yield contaminant levels acceptable to the DoD, the practice has never truly been tested. Designed as a …


Conversion From Coal To Natural Gas At Wright Patterson Air Force Base: An Analysis And Case Study, Tyler A. Ferry Mar 2021

Conversion From Coal To Natural Gas At Wright Patterson Air Force Base: An Analysis And Case Study, Tyler A. Ferry

Theses and Dissertations

Over the last 20 years, natural gas has replaced coal as the preferred fossil fuel for heat and power generation across the United States, due to its increased prevalence, lower cost, and reduced environmental impacts. While most conversion decisions are driven by cost savings, proponents of energy transitions often cite emissions reductions as a tangential benefit. Over the same time, climate change and its impact on the environment and society have come to the forefront of scientific inquiry. One example of the transition from coal to natural gas can be found in Dayton, Ohio. Wright Patterson Air Force Base (WPAFB) …


Evaluation Of Efficient Water Reuse Technologies For Sustainable Forward Operating Bases, Kelsie L. Crouch Mar 2021

Evaluation Of Efficient Water Reuse Technologies For Sustainable Forward Operating Bases, Kelsie L. Crouch

Theses and Dissertations

A secure water source is essential to the resiliency and readiness of military installations and contingency operation locations, especially those located in the dry climates the US military operates in today. There are multiple issues of concern when identifying water sources, such as security, cleanliness, accessibility, and sustainability. Water resources pose a potential vulnerability to mission readiness in a remote, agile environment, such as a forward operating base (FOB). Having a secure water resource helps facilitate mission readiness in the contingency environment, offering the opportunity to be more resilient and cost-effective. Current water treatment technologies present the possibility to perform …


Characterization And Analysis Of Bomarc Accident Debris, Aaron J. Heffelfinger Mar 2021

Characterization And Analysis Of Bomarc Accident Debris, Aaron J. Heffelfinger

Theses and Dissertations

Accidents involving nuclear weapons, such as the Boeing Michigan Aeronautical Research Center (BOMARC) accident in 1960, always pose a significant risk of allowing particles composed of nuclear materials to enter the environment. These particles often differ in characteristics and can be of greatly varying sizes. Gamma ray analysis was conducted on the soil sample and radioisotopes within the sample were identified. Two non-destructive methods for locating actinide bearing particles within the sample were testing, resulting in 70 actinide bearing particles ranging from 1-34 microns being identified. These 70 particles underwent both morphological and elemental characterization, indicating uranium and other elements.


Numerical And Experimental Investigation Of Aeration Self Mixing By Using Pulsating And Continuous Air Flow, Ahmed Ali Alkhafaji Dec 2020

Numerical And Experimental Investigation Of Aeration Self Mixing By Using Pulsating And Continuous Air Flow, Ahmed Ali Alkhafaji

Theses and Dissertations

Wastewater treatment is considered one of the most common forms of pollution control in the united states. Considered as an integral part of the wastewater treatment, the aeration process is the most energy-consuming process among all the processes that take place in any wastewater treatment plant. According to the United States Environmental Protection Agency (EPA), a wastewater treatment plant is expected to remove at least 85% of the suspended solids and dissolved organic compounds from the wastewater before discharging it to a river or a lake. The normal operation of the aeration process is by compressing air continuously to basin …


Developing Highly Reversible Li Metal Anode With Mossy/Dendritic Li Suppression In High Energy Density Batteries, Xi Chen Dec 2020

Developing Highly Reversible Li Metal Anode With Mossy/Dendritic Li Suppression In High Energy Density Batteries, Xi Chen

Theses and Dissertations

Lithium-ion battery technology has wide impact on our daily life. However, most of the commercial batteries with limited energy density are unable to meet the growing demand of electrical vehicles, portable electronic devices and other energy storage systems. Therefore, the development of new electrode materials with high energy density and reliable performance has become a critical mission for researchers. Particularly replacing graphite anode with Li metal is one of most viable approaches to break the limitation of energy density in batteries. Metallic lithium is one of the most promising anode materials, which has a high theoretical specific capacity of 3860 …


Sustainability In Construction: Using Lean Management Principles To Reduce Waste, Matthew Waite Dec 2020

Sustainability In Construction: Using Lean Management Principles To Reduce Waste, Matthew Waite

Theses and Dissertations

The construction industry is facing many challenges. There are growing consumer demands for sustainable building. The construction industry generates a significant portion of the waste going into landfills. The construction industry has failed to keep pace with productivity in the manufacturing industry. Through adoption of Lean management principles, the construction industry can become more sustainable while increasing productivity. The literature was evaluated for three concepts: Lean management principles interaction with sustainability, the current state of sustainability in the construction industry, and the current state of Lean management principles in the construction industry. Lean management philosophies interactions with sustainability has been …


Numerical And Experimental Investigation Of Performance For Very-Low-Head Micro And Pico Kaplan Hydro-Turbines With Rim-Driven Generators, Ahmad Ibrahim Mohammad Abbas May 2020

Numerical And Experimental Investigation Of Performance For Very-Low-Head Micro And Pico Kaplan Hydro-Turbines With Rim-Driven Generators, Ahmad Ibrahim Mohammad Abbas

Theses and Dissertations

Renewable energy plays a significant role in new power generation worldwide, and hydropower is contributing to 86% of renewable electricity production within all other renewable energy resources. Simultaneously, hydropower shares 83% of U.S. renewable energy capacity and accounts for 77% of actual renewable electricity generation. However, most of the installed hydropower consists of large plants. Much potential hydro generation remains untapped, particularly at lower power and head levels. There is a substantial opportunity worldwide and across the U.S. in specific to add new hydropower generating capabilities at low-head sites such as non-powered dams, canals, and conduits with a water height …


An Analysis Of Tinker Air Force Base Thermal Spray Hazardous Waste Stream From 2003-2019 And Its Potential Reclamation, Amy E. Silverbush Mar 2020

An Analysis Of Tinker Air Force Base Thermal Spray Hazardous Waste Stream From 2003-2019 And Its Potential Reclamation, Amy E. Silverbush

Theses and Dissertations

The disposal of hazardous waste threatens the environment and human health. However, certain hazardous wastes can be recycled or reclaimed to alleviate environmental and financial impacts associated with its disposal and resource demand reduction. A hazardous powder produced by the United States Air Force stems from aircraft maintenance and is composed of metals and ceramics, called thermal spray. This waste can be purchased by an industrial recycler if the waste is composed of valuable metals. Historic data from the depot-level maintenance base Tinker Air Force Base initiated an analysis of annual thermal spray hazardous waste disposal fees, which combined with …


A Game Modeling Of A Closed-Loop Supply Chain In A Water-Energy Nexus: Technology Advancement, Market Competition And Capacity Limit, Nabeel Hamoud Dec 2019

A Game Modeling Of A Closed-Loop Supply Chain In A Water-Energy Nexus: Technology Advancement, Market Competition And Capacity Limit, Nabeel Hamoud

Theses and Dissertations

Water and energy are two scarce and concerning resources interconnected in the water-energy nexus. In the nexus, production of energy needs water, and production of water needs energy. For better management of these resources in the nexus, this research considers a supply chain that consists of water suppliers, power suppliers, and consumers of these commodities. In the chain, water suppliers purchase power from power suppliers, and power suppliers purchase water from water suppliers. Other consumers can also buy these resources at the water and power markets. Each firm tries to maximize its own profit. The suppliers of water and power …


Optimizing Hydrogen Sulfide Removal And Biogas Production Using The Water Wash Method, Brian Leightner Dec 2019

Optimizing Hydrogen Sulfide Removal And Biogas Production Using The Water Wash Method, Brian Leightner

Theses and Dissertations

Biogas forms from decomposing organic material in agricultural digesters, landfills, and wastewater treatment plant digesters. Biogas is mostly composed of methane, and can be used as a carbon-based fuel. Microorganisms that consume organics in these waste streams also produce hydrogen sulfide (H2S) as part of the biogas, in varying trace amounts. H2S is corrosive to engines and pipes for machinery, a human health hazard when inhaled, and an aquatic hazard when dissolved in water. Water washing is an absorption process that dissolves hydrogen sulfide and other water soluble compounds in this process and carries it away from the gas, thereby …


Optimizing Self-Healing Wind Turbine Blades Utilizing Dicyclopentadiene Infused Vascular Networks, Giovanni Lewinski Aug 2019

Optimizing Self-Healing Wind Turbine Blades Utilizing Dicyclopentadiene Infused Vascular Networks, Giovanni Lewinski

Theses and Dissertations

Self-healing wind turbine blades can reduce costs associated with maintenance, repair, and energy compensation. Self-healing is the ability to sustain and recover from damage autonomously. The self-healing presented in this paper uses the reaction of two agents Dicyclopentadiene, DCPD, and Grubbs’ first-generation catalyst, henceforward known as a catalyst to fuel this recovery. DCPD is housed as a liquid isolated from the catalyst until a damaging event occurs, causing the two agents to mix and solidify to form the thermoset Polydicyclopentadiene, PDCPD. We discuss the efforts made to optimize the self-healing properties of wind turbine blades and provide new systems to …


Novel Non-Invasive Technology For The Detection Of Thin Biofilm In Piping Systems (Phase - 1), Sachin Davis May 2019

Novel Non-Invasive Technology For The Detection Of Thin Biofilm In Piping Systems (Phase - 1), Sachin Davis

Theses and Dissertations

Biofilms are formed when a group of cells of microorganisms stick to each other and often on a surface. The development of biofilm has been a major issue in many fields (medical field, food, chemical, and water industry are a few such fields). In the medical field alone, biofilm infections have reportedly cost over five billion USD in additional healthcare expenses. The food industry usually halts the operation of its plant eight hours, every day to ensure that their equipment and transportation channels are clean and free from any biofilm presence. Similarly, the water and chemical industry need to ensure …


Novel Non-Invasive Technology For The Detection Of Thin Biofilm In Piping Systems (Phase - 1), Sachin Davis May 2019

Novel Non-Invasive Technology For The Detection Of Thin Biofilm In Piping Systems (Phase - 1), Sachin Davis

Theses and Dissertations

Biofilms are formed when a group of cells of microorganisms stick to each other and often on a surface. The development of biofilm has been a major issue in many fields (medical field, food, chemical, and water industry are a few such fields). In the medical field alone, biofilm infections have reportedly cost over five billion USD in additional healthcare expenses. The food industry usually halts the operation of its plant eight hours, every day to ensure that their equipment and transportation channels are clean and free from any biofilm presence. Similarly, the water and chemical industry need to ensure …


Novel Solar Cells Based On Two-Dimensional Nanomaterials And Recycled Lead Components, Xiaoru Guo May 2018

Novel Solar Cells Based On Two-Dimensional Nanomaterials And Recycled Lead Components, Xiaoru Guo

Theses and Dissertations

To meet the rapidly growing demand for energy and reduce the use of dwindling fossil fuels, the efficient utilization of renewable energy is a constant pursuit globally. Because solar cells convert vastly available sunlight into electricity, developing high-performance and low-cost solar cells is a top strategy for future energy supply. Dye-sensitized solar cells (DSSCs) and perovskite solar cells (PSCs) are the most promising choices. In the meantime, highly concentrated sulfuric acids from retired lead-acid batteries become an environmental concern, and lead contamination in drinking water raises concerns in general public. This study addresses both above-mentioned problems by using two-dimensional (2D) …


Quantifying Permafrost Extent, Condition, And Degradation Rates At Department Of Defense Installations In The Arctic, Christopher A.J. Edlund Mar 2018

Quantifying Permafrost Extent, Condition, And Degradation Rates At Department Of Defense Installations In The Arctic, Christopher A.J. Edlund

Theses and Dissertations

The DoD is planning over $500M in military construction on Eielson Air Force Base (AFB) within the next three years. This construction program will expand the footprint of facilities and change parts of the storm water management scheme, which may have second order effects on the underlying permafrost layer. These changes in permafrost will drive engineering decision making at local and regional levels, and help shape the overall strategy for military readiness in the Arctic. Little site-specific knowledge exists on the human caused effects to permafrost at this location. In 2016, the permafrost degradation rates at Eielson AFB were modeled …


Experimental Evaluation Of Uranyl Transport Into Mesoporous Silica Gel Using Fluorescence, Brandon M. Dodd Jan 2018

Experimental Evaluation Of Uranyl Transport Into Mesoporous Silica Gel Using Fluorescence, Brandon M. Dodd

Theses and Dissertations

This research investigated parameters that can affect the use of nanoporous silica gel as a media for accumulating a detectable amount of uranium. The unique fluorescence of the Uranyl (UO22+) ion was used to evaluate the transport kinetics and accumulation within silica gel in a static fluid and under pressure driven flow. The addition of fluid flow decreased the time constant from on the order of an hour to approximately 2s with a very low fluid velocity of 0.36cm/s. The 0.36cm/s fluid velocity was found to be the critical velocity above which there was no gain in …