Engineering Commons^™

A Network Of Low-Cost Multi-Pollutant Air Quality Sensors For Evaluating Fine-Scale Exposure Disparity In Twin Cities, Mn, P M Varuni Abhayaratne

Masters Theses

"Poor air quality is detrimental to health and is a leading environmental risk factor for early death globally. The massive scale of urbanization and population growth has led urban air quality to become a global concern as the release of air pollutants into the atmosphere continues to increase. Air quality has traditionally been monitored using reference-grade monitoring stations that are expensive and sparsely distributed. Low-cost sensors can complement existing regulatory networks to provide more spatial detail, capturing fine-scale variations. This study investigates spatiotemporal pollutant patterns, exposure disparities and environmental justice using data collected from a two-year (2019-2021) deployment of a …

Rapid-Throughput Analysis Of 1,4-Dioxane In Plants By Centrifugal Sampling And Phytoforensic Analysis For Site Delineation And Assessing Enhanced Rhizodegradation, Anthony Eberechukwu Oha

Masters Theses

"Owing to its broad use and environmental persistence, 1,4-dioxane (dioxane) poses a notable threat to public health and is recalcitrant to traditional remedial systems. Dioxane moves readily in an aqueous environment and is an emerging contaminant in drinking water, surface water, groundwater, and wastewater. The extent of dioxane in the biosphere is also difficult to delineate, particularly in the subsurface. Phytoremediation has demonstrated the potential for dioxane groundwater remediation. Recent findings indicate that plant-microbial symbiosis may be more advantageous for limiting potential transport and transfer into plant tissues and the atmosphere. Bioaugmentation of the rhizosphere paired with soil amendments has …

Performance Evaluation Of Sediment Basin Designs For Highway Construction Sites In Tennessee, Jeffery Cole Emmett Jr

Masters Theses

Performance of three sediment basin designs were tested; they were: 1) the TDEC standard design with a forebay, 2) the TDOT design with an inlet check dam, and 3) the TDOT standard design that does not include an inlet check dam. An 1/17 of an acre scaled physical model sediment basin, was constructed next to an elevated outdoor open flume used to mix known water volumes and sediment mass routed by gravity-flow into the basin. The measurement for performance was simply the percent sediment mass retained in the basin from the total input per experimental run (percent sediment removal). Three …

Joint Failure Probability Of Dams Based On Probabilistic Flood Hazard Analysis, Matthew G. Montgomery

Masters Theses

Probabilistic risk methods are becoming increasingly accepted as a means of carrying out risk-informed decision making regarding the design and operation of structures such as dams. Probabilistic risk calculations require the quantification of epistemic and aleatory uncertainties not investigated through deterministic methodologies. In this hydrological study, a stochastic sampling methodology is employed to investigate the joint failure probability of three dams in adjacent, similarly sized watersheds within the same Hydrologic Unit Code (HUC) 6 basin. A Probabilistic Flood Hazard Analysis (PFHA) framework is used to simulate the hydrologic loading of a wide range of extreme precipitation events across the combined …

Assessing Phenotypic Response Of Plants Irrigated With Municipal Solid Waste Landfill Leachate Using Computer Visualization, Rahel Pommerenke

Masters Theses

"Most solid waste collected in the US is disposed of in sanitary landfills, which have a lingering legacy of unintended negative impacts on the environment. Landfill design and operation are expensive, prone to multiple failure modes, and often do not address human and ecological risks presented by contaminants of emerging concern. A notable and common failure mechanism is leachate production. Moisture in the waste mixes with infiltrating water to form wastewater that must be collected and treated prior to discharge. Recycling leachate at landfills by recirculating it onto vegetated landfill covers relies on the evapotranspiration potential of plants to reduce …

Dissolved Organic Carbon And The Potential Role To Stream Acidity In The Great Smoky Mountains National Park, Jason R. Brown

Masters Theses

A substantial societal shift towards environmental awareness has focused research efforts on the impacts of pollution on natural landscapes. Improvements to pollutant regulations and technology have resulted in sizeable reductions of atmospheric deposition of anthropogenic acids, especially nitrates and sulfates, which has altered the role of these ions in the environment. As such, understandings of environmental chemistry dynamics have required regular updating.

Through the National Park Service Vital Signs monitoring program, increases in precipitation pH observed in Great Smoky Mountains National Park (GRSM) has been attributed to the reduction of inorganic acid concentrations. Unfortunately, these improvements have not been uniformly …

Terrestrial Laser Scanning Technology For Measuring Streambank Retreat Along East Fork Poplar Creek And Calculating The Effect On Mercury Release., José L. Martínez Collado

Masters Theses

Mercury (Hg) is a globally distributed inorganic pollutants of human concern. The high toxicity is mainly related to the capacity of Hg species to accumulate and biomagnify along aquatic food webs. Along East Fork Poplar Creek (EFPC), erosion represents the principal mercury input into the local waters, eventually reaching humans through the food chain. This research project aimed to monitor streambank erosion along a mercury-contaminated creek using Light Detention and Ranging (Lidar) technology and erosion pins. A Terrestrial Laser Scanner (TLS) was used to generate high-resolution point clouds from August 2020 to January 2021 across nine streambank locations to detect …

Quantifying Tree Canopy Contributions To Stormwater Runoff Reductions In Urban Watersheds Of The Southeastern United States, Matthew C. Howard

Masters Theses

Urban stormwater is a major contributor to surface water degradation in the United States, prompting cities to invest in ways to naturally capture, store, and slowly release runoff through “Green Infrastructure” (GI). One often overlooked potential contributors to stormwater management are urban trees, an integral part of a given city’s GI. Interception is of particular interest and describes a tree’s ability to capture and store rainfall, reducing the volume of stormwater that can degrade urban streams during storm events. While rainfall interception for full canopy, forested environments is well studied, limited research is available that characterizes the interception of open-grown …

Bioretention Cell Performance Under Shifting Precipitation Patterns Across The Contiguous United States, Matthew Weathers

Masters Theses

As climate change produces shifts in precipitation patterns, communities will need to understand how the performance of green stormwater infrastructure (GSI) may be impacted. Bioretention cells are one of the most commonly implemented forms of GSI for their ability to reduce peak discharge and filter pollutants and are a vulnerable component of stormwater infrastructure. Projections in future climate indicate that bioretention cells may be at risk of losing their existing function due to deviations in precipitation frequency and intensity. General circulation models (GCMs) downscaled to regional climate models (RCMs) can provide climate change projections at a high spatial resolution but …

Early Wildfire Detection By Air Quality Sensors On Unmanned Aerial Vehicles: Optimization And Feasibility, Doaa Rjoub

Masters Theses

“Millions of acres of forests are destroyed by wildfires every year, causing ecological, environmental, and economical losses. The recent wildfires in Australia and the Western U.S. smothered multiple states with more than fifty million acres charred by the blazes. The warmer and drier climate makes scientists expect increases in the severity and frequency of wildfires and the associated risks in the future. These inescapable crises highlight the urgent need for early detection and prevention of wildfires. This work proposed an energy management framework that integrated unmanned aerial vehicle (UAV) with air quality sensors for early wildfire detection and forest monitoring. …

High-Resolution Timeseries Analysis Of Dynamic Geochemistry: A 27-Well Survey Of Contaminated Groundwater Downstream Of The Former S-3 Ponds, Oak Ridge, Tennessee, Emma Dixon

Masters Theses

Spatiotemporal variability of geochemistry of contaminated groundwater has large implications on overall water quality and ability to respond to remedial applications. Gaining knowledge of how geochemistry changes over time in an area can help establish response trends to changing external conditions like weather and level of contamination. In this study, a spatiotemporal survey was performed on 27 wells at the Y-12 Complex in Oak Ridge, Tennessee. This was completed to measure diurnal fluxes in geochemistry from seasonal changes and extreme weather conditions in three areas of historically different contamination levels from a single point contamination source. Measurements were gathered over …

Improving Stream Bank Erosion Estimates By Adjusting The Applied Shear Stress For Different Bank Characteristics, Justin Condon

Masters Theses

Stream bank erosion rates are commonly modeled using the excess shear stress equation ε_r = k_d(τ-τ_c)^a, where the exponent a is assumed to be unity. The coefficient of erodibility k_d, and the critical shear stress τ_c [Tau _c] are properties of the bank soil and the applied shear stress τ [Tau] is a function of the channel geometry and discharge. This equation appears to overstimate bank erosion likely due to effects of channel morphology and bank vegetation, among other factors. The objective of this study was to determine whether …

Lagrangian Bedload Movement Prediction Using The Virtual Velocity Approach, Theodoros Kyriakopoulos

Masters Theses

The advances in particle tracking codes in the recent years has made possible to track the intermittent movement of a large number of sediment particles with precision and in an automated way. The present study used this technique to study the velocity of the particle while it is in motion, the length it travels once it gets mobilized until it deposits, and the time it rests once deposited until it gets mobilized again. New modeling equations were developed to predict these quantities for a wide range of flow conditions and sediment sizes. These equations were combined to predict the virtual …

Modeling Of Electrical Grid Systems To Evaluate Sustainable Electricity Generation In Pakistan, Muhammad Mustafa Amjad

Masters Theses

Pakistan has always had a history of severe energy shortfalls, which rose up to an alarming 33% in 2013. This situation was countered by investments in the energy sector through the China Pakistan Economic Corridor (CPEC), which were unfortunately largely based on brown fuels. Although beneficial in the short term, these investments do not bode well for the climate scenario of Pakistan, with various parts of the country already having experienced temperatures rise of 1-3°C. To ensure that the current situation doesn’t exacerbate and is tackled in a timely manner, this research aims to examine how the untapped potential of …

Development Of Amine-Functionalized Mesoporous Alumina For Radioiodine Removal From Water, Mansour Mohammed Alsalbokh

Masters Theses

“Radioactive materials have spread due to careless disposal and nuclear disasters. Some radionuclides can exist in an aqueous media, like radioactive iodine. As a result, in this work amine-functionalized mesoporous alumina was developed to adsorb radioactive iodine from the liquid phase. Bismuth was incorporated, using a wet impregnation method, to test it as a possible silver replacement. Amine grafting was used to functionalize the surface of the mesoporous alumina. All materials prepared in this work were characterized by N₂ physisorption, FTIR and TGA to determine the textural properties, surface functionality, and amine loading. The synthesized materials were tested for …

Soil-Water-Energy Nexus Of Green Roofs, Katherine Ann Bartels

Masters Theses

"As the urban landscape continues to sprawl into previously undeveloped land to accommodate population growth, the need to design cities that effectively manage urban stormwater is imperative for a sustainable future. Green roofs use rain-harvesting techniques to reduce urban stormwater discharge while simultaneously providing traditional roof services as well as several ecosystem services. However, green roof media design varies greatly among commercial applications, and little guidance is available to engineers when selecting the media for prospective green roofs. Efforts to maximize stormwater retention and enhance urban heat island mitigation capabilities of green roofs while concurrently reducing nutrient loading were examined …

Evaluation Of Naturally Occurring And Anthropogenic Contamination In Missouri Streams, Christina Jane Sehrt

Masters Theses

"The goal of this study is to observe the values and variability of water quality parameters and benthic macroinvertebrates in watersheds with very little anthropogenic impact and to compare these values with those acquired in watersheds with more anthropogenic impact. The following five HUC 12-digit watersheds had very little anthropogenic impact and were considered "pristine": Rogers Creek, Mill Creek, Middle West Fork-Black River, Bee Fork, and Ottery Creek. Five largely urban sub-basins were also considered; these basins are: Grand Glaize Creek, Glaize Creek, Sugar Creek, Hominy Creek, and Grindstone Creek. For each watershed, both water quality parameters and benthic macroinvertebrates …

Enabling Robust Distributed Real-Time Hybrid Simulation Method And Expanding Its Applications In Floating Wind Turbine Systems, Mehmet Cinar

Masters Theses

Real-time hybrid simulation (RTHS), which integrates physical experiment and numerical simulation, plays an essential role in understanding the time-dependent behavior of structures when subject to hazardous loadings. On the other hand, RTHS might not yield accurate results for complex structural systems due to experimental and computational limitations. Distributed real-time hybrid simulation (dRTHS), which takes the advantage of distributed laboratory facilities using network communications, was proposed and proven to address some limitations in RTHS. During dRTHS, Internet delay due to the network communication is added to the actuator delay in RTHS, which may cause inaccurate results or even unstable tests. To …

Cellulose And Sulfate Degradation In A Biochemical Reactor During Treatment Of Mine Drainage, Sweta Ojha

Masters Theses

"Seventy-two biochemical reactors were set up, and operated using a mixture of chip-bark, horse manure, and gravel as the biochemical treatment substrate. The simulated mine water containing sulfate (1000 mg/l) was pumped into each reactor at a flow rate of 0.5 ml/minute (approximate), giving an empty bed contact time of 8 days. The main idea is that the microorganisms present in horse manure would convert the cellulose in chip-bark into volatile fatty acids. The produced volatile fatty acid would enhance the metabolism of sulfate-reducing bacteria (SRB) initially present in horse manure, which would degrade (and eventually remove) the sulfate from …

Bioaccessibility Of Lead From Contaminated Soil Using Phosphate Treatment -- Physiologically Based Extraction Test And In Vitro Gastrointestinal Method Test, Austin Charles Doss

Masters Theses

"Phosphate treatments are used to immobilize lead in soil by forming pyromorphite. Soil from Bonne Terre, Mo was collected to study whether such treatment decreases the bioaccessibility of lead. The soil was treated using 0.5 soil wt% of phosphate. Treatments were: none, phosphoric acid, triple super phosphate, and organic bone meal. Each sample was studied after one, four, sixteen, and twenty weeks; during this time span, water was added approximating the average rainfall rate. Percolated water was collected to test the leached phosphate concentrations. Phosphate was below the detection limit in that leachate. Remediated soil samples were used in Physiologically …

Numerical Modeling Of Capillary-Driven Flow In Open Microchannels: An Implication Of Optimized Wicking Fabric Design, Mehrad Gholizadeh Ansari

Masters Theses

"The use of microfluidics to transfer fluids without applying any exterior energy source is a promising technology in different fields of science and engineering due to their compactness, simplicity and cost-effective design. In geotechnical engineering, to increase the soil's strength, hydrophilic wicking fibers as type of microfluidics have been employed to transport and drain water out of soil spontaneously by taking advantage of natural capillary force without using any pumps or other auxiliary devices. The objective of this study is to understand the scientific mechanisms of the capability for wicking fiber to drain both gravity and capillary water out of …

Impact Of Transportation Infrastructure On Stream Water Quality: Contribution From Stormwater Runoff, Andrew James Steinman

Masters Theses

Stormwater runoff is a vital concern to the health of natural waterbodies and ecosystems within urban watersheds. While there is already ample research dedicated to understanding water quality from urban roadways, few of those studies have focused on measuring the dynamics of how stream water quality during storm conditions changes due to increased pollutant load from major urban roadways. With the goal to develop effective water resource management strategies for an impaired tributary watershed, water quality was monitored at four locations within a subwatershed to determine what impact pavement runoff of a major interstate has on the impaired receiving stream. …

A Bug’S Life: Integration Of Anaerobic Digestion And Bioelectrochemical Systems For Enhanced Energy Recovery From Wastewater Solids And Other Waste Substrates, Jeff Ryan Beegle

Masters Theses

Organic waste streams, like domestic wastewater and municipal solid waste, have the potential to be used as feedstocks for biotechnology processes to produce high value products and energy. This thesis investigated the technological, economical, and environmental potential for integrated anaerobic digestion (AD) and bioelectrochemical system (BES) platforms as they were theoretically and physically evaluated for energy recovery from domestic wastewater. The first chapter of this thesis compared the theoretical energy efficiencies of converting waste directly into electricity, using AD and BES alone and in various combinations. This chapter reviewed the experimentally demonstrated energy efficiencies reported in the literature with comparisons …

Cloth-Air Partitioning Of Oxybenzone, Jonathan T. Hill

Masters Theses

"Clothing has been proven to be a significant accumulator of chemicals from the air. Semi-volatile organic compounds (SVOCs) have a high affinity towards textiles, and measuring the equilibrium partition coefficient between cloth and air (K_cloth-air) for SVOCs is crucial in predicting human exposure to these compounds. This study aims to quantify K_cloth-air for oxybenzone to contribute to a larger human exposure experiment carried out at the Technical University of Denmark (DTU). K_cloth-air for oxybenzone was calculated using data collected from the exposure chamber at DTU and from performing extractions of oxybenzone in fabric samples from the …

Towards A Better Understanding Of Indoor Exposure To Air Pollutants: Window Opening Occurrence In U.S. Residences, Gauri Dilip Date

Masters Theses

"Opening a window dramatically alters how we are exposed to air pollutants. Online questionnaire surveys were deployed to assess window-opening occurrence of the occupants of US homes. This information will be used to better quantify population exposure to pollutants of indoor and outdoor origin. Frequency distributions of demographics were generated which showed percentages of respondents who participated in the surveys from categories including gender, race, household income and occupancy. In April 2016, 49.3% of the people surveyed opened their windows for at least 1 hour in a day. This increased to 52.5% in September 2016 and reduced considerably to 24.4% …

Advanced Buffer Materials For Indoor Air Co₂ Control In Commercial Buildings, Pavithra Ethi Rajan

Masters Theses

"The following describes a novel passive approach to control the indoor CO₂ levels in enclosed spaces, primarily focusing on commercial buildings. Amine impregnated silica sorbents were identified as suitable candidates and synthesized; the amine loading ratio was varied to create a range of materials. These samples along with other commercial zeolite candidates have been tested over a range of CO₂ concentrations to determine the CO₂ adsorption capacity in laboratory systems and under simulated room conditions. The research work also focuses on the CO₂ desorption capacity of the candidate adsorbents. The desorption is allowed to occur gradually …

The Use Of Ceramic Water Filters Under Pressure In An In-Line Water Pumping System, Travis Dean Gardner

Masters Theses

"Ceramic pot filters (CPFs) have proven an effective point of use (POU) filter due to their relative low cost, ease to manufacture, and effectiveness at treating contaminated water. These filters are used by individual homes, and sometimes multiple filters are needed for each home in order to produce enough water for the family's household. If these filters could be used in-line with a pumping system or elevated storage tank, water could be filtered and used on demand for a community in an economically feasible way. However, CPFs are too fragile to use under pressure due to the weak points where …

Vegetation Based Assessment And Monitoring Tools For Landfill Leachate Treatment And Fugitive Plumes, Rahul Sukharia

Masters Theses

"Solid waste and leachate generation from solid waste landfills has a legacy of detrimental and toxic impacts on the environment. Disposal practices are expensive, failure prone and have not been able to keep up with the pace of disposal of toxic compounds. In general, a landfill acts as a "bathtub" with infiltration of water through the landfill cover into the landfill, reacting with the waste and transferring toxic components into the leachate. Irrigating the evapotranspiration (ET) covers with leachate collected from the landfill has been developed and applied. Such methods can keep the leached pollutants in a loop, which reduces …

Bioaccessibility Of Lead From Lead-Contaminated Soil Upon Phosphate Amendment Using A Physiologically-Based Extraction Test, Samantha Jo Dicenso

Masters Theses

"Lead is known to cause health problems in humans, especially children, and an effective in‐situ remediation option has been sought for years. Adding phosphoric acid (PA) to contaminated soil causes a reaction that binds the lead to phosphate to produce pyromorphite (Pb₅(PO₄)₃Cl), a form of lead believed to be non‐bioavailable; however, field trials have given varied results (Bosso et al 2008; Munksgaard and Lottermoser 2011; Tang et al. 2009). One explanation for these results might be the impact of the agent used to raise pH after phosphoric acid addition. In order to examine this explanation soil was collected from the …

Long-Term Health Risk Of Climate Change Associated Surface Pm2.5 Concentration Variation: Multiple Accmip Model Data Under Different Emission Scenarios (Rcp26, 45, 60, 85) And Population Scenarios (Ssp1, Ssp2, Ssp3), Xiufen Zhu

Masters Theses

In this study, multiple models from Atmospheric Chemistry and Climate Model Intercomparison Project (ACCMIP) are utilized to derive the global burden of disease of chronic obstructive pulmonary disease (COPD), lung cancer (LNC), and lower respiratory infection (LRI) derived from surface PM_2.5 elevation. Various Representative Concentration Pathways and Shared Socio-economic Pathways scenarios are compared as well as various models to deduct the impact from various scenarios. The time series variation and seasonal variation are also illustrated in this study. Multi-model ensemble was conducted to reduce the deviation in model projection output.

Projection shows increase in the population normalized relative risk …