Engineering Commons^™

Sustainability And Health Impacts Of Pulse Crops In The United States Using Life Cycle Assessment, Prathamesh A. Bandekar

Graduate Theses and Dissertations

Environmental sustainability and human health impact of pulses produced and consumed in the United States was assessed using life cycle assessment (LCA). The study included three objectives 1) to estimate environmental impact of current production and consumption practices in the United States using attributional LCA; 2) to estimate environmental and human health impact of iso-caloric diets containing varying amounts of pulses using Hybrid-LCA and Combined Nutritional and Environmental-LCA (CONE-LCA); and 3) to estimate environmental impact of increased demand for pulses using consequential LCA. Scope of the study varied for each objective with system boundary encompassing cradle-to-grave activities for objective 1 …

Port Infrastructure Resilience Through Combined Wind-Surge Demand Characterization, Kaley Callaway

Graduate Theses and Dissertations

The United States economy is reliant on maritime transportation for 70% of imports and exports. Structures that are integral to the operation of ports, such as cranes, are jeopardized when tropical storms approach land. While wind is the only environmental load used to design dockside container cranes, storm surge often accompanies severe wind events and can create large structural loads. This study focuses on determining coupled storm-surge demands and the effect of waves on dockside container cranes. A damage index prediction tool that considers both maximum wind speed and storm surge height is developed and applied to historical hurricane data …

Formation Of Reactive Nitrogen Species During Dichloramine Decay And Their Impact On N Nitrosodimethylamine Formation Under Drinking Water Conditions, Huong Thu Pham

Graduate Theses and Dissertations

NDMA occurrence and formation pathways in drinking water systems are reviewed and NDMA yields are compared on the basis of disinfectant type, water chemistry, and precursor category. In chloramination, despite monochloramine being the predominant species between pH 7-9, evidence suggests that dichloramine is the primary species involved in NDMA formation. This is somewhat confounding as NDMA yields are maximal at pH 9, yet at pH 9 dichloramine decays faster than it forms and hence is present at trace levels; additionally, the proposed mechanism involves a spin-forbidden incorporation of dissolved oxygen as a triplet, which is presumably kinetically slow. This review …

Comparison Of The Resistance Of Belitic Calcium Sulfoaluminate Cement And Portland Cement To Sulfate Attack And Sulfuric Acid, Rilye Dillard

Graduate Theses and Dissertations

Microbially induced corrosion (MIC) is a fairly common concrete deterioration mechanism with many negative effects. MIC is a complex chemical and biological process that occurs in sewage systems and is nearly impossible to replicate in a laboratory setting. For this study, sulfate and sulfuric acid attack on concrete were studied to mimic two stages of the MIC process. The ASTM C1012, Standard Test Method for Length Change of Hydraulic-Cement Mortars Exposed to a Sulfate Solution and a modified ASTM C1012 accelerated method were used to compare the sulfate resistance of belitic calcium sulfoaluminate (BCSA) cement, portland cement (PC), and PC-fly …

Moisture Monitoring Of A Clt Structure In A Southern Climate, Elizabeth Poblete

Graduate Theses and Dissertations

Understanding of moisture behavior in cross laminated timber (CLT) is critical to the widespread use of CLT in construction in the United States. Currently, very little data exists on the long-term impact of moisture on CLT. The objective of this research is to collect data regarding the long-term moisture variation in the CLT panel at the University of Arkansas Adohi Hall residence hall. The climate of Northwest Arkansas is different from previously monitored buildings, as they were in the Pacific Northwest. Comparatively, Northwest Arkansas has a warmer climate with higher average annual precipitation. Waterproofing efforts are usually employed to prevent …

Surface Modified Polypropylene Membranes For Treating Hydraulic Fracturing Produced Waters By Membrane Distillation, Tharaka Hawpe Gamage

Graduate Theses and Dissertations

Membrane distillation is an emerging technology for treating hydraulic fracturing flowback and produced waters. Suppression of membrane fouling by inorganic and polar and non-polar organic compounds is a challenge. Here polyhydroxyethyl methacrylate, polyacrylic acid, polvinylallyl imidazolium bromide and polyvinylhexyl imidazolium bromide chains have been grafted from the membrane surface. Fouling is initially due to adsorption of organic compounds followed by scale formation. When challenged with produced water, membranes modified with polvinylallyl imidazolium bromide chains provided the greatest resistance to fouling. For EC pretreated produced water and synthetic produced water that contained mainly inorganic species, the flux decline was much less.

Cytotoxicity And Mutagenicity Of Disinfection Byproduct Mixtures Formulated Using Free Chlorine And Monochloramine, Yonas Ghebremedhin

Graduate Theses and Dissertations

Bioassays have been used extensively to assess various toxicity endpoints of drinking water disinfection byproducts (DBPs), but an emphasis on single compounds prevails. In this research, DBP mixtures were assessed using a cytotoxicity test with Chinese Hamster Ovary (CHO) cells and an Ames fluctuation test with Salmonella typhimurium TA-98 and TA-100 with and without S9 rat liver homogenate. Seven whole mixture DBP concentrates were formulated using reconstituted natural organic matter (NOM) extracts from the Upper Mississippi River using scaled disinfectant dosing protocols with free chlorine and monochloramine in the presence and absence of added bromide. DBPs were identified by gas …

Development Of A Multimode Instrument For Remote Measurements Of Unsaturated Soil Properties, Sean Elliott Salazar

Graduate Theses and Dissertations

The hydromechanical behavior of soil is governed by parameters that include the moisture content, soil matric potential, texture, and the mineralogical composition of the soil. Remote characterization of these and other key properties of the soil offers advantages over conventional in situ or laboratory-based measurements: information may be acquired rapidly over large, or inaccessible areas; samples do not need to be collected; and the measurements are non-destructive. A field-deployable, ground-based remote sensor, designated the Soil Observation Laser Absorption Spectrometer (SOLAS), was developed to infer parameters of bare soils and other natural surfaces over intermediate (100 m) and long (1,000 m) …

Towards Environmentally Sustainable And Cost-Effective Food Distribution In The U.S., Jasmina Burek

Graduate Theses and Dissertations

Distribution centers (DCs) and supermarkets have an important role in food sustainability, but no previous research has accounted for their environmental impact. The purpose of this research was to assess environmental sustainability of grocery, perishables, and general merchandise DCs; to estimate food storing and retailing impact; and to provide cost-effective strategies to reduce DCs’ environmental impacts. The importance and relevance of the research is threefold: improving sustainability of DCs, food storing, and food retailing. The main method used in this research was the life cycle assessment (LCA) method. An initial study calculated environmental impacts of the Wal-Mart Stores, Inc. DCs, …

Accumulation Of Lead By Biofilms In Drinking Water Distribution Systems, Kaleb Oren Belcher

Graduate Theses and Dissertations

Recent crises, such as the one in Flint, MI, indicate that lead exposure from drinking water is a major health concern in the United States. Over six million lead service lines are still in use in the United States, and a universal protocol to safely remove these lead service lines from drinking water distribution systems has not yet been established. This paper calls to attention the potential hazard that biofilms pose as a source of lead in distribution systems, even after the removal of lead pipes. This study used a simulated water distribution system containing a lead source pipe and …

Assessing Biofiltration Without Ozonation For Removal Of Trihalomethane Precursors In Drinking Water At The Beaver Water District Drinking Water Treatment Plant, Sana Ajaz

Graduate Theses and Dissertations

Biofiltration without pre-ozonation has the capability to remove natural organic matter (NOM) fractions that serve as precursors of disinfection byproducts (DBPs), which include the four regulated trihalomethanes (THMs) and dichloroacetonitrile (DCAN). Rapid small-scale column tests (RSSCTs) and Pilot Plant filters operated at empty-bed contact times (EBCTs) of 4, 8, and 16 minutes were used to evaluate the performance of nutrient-amended (free ammonia and phosphorus) biofiltration for THM and DCAN precursor removal, as measured using formation potential (FP) tests. NOM surrogates – which include dissolved organic carbon (DOC), specific ultraviolet absorbance (SUVA254) and fluorescence-PARAFAC components – were measured weekly throughout the …

Computer Modeling Of Close-To-Ground Tornado Wind-Fields For Different Tornado Widths, Mohammadhossein Kashefizadeh

Graduate Theses and Dissertations

Tornadoes induce different wind forces on buildings than straight-line (SL) winds. The tangential velocity (Vθ) of tornados is the main parameter that causes damage to the buildings. In-field tornado measurements cannot evaluate the tornado’s Vθ at less than 20m above ground level (AGL). The laboratory tornado simulators suggest that the Swirl ratio (S) and the radius (ro) are the most influential factors affecting Vθ. However, due to scaling problems, laboratory simulators cannot report the Vθ for elevations less than 10m AGL. Well refined computational fluid dynamics (CFD) models can evaluate the Vθ at less than 10m AGL. However, the CFD …

Development Of A Digital Rain-Sensing Irrigation Pump Controller And An Android Enabled Bluetooth Paddlewheel Flowmeter, Jayendra Mishra

Graduate Theses and Dissertations

For better irrigation efficiency, it is recommended that farmers track their water consumption to avoid over-irrigating. However, it is difficult to implement this as it is labor intensive to supervise pumps manually and available technologies require high investment. Therefore, a rain sensing pump controller for 3-phase electric irrigation pumps and a stand-alone portable Android enabled paddlewheel flowmeter has been developed to test their feasibility.

The pump timer is a retrofit device for irrigation pump panels. The controller allows an irrigator to start and stop the pump with less supervision. An infrared rain sensor is integrated with the controller to measure …

Investigating Fate Of Silver Nanoparticles In Wastewater Biofilms, Connie Marie Walden

Graduate Theses and Dissertations

As industrial advances make everyday life easier for human kind, the processes by which we need to maintain sanitary conditions for both water and wastewater treatment will become increasingly complex. Innovations in food packaging and textile design incorporate engineered nanoparticles (ENPs) to increase antimicrobial properties of clothing, maintain product color, and keep food in packaging from spoilage. For most products, ENPs released will enter the sanitary sewer system, and ultimately wastewater treatment plants. Biofilms grow universally on surfaces where a protective layer of extracellular polymeric substances (EPS) shields attached cells from stressors. In wastewater treatment, complex biofilms are utilized as …

Development Of Pre-Stressed Retrofit Strategies For Mitigating Fatigue Cracking In Steel Waterway Lock Gate Components, Christine Michelle Lozano

Graduate Theses and Dissertations

Lock gates are an important part of the transportation infrastructure within the United States (US), having many economic, safety, and environmental benefits over rail and highway transportation systems. Unfortunately, many existing lock gates throughout the US have reached or exceeded their initial design life and require frequent repairs to remain in service. Unscheduled repairs often increase as gates age, having a local economic impact on freight transport which can create economic ripples throughout the nation. Fatigue and corrosion are key causes of unscheduled service interruptions, degrading lock gate components over time. Additionally, because lock gates are submerged during operation, crack …

Trihalomethane, Dihaloacetonitrile, And Total N-Nitrosamine Precursor Adsorption By Carbon Nanotubes: The Importance Of Surface Oxides And Pore Volume, Erin Needham

Graduate Theses and Dissertations

As drinking water sources become increasingly impaired, enhanced removal of natural organic matter (NOM) may be required to curb formation of disinfection byproducts (DBPs) upon chlor(am)ination. While carbon nanotubes (CNTs) can adsorb NOM, their properties for DBP precursor adsorption have not been elucidated. Nine types of CNTs were assessed for trihalomethane (THM), dihaloacetonitrile (DHAN), and total N-nitrosamine (TONO) precursor adsorption. Batch isotherm experiments were completed with lake water and, to simulate an impaired condition, effluent from a wastewater treatment plant (WWTP). Adsorption varied with CNT type and dose, with TONO precursors having the highest percent removals from WWTP effluent (up …

Understanding N-Nitrosodimethylamine Formation In Water: Chloramine Chemistry, Kinetics, And A Proposed Reaction Pathway, Huong Thu Pham

Graduate Theses and Dissertations

The formation of N-nitrosodimethylamine (NDMA) in drinking water systems is a concern because of its potential carcinogenicity and occurrence at toxicologically relevant levels. The postulated mechanism for NDMA formation involves a substitution between dichloramine and amine-based precursors to form an unsymmetrical dimethylhydrazine (UDMH), which is then oxidized by ground-state molecular oxygen to form NDMA. However, this latter reaction is spin forbidden, thus likely occurs at a slow rate. It is hypothesized that the reaction between monochloramine and hydroxylamine (a nitrification product) may form an intermediate, which is involved in the NDMA formation pathway. This intermediate may also be generated from …

Total N-Nitrosamine Precursor Adsorption With Carbon Nanotubes: Elucidating Controlling Physiochemical Properties And Developing A Size-Resolved Precursor Surrogate, Erin Needham

Graduate Theses and Dissertations

As drinking water sources become increasingly impaired with nutrients and wastewater treatment plant (WWTP) effluent, formation of disinfection byproducts (DBPs) – such as trihalomethanes (THMs), dihaloacetonitriles (DHANs), and N-nitrosamines – during water treatment may also increase. N-nitrosamines may comprise the bulk of the chronic toxicity in treated drinking waters despite forming at low ng/L levels. This research seeks to elucidate physicochemical properties of carbon nanotubes (CNTs) for removal of DBP precursors, with an emphasis on total N-nitrosamines (TONO).

Batch experiments with CNTs were completed to assess adsorption of THM, DHAN, and TONO precursors; physiochemical properties of CNTs were quantified through …

The Role Of Organic Matter In The Fate And Transport Of Antibiotic Resistance, Metals, And Nutrients In The Karst Of Northwest Arkansas, Victor Lee Roland Ii

Graduate Theses and Dissertations

Organic matter (OM) in the environment acts as a nutrient, but may also act as a transport vector for harmful chemical compounds and bacteria. Acetate is a labile form of OM produced during fermentation in anaerobic lagoons used to store animal fecal-waste from concentrated animal feeding operations (CAFOs). Dry and liquid fertilizers from CAFOs pose a threat to groundwater by introducing excessive amounts of nutrients (e.g. OM, nitrate and ammonia), metals, and antibiotic compounds. In the epikarst of Northern Arkansas in the Buffalo River watershed additional input of labile dissolved organic carbon (DOC) from liquid CAFO waste-fertilizers was hypothesized to …

Nanofiltration Rejection Of Contaminants Of Emerging Concern From Municipal Water Resource Recovery Facility Secondary Effluents For Potable Reuse Applications, Steven Michael Jones

Graduate Theses and Dissertations

As reuse of municipal water resource recovery facility (WRRF) effluent becomes vital to augment diminishing fresh drinking water resources, concern exists that conventional barriers may prove deficient and the upcycling of contaminants of emerging concern (CECs) could prove harmful to human health and aquatic species if more effective and robust treatment barriers are not in place.

There are no federal Safe Drinking Water Act (SDWA) regulations in place specifically for direct potable reuse (DPR) of WRRF effluent. Out of necessity, some states are developing their own DPR reuse regulations. Currently, reverse osmosis (RO) is the default full advanced treatment (FAT) …

Biofilm-Related Materials As Total N-Nitrosamine (Tono) Precursors And Hydroxylamine-Based Interferences In Tono And N-Nitrosodimethylamine (Ndma) Measurements, David Allen Meints

Graduate Theses and Dissertations

In this study, a chemiluminescence-based total N-nitrosamine (TONO) assay was adapted to include a solid-phase extraction (SPE) step to assess the role of biologically derived materials as N-nitrosamine precursors. Methanol was determined to be a suitable solvent for the SPE-TONO assay, with N-nitrosodimethylamine (NDMA) losses estimated to be 30% by SPE alone and an additional 15% from concentration of the methanol extracts by N2-gas blowdown. Three biofilm-derived materials - poly-N-acetylglucosamine (PNAG), Pseudomonas aeruginosa, and tryptophan - were individually chloraminated and dose-response relationships were observed with the SPE-TONO assay, indicating biofilm are potential N-nitrosamine precursors. The role of hydroxylamine - a …

Microbial Community Shifts Caused By Changes In The Primary Oxidant At A Drinking Water Treatment Plant, Connie Marie Moloney

Graduate Theses and Dissertations

Microbial communities resistant to common oxidants can cause concerns for water treatment plants (WTPs). If a bacterium is not fully oxidized during disinfection, these species can impede upon filtration processes or seed biofilms in the distribution system. In an effort to minimize disinfection by-products (DBP's) that result from the reaction of chlorine (Cl2) with natural organic matter, water treatment plants have the option to change their primary oxidant to chlorine dioxide (ClO2). The following study examines the change in microbial communities during the sedimentation process under differing oxidation regimes, specifically chlorine (Cl2) and ClO2 at the local water treatment plant …

Lab-Scale Experiment For Assessing The Effect Of Resuspension And Oxygenation On Sediment Oxygen Demand, Grace Richardson

Graduate Theses and Dissertations

This study examined the effects of resuspending lake sediment for different time periods in a lab-scale tank under both oxic and anoxic conditions on sediment oxygen demand (SOD) and other related sediment properties. This lab-scale study was conducted as a first step to determine if a proposed method for reducing SOD by treating sediments in lakes and reservoirs is feasible. SOD is a critical process responsible for the formation of anoxic hypolimnia in lakes and reservoirs. A reduction in SOD may delay or eliminate the onset of anoxia in the hypolimnia, preventing adverse ecosystem effects and improving water quality and …

Comparing Ferrous Chloride And Ferrous Sulfate As Secondary Coagulants At The Beaver Water District Drinking Water Treatment Plant, Jenny Doyle

Graduate Theses and Dissertations

In November 2012, the Beaver Water District (BWD) switched primary oxidants from free chlorine to chlorine dioxide (ClO2) to curb formation of trihalomethanes, a regulated group of organic disinfection byproducts (DBPs). Because ClO2 is reduced to chlorite (ClO2-), a regulated inorganic DBP, BWD incorporated ferrous salt into their coagulation regime to quench chlorite to chloride. In this study, two ferrous salts - ferrous chloride (FC) and ferrous sulfate (FS) - were compared as secondary coagulants in combination with alum, the primary coagulant. Ferrous salts were dosed stoichiometrically to reduce chlorite and alum was dosed at percentages (0-100%) relative to a …

Assessing Trichloromethane Formation And Control In Algal-Stimulated Waters Amended With Nitrogen And Phosphorus, Clinton Mash

Graduate Theses and Dissertations

Nitrogen (N) and phosphorus (P) enrichments can stimulate algal growth in drinking water sources, which can cause increased production of disinfection byproduct (DBP) precursors. However, the effect of systematic N and P enrichments on DBP formation and control has not been adequately studied. In this work, we enriched samples from a drinking water source - sampled on April 5, May 30, and August 19, 2013 - with N and P to stimulate algal growth at N:P ratios covering almost five orders of magnitude (0.2-4,429). To simulate DBP-precursor removal processes at drinking water treatment plants (DWTPs), the samples were treated with …

Assessing The Impact Of Chlorine Residual On Trihalomethane And Haloacetonitrile Formation Under Chlorination And Chloramination Disinfection Regimes, Thien Duc Do

Graduate Theses and Dissertations

A disinfection byproduct (DBP) formation potential (FP) test can be used to indirectly measure the concentration of DBP precursors in natural waters, permitting assessment of various DBP-related treatment processes and control strategies. While these tests require a 7-day chlorine residual (CR) between 3-5 mg L^-1 as Cl², it is not well known if this recommended residual corresponds to the true DBPFP (i.e., the maximum concentrations) for trihalomethanes (THMs) and haloacetonitriles (HANs). In this study, THMs and HANs were quantified as a function of CR under three common disinfection regimes: (1) free chlorine at pH 7.0 (FC7), (2) …

Evaluation Of Broiler Litter Heat Production During Windrowing & Nitrogen Based Gas Emission Mitigation Using Biofilter, Min Lei

Graduate Theses and Dissertations

Ammonia emission from animal feeding operations (AFOs) has negative effects on environment and animals' health. Thus measuring and mitigating ammonia emission from AFOs is important for environmental protection. In chapter I, different ammonia measurements were discussed and a mitigation technology- biofilter was represented.

In-house windrowing of built-up litter has been used by broiler producers to reduce pathogen loads and rejuvenate litter for the next flock. When litter is piled up for an extended period during downtime, heat generated by the litter pile can become a substantial heat source due to the metabolism of microorganisms. In chapter II, heat production rates …

A Watershed Scale Evaluation Of Selected Second Generation Biofeedstocks On Water Quality, Gurdeep Singh

Graduate Theses and Dissertations

This study compares a novel simulation approach to the conventional Soil and Water Assessment Tool (SWAT) modeler's approach for targeting biofuel crop production on marginal lands. In conventional SWAT modeling approach, non-spatial definition of hydrological response units (HRUs) results in the simulation of biofuel crops on both marginal and non-marginal land. This study provides an alternative approach in which a marginal-land raster was integrated into the land use and land cover (LULC) raster in such a way that the land uses were divided into marginal and non-marginal components. This modified LULC was used for model setup which resulted in marginal …

Effects Of Testing Time On Anaerobic Toxicity Assessment, Omolola Atinuke Akintomide

Graduate Theses and Dissertations

Anaerobic digestion has been widely used for wastewater treatment for decades. Several Anaerobic Toxicity tests have been developed to screen wastewater for toxicity and assess the treatability of such toxicants. However, past research and reviews on Biochemical Methane Potential (BMP) test and Anaerobic Toxicity Assay (ATA) were considered in this study.

The experimental tests included ammonium-nitrogen and sodium chloride toxicity tests with varied concentration and solid retention time. These tests were designed to demonstrate the impact of ammonia- nitrogen and sodium chloride on the biological degradation process. The anaerobic test set-up includes bench-scale test reactors and respirometers used for measuring …

The Development Of A High Performance Concrete To Store Thermal Energy For Concentrating Solar Power Plants, Emerson Esmond John

Graduate Theses and Dissertations

In recent years, due to rising energy costs as well as an increased awareness of the environmental effects of greenhouse gas emissions produced through traditional forms of energy production, there is great interest in developing alternative sources of energy. One of the most viable alternative energy sources is solar energy. In particular, concentrating solar power (CSP) technologies have been identified as an option for meeting utility needs in the U.S. Southwest. These systems are required to produce electricity not only during periods of high solar radiation but also during times of reduced radiation due to cloud cover, and even extend …