Engineering Commons^™

Nanocellulose Based Foams For Low-Cost Disposable Medical Applications, Dominic Kugell

Electronic Theses and Dissertations

Polyurethane foams have been a staple material for their use in medical positioners, such as post-surgery elevation pillows as well as specific tailored positioners for their use during surgery. Polyurethane foams are preferred because of their lower cost compared to other petroleum derived foams, their versatility, and suitable mechanical properties. However, the environmental impact, including both cost and perception, of these foams is immense. Therefore, alternatives are being explored with biopolymers emerging as a promising class of materials. Cellulose is one such polymer that has recently demonstrated desirable properties. In this study, cellulose nanofibrils (CNF), a household foaming agent, and …

Dynamic Distributed Energy Resources For Expansion Of Ontario’S Greenhouse Sector, Lysandra Naom

Electronic Theses and Dissertations

The vegetable greenhouse sector is rapidly growing and adopting technology advances like supplemental lighting. Supplemental lighting has a dynamic impact on the demand and consumption of a greenhouse’s electricity load. There is uncertainty on the rate of adaptation of technologies and the impact this could have on the power consumption of the sector. Without electricity availability, the sectors innovation and expansion can come to a halt. This research focused on investigating greenhouse electrical load models and lighting trends to forecast demand on electricity grids and discover potential for Distributed Energy Resource (DER) applications.

This thesis presents a series of studies …

Quantifying Spatial Heterogeneity Of Wild Blueberries And Crop Water Stress Monitoring Using Remote Sensing Technologies, Kallol Barai

Electronic Theses and Dissertations

The wild blueberry is one of the major crops of Maine, with significant economic value and potential health benefits. Due to global climate change, drought impacts have been increasing significantly in recent years in the northeast region of the USA, causing significant economic losses in the agricultural sectors. It has been predicted to increase further in the future. Changing patterns of the elevated atmospheric temperatures, increased rainfall variabilities, and more frequent drought events have made the wild blueberry industry of Maine vulnerable, suggesting the adoption of novel approaches to mitigate the negative impacts of global climate changes. Also, wild blueberry …

Structural, Charge Transport, Gas Sensing, Magnetic, Pseudocapacitive, And Electrocatalytic Properties Of Perovskite Oxides., Surendra Bahadur Karki

Electronic Theses and Dissertations

Perovskites are functional materials with the general formula ABO₃ (A = alkali, alkaline earth or lanthanoid cations and B = transition metal or main group cations). These materials are marked by a variety of crystal structures and interesting properties such as colossal magnetoresistance, ferroelectricity, multiferroicity, superconductivity, pseudocapacitance, gas sensing, charge transport, and electrocatalytic properties. The formula of perovskite can be written as AA’BB’O₆, when there is ordering between two cations over A and B-sites. Such compounds are called double perovskite oxides. Some amount of oxygen could be lost from crystal structure without decomposition of the phase. Such …

Analysis Of Bio-Alcohols With Mie-Scattering And Ltc For Lowered Emissions In Pcci, Cesar E. Carapia

Electronic Theses and Dissertations

An investigation was conducted on the optimal engine parameters for facilitating lower NOX and soot emissions of PCCI combustion with either ethanol or n-butanol. The PFI fuels selected were tested at loads of 3, 4, and 5 Bar IMEP for a total of 28 total combustion tests with variations made to the EGR% and boost pressure for each test in order to find the optimal emissions strategy. A Mie-scattering spray fuel analysis was also conducted on the three fuels to gain insight on their influence on combustion/emissions characteristics. It was found that ethanol had a greater average Sauter Mean Diameter …

Using An Inventory Of Unstable Slopes To Prioritize Probabilistic Rockfall Modeling And Acid Base Accounting In Great Smoky Mountains National Park, Thomas A. O'Shea

Electronic Theses and Dissertations

An inventory of unstable slopes along transportation corridors and performance modeling are important components of geotechnical asset management in Great Smoky Mountains National Park (GRSM). Hazards and risk were assessed for 285 unstable slopes along 151 miles of roadway. A multi-criteria model was created to select fourteen sites for two-dimensional probabilistic rockfall simulations and Acid Base Accounting (ABA) tests. Simulations indicate that rock material would likely enter the roadway at all fourteen sites. ABA test results indicate that influence of significant acid-producing potential is generally confined to slaty rocks of the Anakeesta Formation and graphitic schist of the Wehutty Formation. …

Quantification Of Climate Variability And Extreme Events In The Great Plains, Angelinah Ntsieng Rasoeu

Electronic Theses and Dissertations

Climate variability and extreme events continue to worsen resulting in significant impacts to society and the environment. Quantifying precipitation variability, streamflow, and extreme events at local scale is crucial for local planning and management due to spatial and temporal precipitation variability which influences streamflow and thus, water resources. This study uses statistical tools to analyze 1895-2019 (125 years) of historical precipitation data to examine how long-term precipitation varies annually, seasonally, and monthly, and create climate classifications. The results show that annual precipitation is increasing linearly over time ranging from 13.2 in (1976) to 43.1 in (2010) and 5 climate classes …

Laboratory Measurements Of Bed Shear Stress In Open Channel Flow And Soil Erosion Rate In Cohesive Soils, Gunnar Schurmann Kern

Electronic Theses and Dissertations

The relationship between soil erosion rate and bed shear stress is an important problem in sediment transport and scour. However, reliable measurements of the soil erosion function are challenging, both in the field and in the laboratory. The objective of this study is to investigate an experimental setup for conducting bed shear stress and soil erosion rate measurements using an open channel flume with a rough bed. These experiments were performed in an A-8 Hydraulic Channel with a fixed gravel bed. The flow discharge was kept constant at 0.158 ft.3/s, and bed shear stress was varied by changing the channel …

A Study Of Geographic Information System-Based Watershed Processing For Hydrologic Analysis Of Ungauged Watersheds, Philip Adanbe Adalikwu

Electronic Theses and Dissertations

The increasing application of geographic information system (GIS) technology in watershed modeling makes is necessary to further evaluate its impacts on runoff characteristics as a basis for improved hydrologic analysis in ungauged watersheds. Experts in the field of water resources and hydrology have recommended the practice of subdivision when modeling a watershed, and the use of observed data from hydrologically similar watershed to calibrate and validate an ungauged watershed’s model. However, previous studies have failed to adequately address the issues of watershed heterogeneity, spatial and temporal variability in physical parameters, GIS data resolution issues, including artifacts in automated extraction of …

A Hydrologic Climate Study For An Arid Region, Ali Alsubeai

Electronic Theses and Dissertations

Water is the most precious natural resource in arid regions due to the limitation of water resources, expanding population, and increasing volumes of industrial and domestic waste. The purpose of this research was to evaluate methods to estimate water quantity in an arid region. The research consisted of three separate studies. In the first study, hydrologic models used to estimate water quantity were evaluated for suitability of use in arid regions. Most hydrologic models that have been used in arid regions were originally developed for humid regions. Rainfall events in arid regions can be characterized as short-term, high intense rainstorms …

Observation Of New Particle Formation In The Northern Hemisphere At Altitude From 4 To 20 Km, Mohamed Saad

Electronic Theses and Dissertations

New particle formation (NPF) is investigated using measurements of aerosol size distributions and meteorological variables made in two continents, including USA and Europe. Despite the considerably different aerosol particle abundances among the sites, a common relationship was found between the characteristics of NPF events and the air mass convective and/or advective transport. CO and O3 act as tracers of tropospheric and stratospheric air, respectively, their statistical relationship can be used to quantify air mass characteristics and origins. The mixing ratio values of CO increased within the upper troposphere layer before/during NPF events, which may serve as an indicator of occurring …

Evaluating And Predicting The Risk Of Algal Blooms In A Freshwater Lake Through A 4-Dimensional Approach: A Case Study On Lake Mitchell, Sumit Kumar Ghosh

Electronic Theses and Dissertations

Excessive algal growth in freshwater lakes can negatively impact ecosystems, recreation, and human health. Though algae are a natural part of freshwater ecosystems, elevated nutrient loading from anthropogenic and natural sources can lead to algal blooms. Both algae and blue-green algae (BGA) are responsible for algal blooms; however, BGA (cyanobacteria) is more dangerous. The first objective of this research was to prepare a conceptual model to understand how various environmental variables affect algae. This conceptual model was used to choose the environmental variables that help increase or decrease algae in the water environment. The second objective was to develop empirical …

A Hydrologic Study Of Climate Variability In Arid Region, Abdullah Alzaydani

Electronic Theses and Dissertations

Climate variability is an important subject to study. It is the change of climate over a long time, which could have a positive or negative impact on humans, soil, and wildlife. Many environments, such as arid environment could be affected by climate variability. The research goal is studying and examining climate variability in arid environment. The research includes three different studies. The first study includes reviewing and understanding of climate variability over extended time through existing studies in arid environments. In addition, this study includes knowledge about climate negative or positive impact on the environment. This study will be reviewing …

A Speciation Modeling Study Of Heavy Metal Adsorption To Plastic In Municipal Wastewater Treatment Plant Units, Kaitlyn Hague

Electronic Theses and Dissertations

Microplastics are an emerging concern due to their harmful effect to organisms and their ability to facilitate transport of contaminants including heavy metals. Microplastics can enter the environment through wastewater treatment plants, landfill leachate, and littering. Once in the environment microplastics can be distributed throughout rivers, the ocean, and lakes. In order to understand the adsorption of heavy metals to microplastics a geochemical modeling study was completed using Visual Minteq. Lab tests were completed to better understand what constituents are available in wastewater at four different locations: influent, clarifiers, digesters, and effluent. These constituents were then used to observe how …

Monitoring Methods And Performance Assessment For Implementation Of Low Impact Development Practices In South Dakota, Farhana Akhter

Electronic Theses and Dissertations

Urbanization increases impervious surface area, which changes the hydrology of a watershed. Impervious surfaces prevent the infiltration of stormwater water into the ground surface which results in a higher volume of stormwater runoff and higher peak flow. Low Impact Development (LID) practices help to restore pre-development hydrology by increasing infiltration, evaporation, and transpiration. While the hydrologic performance of LID practices has been studied extensively and continues to be an area of active research, there has been very limited monitoring or demonstration of LID practices in South Dakota. In addition, municipalities in South Dakota and elsewhere that implement new LID practices …

Modeling Response Of Water Quality To Land-Use And Climate Change In Lake Auburn, Me, Nicholas Messina

Electronic Theses and Dissertations

Lake Auburn, Maine, USA, is a historically unproductive lake that has experienced multiple algal blooms since 2011. The lake is the water supply source for a population of ~60,000. We modeled past temperature, and concentrations of dissolved oxygen (DO) and phosphorus (P) in Lake Auburn by considering the watershed and internal contributions of P as well as atmospheric factors, and predicted the change in lake water quality in response to future climate and land-use changes. A stream hydrology and P-loading model (SimplyP) was used to generate input from two major tributaries into a lake model (MyLake) to simulate physical mixing, …

Perspectives On Water Resources Risk, Policy, And Stewardship, Anne Marie Lausier

Electronic Theses and Dissertations

Water management approaches have historically optimized water for human use and placed lower emphasis on the relationship between ecosystems and humans. Despite efforts to balance human and ecosystem needs, existing management approaches tend to prioritize some needs, knowledges, and values over others. Natural and anthropogenic changes pose challenges to water governance institutions due to policy inflexibility, and may lead to ecosystem degradation, water stress, and conflict among water users. This work seeks to redress these shortcomings through three scholarly contributions. First, a conceptual framework for Water Resources Stewardship is developed in support of equitable and adaptive solutions under changing conditions. …

Analysis Of Hydrodynamic And Bathymetric Gradients In Canaveral National Seashore Following Living Shoreline And Oyster Restorations, David Spiering

Electronic Theses and Dissertations

Coastal vulnerability has been gaining recognition as a critical issue, especially with the increasing predictions of sea level rise. Susceptibility to extreme events, eutrophication, and shoreline modification has left many coastal regions in a degraded state. Shoreline protection has traditionally taken the form of seawalls and offshore breakwaters which can be detrimental to both the local ecosystems and adjoining shorelines. The objective of this thesis is to analyze the hydrodynamic and bathymetric variation that occurs within Mosquito Lagoon, Florida following living shoreline and oyster reef restorations. The shoreline sites were sampled using a Before-After-Control-Impact (BACI) design and data were analyzed …

The Effect Of Edge-Of-Field Nutrient Management Practices On Microbial Concentrations In Subsurface Drainage Water And The Associated Risk Of Antibiotic Resistance Dissemination, Sara Mardani

Electronic Theses and Dissertations

Many in-field and edge-of-field management practices have been used to reduce nutrient loads from agricultural fields. The denitrification woodchip bioreactor (WB) is one edgeof- field management practice that has proven to be effective in removing nitrate from subsurface drainage water. The success in nitrate removal achieved with WBs has raised interest in expanding their capabilities for removing other agricultural pollutants, including phosphorus, by using other types of media like phosphorus-sorbing filters or combining these filters with woodchips to remove both nitrate and phosphorus as dual-nutrient removal systems. Despite the extensive research done on WBs and nutrient filter materials, little consideration …

Adsorption Capacity Assessment Of Advance Green Environmental Media To Remove Nutrients From Stormwater-Runoff, Hanan Elhakiem

Electronic Theses and Dissertations

Best Management Practices (BMPs) in stormwater treatment are a suite of treatment alternatives to deal with pollutant removal problems from stormwater runoff. Biosorption-activated media (BAM) are green sorption media consists of recycled materials have shown excellent nutrient removal as an effective BMP by enhancing physicochemical and microbiological processes. In this study, Iron-Filling Green Environmental Media (denoted as IFGEM-3) and Advanced Green Environmental Media 1 and 2 (denoted as AGEM-1 and AGEM-2) were produced and tested for their adsorption capacities as well as removal and recovery potential for phosphate, nitrate, and ammonia against natural soil (baseline) collected from a stormwater retention …

Variability Of E. Coli In Streambed Sediments And Its Implication For Water Quality, Sadia Salam

Electronic Theses and Dissertations

Fecal indicator bacteria (FIB), including E. coli, are the number one cause of water quality impairments in the United States according to the USEPA. FIB are used as a predictor to identify the possible presence of pathogens in waterbodies. E. coli is a useful indicator of gastrointestinal (GI) related illnesses from contact with fresh water. While surface water is routinely monitored for water quality, streambed sediments are rarely considered as a source of FIB to the overlying water column. This study focuses on understanding the variation of E. coli concentrations in streambed sediments and the potential impact of sediment sources …

Natural Sunlight Photodegradation Of Halogenated Disinfection Byproducts In Water, Ibrahim Abusallout

Electronic Theses and Dissertations

Disinfection byproducts (DBPs) presence in wastewater effluents and receiving waters may impact the quality of drinking water during water reuse practices. Natural solar photolysis is one of the biogeochemical processes that may lead to decreased DBPs concentrations in water. The purpose of this dissertation is to determine the fate of chlorinated, brominated and iodinated DBPs in surface water by natural sunlight photolysis and investigate the use of solar-based advanced oxidation processes (AOPs) for removal of DBPs in water. Total organic halogen (TOX) was used to measure total chlorinated- (TOCl), brominated- (TOBr) and iodinated-DBPs (TOI) in water. The first objective was …

Assessment Of A Surface Water Supply For Source And Treated Distribution System Quality, Angela Rodriguez

Electronic Theses and Dissertations

This study focused on providing a source to tap assessment of surface water systems with respect to (i) the use of alternative biomonitoring tools, (ii) disinfection byproduct (DBP) formation and control, and (iii) corrosion control. In the first study component, two water systems were microbiologically evaluated using adenosine triphosphate (ATP) bioluminescence technology. It was determined that microbial ATP was useful as a surrogate for biomonitoring within a surface water system when paired with traditional methods. Although microbial activity differed between distribution systems that used either chloramine or chlorine disinfectant, in both cases flowrate and season affected microbial ATP values. In …

An Assessment Of Biosorption Activated Media For The Removal Of Pollutants In Up-Flow Stormwater Treatment Systems, Andrew Hood

Electronic Theses and Dissertations

Nitrogen and phosphorus are often the limiting nutrients for marine and freshwater systems respectively. Additionally, stormwater often contains elevated levels of pathogens which can pollute the receiving water body and impact reuse applications [1-4]. The reduction of limiting nutrients and pathogens is a common primary target for stormwater best management practices (BMPs) [5]. Traditional BMPs, such as retention/detention treatment ponds require large footprints and may not be practical in ultra-urban environments where above ground space is limited. Upflow filters utilizing biosorption activated media (BAM) that can be placed underground offer a small footprint alternative. Additionally, BAM upflow filters can be …

Design, Synthesis And Characterization Of Biomimetic, Bioinspired And Bio-Related Functional Polymers For Atmospheric Water Recovery, Abdullah Alqassar

Electronic Theses and Dissertations

Atmospheric water recovery in changing environments has received wide attention in environmental science and engineering communities due to rapid population growth and frequent droughts. This study is focused on the design, synthesis, and characterization of biomimetic, bioinspired, and bio-related functional polymers (b3p) to help resolve the water supply issue especially in arid or semi-arid regions. It is aimed to develop unique synthetic methods to access well-defined polymers with the aid of nanomaterials and metal to produce next generation polymer materials for better atmospheric water recovery. The design of such new b3p is bioinspired by some skin materials of biological species …

Long-Term Carbon And Copper Impact On Nutrient Removal Via Green Sorption Media In Dynamic Linear Ditch Environments, Diana Ordonez

Electronic Theses and Dissertations

Nutrient-laden stormwater runoff causes environmental and ecological impacts on receiving water bodies. Biosorption Activated Media (BAM) composed of the sand, tire crumb, and clay have been implemented in stormwater best management practices due to its ability to efficiently remove nutrients from stormwater runoff, such as in roadside linear ditches, via unique chemophysical and microbiological processes. In this study, a set of fixed-bed columns were set up to simulate some external forces in roadside linear ditches and examine how these external forces affect the performance of BAM. In our experiment, scenario 1 simulates the impact that animals such as tortoises, moles …

Stream Flow Analysis Of The Big Sioux River Just South Of Brookings, South Dakota, Samuel Ruppert

Electronic Theses and Dissertations

Floods are the most common type of natural disaster in the world and one of the most damaging. Changes in climate conditions such as precipitation and temperature are causing changes in stream flow. This means that in order to better understand flooding and possibly develop a system for making flood predictions, stream flow needs to be analyzed more closely. The primary objective of this thesis is to analyze the Big Sioux River just south of Brookings, South Dakota, both annually and seasonally. The United States Geological Survey (USGS) has stream gauges placed in rivers and streams all over the United …

Comparison Of A Modified And Traditional Rapid Infiltration Basin For Treatment And Control Of Nutrients In Wastewater Effluent, Jessica Cormier

Electronic Theses and Dissertations

Rapid infiltration basins (RIB) have been historically used in Florida for groundwater recharge, effluent disposal, or a combination of both. However, this technique has proven ineffective in providing nitrogen control unless the RIB is modified in some manner. In this study, a traditional RIB was compared to a modified RIB constructed with manufactured biosorption activated media (BAM) to evaluate nitrate removal from reclaimed water. The RIBs are used for reclaimed and excess storm water disposal. Few, if any, studies have been published where BAM-modified RIBs have been used for this purpose. In this work, a mixture of clay, tire crumb, …

Application Of Drainage Water Management And Saturated Buffers For Conservation Drainage In South Dakota, Abhinav Sharma

Electronic Theses and Dissertations

Edge of field practices such as drainage water management (DWM) and saturated buffers can reduce nutrient transport from croplands to surface waterbodies. DWM uses stackable weir boards in a control structure to manipulate the water table depth throughout the cropping season and reduce the amount of nutrient rich water draining out from the field. Saturated buffers, on the other hand, use a control structure to divert water draining out from the cropland to a vegetative strip via a subsurface tile installed parallel to a waterway. For the saturated buffer systems, a combination of natural denitrification, nitrogen mineralization, and plant uptake …

A Development Of Travel Time Equation For Overland Flow As Affected By Vegetation, Naga Vara Prasad Ganti

Electronic Theses and Dissertations

In overland flow water research, travel time is a significant parameter used in estimating peak discharge in channels or rivers. Overland flow is assumed to be in turbulent condition to estimate travel time using Manning’s Velocity Equation (MVE). When the flow is in a laminar condition, Grismer’s Laminar Mean Velocity Equation (GLMVE) is applied but fails to consider the roughness parameter. A review of the literature shows numerous equations for overland travel time, but there is no known equation that determines the mean velocity of overland flow under laminar condition with a roughness coefficient or other coefficient related to the …