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Doctoral Dissertations

2014

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Full-Text Articles in Engineering

Behavior Of Larger-Diameter Strands In The Disturbed Region Of Prestressed Concrete Girders, John Verlin Cabage Jr. Dec 2014

Behavior Of Larger-Diameter Strands In The Disturbed Region Of Prestressed Concrete Girders, John Verlin Cabage Jr.

Doctoral Dissertations

Traditionally, the Tennessee Department of Transportation has been using American Association of State Highway and Transportation Officials – Prestressed/Precast Concrete Institute Bulb Tee (AASHTO-PCI BT) sections for its prestressed concrete bridges. These sections have limited bottom flange widths where the prestressing strands are located. To increase span capacities of these sections, other States have adopted new sections with a wider flange width. Producers in Tennessee have raised concerns about the cost of the new steel forms to accommodate these new sections. As an alternative, this research examines the use of larger diameter strand in conjunction with high-strength concrete and standard …


Photosystem I-Based Applications For The Photo-Catalyzed Production Of Hydrogen And Electricity, Rosemary Khuu Le Dec 2014

Photosystem I-Based Applications For The Photo-Catalyzed Production Of Hydrogen And Electricity, Rosemary Khuu Le

Doctoral Dissertations

The aim of this dissertation was to optimize systems integrating the photosystem I (PSI) redox protein, which is involved in photosynthesis, with noble metals for electron transfer to show its versatility: 1) in solution coupled with platinum to mediate hydrogen evolution and 2) on a planar gold surface for electricity production.

Response surface methodology was utilized to study variables that affect hydrogen (H2) yield from platinized-PSI. Light intensity, temperature, and platinum concentration were varied during the platinum-photo-reduction process. Analysis of the effects of the variables on H2 yield allowed for determination of a condition for optimized hydrogen …


Flatness-Based Control Methodologies To Improve Frequency Regulation In Power Systems With High Penetration Of Wind, Maryam Hassani Variani Dec 2014

Flatness-Based Control Methodologies To Improve Frequency Regulation In Power Systems With High Penetration Of Wind, Maryam Hassani Variani

Doctoral Dissertations

To allow for high penetration of distributed generation and alternative energy units, it is critical to minimize the complexity of generator controls and to minimize the need for close coordination across regions. We propose that existing controls be replaced by a two-tier structure of local control operating within a global context of situational awareness. Flatness as an extension of controllability for non-linear systems is a key to enabling planning and optimization at various levels of the grid in this structure. In this study, flatness-based control for: one, Automatic Generation Control (AGC) of a multi-machine system including conventional generators; and two, …


Characterizing The Mechanical Behavior Of Single And Polycrystalline Silicon Carbide Using Nanoindentation., Amit Datye Dec 2014

Characterizing The Mechanical Behavior Of Single And Polycrystalline Silicon Carbide Using Nanoindentation., Amit Datye

Doctoral Dissertations

This research aims at enhancing the fundamental understanding of mechanisms controlling the deformation and fracture of silicon carbide based ceramics (single- and poly-crystal). The role of microstructure and material properties on the energy absorption capability of SiC is studied. This research helps to improve the ability to quantitatively predict the initiation and propagation of fracture and the interaction between fracture and plasticity, which provides a step towards a mechanistic understanding of deformation and failure properties of ceramic single crystals and polycrystals. The validity of the indentation-cracking method for toughness measurement is examined using nanoindentation tests with different indenters (spherical, pyramidal). …


Blending Issues Of Hot And Warm Mix Asphalt Containing Recycled Asphalt Pavement And Recycled Asphalt Shingle, Sheng Zhao Dec 2014

Blending Issues Of Hot And Warm Mix Asphalt Containing Recycled Asphalt Pavement And Recycled Asphalt Shingle, Sheng Zhao

Doctoral Dissertations

The current tendency in paving industry is to increase the use of recycled asphalt pavement (RAP) and recycled asphalt shingle (RAS). However, one of the reasons that limit the high recycled amount is the unknown blending between virgin and RAP/RAS binders. A series of studies were conducted in this dissertation to address blending issues in warm mix asphalt (WMA) and hot mix asphalt (HMA) containing RAP and RAS, in terms of evaluation of recycled binder mobilization, binder homogeneity and WMA effects on blending.

Partial blending was observed in RAS mixtures and the most efficient blending occurred at approximately 5% RAS …


Development And Modeling Of A Biosensor Platform Using Algan/Gan Hemt Devices, Fahmida Shaheen Tulip Dec 2014

Development And Modeling Of A Biosensor Platform Using Algan/Gan Hemt Devices, Fahmida Shaheen Tulip

Doctoral Dissertations

The history of biosensors began in 1962 with the invention of enzyme electrodes by Leland C. Clark. Since then, biosensors have come a long way with simultaneous contributions in various fields such as biology, chemistry, material science, electronics, physics and VLSI. With the advancement in science and technology, smaller, more sensitive and dependable biosensors have become a reality. Still the need for cost-effective, sophisticated, reliable, robust biosensors that can be used to detect multiple types of biomolecules remains a technological challenge to be resolved.

The proposed AlGaN/GaN High Electron Mobility Transistors (HEMTs) have excellent prospect to become the biosensor platform …


Lifetime Estimation Of Igbts In A Grid-Connected Statcom, Lakshmi Reddy Gopi Reddy Dec 2014

Lifetime Estimation Of Igbts In A Grid-Connected Statcom, Lakshmi Reddy Gopi Reddy

Doctoral Dissertations

Lifetime estimation of power semiconductor devices, and IGBT devices in particular, used in the power electronics integrated with power systems has gained technical importance in recent times with increased scope of distributed generation, renewable energy systems and FACTS. Since most of the common failures (wire bond and solder fatigue) are caused by thermo-mechanical stresses, the methodology of lifetime estimation starts with temperature estimation, cycle counting based on rainflow algorithm, and finally degradation calculation based on linear accumulation model.

Different number of RC cells for each packaging layer in the module for the thermal model, including the influence of encapsulant is …


Stability Analysis Of The Rotary Drill-String, Liangming Pan Dec 2014

Stability Analysis Of The Rotary Drill-String, Liangming Pan

Doctoral Dissertations

Oil and natural gas are major energy sources for modern society. A rotary drilling system is the best known technology to extract them from underground. The vibration and stability of drilling systems have been studied for decades to improve drilling efficiency and protect expensive down-hole components. It is well known that severe drill-string vibrations are caused by many different loads: axial loads such as the hook load and the self-weight of the drill-string, end torques applied by the surface motor and restrained at the bit, the inertial load caused by whirling, the fluid drag force, and the contact force between …


Single Cell Biophysics: Applications In Cardiomyocyte Mechanobiology And Stem Cell Mechanotransduction, Benjamin Edward Reese Dec 2014

Single Cell Biophysics: Applications In Cardiomyocyte Mechanobiology And Stem Cell Mechanotransduction, Benjamin Edward Reese

Doctoral Dissertations

While a great deal of work has been done to analyze cardiac dynamics and mechanics at the organ and tissue levels, there remains much less data regarding these metrics at the single cell level. Additionally, as fields such as regenerative medicine and tissue engineering are beginning to demonstrate greater therapeutic potential, the study and influence of stem cell mechanics on differentiation has become a major area of interest. For these reasons, along with the continued advancement of molecular techniques and assays, there is a growing need to develop functional assays that can integrate and bridge the findings from multiple length …


Unlocking The Secrets Of Multi-Flagellated Propulsion, Stefan Oma Nwandu-Vincent Dec 2014

Unlocking The Secrets Of Multi-Flagellated Propulsion, Stefan Oma Nwandu-Vincent

Doctoral Dissertations

In this work, unique high-speed imaging platforms and an array of theoretical analysis methods are used to thoroughly investigate eukaryotic multi-flagellated propulsion using Tritrichomonas foetus as a test case. Through experimental observations through our imaging system with superior resolution and capture rate exceeding that of previous studies, it was discovered for the first time that the T. foetus employs a strategy similar to that of the “run and tumble” strategies found in bacteria and Chlamydomonas; it has two distinct flagellar beating patterns that result in two different body swimming motions, linear and turning swimming.

These two flagella patterns were …


Thermodynamic Modeling Of Uranium And Oxygen Containing Ternary Systems With Gadolinium, Lanthanum, And Thorium, Jacob Wesley Mcmurray Dec 2014

Thermodynamic Modeling Of Uranium And Oxygen Containing Ternary Systems With Gadolinium, Lanthanum, And Thorium, Jacob Wesley Mcmurray

Doctoral Dissertations

The CALPHAD method is used to assess the thermodynamic properties and phase relations in the U-M-O system where M = Gd, La, and Th. A compound energy formalism (CEF) model for fluorite UO2±x [urania] is extended to represent the complex U1-yMyO2±x [urania solid solution] phases. The lattice stabilities for fictive GdO2 [gadolinia] and LaO2 [lanthana] fluorite structure compounds are calculated from density functional theory (DFT) for use in the CEF for U1-yMyO2±x [urania solid solution phase] while U6+ [uranium 6 plus cation] is introduced into the …


Elucidating Fundamental Mechanisms In Focused Electron- And Ion-Beam Induced Synthesis, Carlos M. Gonzalez Dec 2014

Elucidating Fundamental Mechanisms In Focused Electron- And Ion-Beam Induced Synthesis, Carlos M. Gonzalez

Doctoral Dissertations

A focused electron beam deposition process (FEBID) coupled with in-situ infrared pulsed laser assist (LA-EBID) has been implemented for higher purity tungsten nanowires using W(CO)6 [tungsten hexacarbonyl] as parent precursor gas. Nanowires made of Co from Co2(CO)8 [dicobalt octacarbonyl] and Pt from MeCpPtIVMe3 [trimethyl methylcyclopentadienyl platinum] have also been realized by using inert focused ion beams of helium and helium and neon, respectively. In all cases, higher electrical conductivities, higher purities and larger grain sizes have been obtained when compared with preceding traditional additive edit techniques. These new approaches will make possible successful nanoscale direct-write …


Computing Approximate Solutions To The Art Gallery Problem And Watchman Route Problem By Means Of Photon Mapping, Bruce Andrew Johnson Dec 2014

Computing Approximate Solutions To The Art Gallery Problem And Watchman Route Problem By Means Of Photon Mapping, Bruce Andrew Johnson

Doctoral Dissertations

Wireless sensor networks (WSNs) can be partitioned component sensor nodes (SNs) who are meant to operate and sense information arriving from multiple spectra in their environment. Determining where to place a single SN or multiple SNs such that the amount of information gained is maximized while the number of SNs used to gain that information is minimized is an instance of solving the art gallery problem (AGP). In order to solve the AGP, we present the Sensor Placement Optimization via Queries (SPOQ) algorithm that uses level sets populated by queries to a photon map in order to find observation points …


Synthesis And Thermodynamic Analysis Of Volatile Beta-Diketone Complexes Of Select Lanthanides Via Gas-Phase Separations, Daniel Hanson Dec 2014

Synthesis And Thermodynamic Analysis Of Volatile Beta-Diketone Complexes Of Select Lanthanides Via Gas-Phase Separations, Daniel Hanson

Doctoral Dissertations

Rapid separation techniques for fission and activation products have long been desired to supplant the slow solution-based methodologies currently used. In this work, rare earth elements were derivatized with β [beta]-diketones to synthesize rare earth complexes with high volatility suitable for gas-phase separations. Rare earth elements samarium and dysprosium were combined with hfac (1,1,1,5,5,5-hexafluoro-2,4-pentadione) and fod (6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedione) and analyzed using a gas-phase separation technique. Rare earth elements praseodymium and europium were combined with dpm (2,2,6,6-tetra-methyl-3,5-heptanedione) and similarly analyzed. Employing the data from the separations, the entropy (Δ [delta] S) and enthalpy (Δ [delta] H) of adsorption were evaluated mathematically based …


Automated Doppler Broadening Of Cross Sections For Neutron Transport Applications, Shane William Daniel Hart Dec 2014

Automated Doppler Broadening Of Cross Sections For Neutron Transport Applications, Shane William Daniel Hart

Doctoral Dissertations

This dissertation discusses the research and development of new cross section temperature handling techniques for the SCALE computer code, which is developed and maintained at Oak Ridge National Laboratory. In particular, methods will be added to the KENO Monte Carlo code.

Areas of interest include: neutron scattering off of heavy isotopes in the epithermal energy range, implementation of Doppler pre-broadening of continuous energy one-dimensional cross-section data, implementation of interpolation on the continuous energy two-dimensional cross sections, and implementation of the direct S(A,B) [S alpha beta] method for thermal neutron scattering and interpolation on that data.

Accurate cross section scattering off …


The Structure And Function Of Photosystem I And Photosystem I – Hydrogenase Protein Fusions: An Experimental And Computational Study, Bradley Jordan Harris Dec 2014

The Structure And Function Of Photosystem I And Photosystem I – Hydrogenase Protein Fusions: An Experimental And Computational Study, Bradley Jordan Harris

Doctoral Dissertations

Photosystem I (PSI) is a membrane protein involved in the photosynthetic cycle of plants, algae, and cyanobacteria that is of specific interest due to its ability to harness solar energy to generate reducing power. This work seeks to form an in vitro hybrid protein fusion between the membrane integral PSI protein and the membrane-bound hydrogenase (MBH) enzyme, in an effort to improve electron transport between these two proteins.

Small-angle neutron scattering (SANS) was used to characterize the detergent-solubilized solution structure of trimeric PSI from the cyanobacterium Thermosynechococcus elongatus, which showed that the detergent interacts primarily with the hydrophobic periphery …


Influence Of Texture And Grain Size On The Plastic Anisotropy In A Wrought Mg Alloy: Synchrotron X-Ray Diffraction And Visco-Plastic Self-Consistent Modeling, Yi Wang Dec 2014

Influence Of Texture And Grain Size On The Plastic Anisotropy In A Wrought Mg Alloy: Synchrotron X-Ray Diffraction And Visco-Plastic Self-Consistent Modeling, Yi Wang

Doctoral Dissertations

The combined effects of texture and grain size on the yielding and hardening behavior in a hot-rolled AZ31B Mg alloy were studied by using synchrotron x-ray diffraction and visco-plastic self-consistent (VPSC) simulation methods.

First, the influence of texture on Hall-Petch relationships (namely, critical resolved shear stresses and hardening parameters) in a Mg alloy was investigated to establish a constitutive basis for the VPSC simulation.

Then, the changes in dominant deformation mechanisms (basal, prismatic, and pyramidal slip as well as extension twin) and their relative interactions were studied systematically as a function of the initial texture using a VPSC scheme. The …


Uwb Precise Indoor Localization System Performance, Limitations And Its Integration, Essam Abdelkadir Elkhouly Dec 2014

Uwb Precise Indoor Localization System Performance, Limitations And Its Integration, Essam Abdelkadir Elkhouly

Doctoral Dissertations

An indoor localization system that was built at University of Tennessee is extensively studied and improved. The goal of the system is to achieve mm down to sub-mm accuracy/precision.

Sub-sampling is used to alleviate the high sampling rate required for UWB signals. Current commercial direct sampling systems are still too slow or prohibitively expensive for UWB applications. We developed two different sub-sampling techniques, but the two systems suffer numerous shortcomings: low throughput, non-robustness, non-linearity. A third system is introduced that achieve both high accuracy and high through-put. Changes in the detection algorithm and the frame synchronization are developed to accommodate …


A Study Of Energy Resolution And Non-Proportionality Of Yalo3:Ce And Gd3ga3al2o12:Ce, Samuel Bradley Donnald Dec 2014

A Study Of Energy Resolution And Non-Proportionality Of Yalo3:Ce And Gd3ga3al2o12:Ce, Samuel Bradley Donnald

Doctoral Dissertations

For many radiation detection applications, energy resolution is one of the most important detector characteristics. In well designed scintillation detectors, the energy resolution is primarily driven by two main factors - the light output and light yield non-proportionality. A great deal of research has already focused on understanding and improving the light yield of scintillation detectors; however, light yield non-proportionality is less well understood. Until recently, light yield non-proportionality was thought to be an intrinsic scintillator property with very little sample-to-sample variation. In this work, two materials have been investigated that demonstrate a variable light yield non-proportionality. The first material …


High-Efficiency Three-Phase Current Source Rectifier Using Sic Devices And Delta-Type Topology, Ben Guo Dec 2014

High-Efficiency Three-Phase Current Source Rectifier Using Sic Devices And Delta-Type Topology, Ben Guo

Doctoral Dissertations

In this dissertation, the benefits of the three-phase current source rectifier (CSR) in high power rectifier, data center power supply and dc fast charger for electric vehicles (EV) will be evaluated, and new techniques will be proposed to increase the power efficiency of CSRs.

A new topology, referred as Delta-type Current Source Rectifier (DCSR), is proposed and implemented to reduce the conduction loss by up to 20%. By connecting the three legs in a delta type on ac input side, the dc-link current in DCSR can be shared by two legs at the same time.

To increase the switching speed …


A Low-Power, Reconfigurable, Pipelined Adc With Automatic Adaptation For Implantable Bioimpedance Applications, Terence Cordell Randall Dec 2014

A Low-Power, Reconfigurable, Pipelined Adc With Automatic Adaptation For Implantable Bioimpedance Applications, Terence Cordell Randall

Doctoral Dissertations

Biomedical monitoring systems that observe various physiological parameters or electrochemical reactions typically cannot expect signals with fixed amplitude or frequency as signal properties can vary greatly even among similar biosignals. Furthermore, advancements in biomedical research have resulted in more elaborate biosignal monitoring schemes which allow the continuous acquisition of important patient information. Conventional ADCs with a fixed resolution and sampling rate are not able to adapt to signals with a wide range of variation. As a result, reconfigurable analog-to-digital converters (ADC) have become increasingly more attractive for implantable biosensor systems. These converters are able to change their operable resolution, sampling …


Adaptive Control For Power System Voltage And Frequency Regulation, Yao Xu Dec 2014

Adaptive Control For Power System Voltage And Frequency Regulation, Yao Xu

Doctoral Dissertations

Variable and uncertain wind power output introduces new challenges to power system voltage and frequency stability. To guarantee the safe and stable operation of power systems, the control for voltage and frequency regulation is studied in this work.

Static Synchronous Compensator (STATCOM) can provide fast and efficient reactive power support to regulate system voltage. In the literature, various STATCOM control methods have been discussed, including many applications of proportional–integral (PI) controllers. However, these previous works obtain the PI gains via a trial and error approach or extensive studies with a tradeoff of performance and applicability. Hence, control parameters for the …


Scalable Hardware Efficient Deep Spatio-Temporal Inference Networks, Steven Robert Young Dec 2014

Scalable Hardware Efficient Deep Spatio-Temporal Inference Networks, Steven Robert Young

Doctoral Dissertations

Deep machine learning (DML) is a promising field of research that has enjoyed much success in recent years. Two of the predominant deep learning architectures studied in the literature are Convolutional Neural Networks (CNNs) and Deep Belief Networks (DBNs). Both have been successfully applied to many standard benchmarks with a primary focus on machine vision and speech processing domains.

Many real-world applications involve time-varying signals and, consequently, necessitate models that efficiently represent both temporal and spatial attributes. However, neither DBNs nor CNNs are designed to naturally capture temporal dependencies in observed data, often resulting in the inadequate transformation of spatio-temporal …


Investigation Of Deformation And Failure Mechanisms In Nanoindentation Mechanics, Yuzhi Xia Dec 2014

Investigation Of Deformation And Failure Mechanisms In Nanoindentation Mechanics, Yuzhi Xia

Doctoral Dissertations

This dissertation further extends nanoindentation to study the initiation of plasticity in single crystals in nanoscale stressed volumes, to the instrumented tests for damage evaluation and monitoring, and to the fundamental issues in deformation and failure mechanisms in relationship to the defect evolutions.

In the first project, model Fe-Cr, Fe-Ni and Fe-Cr-Ni alloys that are the basis of many structural steels were synthesized as single crystals and characterized. The compositions investigated were Fe-15Cr, Fe-30Cr, Fe-30Ni and Fe-15Cr-15Ni (atomic percent). Several key mechanical properties were determined which will be useful in further studies of irradiation/deformation-induced defects. Incipient plasticity and slip characteristics …


A Study Of Espoused Corporate Cultural Factors And Their Relationship With Business Success, Tonya Denise Brown Dec 2014

A Study Of Espoused Corporate Cultural Factors And Their Relationship With Business Success, Tonya Denise Brown

Doctoral Dissertations

Reshoring of manufacturing companies is vital to the United States’ economy. Although one may assume that all of the business reshored will be large companies, statistics show that small businesses comprise the largest share of the U.S. economy. Small businesses make up 99.7% employer firms. Yet, 80% of entrepreneurs and small businesses who start will fail within the first 18 months.

This study defines the key success variables of the espoused culture for selected Fortune 500 companies that could be used by entrepreneurs and small businesses to emulate their continued successes. The method to define the key success variables was …


Effective Multi-Echelon Inventory Systems For Supplier Selection And Order Allocation, Cong Guo Dec 2014

Effective Multi-Echelon Inventory Systems For Supplier Selection And Order Allocation, Cong Guo

Doctoral Dissertations

Successful supply chain management requires an effective sourcing strategy to counteract uncertainties in both the suppliers and demands. Therefore, determining a better sourcing policy is critical in most of industries. Supplier selection is an essential task within the sourcing strategy. A well-selected set of suppliers makes a strategic difference to an organization's ability to reduce costs and improve the quality of its end products. To discover the cost structure of selecting a supplier, it is more interesting to further determine appropriate levels of inventory in each echelon for different suppliers. This dissertation focuses on the study of the integrated supplier …


Plastic Anisotropy Of Complex Crystals And Hierarchically Structured Alloys Using Micro-Mechanical Computational Analysis, Lin Li Dec 2014

Plastic Anisotropy Of Complex Crystals And Hierarchically Structured Alloys Using Micro-Mechanical Computational Analysis, Lin Li

Doctoral Dissertations

The material anisotropy is one of the most important material properties that cannot be disregarded in today’s world of materials designing and manufacturing. As new materials being developed and new material demands are introduced the inevitable focus on anisotropic materials has been brought under the spotlight. In this dissertation, several experimental and simulation project regarding material anisotropic effects on hexagonal close packed crystals such as Silicon Carbide as well and hierarchically structured solid solution ferritic based alloys. The general purpose was to demonstrate the improvement on various intended material properties using finite element method. Since indentation is a widely used …


Single Fiber Mechanical Properties Using Nano-Tensile Testing And Carbon Fiber Structure-Property Relationship, Matthew Erich Kant Dec 2014

Single Fiber Mechanical Properties Using Nano-Tensile Testing And Carbon Fiber Structure-Property Relationship, Matthew Erich Kant

Doctoral Dissertations

Single carbon fibers are studied using a nano-tensile testing system. This system has unprecedented load and displacement resolution, nN and nm respectively, and the ability to perform dynamic testing for storage and loss modulus during quasi-static tensile extension. Furthermore, improved fiber mounting and alignment procedures coupled with the precision of the nano-tensile testing system assist in unprecedented resolution in single fiber mechanical testing for axial modulus and strength. Hence, using these unique capabilities, the moduli and their statistical distribution of many high performance carbon fibers are reported here. From this, a simplified single parameter model describing the strain dependent modulus …


Fatigue, Fracture, And Environmentally-Assisted Behavior Of Advanced Engineering Materials, Zhi Tang Dec 2014

Fatigue, Fracture, And Environmentally-Assisted Behavior Of Advanced Engineering Materials, Zhi Tang

Doctoral Dissertations

The objective of the present study is to provide a fundamental understanding of fatigue, fracture, and environmentally-assisted behavior of high-entropy alloys (HEAs). The work involves fatigue, fracture, and environmentally-assisted behavior of a new kind of advanced engineering materials, called HEAs. Three tasks are studied: (1) microstructures and fracture mechanisms of HEAs, (2) fatigue failure and life prediction of HEAs, and (3) corrosion and environmentally-assisted behavior of HEAs.

In the first task, microstructural stability and fracture mechanism of the AlCoCrFeNi alloy are studied and compared with thermodynamic calculations. In the second task, high-cycle fatigue-failure mechanisms of the cold-rolled Al0.5CoCrCuFeNi alloy are …


Characterization Of The Fine-Scale Weld Deposit Microstructure And Its Influence On The Elevated Temperature Properties Of 2.25cr - 1mo - 0.25v Weldments In Heavy Wall Pressure Vessels, Dewey Joshua Burgess Dec 2014

Characterization Of The Fine-Scale Weld Deposit Microstructure And Its Influence On The Elevated Temperature Properties Of 2.25cr - 1mo - 0.25v Weldments In Heavy Wall Pressure Vessels, Dewey Joshua Burgess

Doctoral Dissertations

The research herein was conducted to characterize the fine-scale microstructure of 2.25Cr‑1Mo‑0.25V (22V) submerged arc weld deposits and to study the influence of the microstructure on creep behavior and reheat cracking susceptibility. Scanning electron microscopy and transmission electron microscopy examinations concentrated on carbide morphology and evolution as a function of time and temperature, since the majority of properties that are associated with 22V weld deposits are attributable to the carbide type and location throughout the microstructure.

Five distinct carbides were observed in the range of heat treatments studied: MC, M2C, M23C6, M7C3, and M6C. It was shown that each carbide …