Engineering Commons^™

Turbulent Mixing And Chemical Reaction In Baffled Stirred Tank Reactors : A Comparison Between Experiments And A Novel Micromixing-Based Computational Fluid Dynamics Model, Otute Akiti

Dissertations

The optimization of reaction processes to maximize the yield of a desired product while minimizing the formation of undesired by-products is one of the most important steps in process development for drug manufacturing or fine chemical production. In many situations the kinetics of product formation can be quite complex and involve a number of intermediate steps as well as parallel and serial reactions. This renders the systems sensitive to the operating conditions. Often, upon scale-up, a decrease in the yield of the desired product is experienced, while more undesired by-products are produced. A large number of interrelated variables influence the …

Feasibility Study To Extract Iron And Chromium From Chromium Contaminated Soils, Wiwat Kamolpornwijit

Dissertations

Chromium contaminated soils, besides being recognized for toxic and hazardous hexavalent chromium, contain high iron concentrations. At some sites, concentrations of iron oxide are higher than 30%. Both iron and chromium in soils have recyclable value provided they can be either concentrated in the oxide form or separated as metal. The concentrated oxide can be used as a substitute for the iron ore. The extracted metal can also be recycled in the steel industry. The objective of this study is to study the feasibility of extracting iron and chromium from soils.

Chromium contaminated soils, can be classified into two groups, …

Axisymetric Vibrations Of Homogeneous And Sandwich Spherical Shells With A Hole At The Center, Wai-Kwong Wong

Dissertations

Based on Hamilton's principle and the theory of elasticity, both linear and nonlinear governing equations of motion are derived for elastic spherical shells. Most of the analysis is focused on the free axisymmetric vibrations of homogeneous and sandwich shallow spherical shells. The nonlinear behavior, which allows for small deflections, is also discussed.

The linear vibrations of homogeneous and sandwich shallow spherical shells with a hole at the center are investigated with emphasis placed on the effect of thickness-shear deformation and rotatory inertia. The effects of curvature and the size of the central hole are studied for free axisymmetric motions of …

Intermodal Transit System Coordination With Dynamic Vehicle Dispatching, Md. Shoaib Chowdhury

Dissertations

In most urban areas where transit demand is spread widely, passengers may be served by an intermodal transit system, consisting of a rail transit line (or a bus rapid transit route) and a numbers of feeder routes connecting at different transfer stations. In such a system, passengers may need one or more transfers to complete their journey. Therefore, scheduling vehicles operating in the system with special attention to reduce transfer time can contribute significantly service quality improvements. In this study two models, one for coordination of a general intermodal. transit system and another for dynamic dispatching of vehicles on coordinated …

Multimedia Modeling Of Organic Contaminants In The Passaic River Watershed, Lansana Coulibaly

Dissertations

A dynamic fate and transport multimedia environmental model was developed and applied to assess the release of five priority contaminants in the Passaic River Watershed, including: napthalene, toluene, trichloroethylene, 1-1-1 trichloroethane and xylene. The model uses the current releases of contaminants as well as cross-boundary advection to determine the fate and environmental distribution of these chemicals in the watershed. The model was developed using a dynamic fugacity approach in order to allow for scenario analysis such as source reductions and no-action alternatives. This modeling effort is expected to achieve a comprehensive assessment of contaminants not only in the proximity of …

The Impact And Fate Of Aqueous Sodium Nitrate On Hydrocarbon Flames, Ann Marie Flynn

Dissertations

This study examined the impact and fate of sodium (fed as an aqueous nitrate solution) in fuel-rich methane/air and methane/methyl chloride/air flames as a function of equivalence ratios that experienced diffusion of air from the surroundings. The flames were stabilized on a slotted, uncooled burner. The data set was divided into profiles of relative sodium atom concentrations, temperatures, and selected stable species concentrations. The flames were simulated using a modified version of the Sandia FORTRAN program for modeling steady laminar one-dimensional premixed flames complete with detailed mechanisms. The results showed that maximum sodium atom concentration in the flame is decreased …

Endotoxin Removal From Protein Solutions By Immobilized Metal Ion Affinity Chromatography, Yun Kang

Dissertations

In the biotechnology/pharmaceutical industry, the removal of endotoxins from final protein product has always been a challenge. A novel method for endotoxin removal from protein solutions, immobilized metal (ion) affinity chromatography (IMAC) has been developed in this study. Fe³⁺ was charged to a chelating gel that contains iminodiacetic acid (IDA). The IDA- Fe³⁺ IMAC column was exploited to remove endotoxin from protein solutions. This method involves the adsorption of the endotoxin on IMAC column. More than 99% endotoxin is removed and protein yield is higher than 90%. IDA-Fe³⁺ IMAC has proved to be an economical and efficient …

Video Traffic Modeling And Delivery, Hai Liu

Dissertations

Video is becoming a major component of the network traffic, and thus there has been a great interest to model video traffic. It is known that video traffic possesses short range dependence (SRD) and long range dependence (LRD) properties, which can drastically affect network performance. By decomposing a video sequence into three parts, according to its motion activity, Markov-modulated self-similar process model is first proposed to capture autocorrelation function (ACF) characteristics of MPEG video traffic. Furthermore, generalized Beta distribution is proposed to model the probability density functions (PDFs) of MPEG video traffic.

It is observed that the ACF of MPEG …

Fluidization And Soot Filtration In A Rotating Fluidized Bed, Gui-Hua Qian

Dissertations

A horizontal rotating fluidized bed (RFB) has been investigated for the removal of soot from diesel engine exhaust. This requires necessitating an understanding of the nature of fluidization, particle mixing and filtration in the RFB.

In an RFB, particles are subject to a centrifugal force which can be much larger than the force of gravity. Therefore the Geldart classification for conventional fluidized beds must be modified for rotating fluidized beds. A theoretical analysis shows that group A particles (minimum bubbling velocity U_mb > minimum fluidization velocity U_mf can shift to group B U_mb = U_mf and group …

Virtual Reality Based Creation Of Concept Model Designs For Cad Systems, Bilal Yehya Maiteh

Dissertations

This work introduces a novel method to overcome most of the drawbacks in traditional methods for creating design models. The main innovation is the use of virtual tools to simulate the natural physical environment in which freeform. Design models are created by experienced designers. Namely, the model is created in a virtual environment by carving a work piece with tools that simulate NC milling cutters.

Algorithms have been developed to support the approach, in which the design model is created in a Virtual Reality (VR) environment and selection and manipulation of tools can be performed in the virtual space. The …

Investigation Of The Baroreflex Of The Rat : Steady State And Dynamic Features, Xiaorui Tang

Dissertations

The baroreflex is one of the most important feedback systems in the body to maintain blood pressure variation within the homeostatic range. In this dissertation, the important features of the carotid and aortic baroreflexes have been extensively investigated on ventilated, central nervous system intact, neuromuscular blocked (NMB) rats using different control system and signal processing tools. Studies have demonstrated that sinoaortic denervation (SAD) caused substantial increases in the blood pressure variability. Comparing the pre- and post-SAD blood pressure spectra, there was a significant increase of power in the very low frequency region (0.00195 -0.2 Hz), and a significant decrease of …

Rapid Tooling By Integration Of Solid Freedom Fabrication And Electrodepostion, Bo Yang

Dissertations

Rapid tooling (RT) techniques based on solid freeform fabrication (SFF) are being studied worldwide to speed up the design-production cycle and thus keep manufacturers at a competitive edge. This dissertation presents a novel rapid tooling process that integrates SFF with electrodeposition to produce molds, dies, and electrical discharge machining (EDM) electrodes rapidly, accurately and cost effectively. Experimental investigation, thermornechanical modeling and analysis, as well as case studies reveal that integration of electroforming with solid freeform fabrication is a viable way for metal tool making.

The major research tasks and results of this dissertation study are as follows:

• Rapid electroforming tooling …

Laminar Viscous Resuspension In Two-Dimensional Channels, Wenyue Yin

Dissertations

The laminar viscous resuspension of sphere particles in two-dimensional channel with gravity and electrostatic effects is studied numerically. The constitutive equation for particles include the shear-induced diffusion flux, gravitational sedimentation flux and electro-static diffusion flux. In addition the continuity equation and the momentum equations for incompressible flow are solved for developing flow using finite element method.

The parameters in this study are ratio of particle diameter to channel height d/h, Reynolds number Re, Froude number Fr, uniform inlet particle volume fraction Φ₀, and electrostatic parameter Q. The numerical simulation included d/h from 0.03 to 0.12, Re from 5 …

An Integrated Membrane-Based Chromatographic Process For Biomolecule Isolation And Purification, Xiaoping Dai

Dissertations

Biomolecules obtained from fermentation and cell-culture processes are present in low concentrations in a complex medium/broth. For intracellular products, cells are first harvested. Subsequently, cell lysis and homogenization are undertaken to produce a homogenate. The biomolecules are next separated from the cell debris by lysate clarification. For extracellular products, the biomolecules are separated from the whole cells by clarification. The overall yield is reduced with each additional step. As the cost of bioseparation process accounts for 50-80% of the final product cost, innovations in and improvement of bio-downstream processing are greatly needed.

In this research, a cyclic process integrating a …

Simulation And Modeling Of Magnetically-Assisted Impaction Coating (Maic) Process For Dry Particle Coating, Bodhisattwa Chaudhuri

Dissertations

The objective of proposed research is to model, and understand the processes happening at multiple length and time scales in magnetically assisted impaction coating process. The smallest length scale is of the order of the molecular size and is important because during collisions the molecules rearrange themselves to form a semi-permanent bond between the core and secondary particles, which is studied by using the results of direct numerical integration of the governing Newton's equations. The effect of parameters such as size, orientation and relative velocity of particles on the collision mechanics is quantified. The largest length scale which is the …

Design And Analysis Of A Scalable Terabit Multicast Packet Switch : Architecture And Scheduling Algorithms, Feihong Chen

Dissertations

Internet growth and success not only open a primary route of information exchange for millions of people around the world, but also create unprecedented demand for core network capacity. Existing switches/routers, due to the bottleneck from either switch architecture or arbitration complexity, can reach a capacity on the order of gigabits per second, but few of them are scalable to large capacity of terabits per second.

In this dissertation, we propose three novel switch architectures with cooperated scheduling algorithms to design a terabit backbone switch/router which is able to deliver large capacity, multicasting, and high performance along with Quality of …

Synthesis And Characterization Of Low Pressure Chemically Vapor Deposited Boron Nitride And Titanium Nitride Films, Narahari Ramanuja

Dissertations

This study has investigated the interrelationships governing the growth kinetics, resulting compositions, and properties of boron nitride (B-C-N-H) and titanium nitride (Ti-N-Cl) films synthesized by low pressure chemical vapor deposition (LPCVD) using ammonia (NH₃)/triethylamine-borane and NH₃/titanium tetrachloride as reactants, respectively.Several analytical methods such as the FTIR, UVNisible spectroscopy, XPS, AES, RBS, SEM, and XRD were used to study the stoichiometry and structure of the deposited films.

The B-N-C-H films were synthesized over a temperature range of 300 to 8500C at various flow rate ratios of the reactants and total pressure range of 50 to 150 mTorr. …

Interaction Of A Vortex Pair And A Free-Surface : Numerical Simulation, Haisheng Ruan

Dissertations

The interaction between a submerged vortex pair with a deformable free-surface in a viscous, incompressible fluid is directly simulated and the flow is thoroughly analyzed. This is a time-dependent nonlinear free-surface problem which we solve numerically by integrating the two-dimensional Navier-Stokes equations and using boundary-fitted coordinates capable of handling large free-surface deformations. In particular, the numerical simulation of the flow at relatively high Reynolds numbers (Re = 500,1000, 2000 ) and relatively high Froude numbers (Fr = 1. 125, Fr = 2.0) is investigated and analyzed for the first time. Details are given regarding the space-time deformation of …

Optimum Design And Machining Parameters Of A Permanent Magnet Brushless Dc Linear Motor As A Cnc Feed Drive, William Tereshkovich

Dissertations

A new heuristic has been developed to determine optimal operating parameters applied to a permanent magnet brushless DC linear motor (PMBDCLM) as a CNC feed drive. An FEA model has been developed utilizing an -electromagnetic postprocessor to provide performance output of a PMBDCLM and DC servomotor. Based on the developed FEA models, velocity results have been utilized to provide feedrate levels for design of experiments (DOE). DOE has been conducted to provide force, tolerance, and surface finish data necessary for the performance comparison of a DC servo motor/ballscrew equipped CNC vertical milling machine and a PMBDCLM equipped CNC vertical milling …

Performance-Based Seismic Engineering Of Low And Medium-Rise Steel Frames, Saeid Rashidi

Dissertations

The performance level of low and medium-rise steel frames designed according to the common force/strength approach of the UBC or NEHRP is determined. Several combinations of soil profile type, lateral-force-resisting system, and frame-member proportioning are included in the designs.

To evaluate the expected damage, nonlinear models of the designed frames are subjected to a number of actual and simulated ground motion accelerograms and appropriate structural response parameters such as, interstory drift, ductility demand, and dissipated hysteretic energy are obtained. In addition, a modified form of Park-Ang damage index is calculated for moment-resisting frames. The seismic performance of the steel frames …

Development And Application Of Dynamic Models For Predicting Transit Arrival Times, Yuqing Ding

Dissertations

Stochastic variations in traffic conditions and ridership often have a negative impact in transit operations resulting in the deterioration of schedule/headway adherence and lengthening of passenger wait times. Providing accurate information on transit vehicle arrival times is critical to reduce the negative impacts on transit users. In this study, models for dynamically predicting transit arrival times in urban settings are developed, including a basic model, a Kalman filtering model, link-based and stop-based artificial neural networks (ANNs) and Neural/Dynamic (ND) models. The reliability of these models is assessed by enhancing the microscopic simulation program CORSIM which can calculate bus dwell and …

Reconfiguration And Tool Path Planning Of Hexapod Machine Tools, Zhenqun Li

Dissertations

Hexapod machine tools have the potential to achieve increased accuracy, speed, acceleration and rigidity over conventional machines, and are regarded by many researchers as the machine tools of the next generation. However, their small and complex workspace often limits the range of tasks they can perform, and their parallel structure raises many new issues preventing the direct use of conventional tool path planning methods. This dissertation presents an investigation of new reconfiguration and tool path planning methods for enhancing the ability of hexapods to adapt to workspace changes and assisting them in being integrated into the current manufacturing environments.

A …

The Influence Of High Performance Matrices On Fracture Behavior Of Concrete, Pusit Lertwattanaruk

Dissertations

Modification of cement matrices by the addition of micro particle pozzolanic materials such as silica fume and fly ash is known to improve the strength of concrete, but its contributions to fracture behavior remains unclear. In this study, the influence of replacing cement by silica fume and fly ash on the cement matrix-coarse aggregate interfacial bond, compressive stress-strain behavior and fracture behavior of concrete is investigated.

While the linear elastic fracture mechanics (LEFM) concept is not appropriate for concrete, a nonlinear fracture model based on the load vs. load-line deflection and the load vs. crack-mouthopening displacement (CMOD) responses of the …

Utilization Of Municipal Solid Waste Incinerator Fly Ash In Cement Mortars, Manaskorn Rachakornkij

Dissertations

Disposal of municipal solid waste has become a major problem in many countries around the world. With the benefits of substantial weight and volume reduction and potential energy recovery, incineration has become a promising municipal solid waste (MSW) management option. Despite the fact that incineration reduces volume and mass of the wastes by as much as 80%, there are still residues to be properly managed. This research is aimed at evaluating the potential of different types of MSWI fly ash from an incineration facility to be used in cement mortars by using existing standard test methods for cement and coal …

Space/Time/Frequency Methods In Adaptive Radar, Christopher D. Peckham

Dissertations

Radar systems may be processed with various space, time and frequency techniques. Advanced radar systems are required to detect targets in the presence of jamming and clutter. This work studies the application of two types of radar systems.

It is well known that targets moving along-track within a Synthetic Aperture Radar field of view are imaged as defocused objects. The SAR stripmap mode is tuned to stationary ground targets and the mismatch between the SAR processing parameters and the target motion parameters causes the energy to spill over to adjacent image pixels, thus hindering target feature extraction and reducing the …

Multi-User Detection For Multi-Rate Ds/Cdma Systems, Jinwen Ma

Dissertations

Wireless cellular communication is witnessing a rapid growth in market, technology and range of services. Current and future demands for wireless communication services motivate the need for handling multi-media traffic types. In a multimedia communication system, users with different and even time-varying rates and quality of services (QoS) requirements, such as voice, image and data, must be accommodated. The use of Spread Spectrum modulation with Code Division Multiple Access (CDMA) technology is an attractive approach for economical spectrally efficient and high quality cellular and personal communication services. This dissertation explores the technologies of applying different interference cancellation techniques to multi-rate …

In-Line Measurement Of Solibility Of Physical Blowing Agents In Thermoplastic Melts As Related To Extrusion Foaming, Qiang Zhang

Dissertations

A novel in-line method for measuring physical blowing agent solubility in thermoplastic melts in extrusion foaming equipment has been developed in this study. This method uses video microscopy in connection with a foaming extruder (single or twin-screw) to generate solubility data by observing the onset of gas bubble formation/dissolution. This method offers a number of advantages over the existing conventional methods. It can be easily used to obtain solubility data for many foamable thermoplastic-physical blowing agent systems at high pressure and temperature near actual foaming conditions. Data generated using this method could be directly used to characterize and control a …

Finite Fraction Method For Tracking Desinfection By-Product Precursors In Water Treatment, Doanh Van

Dissertations

Dissolved Organic Matter (DOM) has been the subject of recent regulatory activities and agenda. Among them are the Infonnation Collection Rule (ICR), the Disinfectants/Disinfection By-Product Rule (D/DBPR) and the Interim Enhanced Surface Water Treatment Rule (ESWTR). Both the latter two have provisions to limit the formation of disinfection by-products (DBP) by controlling reactivity and removal of DOM or both. Brief regulatory review of these rules was given.

Although the topic of DBP formation potential and DBP precursor removal have been studied by many researchers since Rooks (1974), the efficacy of methods that have been developed to date has been handicapped …

Integrated Product And Process Development Methodologies For Environmentally Conscious Electronic Products, Pingtao Yan

Dissertations

This research focuses on integrated product and process development (IPPD) methodologies for environmentally conscious electronic products. After a review of current research issues in the field of product and process development, a generic framework for IPPD is proposed which describes most of the concerned issues formally as constrained optimization problems. These problems may include such optimization objectives as cost, benefit, and environmental impact. Based on this framework, an IPPD methodology is proposed as a systems approach to competitive and environmentally conscious product and process development. A case study on personal computer development is performed illustrating how to apply the methodology …

Experimental Studies And Modeling Of Mechanical Properties And Morphologies Of In Situ Polymer Composites, Zhigang Li

Dissertations

In this study, a series of experiments was set up in order to analyze the morphology development and mechanical properties of poly(ethylene terephthalate) (PET)/ liquid crystalline polymer (LCP) blends. Simulations of the injection molded blends at various process conditions were performed using CMOLD. In order to determine the effect of the processing parameters on the deformation of the LCP domains during the injection molding, a new analytical method to analyze the melt flow in the advancing melt front (AMF) region was developed. By combining the simulations of the injection molding and analysis of the melt flow in the AMF region, …