Engineering Commons^™

Evaluation Of Iron And Manganese Control For A Volcanic Surface Water Supply Treated With Conventional Coagulation, Sedimentation And Filtration Processes, Christine Hall

Electronic Theses and Dissertations

A research project assessing the effectiveness of potassium permanganate (KMnO4) for the treatment of iron (Fe) and manganese (Mn) has been conducted by the University of Central Florida (UCF) on behalf of the United States Navy with regards to the water supply on the island of Guam, located in the Marianas Islands. The study consisted of three basic investigative components: one that examined the use of potassium permanganate for iron and manganese control for Fena Lake, a second that examined the existing unit operations that comprised the Navy's water treatment plant (NWTP), and a third that examined iron and manganese …

In-Plant And Distribution System Corrosion Control For Reverse Osmosis, Nanofiltration, And Anion Exchange Process Blends, Samantha Jeffery

Electronic Theses and Dissertations

The integration of advanced technologies into existing water treatment facilities (WTFs) can improve and enhance water quality; however, these same modifications or improvements may adversely affect finished water provided to the consumer by public water systems (PWSs) that embrace these advanced technologies. Process modification or improvements may unintentionally impact compliance with the provisions of the United States Environmental Protection Agency’s (USEPA’s) Safe Drinking Water Act (SDWA). This is especially true with respect to corrosion control, since minor changes in water quality can affect metal release. Changes in metal release can have a direct impact on a water purveyor’s compliance with …

Evaluation Of An On-Line Device To Monitor Scale Formation In A Brackish Water Reverse Osmosis Membrane Process, Jennifer C. Roque

Electronic Theses and Dissertations

A modified two-element membrane pressure vessel assembly has been used to monitor process operational changes in a full-scale reverse osmosis (RO) water treatment plant (WTP). This study evaluated the effectiveness of the assembly as an on-line monitoring device intended to detect scale formation conditions when connected to an operating RO process train. This study was implemented to support the requirements of a larger University of Central Florida (UCF) research project ongoing at the city of Sarasota’s Public Works and Utilities (City) water treatment facilities located in Sarasota, Florida. During the time-frame of this study, the City was in the process …

A Comparison Of Aluminum And Iron-Based Coagulants For Treatment Of Surface Water In Sarasota County, Florida, David Yonge

Electronic Theses and Dissertations

In this research, five different coagulants were evaluated to determine their effectiveness at removing turbidity, color and dissolved organic carbon (DOC) from a surface water in Sarasota County, Florida. Bench-scale jar tests that simulated conventional coagulation, flocculation, and sedimentation processes were used. Iron-based coagulants (ferric chloride and ferric sulfate) and aluminum-based coagulants (aluminum sulfate, polyaluminum chloride (PACl) and aluminum chlorohydrate (ACH)) were used to treat a highly organic surface water supply (DOC ranging between 10 and 30 mg/L), known as the Cow Pen Slough, located within central Sarasota County, Florida. Isopleths depicting DOC and color removal efficiencies as a function …

Rule-Based Decision Support System For Sensor Deployment In Drinking Water Networks, Natthaphon Prapinpongsanone

Electronic Theses and Dissertations

Drinking water distribution systems are inherently vulnerable to malicious contaminant events with environmental health concerns such as total trihalomethanes (TTHMs), lead, and chlorine residual. In response to the needs for long-term monitoring, one of the most significant challenges currently facing the water industry is to investigate the sensor placement strategies with modern concepts of and approaches to risk management. This study develops a Rule-based Decision Support System (RBDSS) to generate sensor deployment strategies with no computational burden as we oftentimes encountered via large-scale optimization analyses. Three rules were derived to address the efficacy and efficiency characteristics and they include: 1) …

Impact Of Corrosion Inhibitor Blended Orthophosphate On Water Quality In Water Distribution Systems, Abdulrahman Alshehri

Electronic Theses and Dissertations

The impact of blended orthophosphate (BOP) inhibitor addition on the corrosion of iron, copper, and lead in drinking water distribution systems was studied under changing water quality environment. Release of iron, copper, and lead were monitored at varying inhibitor doses and changing blends of source waters (groundwater, surface water, and desalinated water). Solid corrosion products on pipe surfaces under BOP treatment were evaluated with surface characterization techniques. Performance of the BOP inhibitor was compared to other corrosion control strategies. Iron scales for iron and galvanized steel coupons incubated in different blended waters in the presence of BOP inhibitor were analyzed …

Using Electrochemical Monitoring To Predict Metal Release In Drinking Water Distribution Systems, Rajendra D. Vaidya

Electronic Theses and Dissertations

Corrosion of distribution system piping and home plumbing materials is a major concern in the water community. Iron release adverse affects aesthetic water quality and the release of copper and lead is regulated by the Lead and Copper rule (LCR) and can adversely affect consumer health. Corrosion control is typically done by pH regulation and/or addition of corrosion inhibitors. Monitoring of corrosion control is typically done after the fact by monitoring metal release, functional group concentration of the selected chemical species or water quality. Hence, the associated laboratory analyses create a significant delay prior to the assessment of corrosion in …

The Effect Of Free Chlorine And Chloramines On Lead Release In A Distribution System, Ferdinand Vasquez

Electronic Theses and Dissertations

Total lead release in drinking water in the presence of free chlorine and chloramine residuals was investigated in field, laboratory and fundamental investigations for finished waters produced from ground (GW), surface (SW), saline (RO) and blended (B) sources. Field investigations found more total lead was released in the presence of chloramines than in the presence of free chlorine for RO and blended finished waters; however, there were no statistical differences in total lead release to finished GW and SW. Laboratory measurements of finished waters oxidation-reduction potential (ORP) were equivalent by source and were not affected by the addition of more …

Biostability In Drinking Water Distribution Systems Study At Pilot-Scale, Michael Le Puil

Electronic Theses and Dissertations

Biostability and related issues (e.g. nitrification) were investigated for 18 months in 18 pilot distribution systems, under various water quality scenarios. This study specifically investigated the impact of steady-state water changes on HPC levels in chlorinated and chloraminated distribution systems. Chlorination was more effective than chloramination in reducing HPC levels (1-2 log difference). There was a rapid increase in HPC corresponding to the change in steady-state water quality, which was observed in all PDS. Modeling effort demonstrated that HPC levels reached a maximum within five days after water quality change and return to initial level ten days after the change. …

Nitrification Investigation And Modeling In The Chloraminated Drinking Water Distribution System, Suibing Liu

Electronic Theses and Dissertations

This dissertation consists of five papers concerning nitrification in chloraminated drinking water distribution systems in a one and a half year field study. Seven finished waters were produced from different treatment processes and distributed to eighteen pilot distribution systems (PDSs) that were made pipes taken from actual distribution systems. Unlined cast iron (UCI), galvanized steel (G), lined cast iron (LCI), and PVC pipes were used to build the PDSs. All finished waters were stabilized and chloraminated before entering the PDSs. This dissertation consists of five major parts. (1) System variations of nitrates, nitrites, DO, pH, alkalinity, temperature, chloramine residuals and …

Water Quality Variations During Nitrification In Drinking Water Distribution Systems, David W. Webb

Electronic Theses and Dissertations

This thesis documents the relationship among the major water quality parameters during a nitrification episode. Nitrification unexpectedly occurred in a chloraminated pilot drinking water distribution system practicing with a 4.0 mg/L as Cl2 residual dosed at 4.5:1 Cl2:NH3-N. Surface, ground and sea water were treated and disinfected with monochloramines to produce finished water quality similar to regional utility water quality. PVC, galvanized, unlined cast iron and lined iron pipes were harvested from regional distribution systems and used to build eighteen pilot distribution systems (PDSs). The PDSs were operated at a 5-day hydraulic residence time (HRT) and ambient temperatures. As seasonal …

Influence Of Bromide Upon Trihalomethane Formation And Speciation, Thomas J. Christ

Retrospective Theses and Dissertations

This research investigated the influence of bromide-ion concentrations upon trihalomethane (THM) formation and speciation. There is some speculation that bromide will increase the amount of THMs on a mass and/or molar basis. Previous research had indicated that bromide will affect the speciation to form the more brominated forms of THMs, but the extent of this speciation has not been clearly defined. Speciation is important when evaluating THM removal processes. The brominated species may require activated carbon for removal as opposed to air stripping for removal of the volatile species (chloroform).

To investigate the role of bromide ion, a half-fractional, factorial …