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Missouri University of Science and Technology

Nuclear Engineering

Doctoral Dissertations

<p>Gamma rays -- Research<br />Irradiation<br />Nanoparticles<br />Nuclear medicine<br />Radiation chemistry</p>

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Synthesis Of Radioactive And Nonradioactive Nanostructures Through Radiolytic And Wet Chemistry, Jessika Viviana Rojas Marin Jan 2014

Synthesis Of Radioactive And Nonradioactive Nanostructures Through Radiolytic And Wet Chemistry, Jessika Viviana Rojas Marin

Doctoral Dissertations

"In this work the synthesis of non radioactive and radioactive nanoparticles (NPs) through radiolytic and wet chemistry was studied. Non radioactive NPs of rhenium, iridium, and rhodium were synthesized from aqueous solutions containing the metal salt precursors by gamma irradiation. The solutions were irradiated to generate reducing species that led to the nucleation and growth of the nanoparticles. Amorphous rhenium oxide nanoparticles with average sizes ranging from 10 nm to 55 nm were obtained. Metallic iridium and rhodium nanoparticles were produced in polyvinyl-pyrrolidone (PVP) having narrow particle size distributions and average particle sizes from 2 nm to 6 nm. The …