Engineering Commons^™

Synthesis And Characterization Of Multi-Component Enrichment Polymer Layers For Chemical Sensor Applications, James Giammarco

All Dissertations

This dissertation presents the building and study of a "universal" enrichment polymer layer system (EPLS). Thin polymer films have been utilized as enrichment layers for evanescent waveguide chemical sensors. The chemical nature of the polymer provides affinity which promotes the analyte to be absorbed. Having one highly sensitive polymer layer is suitable for a single target volatile organic compound (VOC). Here, the development of multi-layered and multi-component thin polymer films has been done to allow for more diverse affinity. Several parameters were identified to make the EPLSs suitable as enrichment layers for chemical sensor devices. The evanescent sensor devices used …

Pyrene Oligomers: Their Isolation, Molecular Characterization, And Phase Behavior, David Esguerra Taborda

All Dissertations

Carbonaceous pitches can serve as attractive precursors for advanced carbon materials such as high thermal conductivity fibers or carbon-carbon composites. Yet the effects of composition and molecular structure on the bulk properties (e.g., mesophase content and melting point) of these precursors remain only partly known, mainly because of the difficulties associated with the isolation, identification, and quantification of the large (i.e., molecular weight (mol wt) > 350-400 Da) polycyclic aromatic hydrocarbon (PAH) oligomers comprising these pitches. In this study, oligomeric fractions were isolated via supercritical extraction (SCE) from two representative pitches: a petroleum pitch (M-50) produced by the thermal polymerization of …

Synthesis And Characterization Of Polymer Layers For Control Of Fluid Transport, Fehime Vatansever

All Dissertations

The level of wetting of fiber surface with liquids is an important characteristic of fibrous materials. It is related to fiber surface energy and the structure of the material. Surface energy can be changed by surface modification via the grafting methodologies that have been reported for introducing new and stable functionality to fibrous substrates without changing bulk properties.

Present work is dedicated to synthesis and characterization of macromolecular layers grafted to fiber surface in order to achieve directional liquid transport for the modified fabric. Modification technique used here is based on formation of stable polymer layer on fabric surface using …

Identification Of Novel Genes Regulating Elastic Fiber Formation Through Expression Profiling Analysis Of Elastogenic Models, Erin Sproul

All Dissertations

Background: Particularly important to the mechanical performance of native arterial blood vessels is elastin, an extracellular matrix (ECM) protein deposited by VSMCs in the form of elastic fibers, arranged in concentric lamellae in the media of the vessel wall. In addition to serving as major structural elements of arterial walls, providing extensibility and elastic recoil, elastic fibers also influence vascular cell behaviors. For these reasons tissue engineers are attempting to exploit elastic fiber biology to enhance vascular graft design and patency. Therefore, developing a greater understanding of the molecular mechanisms of elastogenesis may offer opportunities to control elastogenesis in tissue …

In Vitro Simulation Of Pathological Bone Conditions To Predict Clinical Outcome Of Bone Tissue Engineered Materials, Duong Nguyen

All Dissertations

According to the Centers for Disease Control, the geriatric population of ≥65 years of age will increase to 51.5 million in 2020; 40% of white women and 13% of white men will be at risk for fragility fractures or fractures sustained under normal stress and loading conditions due to bone disease, leading to hospitalization and surgical treatment. Fracture management strategies can be divided into pharmaceutical therapy, surgical intervention, and tissue regeneration for fracture prevention, fracture stabilization, and fracture site regeneration, respectively. However, these strategies fail to accommodate the pathological nature of fragility fractures, leading to unwanted side effects, implant failures, …

Adaptive Transmission Protocols For Wireless Communication Systems With Fountain Coding, Jason Ellis

All Dissertations

We present low-complexity adaptive protocols for both unicast and multicast transmission in wireless communication systems that employ higher layer fountain codes. Our adaptive protocols respond to variations in channel conditions by adapting the modulation and channel coding of transmitted packets, and they provide efficient communication over wireless channels that experience fading, shadowing, and other time-varying propagation losses. The operation of our protocols is governed by simple receiver statistics that can be obtained during the demodulation of received packets. We present three adaptive protocols for fountain-coded unicast transmission, and compare the throughput performance of our protocols with that of fixed-rate systems, …

Predictive Maturity Of Inexact And Uncertain Strongly Coupled Numerical Models, Ismail Farajpour

All Dissertations

The Computer simulations are commonly used to predict the response of complex systems in many branches of engineering and science. These computer simulations involve the theoretical foundation, numerical modeling and supporting experimental data, all of which contain their associated errors. Furthermore, real-world problems are generally complex in nature, in which each phenomenon is described by the respective constituent models representing different physics and/or scales. The interactions between such constituents are typically complex in nature, such that the outputs of a particular constituent may be the inputs for one or more constituents. Thus, the natural question then arises concerning the validity …

Optimization Of Porous Pavement Mixtures Based On Aggregate Structure, Andrew Neptune

All Dissertations

Porous pavements are sustainable features that are used to help manage the quantity and quality of stormwater runoff. These pavements may include porous asphalt, permeable interlocking concrete pavers and pervious concrete. Since pavements that are purposefully designed to drain water through their matrix are relatively new, contractors and engineers are faced with various challenges such as improper design and installation, poor workability, and excessive finishing which may lead to clogged pores. Therefore, this study on porous pavements examined pervious concrete mixtures to evaluate an optimization process for the preparation of porous pavement mixtures based on aggregate structure to meet desired …

Vascular Nanomedicine: Site Specific Delivery Of Elastin Stabilizing Therapeutics To Damaged Arteries, Aditi Sinha

All Dissertations

Elastin, a structural protein in the extra-cellular matrix, plays a critical role in the normal functioning of blood vessels. Apart from performing its primary function of providing resilience to arteries, it also plays major role in regulating cell-cell and cell-matrix interactions, response to injury, and morphogenesis. Medial arterial calcification (MAC) and abdominal aortic aneurysm (AAA) are two diseases where the structural and functional integrity of elastin is severely compromised. Although the clinical presentation of MAC and AAA differ, they have one common underlying causative mechanism--pathological degradation of elastin. Hence prevention of elastin degradation in the early stages of MAC and …

Study On Electromagnetic Scattering Of Cylinders Buried In A Half Space With Random Rough Surfaces Of Finite/Infinite Length, Yueyang Dai

All Dissertations

Analysis of electromagnetic scattering of buried objects is a subject of great interest due to its practical importance in both military and civil applications, such as subsurface investigation and target detection. In reality, the earth is of layered structure of random rough interfaces, which leads to a greatly increased complexity of the analysis. However, it is necessary to incorporate the nature of random rough surface and the layered structure because they both have substantial impact on the scattered signature and hence affect the study of inverse scattering and detection of buried objects. In this dissertation, a Monte-Carlo multidomain pseudospectral time …

Biological Scaffolds For Peripheral Vascular Surgery, George Fercana

All Dissertations

The gold standards for small diameter peripheral vascular graft replacement are autologous arteries or veins; however, one-third of patients lack such vessels due to previous vessel harvesting or advanced vascular disease. A promising approach for patients in this category is tissue engineering with off-the-shelf biological vascular grafts. Three small diameter acellular scaffolds were developed and evaluated as vascular grafts. Porcine renal arteries (2-3 mm diameter, 20 mm length) were decellularized by immersion and stabilized with penta-galloyl glucose (PGG) with and without subsequent heparinization via carbodiimide chemistry. Bovine mammary (4-6 mm ID, 250 mm length) and femoral arteries (6-8 mm ID, …

Engineering Beta-Cell Spheroids For Type 1 Diabetes Treatment, Xiaoyan Liu

All Dissertations

Diabetes mellitus, the third most common disease in the world, is a chronic metabolic disorder caused by a failure of insulin production and/or an inability to respond to insulin. Specifically, type 1 diabetes is a disorder characterized by targeted autoimmune-directed destruction of a patient's beta-cell population within the pancreatic islets of Langerhans. The current primary treatment for type 1 diabetes is daily multiple insulin injections. However, this treatment cannot provide sustained physiological release, and the insulin amount is not finely tuned to glycemia. Pancreatic transplants or islet transplants would be the preferred treatment method but the lack of donor tissue …

Effect Of Graphitic Carbon Nanomodifiers On The Electromagnetic Shielding Effectiveness Of Linear Low Density Polyethylene Nanocomposites, Byron Villacorta Hernandez

All Dissertations

Conductive polymer composites have become alternative materials for providing electromagnetic and electrostatic shielding where metals are not suitable. In this study, the effect of crystallinity, morphology, concentration and orientation of carbon nanomodifiers on shielding provided by their polyethylene-based composites has been investigated relative to their transport properties.

First, the electrical properties and EM SE of composites consisting of heat-treated carbon nanofibers (Pyrograf^® -III PR-19 CNF) in a linear low density polyethylene (LLDPE) matrix were assessed. Heat treatment (HT) of CNF at 2500°C significantly improved their graphitic crystallinity and intrinsic transport properties, thereby increasing the EM SE of the nanocomposites. …

Large Scale 3d Mapping Of Indoor Environments Using A Handheld Rgbd Camera, Brian Peasley

All Dissertations

The goal of this research is to investigate the problem of reconstructing a 3D representation of an environment, of arbitrary size, using a handheld color and depth (RGBD) sensor. The focus of this dissertation is to examine four of the underlying subproblems to this system: camera tracking, loop closure, data storage, and integration. First, a system for 3D reconstruction of large indoor planar environments with data captured from an RGBD sensor mounted on a mobile robotic platform is presented. An algorithm for constructing nearly drift-free 3D occupancy grids of large indoor environments in an online manner is also presented. This …

Sulfonated Perfluorocyclobutyl (Pfcb) Aryl Ether Polymers: Synthesis, Reactivity, And Characterization For Polymer Electrolyte Applications, Jiyoung Park

All Dissertations

Perfluorocyclobutyl (PFCB) aryl ether copolymers are excellent candidates for proton exchange membrane (PEM) component in PEM fuel cells. Sulfonated PFCB copolymer membranes exhibit not only high chemical/thermal/mechanical stability but also high proton conductivity. In this regard, PFCB aryl ether copolymers were synthesized via thermal step-growth [2 + 2] cyclopolymerization from aryl bis-(trifluorovinyl ether) (TFVE) monomers and oligomers. Experimental and computational studies confirmed that copolymerization of relatively electron-rich and electron-poor TFVE monomers gave selective-segmented copolymers in an one-pot polymerization. After sulfonation, the PFCB copolymers comprising hydrophilic and hydrophobic segments gave membranes with high proton conductivity. Cross-linked membranes of the sulfonated PFCB …

Encapsulated And Monolithic Resonant Structures For Laser Applications, Aaron Pung

All Dissertations

Typically, the composition of a laser system includes a gain medium, a pump illumination source, and an external feedback cavity. This cavity consists of a highly reflective mirror and an outcoupler component. The geometry of the outcoupler can be engineered to tailor the reflected or transmitted beam's spatial and spectral distribution. Functionally, the transmitted beam profile is dependent on the laser application. Broadband reflection profiles can be obtained by utilizing a distributed Bragg reflector (DBR). A DBR device consists of multiple layers of alternating materials. Constructive interference of the reflected light off each interface between different materials produces the spectrally …

Predicting Surgical Flow Disruption Recovery In Cardiothoracic Operating Rooms, Gary Palmer Ii

All Dissertations

Disruptions are common occurrences in a variety of healthcare settings and early research has shown that they are likely contributors to medical errors. For this reason, healthcare researchers have focused on studying and understanding the nature of Surgical Flow Disruptions (SFDs) to increase patient safety and quality of care within the operating room (OR). Many researchers have used simplistic taxonomies to collect and categorize the types of SFD that occur within the OR. Others have gone further to study SFD recovery and have link unrecovered and recovered SFD to minor and major adverse events experienced by patients. This dissertation, focused …

Design And Synthesis Of Polymer - Magnetic Nanoparticle Composites For Use In Biomedical Applications, Roland Stone

All Dissertations

The future of diagnostics and therapeutic drugs in biomedicine is nanoparticles. These nanoparticles come in many different shapes, sizes, and combination of materials. Magnetic nanoparticles have been studied for many years for use in biomedicine, not only for their high surface area, but also because of its unique magnetic properties. They can magnetically interact with their environment, be guided to a specific location, and manipulated to release energy in the form of heat. To ensure that these magnetic nanoparticles survive in the circulatory system, they must be modified with materials to make them colloidally stable in water and shield them …

Hybrid Low-Order Modeling For Conceptual Vehicle Design, Robert Mau

All Dissertations

Design freedom, and particularly the freedom to incorporate innovative designs and strategies, is greatest at the very beginning of vehicle conceptual design. Conversely, this is when the least knowledge of the product exists. As product content decisions are made the level of freedom in the design decreases and the design becomes "locked in." The majority of vehicle lifecycle cost is also set by the end of vehicle conceptual design. This makes it critical to make well-informed and validated decisions in the concept design phase to avoid expensive iterations and redesign in the detailed design phase. Parametric vehicle modeling permits rapid …

Understanding The Role Of Requirements In Engineering Design By Novices, Shraddha Joshi

All Dissertations

Requirements play a critical role in the design process. The broader impact of this research is to develop a systematic understanding of the current use of requirements with an ultimate goal to develop guidelines and recommendations for more effective use of requirements throughout the design process. Thus, this research begins to answer the question about what is the role of requirements in design process and, specifically, its role in idea generation? The answer to this question is explored in three phases. The first phase is to understand how requirements are currently taught to students. To that end, two surveys were …

Seismic Site Coefficient Model And Improved Design Response Spectra Based On Conditions In South Carolina, Shimelies Aboye

All Dissertations

A new seismic site coefficient model is developed from the results of over 60,000 total stress, one-dimensional equivalent ground response simulations assuming conditions in South Carolina. Computed site coefficients ( F ) are plotted versus average shear wave velocity in the top 30 m (V_S30 ) and grouped by location, spectral acceleration (S_outcrop ) and spectral period. Locations considered in the Coastal Plain include Aiken, Charleston, Columbia, Florence, Lake Marion, Myrtle Beach, and the South Carolina side of Savannah. Locations considered in the Piedmont include Columbia, Greenville, Greenwood, and Rock Hill. In all the plots of …

Enhancing Energy Efficiency In Connected Vehicles Via Access To Traffic Signal Information, Grant Mahler

All Dissertations

This dissertation expounds on algorithms that can deterministically or proba-bilistically predict the future Signal Phase and Timing (SPAT) of a traffic signal by relying on real-time information from numerous vehicles and traffic infrastructure, historical data, and the computational power of a back-end computing cluster. When made available on an open server, predictive information about traffic signals’ states can be extremely valuable in enabling new fuel efficiency and safety functionalities in connected vehicles: Predictive Cruise Control (PCC) can use the predicted timing plan to calculate globally optimal velocity trajectories that reduce idling time at red signals and therefore improve fuel efficiency …

Uv-Assisted Stabilization Of Polyacrylonitrile-Based Carbon Fiber Precursors, Marlon Salvador Morales Sandoval

All Dissertations

Due to their high strength and stiffness coupled with low density, carbon fibers are the preferred reinforcing fibers used in high-performance polymer matrix composites. Consequently, the demand for carbon fibers is expected to grow from 40,000 metric tons to about 150,000 metric tons over the next decade. A large fraction of the increase is anticipated in the industrial sector that is cost-sensitive. Therefore, there is a need for the development of novel processes and precursors to reduce the carbon fiber production cost and expand the use of carbon fibers. This research focuses on the development of an alternative, rapid stabilization …

Effects Of Iteration On Concept Development, Shivraj Ranganathan

All Theses

Iteration in the conceptual design stage is defined as repetition of design tasks to incorporate new information. A more concise definition of iteration relevant to this research would be the progression of design through different abstraction levels or design stages, defining and refining design solutions while progressing from initial concepts to a more detailed design. Although it is believed that iteration has a positive effect on the quality of ideas in the design process, this experimental study presents an opportunity to determine the effects of iteration on quality of concepts and the factors that lead to increased quality of concepts. …

Cost And Embodied Energy Optimization Of Rectangular Reinforced Concrete Beams, Alexander Kosloski

All Theses

Concrete has a large environmental footprint so it is desirable to find ways to efficiently design structural members. Engineers can exercise their abilities early on in the design phase of construction projects to reduce the environmental footprint by minimizing the amount of materials required. One way to achieve these results is to optimize the design of structural concrete. In this study, simple-span rectangular reinforced concrete (RC) beams with a range of different bending moments were analyzed. The primary goal was to combine life cycle analysis (LCA), numerical optimization, and reinforced concrete mechanics to create a framework for designing efficient RC …

Knowledge Base Representation With Axiomatic Design Rules For Concept Level Up Implement In Ontological Framework, Zhuochen Shi

All Theses

Axiomatic Design has been applied and developed as a tool, offering a scientific basis for design and improving design activities. Axiomatic Design has been used in various fields such as software system design, structure design, and product design. However, several challenges and limitations exist in Axiomatic Design including: the inconsistency in identifying design parameters, existence of coupled design, and multiple groups of functional requirements and design parameters. Aimed at using Axiomatic Design to generate conceptual solutions in engineering design while overcoming its limitations, a formal ontology is developed. The ontology defines functional requirements, design parameters, concepts, components and variables and …

Twelve Mile Creek Channel Morphology, Substrate Composition, And The Macroinvertebrate Community Changes Resulting From Multiple Dam Removals, Patricia Whitener

All Theses

Dam removal is gaining global attention as a potential restoration tool for impacted rivers. As the practice of dam removal increases, physical, chemical and biological monitoring before and after dam removal is essential to our understanding of the ecological consequences of this type of disturbance. Under the Lake Hartwell Restoration and Compensation Determination Plan, two dams (>9 m height) were removed from the Twelve Mile Creek watershed (170 km2) in Pickens county, South Carolina. To assess the short term impacts of dam removal on the Twelve Mile Creek ecosystem we conducted biomonitoring of macroinvertebrate species and surveys of river …

Dissolved Carbon Dioxide For Scale Removal In Reverse Osmosis, Erin Partlan

All Theses

Membrane fouling is a major operational issue in reverse osmosis (RO) desalination plants. In particular, plants treating brackish groundwater can encounter troublesome inorganic scales, including carbonates, sulfates, and silicates. A novel cleaning method is proposed to remove inorganic scales from fouled RO membranes usinag dissolved CO ₂ . As CO₂ molecules encounter membrane foulants, the surfaces serve as nucleation sites for small bubbles to form and shear off foulants. Dissolved CO₂ solutions were prepared by bubbling CO₂ gas into water held in a pressure vessel. Gas dissolution was confirmed by enhanced exit velocities for water containing CO …

Design Of An Optical Position Sensor For Microfiber Actuators, Luxi Cheng

All Theses

This thesis introduces a new type of sensor that detects the position information of a paramagnetic microfiber and transforms it to computational electrical signal. The original purpose of the sensor is to solve the problem of feedback signal detection of the microfiber control system, which is the problem of detecting the position information for the microfiber. The microfiber will be presented as the experimental object of this sensor to test its capability. A novel optical based approach is used to transfer the position signal to a computer scrutable signal for further analysis.

The purpose of the sensor design comes from …

Adaptive Transmission For Ofdm, Michael Juang

All Theses

To respond to dynamic channel conditions caused by fading, shadowing, and other time-varying disturbances, orthogonal frequency division multiplexing (OFDM) packet radio systems should adapt transmission parameters on a packet-by-packet basis to maintain or improve performance over the channel. For this to be possible, there are three key ideas that must be addressed: first, how to determine the subchannel conditions; second, which transmission parameters should be adapted; and third, how to adapt those parameters intelligently. In this thesis, we propose a procedure for determining relative subchannel quality without using any traditional channel measurements. Instead, statistics derived solely from subcarrier error counts …