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Articles 1 - 30 of 154
Full-Text Articles in Engineering
Fate And Transport Of Per- And Polyfluoroalkyl Substances (Pfas) At Aqueous Film Forming Foam (Afff) Discharge Sites: A Review, Jeffery T. Mcgarr, Eric G. Mbonimpa, Drew C. Mcavoy, Mohamad R. Soltanian
Fate And Transport Of Per- And Polyfluoroalkyl Substances (Pfas) At Aqueous Film Forming Foam (Afff) Discharge Sites: A Review, Jeffery T. Mcgarr, Eric G. Mbonimpa, Drew C. Mcavoy, Mohamad R. Soltanian
Faculty Publications
Per- and polyfluorinated alkyl substances (PFAS) are an environmentally persistent group of chemicals that can pose an imminent threat to human health through groundwater and surface water contamination. In this review, we evaluate the subsurface behavior of a variety of PFAS chemicals with a focus on aqueous film forming foam (AFFF) discharge sites. AFFF is the primary PFAS contamination risk at sites such as airports and military bases due to use as a fire extinguisher. Understanding the fate and transport of PFAS in the subsurface environment is a multifaceted issue. This review focuses on the role of adsorbent, adsorbate, and …
Filter-Based Air Sampler Capable Of Integration Into Small Unmanned Aerial Vehicles, Robert M. Eninger, Stepanie A. Ohms, Jeremy M. Slagley
Filter-Based Air Sampler Capable Of Integration Into Small Unmanned Aerial Vehicles, Robert M. Eninger, Stepanie A. Ohms, Jeremy M. Slagley
AFIT Patents
A filter-based air sampler, more specifically a filter-based air sampler capable of integration into small unmanned aerial systems is disclosed. The filter-based air sampler may include a filter assembly which has as its component parts: an open faced air intake component, a filter, and a filter support that has a central supporting grid. The filter assembly may joined to the housing of a fan, such as a centrifugal fan, with the supporting grid of the filter support being disposed over the air inlet of the fan.
Efficiency Mapping And Determination Of Reliability, Resiliency And Vulnerability Of Atmospheric Water Generators In The United States, Erica F. Sadowski
Efficiency Mapping And Determination Of Reliability, Resiliency And Vulnerability Of Atmospheric Water Generators In The United States, Erica F. Sadowski
Theses and Dissertations
Atmospheric Water Generators (AWG) extract water from the air using one of three available technologies: refrigeration, sorption, and fog harvesting. A refrigeration device works like a dehumidifier and works best in conditions above 60% relative humidity. A sorption device utilizes a desiccant to extract the water vapor from the air and works in very low humidity levels. A fog harvesting device utilizes a mesh to capture the water vapor from the air and requires 100% relative humidity. In this research, I analyze two refrigeration-based devices and one sorption-based device and their efficacy in providing supplemental water supply. Due to climatological …
Carbon Estimation And Decision Making In Usaf Acquisition, Robert F. Gray
Carbon Estimation And Decision Making In Usaf Acquisition, Robert F. Gray
Theses and Dissertations
Recent executive orders and international agreements require the United States to significantly reduce its carbon and greenhouse gas emissions. The DoD is a significant contributor to the carbon emissions of the USA and will be required to reduce the emissions. Therefore, in order to make appropriate programmatic decisions the DoD needs to develop an appropriate method for estimating carbon and making programmatic decisions; trading-off carbon emissions with the traditional cost-schedule-performance metrics. This thesis examines the possibility of developing a model that can be used to estimate the carbon footprint of producing a system before detailed engineering designed have been complete.
Climate Change Risk To Coastal Airfield Stormwater Systems, Jedidiah R. Langlois
Climate Change Risk To Coastal Airfield Stormwater Systems, Jedidiah R. Langlois
Theses and Dissertations
Climate change is resulting in rising sea levels and increased rainfall, posing new challenges to stormwater management, particularly along coastlines. The airfield stormwater systems of Tyndall Air Force Base discharge directly into an interior bay of the Gulf of Mexico through tidal canals and ditches, creating a risk of system inundation from high tidewater conditions from sea-level rise (SLR). This study explores the performance and consequences of an inundated stormwater system from SLR during rainfall events using the EPA’s Stormwater Management Model (SWMM). One hundred and fifty-three combinations of SLR and return year storms were applied to a model of …
Hydrologic Profiles And Geospatial Trend Analysis Evaluating Recurrent Flooding At Coastal U.S. Air Force Installations, Dylan D. Bechen
Hydrologic Profiles And Geospatial Trend Analysis Evaluating Recurrent Flooding At Coastal U.S. Air Force Installations, Dylan D. Bechen
Theses and Dissertations
Military installations are exposed to numerous threats, including a changing climate and the risk of recurrent flooding. The four components of recurrent flooding are sea-level rise, tidal fluctuations, storm surges, and precipitation. This research analyzed 40 years of historical precipitation and tidal data at 17 coastal U.S. Air Force installations using indicators of both peak and threshold exceedances to identify long-term temporal trends in the hydrologic components that make up recurrent flood risk, establishing an installation’s “hydrologic profile” which can be used to better inform decision makers when evaluating portfolio-wide adaptation strategies and prioritization of long-term infrastructure investments.
Persistence And Mitigation Of Pfas Within Concrete Stormwater Drainage Infrastructure, Jason R. Mcdonald
Persistence And Mitigation Of Pfas Within Concrete Stormwater Drainage Infrastructure, Jason R. Mcdonald
Theses and Dissertations
The persistence, fate, and transport of per- and poly-fluoroalkyl substances, which have been shown to have adverse effects on human health, have been previously studied in environmental media such as soils and groundwater. This study investigates concrete, a medium that is rarely studied but frequently present in instances where PFAS originating from AFFF releases and spills have occurred. Used heavily throughout aviation firefighting, AFFF poses environmental hazards due to the length of PFAS degradation and toxicological implications, thus its classification as a forever chemical. From the very limited reports to date, studies have suggested very slow release from concrete, potentially …
Fluid Dynamics Modeling For Per- And Polyfluoroalkyl Substances Removal In Legacy Fire Suppression Systems, Jacob G. Spaulding
Fluid Dynamics Modeling For Per- And Polyfluoroalkyl Substances Removal In Legacy Fire Suppression Systems, Jacob G. Spaulding
Theses and Dissertations
Legacy per- and polyfluoroalkyl substances (PFASs) exist in the form of aqueous film-forming foams within hangar fire suppression systems throughout the country, posing a threat to both surrounding environments as well as local populations. The United States (US) Department of Defense (DoD), in conjunction with the US Environmental Protection Agency (EPA), is investigating best practices to flush out existing contaminants prior to disposal and replacement with a less environmentally harmful replacement. While current procedures dictate a triple rinse of the entire system to yield contaminant levels acceptable to the DoD, the practice has never truly been tested. Designed as a …
An Analysis Of Various Hydrogen Production Methods For Fleet Vehicle Fuel, Eugene J. Denezza Ii
An Analysis Of Various Hydrogen Production Methods For Fleet Vehicle Fuel, Eugene J. Denezza Ii
Theses and Dissertations
As conflict, the environment, and politics cause changes around the world, the United States Air Force is pursuing a diversification of drop-in and alternative fuel sources. Hydrogen fuel cells for vehicles are gaining popularity worldwide. Yet, how to best produce hydrogen gas still remains a question. This thesis will provide an overview of various hydrogen production methods and their respective environmental impacts, costs, efficiencies, and viability; and will perform sensitivity analysis to determine an optimal solution. The optimal production method is Thermolysis followed by Steam Reformation of Landfill or Natural Gas, Coal Gasification, and PEM Electrolysis. Based on varying requirements …
The Effect Of Molar Peroxide Ratio On The Oxidation Of Bisphenol A In An Ultraviolet Light Emitting Diode/Hydrogen Peroxide Advanced Oxidation Process, Megan C. Shade
Theses and Dissertations
Bisphenol A is a compound widely used in industry that is detrimental to human health and ecological systems. Ultraviolet light emitting diodes and hydrogen peroxide can be combined t produces hydroxyl radicals. These highly reactive radicals have the potential to degrade contaminants in water. This research utilized 50, 100, 250, 500, and 1000:1 H2O2:BPA molar ratios for analysis. These results illustrated that the reactions at the 50, 100, and 250:1 ratios were hydrogenperoxide limited. The 1000:1 results exhibited evidence of radical scavenging that limited the degradation of BPA.
The Effect Of Molar Peroxide Ratio On The Oxidation Of 2,4-Dinitroanisole In An Ultraviolet Light Emitting Diode Advanced Oxidation Process, Troy M. Searcy
The Effect Of Molar Peroxide Ratio On The Oxidation Of 2,4-Dinitroanisole In An Ultraviolet Light Emitting Diode Advanced Oxidation Process, Troy M. Searcy
Theses and Dissertations
Insensitive munitions (IMs) are increasingly employed by the U.S. military to prevent unintended detonations associated with conventional munitions. One IM used extensively is 2,4 dinitroanisole (DNAN). This research employed an ultraviolet light emitting diode (LED) and hydrogen peroxide advanced oxidation process (AOP) to treat DNAN-contaminated water at the laboratory scale. Five molar peroxide ratios (50:1, 100:1, 250:1, 500:1, 1000:1) were evaluated using the observed pseudo first-order rate constant as the performance metric. Both peroxide-limiting reactions and radical scavenging were observed over the range of ratios tested, with overall removal of DNAN decreasing above a ratio of 500:1.
Evaluation Of Efficient Water Reuse Technologies For Sustainable Forward Operating Bases, Kelsie L. Crouch
Evaluation Of Efficient Water Reuse Technologies For Sustainable Forward Operating Bases, Kelsie L. Crouch
Theses and Dissertations
A secure water source is essential to the resiliency and readiness of military installations and contingency operation locations, especially those located in the dry climates the US military operates in today. There are multiple issues of concern when identifying water sources, such as security, cleanliness, accessibility, and sustainability. Water resources pose a potential vulnerability to mission readiness in a remote, agile environment, such as a forward operating base (FOB). Having a secure water resource helps facilitate mission readiness in the contingency environment, offering the opportunity to be more resilient and cost-effective. Current water treatment technologies present the possibility to perform …
Re-Aerosolization Of Dense Metal Oxide Simulating Radiological Contamination From Military Clothing, Joseph M. Chapman
Re-Aerosolization Of Dense Metal Oxide Simulating Radiological Contamination From Military Clothing, Joseph M. Chapman
Theses and Dissertations
Radiological contamination from nuclear accidents or the terrorist use of a Radiological Dispersal Device (RDD) are events that first responders must be prepared for. It is currently assumed that removal of the victims clothing will remove 80-90 of contamination. Many RDD radioisotopes produce dense aerosols that would then contaminate victim clothing and re-aerosolize during clothing removal. A series of experiments were conducted during which clothing was contaminated with a dense aerosol simulating the radioisotope of Strontium 90. Compared to background, there was statistically significant re-aerosolization from the clothing. This demonstrates inhalation hazards from re-aerosolization of RDD contamination.
A Life Cycle Comparison Of Remote, Deployed Expeditionary Waste Management Scenarios, David J. Chester [*], Chandrani Mukherjee, Jeremy M. Slagley, Eric Mbonimpa, Thomas Hornstein
A Life Cycle Comparison Of Remote, Deployed Expeditionary Waste Management Scenarios, David J. Chester [*], Chandrani Mukherjee, Jeremy M. Slagley, Eric Mbonimpa, Thomas Hornstein
Faculty Publications
The current barrier to acquisition and utilization of viable waste-to-energy (WTE) technologies at remote or deployed expeditionary sites requires high capital and operation & maintenance costs. The impacts to environment and human health of differing expeditionary waste management strategies were compared using the Life Cycle Assessment software SimaPro 8.0. Emissions of individual waste management scenarios were compiled from peer-reviewed literature, converted to values compatible with SimaPro’s waste scenario inputs, and the calculated impacts compared using SimaPro’s pre-loaded methodologies. These calculated impacts and the economic impacts confirm that open-air burning of waste is not only dangerous to humans and the environment, …
The Effect Of Aeration Rate And Free-Floating Carrier Media On The Emission Of Bacillus Globigii In Bioaerosols, Andrew J. Owens
The Effect Of Aeration Rate And Free-Floating Carrier Media On The Emission Of Bacillus Globigii In Bioaerosols, Andrew J. Owens
Theses and Dissertations
Aerosols produced by turbulent mechanical mixing and bubble aeration at Waste Water Treatment Plants (WWTPs) become bioaerosols with the entrainment of biological materials. Bioaerosols become a public health risk when human pathogens are present. This study evaluated bioaerosols containing Bacillus globigii (BG) spores, and the effects that aeration rate and the addition of Free-Floating Carrier Media (FFCM) had on the amount of BG spores collected following aerosolization. A series of laboratory-scale experiments investigated two different sizes of floating polystyrene spheres as FFCM and four different aeration rates. When the differences in compared aeration rates were sufficiently large, a positive correlation …
Comparison Of The Pfas Adsorption Capabilities Of A Coconut Shell Based Granular Activated Carbon And A Bituminous Coal Based Granular Activated Carbon, Matthew D. Holliday
Comparison Of The Pfas Adsorption Capabilities Of A Coconut Shell Based Granular Activated Carbon And A Bituminous Coal Based Granular Activated Carbon, Matthew D. Holliday
Theses and Dissertations
This research compares the ability of two granular activated carbons (GAC) from different material sources to adsorb perfluoroalkyl substances (PFAS) in deionized water. A bottle study design was used to conduct the research, which measured the reduction in perfluorooctanoic acid (PFOA) and perfluorooctane sulfonic acid (PFOS). The carbons used were the bituminous coal based Calgon Filtrasorb 600 (F600) and the coconut shell based Evoqua AquaCarb 1230CX (AC1230CX). Additionally, the research focused on the rates at which the two contaminants were removed and compared them to previous research conducted with different forms of GAC. Results showed that both GACs were capable …
An Analysis Of Tinker Air Force Base Thermal Spray Hazardous Waste Stream From 2003-2019 And Its Potential Reclamation, Amy E. Silverbush
An Analysis Of Tinker Air Force Base Thermal Spray Hazardous Waste Stream From 2003-2019 And Its Potential Reclamation, Amy E. Silverbush
Theses and Dissertations
The disposal of hazardous waste threatens the environment and human health. However, certain hazardous wastes can be recycled or reclaimed to alleviate environmental and financial impacts associated with its disposal and resource demand reduction. A hazardous powder produced by the United States Air Force stems from aircraft maintenance and is composed of metals and ceramics, called thermal spray. This waste can be purchased by an industrial recycler if the waste is composed of valuable metals. Historic data from the depot-level maintenance base Tinker Air Force Base initiated an analysis of annual thermal spray hazardous waste disposal fees, which combined with …
Cost Performance Index Stability: Insights From Environmental Remediation Projects, Denis S. Clayson, Edward D. White, Alfred E. Thal Jr.
Cost Performance Index Stability: Insights From Environmental Remediation Projects, Denis S. Clayson, Edward D. White, Alfred E. Thal Jr.
Faculty Publications
The purpose of this study was to investigate the stability of the cost performance index (CPI) for environmental remediation projects as the topic is not addressed in the literature. CPI is defined as the earned value of work performed divided by the actual cost of the work, and CPI stability represents the point in time in a project after which the CPI varies by less than 20 percent (measured in different ways).
A Surprising Symbiosis: Examining The Mutualism In Department Of Defense Conservation Partnerships, Andrew J. Lankow
A Surprising Symbiosis: Examining The Mutualism In Department Of Defense Conservation Partnerships, Andrew J. Lankow
Theses and Dissertations
Because of the DoD’s unique and significant role in the conservation of natural resources, military leaders and natural resource managers need a trail guide to frame interagency collaboration in a way that shapes productive partnerships. The purpose of this research was to examine successful DoD conservation partnerships in order to identify key success factors (KSFs) and the most prominent challenges faced, and how those characteristics enable the accomplishment of each partner’s objectives. The research questions were answered through a comprehensive literature review and the use of the multiple-case study method. 19 key informants from three installations participated in semi-structured interviews, …
Cost And Performance Difference Of High Performance Sustainable Buildings, Philip A. Ramsey
Cost And Performance Difference Of High Performance Sustainable Buildings, Philip A. Ramsey
Theses and Dissertations
Varying legislation and executive orders coupled with needs for energy resiliency have led the United States Air Force to pursue sustainable construction. The limited understandings of initial costs to implement these changes have contributed to poor project cost estimating and changed implementation of legal requirements. A student t-test for populations with unequal variance was accomplished on the final normalized contract cost of 1628 Air Force Military Construction (MILCON) projects executed between 2002 and 2017. Future design considerations for net zero energy buildings were compiled from a net zero energy residential community in Fontana, California. There was no statistically significant difference …
The Effect Of Ms2 Bacteriophage On The Activity And Performance Of Activated Sludge, Sean M. Stuntz
The Effect Of Ms2 Bacteriophage On The Activity And Performance Of Activated Sludge, Sean M. Stuntz
Theses and Dissertations
As a medical waste product, the MS2 bacteriophage has been discharged into wastewater distribution and treatment networks. To categorize its impact to suspended growth treatment methods, this research investigated the effect of the MS2 bacteriophage on activated sludge through a series of respirometry tests. The effects of MS2 bacteriophage at a concentration of 3.2x108 PFU/mL were assessed by determining peak O2 consumption, cumulative O2 consumption, molar CO2/O2 ratios, and shape factors. None of the MS2 samples caused statistically significant effects on the peak or cumulative O2 consumption. The molar CO2/O2 …
Dynamics Of Chemical Degradation In Water Using Photocatalytic Reactions In An Ultraviolet Light Emitting Diode Reactor, John E. Stubbs
Dynamics Of Chemical Degradation In Water Using Photocatalytic Reactions In An Ultraviolet Light Emitting Diode Reactor, John E. Stubbs
Theses and Dissertations
This work examined ultraviolet (UV) light emitting diodes (LED) and hydrogen peroxide in an advanced oxidation process in support of a USAF installation net zero water initiative. A UV LED reactor was used for degradation of soluble organic chemicals. There were linear relationships between input drive current, optical output power, and first order degradation rate constants. When drive current was varied, first order degradation rates depended on chemical identities and the drive current. When molar peroxide ratios were varied, kinetic profiles revealed peroxide-limited or radical-scavenged phenomena. Molar absorptivity helped explain the complexity of chemical removal profiles. Degradation kinetics were used …
Characterization Of Jet Fuel Combustion Emissions During A C-130 Aeromedical Evacuation Engines Running Onload, Michelle L. Page
Characterization Of Jet Fuel Combustion Emissions During A C-130 Aeromedical Evacuation Engines Running Onload, Michelle L. Page
Theses and Dissertations
The purpose of this research was to characterize jet fuel combustion emissions (JFCE) in an occupational setting. Prior research demonstrated that aircraft emit hazardous species, especially at engine start-up and ground idle. Complaints of eye, nose, and throat irritation from occupational exposures near aircraft exist. In this study JFCE were tested during an aeromedical evacuation engines running patient onload (ERO) on a C-130 Hercules at the 179th Airlift Wing, Mansfield-Lahm Air National Guard. Ultrafine particles, VOC, formaldehyde, carbon monoxide (CO), sulfuric acid, and metals were sampled simultaneously in approximate crew and patient breathing zones. Testing methods were portable condensation …
Toxicological Differences Between Perfluoroalkyl Substances (Pfas) Isomers Using Developmental Biomarkers, Gabriel A. Cantu
Toxicological Differences Between Perfluoroalkyl Substances (Pfas) Isomers Using Developmental Biomarkers, Gabriel A. Cantu
Theses and Dissertations
Perfluoroalkyl substances (PFAS) are metabolically stable synthetic chemicals that have been manufactured for commercial and industrial purposes since the 1950s. PFAS possess surfactant properties that make them ideal to fight hydrocarbon fires and are therefore present in aqueous film forming foams (AFFF). Furthermore, AFFF may contain blends of both linear and branched PFAS isomers. Research suggests that branched PFAS isomers have greater relative placental transfer efficiencies than their linear counterpart, but few studies have evaluated their toxicity. Therefore, the sustained use of AFFF in the U.S. Air Force presents a risk of branched PFAS exposures in pregnant females. This study …
Adsorption Of Perfluorinated Compounds From Post-Emergency Response Wastewater, Christopher T. Schmidt
Adsorption Of Perfluorinated Compounds From Post-Emergency Response Wastewater, Christopher T. Schmidt
Theses and Dissertations
This research investigated the efficacy of granular activated carbon (GAC) as a method to treat water impacted with aqueous film forming foam (AFFF) after a firefighting response. Bench-top experiments were conducted and compared to field scale adsorber performance removing mg/L concentrations of PFAS in water contaminated with Military Specification AFFF. Batch tests compared four adsorbents, and determined Calgon F600 GAC and Rembind Plus mixed carbon media had the greatest perfluorooctane sulfonate (PFOS) capacities. Additional batch isotherm experiments using AFFF and higher PFOS concentrations (mg/L) indicated larger amounts of GAC are required (>30mg/L) for effective removal. Full-scale testing simulated an …
Nitrogen Rate And Landscape Impacts On Life Cycle Energy Use And Emissions From Switchgrass-Derived Ethanol, Eric G. Mbonimpa, Sandeep Kumar, Vance N. Owens, Rajesh Chintala, Heidi L. Sieverding, James J. Stone
Nitrogen Rate And Landscape Impacts On Life Cycle Energy Use And Emissions From Switchgrass-Derived Ethanol, Eric G. Mbonimpa, Sandeep Kumar, Vance N. Owens, Rajesh Chintala, Heidi L. Sieverding, James J. Stone
Faculty Publications
Switchgrass-derived ethanol has been proposed as an alternative to fossil fuels to improve sustainability of the US energy sector. In this study, life cycle analysis (LCA) was used to estimate the environmental benefits of this fuel. To better define the LCA environmental impacts associated with fertilization rates and farm-landscape topography, results from a controlled experiment were analyzed. Data from switchgrass plots planted in 2008, consistently managed with three nitrogen rates (0, 56, and 112 kg N ha−1), two landscape positions (shoulder and footslope), and harvested annually (starting in 2009, the year after planting) through 2014 were used as input into …
Characterizing Emissions From Open Burning Of Military Food Waste And Packaging From Forward Operating Bases, Thomas Dominguez
Characterizing Emissions From Open Burning Of Military Food Waste And Packaging From Forward Operating Bases, Thomas Dominguez
Theses and Dissertations
Emissions were characterized and compared from the open burning of four compositions of Meals, Ready-To-Eat (MRE) and four types of MRE fiberboard packaging in response to inhalation concerns at military forward operating bases. Measurements of particulate matter (PM2.5, PM10) showed that MREs account for 70-90 percent of PM emissions when burned in unison with the current fiberboard container and liner and that PM2.5 constitutes a vast majority of the particulates emitted. Targeted replacement of MRE constituents may be more effective in reducing volatile organic compound (VOC) and polycyclic aromatic hydrocarbon (PAH) emissions than the variation of fiberboard packaging designs, while …
Material And Design Considerations For A Portable Ultra-Violet (Uv) Light Emitting Diode (Led) Water Purification Device, Drew D. Gallucci
Material And Design Considerations For A Portable Ultra-Violet (Uv) Light Emitting Diode (Led) Water Purification Device, Drew D. Gallucci
Theses and Dissertations
Department of Defense personnel often deploy to austere environments where clean water is not readily available. Ultraviolet (UV) radiation through the use of light emitting diodes (LEDs) in a portable device offers a potential method for expedient water treatment. This research studied the application of one diode, low power, UV LEDs and nine diode, high power, UV LEDs within a portable steel reactor and Teflon reactors of three different wall thicknesses. Reactor efficiency was determined through measuring and comparing the rate constants for Advanced Oxidation of hydrogen peroxide with yellow tartrazine as a witness dye. Experiments conducted with low power …
A Simulation-Based Analysis Of Chemical And Radiological Hazard Zones Adapted To Physical Boundaries, Mickie J. Sundheim
A Simulation-Based Analysis Of Chemical And Radiological Hazard Zones Adapted To Physical Boundaries, Mickie J. Sundheim
Theses and Dissertations
In the United States, industrial and terrorist use of chemical, biological, radiological, and nuclear (CBRN) materials pose a risk to public safety. During the initial phase of typical CBRN incidents, emergency responders establish hazard zones based on standard distances from published guidelines and recommendations. This research investigates how standard hazard zones change in a real world environment that accounts for physical boundaries. Using a python simulation in ArcGIS®, new hazard zones were created by expanding standard hazard zones to follow nearby roads, railroads, and rivers. The new and standard zones were compared by calculating the population and area affected by …
The Effect Of Ph And Pulsed Ultraviolet Light Emitting Diode Duty Cycles On The First Order Rate Constant And Byproduct Profile Of The Advanced Oxidation Of Tartrazine, Brandon M. Stewart
The Effect Of Ph And Pulsed Ultraviolet Light Emitting Diode Duty Cycles On The First Order Rate Constant And Byproduct Profile Of The Advanced Oxidation Of Tartrazine, Brandon M. Stewart
Theses and Dissertations
Water treatment capability is required for military operations, production of drinking water, and industrial wastewater treatment. The Advanced Oxidation Process (AOP) is one of many viable steps for treating water; however, it is important to understand the byproducts of the treatment process to avoid creating other constituents more severe than the first. Tartrazine (TAR) was oxidized with pulsed Ultra- Violet (UV) Light Emitting Diodes (LEDs) in combination with hydrogen peroxide (H2O2) in an AOP at the laboratory scale. The relative concentration of TAR was reduced from 1 to between 1 – 0.75 over pH values between 6 and 9, and …