Engineering Commons^™

Tree Ring Reconstructions Of Streamflow For The Lower Rio Grande Valley Of Texas, Adedolapo Mutiyat Adeyanju

Theses and Dissertations

The Rio Grande River is a major water source for people living within the USA-Mexico border. The Rio Grande River has its headwaters in the San Juan Mountains in Colorado and the Sierra Madre Occidental in Mexico before flowing into Texas through El-Paso. The water supply issues facing the Lower Rio Grande Basin (LRGB) are extremely complex from international restrictions to severe climate change. The river shares its flow between the U.S.A and Mexico based on the provisions of the 1944 treaty between the U.S.A and Mexico. The LRGB flow is regulated by releases from Falcon and Amistad Reservoirs managed …

Impact Of Climate Oscillations/Indices On Hydrological Variables In The Mississippi River Valley Alluvial Aquifer., Meena Raju

Theses and Dissertations

The Mississippi River Valley Alluvial Aquifer (MRVAA) is one of the most productive agricultural regions in the United States. The main objectives of this research are to identify long term trends and change points in hydrological variables (streamflow and rainfall), to assess the relationship between hydrological variables, and to evaluate the influence of global climate indices on hydrological variables. Non-parametric tests, MMK and Pettitt’s tests were used to analyze trend and change points. PCC and Streamflow elasticity analysis were used to analyze the relationship between streamflow and rainfall and the sensitivity of streamflow to rainfall changes. PCC and MLR analysis …

Photocatalytic Degradation Of Organic Contaminants By Titania Particles Produced By Flame Spray Pyrolysis, Noah Babik

Theses and Dissertations

Advanced oxidation of organic pollutants with TiO2 photocatalysts is limited due to the wide bandgap of TiO2, 3.2 eV, which requires ultraviolet (UV) radiation. When nanosized TiO2 is modified by carbon doping, charge recombination is inhibited and the bandgap is narrowed, allowing for efficient photodegradation under visible light. Here, we propose a flame spray pyrolysis (FSP) technique to create TiO2. The facile process of FSP has been successful in preparing highly crystalline TiO2 nanoparticles. Using the same procedure to deposit TiO2 onto biochar, the photocatalyst was doped by the carbonaceous material. The morphology, crystalline and electronic structure of the FSP …

Hydrologic Modeling Study To Determine Hydrologic Impact Of Resacas On The Lower Laguna Madre Watershed, Antonio L. Reyna

Theses and Dissertations

During a high intensity storm events, a series of catastrophic events occur. These catastrophic events include flooding and destruction of infrastructure. Engineers have determined a method to design for high intensity storms based off hydrologic analysis of previous storms. With this data engineers can determine the outflow of major rivers and streams that may impact infrastructure. By determining the watershed engineers can predict the flow of the water and as well as the location of the outfall. In the Rio Grande Valley, water quality is very important because after rain events stormwater from cities is carried out towards the Laguna …

Efficiency Mapping And Determination Of Reliability, Resiliency And Vulnerability Of Atmospheric Water Generators In The United States, Erica F. Sadowski

Theses and Dissertations

Atmospheric Water Generators (AWG) extract water from the air using one of three available technologies: refrigeration, sorption, and fog harvesting. A refrigeration device works like a dehumidifier and works best in conditions above 60% relative humidity. A sorption device utilizes a desiccant to extract the water vapor from the air and works in very low humidity levels. A fog harvesting device utilizes a mesh to capture the water vapor from the air and requires 100% relative humidity. In this research, I analyze two refrigeration-based devices and one sorption-based device and their efficacy in providing supplemental water supply. Due to climatological …

Application Of Deep Learning For Imaging-Based Stream Gaging, Ryan Lee Vanden Boomen

Theses and Dissertations

In the field of water resources management, one vital instrument utilized is the stream gage. Stream gages monitor and record flow and water height within some water body. The United States Geological Survey maintains a network of stream gages at many locations across the country. Many of these sites are also equipped with webcams monitoring the state of the water body at the moment of measurement. Previous studies have outlined methods to approximate stream gage data remotely with limitations such as the requirement of detailed depth information for each site. This study seeks to create a process for training a …

Evaluation Of Efficient Water Reuse Technologies For Sustainable Forward Operating Bases, Kelsie L. Crouch

Theses and Dissertations

A secure water source is essential to the resiliency and readiness of military installations and contingency operation locations, especially those located in the dry climates the US military operates in today. There are multiple issues of concern when identifying water sources, such as security, cleanliness, accessibility, and sustainability. Water resources pose a potential vulnerability to mission readiness in a remote, agile environment, such as a forward operating base (FOB). Having a secure water resource helps facilitate mission readiness in the contingency environment, offering the opportunity to be more resilient and cost-effective. Current water treatment technologies present the possibility to perform …

Numerical And Experimental Investigation Of Aeration Self Mixing By Using Pulsating And Continuous Air Flow, Ahmed Ali Alkhafaji

Theses and Dissertations

Wastewater treatment is considered one of the most common forms of pollution control in the united states. Considered as an integral part of the wastewater treatment, the aeration process is the most energy-consuming process among all the processes that take place in any wastewater treatment plant. According to the United States Environmental Protection Agency (EPA), a wastewater treatment plant is expected to remove at least 85% of the suspended solids and dissolved organic compounds from the wastewater before discharging it to a river or a lake. The normal operation of the aeration process is by compressing air continuously to basin …

Novel Non-Invasive Technology For The Detection Of Thin Biofilm In Piping Systems (Phase - 1), Sachin Davis

Theses and Dissertations

Biofilms are formed when a group of cells of microorganisms stick to each other and often on a surface. The development of biofilm has been a major issue in many fields (medical field, food, chemical, and water industry are a few such fields). In the medical field alone, biofilm infections have reportedly cost over five billion USD in additional healthcare expenses. The food industry usually halts the operation of its plant eight hours, every day to ensure that their equipment and transportation channels are clean and free from any biofilm presence. Similarly, the water and chemical industry need to ensure …

Novel Non-Invasive Technology For The Detection Of Thin Biofilm In Piping Systems (Phase - 1), Sachin Davis

Theses and Dissertations

Biofilms are formed when a group of cells of microorganisms stick to each other and often on a surface. The development of biofilm has been a major issue in many fields (medical field, food, chemical, and water industry are a few such fields). In the medical field alone, biofilm infections have reportedly cost over five billion USD in additional healthcare expenses. The food industry usually halts the operation of its plant eight hours, every day to ensure that their equipment and transportation channels are clean and free from any biofilm presence. Similarly, the water and chemical industry need to ensure …

Experimental Evaluation Of Uranyl Transport Into Mesoporous Silica Gel Using Fluorescence, Brandon M. Dodd

Theses and Dissertations

This research investigated parameters that can affect the use of nanoporous silica gel as a media for accumulating a detectable amount of uranium. The unique fluorescence of the Uranyl (UO₂²⁺) ion was used to evaluate the transport kinetics and accumulation within silica gel in a static fluid and under pressure driven flow. The addition of fluid flow decreased the time constant from on the order of an hour to approximately 2s with a very low fluid velocity of 0.36cm/s. The 0.36cm/s fluid velocity was found to be the critical velocity above which there was no gain in …

Adsorption Of Perfluorinated Compounds From Post-Emergency Response Wastewater, Christopher T. Schmidt

Theses and Dissertations

This research investigated the efficacy of granular activated carbon (GAC) as a method to treat water impacted with aqueous film forming foam (AFFF) after a firefighting response. Bench-top experiments were conducted and compared to field scale adsorber performance removing mg/L concentrations of PFAS in water contaminated with Military Specification AFFF. Batch tests compared four adsorbents, and determined Calgon F600 GAC and Rembind Plus mixed carbon media had the greatest perfluorooctane sulfonate (PFOS) capacities. Additional batch isotherm experiments using AFFF and higher PFOS concentrations (mg/L) indicated larger amounts of GAC are required (>30mg/L) for effective removal. Full-scale testing simulated an …

Modelling Of Dreissenid Mussel Impacts On Lake Michigan, Chunqi Shen

Theses and Dissertations

Invasive dreissenid mussel appear to have profoundly altered Great Lakes food webs and nutrient cycles during the past several decades. Recent declines of phytoplankton were supposed to be highly related with the increase of mussel population. These phytoplankton declines were further found to be coincident with declines in the abundance of planktivorous fish. In addition, the resurgence of Cladophora in Great lakes was estimated to be associated with the high density colonization of mussels. More light is available at lake bottom due to the mussels’ graze effect. The mussels further promote Cladophora growth by fertilizing it with nutrient-rich excrement. And …

Influence Of Permeate From Domestic Reverse Osmosis Filters On Lead Corrosion And Leaching From Plastic Pipes, Jyotsna Shrestha

Theses and Dissertations

Reverse Osmosis filters are gaining popularity nowadays, in domestic water supply system, to meet the increasing demand of pure and improved drinking water. There are various types of domestic RO filters with varying sizes, capacities, and treatment stages available. However, there exist a few concerns regarding the RO treatment system. One of the major issues in the quality and distribution of drinking water is the corrosive water that the RO system produces. Therefore, this research herein tends to focus on the corrosive effect of the permeate water on lead metal, as lead is considered a serious problematic drinking water contaminant. …

Removal Of Perfluorooctanoic Acid From Water Using Primitive, Conventional And Novel Carbonaceous Sorbent Materials, Christopher K. Brown

Theses and Dissertations

Polyfluoroalkyl Substances (PFAS), like perfluorooctanoic acid, have been used for the last 50 years in a wide variety of industrial processes and consumer-based products, including polymer additives, lubricants, fire retardants and suppressants, pesticides, and surfactants (Buck et al. 2015). The Department of Defense (DoD) has used PFAS-based Aqueous Film Forming Foam (AFFF) at fire training facilities and aircraft hangars. AFFF has contaminated approximately 600 sites classified as fire training facilities with PFAS (Huang, 2013).

This study focused on testing the most likely carbonaceous adsorbent compounds to remediate PFAS-contaminated sites on Air Force installations. Batch tests were performed to determine the …

A Systems Approach To Point Source Indication Of Metformin Found In Local Water Systems – The Case Of Milwaukee County, Mohamed Salem Baitelmal

Theses and Dissertations

Pharmaceutical pollutants are present in traceable concentrations in Milwaukee County water system and Lake Michigan. The actual point sources and nature of entry into the water system is difficult to determine with certainty. Pharmaceuticals have been found to persist at the South Shore Wastewater Treatment Facility (SSWTF) in Milwaukee, Wisconsin. The highest concentration was found to be for the pharmaceutical drug metformin. Metformin is a first line drug for the treatment of type 2 diabetes mellitus.

The broad goal of this exploratory study; the first of its kind, is to correlate trace concentrations of drugs to the point sources. Particularly, …

Hydrodynamic Modeling Of The Green Bay Of Lake Michigan Using The Environmental Fluid Dynamics Code, Paula Estefania Cedillo

Theses and Dissertations

In this project we created a hydrodynamic model of the Lower Green Bay of Lake Michigan in Wisconsin, United States using the Visual Environmental Fluid Dynamics Code (EFDC). The model includes four tributary rivers to Lower Green Bay as well as the open boundary flow conditions at Chambers Island. This case study is used to: 1) compare the results obtained with a previous study of Lower Green Bay to validate the creation of the model 2) examine the hydrodynamics of the bay, and 3) create a framework for future studies at Lower Green Bay. The Geographic Information used to build …

A New Correlation For Predicting Aeration Efficiency For Air Diffused Systems, Hasan Baker Mohammad Al Ba'ba'a

Theses and Dissertations

Aeration efficiency is defined as the ratio of the oxygen transfer to the power consumed. It provides the best evaluation of the effectiveness of any aeration system. Most recent studies in oxygenation process focused on investigating the vital parameters affecting the oxygenation process without paying attention to the power consumption. The goal of this study is to establish an empirical correlation that describes aeration efficiency behavior with different orifice diameters.

This work has two main parts: studying bubble hydrodynamics and aeration efficiency investigation. The first goal of examining bubble hydrodynamics was to calculate some necessary parameters that have a known …

Sediment Microbial Fuel Cell As Sustainable Power Resource, Ananta Kothapalli

Theses and Dissertations

This research demonstrates that Ceratophyllum demersum a root less non vascular aquatic plant has negatively affected the power generation from a Sediment Microbial Fuel cell (SMFC). In SMFC the reduced organic matter in the sediment in water produces electrons, which reduces oxygen. Whereas in Plant SMFC continuous supply of organic matter to the anode is done by rhizodeposition (root exudates). Six SMFCs were run for more than 3 months to see the effect of plants, pH and temperature on power generation. Out of six only two SMFC showed stable data. The maximum power density 18 ± 1mW/m3 was generated from …

Optimization Of Nanoscale Zero-Valent Iron For The Remediation Of Groundwater Contaminants, Andrew W. E. Mcpherson

Theses and Dissertations

Nanoscale zero-valent iron (nZVI) is an emerging tool for the remediation of groundwater contaminants. The nanoparticles are capable of reductively destroying or immobilizing a wide range of contaminants. Their small size results in a high surface area to mass ratio, making them much more reactive compared to their more-coarse predecessors. Small particle size also allows nZVI particles to be injected directly into contaminated areas via a well, limiting the above-ground footprint and allowing access to contaminated areas that are beyond the reach of some conventional methods. nZVI technology has the potential to facilitate remediation in difficult situations, improve remediation outcomes, …

Development Of A Screening Model For Design And Costing Of An Innovative Tailored Granular Activated Carbon Technology To Treat Perchlorate-Contaminated Water, William C. Powell

Theses and Dissertations

Perchlorate contamination of drinking water is a problem that has recently gained national attention. The purpose of this research was to develop a tool to predict the cost and performance of tailored granular activated carbon (T-GAC), an innovative technology to treat perchlorate-contaminated water. The ability to predict cost and performance is essential to promote transfer and commercialization of innovative technologies. This study investigated how data obtained from small-scale laboratory tests could be applied to predict cost and performance of a full-scale T-GAC system to treat perchlorate-contaminated water. A technology model was developed using GAC design principles and using a multi-component …

The Effects Of Orthophosphate As A Copper Corrosion Control Inhibitor In High Alkalinity Drinking Water Systems, Stephen Grace

Theses and Dissertations

The purpose of this research was to investigate orthophosphate as a corrosion inhibitor for copper pipe in a high-alkalinity drinking water system. Specifically, this thesis sought to answer three research questions regarding the impact of orthophosphate treatment, the nature of the mechanism by which orthophosphate controls copper corrosion, and the value of equilibrium modeling in predicting orthophosphate’s effects. The research questions were answered through a comprehensive literature review and experimental methodology integrating laboratory jar tests, water sampling and analysis from a field investigation, qualitative solids analysis, and equilibrium model application. This study analyzed field data obtained over the course of …

Characterization Of Chlorinated Ethene Degradation In A Vertical Flow Constructed Wetland, James M. Waldron

Theses and Dissertations

Chlorinated solvents, including perchloroethene (PCE) and trichlorethene (TCE), are among the most common groundwater contaminants found in the United States. Once released into the environment, chlorinated solvents are extremely persistent and often require costly and lengthy remedial actions. The use of constructed wetlands has shown promise as an effective and less costly alternative for the treatment of chlorinated solvent contaminated groundwater. This study characterized and evaluated the concentration of chlorinated ethenes within a vertical flow constructed wetland, fed with PCE contaminated groundwater, at Wright-Patterson Air Force Base (WPAFB), Ohio. Chlorinated ethene concentrations were characterized within three distinct layers of the …

Using Value-Focused Thinking To Evaluate The Use Of Innovative Stormwater Management Technologies On Air Force Installations, Jeffrey T. Falcone

Theses and Dissertations

Stormwater runoff occurs naturally after every storm event; however, traditional development practices have created many impervious surfaces, such as buildings, parking lots, and streets that increase runoff volume and flow rate. Conventional stormwater management practices focus on collecting runoff into centralized channels and conveying it as quickly as possible to local bodies of water. This type of conveyance system decreases the opportunity for stormwater to naturally infiltrate back into the ground. It also prevents contaminants from being naturally filtered out of stormwater flows. As a result, centralized conveyance systems can cause flooding, erosion, and terrestrial and aquatic habitat degradation. Innovative …

Evaluation Of Microbial Diversity In Wetland Through Polymerase Chain Reaction (Pcr) And Restriction Fragment Length Polymorphism (Rflp), Gregory K. Joseph

Theses and Dissertations

The diversity of microbial communities in wetlands has not been fully measured. These communities may offer tools to naturally remediate sites polluted with chlorinated compounds. Polmerase Chain Reaction (PCR) and Restriction Fragment Length Polymorphism (RFLP) are genomic techniques that are capable of rapidly characterizing bacteria communities and can provide valuable information about the diversity of microbial communities.

Molecular Characterization Of Wetland Soil Bacterial Community In Constructed Mesocosms, Ethan C. Bishop

Theses and Dissertations

The use of wetlands to effectively remediate aquifers contaminated with chlorinated solvents is an emerging technique, which shows high promise. In order to better understand this process and test its legitimacy, a treatment wetland was constructed at Wright-Patterson AFB, Dayton, Ohio and, in a joint effort with Wright State University (WSU), has previously shown the effective removal of PCE. The purpose of this research was to characterize the soil bacterial community, pre-PCE injection, among three wetland plant species from the sedge family (Cyperaceae) within constructed wetland mesocosms and to identify any bacterial dominance. Carex comosa, Scirpus atrovirens, and Eleocharis erythropoda …

Investigation Of Copper Contamination And Corrosion Scale Mineralogy In Aging Drink Water Distributions Systems, Nadja F. Turek

Theses and Dissertations

Research has shown higher levels of copper appear in drinking water conveyed through relatively new copper piping systems; older piping systems typically deliver lower copper levels in their drinking water. This research contributes field data from a real drinking water distribution system, providing a better understanding of this phenomenon, as it relates to treatment considerations and compliance with the Lead and Copper Rule. Copper pipes and copper levels were sampled from drinking water taps of 16 buildings with pipes ranging in age from less than 1 to 48 years. Water samples from each building were collected before and following a …

Modeling Study To Quantify The Benefits Of Groundwater Contaminant Source Remediation, David E. Wagner

Theses and Dissertations

The purpose of this research was to quantify the benefits of groundwater contaminant source remediation by using a model to simulate how reduction of source mass was related to reduction of contaminant concentration at a receptor. This thesis sought to answer three research questions: (1) how are contaminant source mass reduction and reduction of mass flux leaving the source-zone related; (2) how can we quantify the effect of the important natural attenuation processes that act upon the dissolved contaminant as it travels from the source zone to downgradient receptors, and (3) under specified site conditions, what is the maximum contaminant …

Analysis Of Bacterial Population And Distribution In The Developing Strata Of A Constructed Wetland Used For Chlorinated Ethene Bioremediation, Milton J. Clausen Jr.

Theses and Dissertations

Chlorinated hydrocarbons and their degradation products are among of the most common organic groundwater contaminates in the United States. These compounds attack the central nervous system in animals and can affect the photosynthesis of plants. These compounds are also resistant to degradation in the environment and, because of this, pose a risk to any ecosystem in which they are present. This study identified the dominant microbial species in a constructed treatment wetland at Wright-Patterson AFB, Dayton, Ohio using 16S rRNA gene sequence analysis. Samples were taken from three different depths and during each of the four seasons. These samples were …

Modeling Application Of Hydrogen Release Compound To Effect In Situ Bioremediation Of Chlorinated Solvent-Contaminated Groundwater, Ryan C. Wood

Theses and Dissertations

This study investigates how application of Hydrogen Release Compound (HRC) might be implemented to remediate a site contaminated with tetrachloroethene (PCE) or its daughter products, under varying site conditions. The 3-D reactive transport model RT3D was coupled with a dual-Monod biodegradation submodel to simulate the effect of the hydrogen generated by HRC on accelerating the biodegradation of dissolved chlorinated solvents. Varying site conditions and injection well configurations were investigated to determine the effect of these environmental and design conditions on overall treatment efficiency. The model was applied to data obtained at a chlorinated solvent contaminated site at Vandenberg AFB, where …