Engineering Commons^™

Enhanced Bioretention Modeling At The Catchment-Scale: An Integrated Drainmod-Urban And Swmm Approach, Ghada Diab

Doctoral Dissertations

Bioretention systems are increasingly being adopted in stormwater management as an effective measure to promote infiltration and restore more natural hydrology in urbanized watersheds. Given the significant financial investment in these practices, reliable bioretention models are necessary to predict the effectiveness of these practices prior to installation. One such model, DRAINMOD-Urban (DM-Urban), was recently developed to produce hydrographs with a high temporal resolution at the site-scale, showing substantial promise during initial testing. However, the dataset used for initial testing was limited, consisting of one bioretention area with minimal occasions of overflow. Additionally, DM-Urban is an input-heavy model and there is …

Exploring Soil Microbial Dynamics In Southern Appalachian Forests: A Systems Biology Approach To Prescribed Fire Impacts, Saad Abd Ar Rafie

Doctoral Dissertations

Prescribed fires in Southern Appalachian forests are vital in ecosystem management and wildfire risk mitigation. However, understanding the intricate dynamics between these fires, soil microbial communities, and overall ecosystem health remains challenging. This dissertation addresses this knowledge gap by exploring selected aspects of this complex relationship across three interconnected chapters.

The first chapter investigates the immediate effects of prescribed fires on soil microbial communities. It reveals subtle shifts in porewater chemistry and significant increases in microbial species richness. These findings offer valuable insights into the interplay between soil properties and microbial responses during the early stages following a prescribed fire. …

Advanced Air Quality Management With Machine Learning, Cheng-Pin Kuo

Doctoral Dissertations

Air pollution has been a significant health risk factor at a regional and global scale. Although the present method can provide assessment indices like exposure risks or air pollutant concentrations for air quality management, the modeling estimations still remain non-negligible bias which could deviate from reality and limit the effectiveness of emission control strategies to reduce air pollution and derive health benefits. The current development in air quality management is still impeded by two major obstacles: (1) biased air quality concentrations from air quality models and (2) inaccurate exposure risk estimations

Inspired by more available and overwhelming data, machine learning …

Predicting Water Quality Vulnerability Under Climate Change With Machine Learning, Khanh Thi Nhu Nguyen

Doctoral Dissertations

Water quality deterioration is a global and pervasive issue due to pollution caused by industrialization, urbanization, agriculturalization, and human population growth in the modern era. This issue is even more challenging in the context of climate change due to warming temperatures and the intensification of precipitation. Therefore, assessing the potential impacts of climate change on water quality is a concern. Assessment is necessary so that planners can prepare for and reduce the negative impacts on water quality. At present, climate change impact assessment frameworks are relatively adolescent. Most studies rely on climate projections from General Circulation Models for simulations of …

Abiotic And Biotic Degradation Of Bisphenols, Yanchen Sun

Doctoral Dissertations

Bisphenol A (BPA), as well as its substitutes bisphenol S (BPS) and bisphenol AF (BPAF), are high production volume chemicals and potential endocrine disruptors. The oxidized manganese (Mn) species, soluble Mn(III) and solid Mn(IV) (i.e., MnO₂), are typically generated in Mn-cycling driven by Mn-oxidizing bacteria and Mn-reducing bacteria. MnO₂ is a strong oxidant capable of oxidizing a variety of organic contaminants including bisphenols. Soluble Mn(III) commonly occurs near oxic-anoxic interfaces and is an important environmental oxidant. Mn(III) is also associated with both biogenic and synthesized MnO₂. However, the effect of Mn(III) on the degradation of …

Wind Flow Characteristics Of Multi-Vortex Tornadoes And Their Wind Effects On Residential Houses, Yi Zhao

Doctoral Dissertations

"Tornadoes strike the USA very frequently, with an average of 1200 reports per year, and the average annual tornado-induced property loss has reached $10B. The devastation from recent tornadoes have prompted a renewed interest in better understanding tornado dynamics, their interactions with the built environment, and the performance of civil structures during tornadoes. In the past, the wind effects caused by single-vortex tornadoes have been widely studied, while the multi-vortex tornadoes were rarely considered. In fact, many previous deadly, costly tornadoes involved multiple vortices. Therefore, it is important to understand the wind flow characteristics of multi-vortex tornadoes in order to …

Enhancing Management Of Built And Natural Water And Sanitation Systems With Data Science, Nelson Da Luz

Doctoral Dissertations

In the age of the data revolution, the civil engineer can enhance the management of infrastructure systems using new techniques focused on data. This dissertation present three studies in which data science approaches are used to enhance management of water and sanitation systems in both the built and natural environments. Chapters 1 and 2 focus on improving methods for data collection relating to water quality monitoring. In Chapter 1, the efficacy of different water quality sampling program designs is evaluated as the programs relate to meeting monitoring goals. Considerations include how timing, location, and distribution system operations can affect monitoring …

Environmental Design And Optimization Of Modular Hydropower Plants, Colin Sasthav

Doctoral Dissertations

This research aimed to understand the pathways to cost-effective and sustainable low-head hydropower. Designing viable hydropower projects requires optimization across many economic, environmental, and social outcomes. However, existing run-of-river hydropower design models often focus on economic performance and customizing technologies for high-head diversion schemes. Standard modular hydropower is a new design approach that uses standardized rather than custom-designed technologies to achieve economies of scale. Oak Ridge National Laboratory established a conceptual outline for module classes based on functions, such as generation modules and fish passage modules, but further research was needed to identify how modules should be selected and operated …

The Role Of Extracellular Polymeric Substances In The Accumulation And Transport Of Polystyrene Nanoparticles In Biofilms, Joann Marie Rodríguez Suarez

Doctoral Dissertations

With the increasing number of nanotechnology applications, it is reasonable to expect nanoparticles to be ubiquitous in biofilms found in natural and engineered aquatic systems. We studied the impact of the degree of cross-linking on the deposition and diffusion of polystyrene nanoparticles (NPs) in alginate model biofilm matrices in the presence and absence of calcium cross-linkers using image correlation methods and single particle tracking. We found that cross-linking increases the viscoelasticity and hydration of the polymeric matrix and leads to structural changes that can restrict and alter the diffusive behavior of NPs, but the magnitude of the effects on diffusion …

Analysis And Fate Of 2,6-Dichloro-1,4-Benzoquinone In Real And Model Drinking Waters, Aarthi Mohan

Doctoral Dissertations

For many years chlorination has served as a barrier to protect human health from waterborne disease outbreaks. Chlorine is viewed as a near-universal oxidant and disinfectant, that provides a stable residual preventing microbial re-growth all the way through the consumer’s tap. Upon reaction with natural organic matter (NOM) however, it forms disinfection by-products (DBPs) many of which are potent human carcinogens and therefore have been of research interest since the 1970’s (Froese et al., 1999; Krasner et al., 2006, 1989; Richardson, 2003; Rook, 1976, 1974; Singer, 1994). The trihalomethanes (THMs) and haloacetic acids (HAAs) are the most prevalent (Krasner et …

Size Progression Of Oxygenic Photogranules (Opgs) And Its Effect On Opg Wastewater Treatment, Ahmed S.A. Abouhend

Doctoral Dissertations

In recent years, the oxygenic photogranule (OPG) process has gained increasing interest because of its potential to treat wastewater without supplemental aeration. Oxygenic photogranules (OPGs) are dense spherical aggregates comprised of phototrophic and nonphototrophic microorganisms. In OPG wastewater treatment reactors, photogranules grow in number as well as in size. The primary goal of this dissertation was to investigate how OPGs grow in size and how the growth affects their structure and functions. We found that OPGs undergo structural changes as they grow bigger in size. As OPGs grow larger, filamentous cyanobacteria become enriched while other phototrophic microbes diminish significantly. OPGs …

Ecological Restoration Of Lead/Zinc/Copper Mine Tailings: Phytomanagement And Amendment Strategies To Enhance Substrate Functionality And Biomass Production, Mariam K. Al-Lami

Doctoral Dissertations

“The extreme physiochemical characteristics of mine tailings inhibit microbial processes and natural plant growth. Consequently, vast and numerous tailings sites remain barren for decades and highly susceptible to wind and water erosion. Phytostabilization is a cost-effective and ecologically productive remediation approach; however, tailings revegetation is generally challenging and must often be assisted with appropriate soil amendments. Amendments applied individually in greenhouse studies discussed herein revealed notable improvement in bioenergy crops growth only with biosolids treatments. Recalcitrant carbon amendments (biochar and humus) showed notable impact only on tailings physichochemical and hydraulic properties. Nevertheless, biosolids may not support sustained vegetation due to …

Sustainable Underground Reactive Barrier To Attenuate Contaminants From Agricultural Drainage, Yuchuan Fan

Doctoral Dissertations

Denitrifying bioreactor (DNBR) has become a popular edge-of-field practice applied to reduce nitrate over the Mississippi river and to prevent a downstream hypoxic zone occurring at the Gulf of Mexico. Despite widespread field and laboratory studies, fewer investigations have been directed toward a systematic means of evaluating the nitrate removal performance achieved by various filling materials, abiotic factors, and other critical parameters. Our ultimate goal is to improve the nitrate removal by choosing the optimum fill materials and operate under optimal conditions, meanwhile, modeling the DNBR by critical variables. This study begins by establishing a global database. Forty filling materials …

A Connectivity Framework To Explore The Role Of Anthropogenic Activity And Climate On The Propagation Of Water And Sediment At The Catchment Scale, Christos Giannopoulos

Doctoral Dissertations

Anthropogenic disturbance in intensively managed landscapes (IMLs) has dramatically altered critical zone processes, resulting in fundamental changes in material fluxes. Mitigating the negative effects of anthropogenic disturbance and making informed decisions for optimal placement and assessment of best management practices (BMPs) requires fundamental understanding of how different practices affect the connectivity or lack thereof of governing transport processes and resulting material fluxes across different landscape compartments within the hillslope-channel continuum of IMLs. However, there are no models operating at the event timescale that can accurately predict material flux transport from the hillslope to the catchment scale capturing the spatial and …

Metabolomics, Genomics And Transcriptomics Unravel Fluoroalkane Metabolism In Pseudomonas Sp. Strain 273., Yongchao Xie

Doctoral Dissertations

Fluorinated organics have been developed and produced for various applications in the industrial, military, medical and agrochemical fields; they are now emerging as persistent organic pollutants with demonstrated adverse health impacts on mammals, including humans. The high bond dissociation energy of C-F bond hinders microbial degradation and defluorination. The present work demonstrates Pseudomonas sp. strain 273 can utilize the 1-fluoroalkanes (C₇ to C₁₀ and C₁₄) and 1,10-difluorodecane (DFD) as the sole carbon source in the presence of oxygen. In this study, fluorine mass balance analysis determined that the majority (> 90%) of the fluorine from the …

Impact And Application Of Real-Time Control On Stormwater Systems, Aaron A. Akin

Doctoral Dissertations

Stormwater control measures (SCMs) such as dry extended detention basins and wet ponds are common practices implemented by engineers and designers to mitigate the impact of stormwater runoff. These practices are designed based on historical rainfall data to attenuate runoff to pre-development conditions and, once they are installed, are unable to adapt to changing rainfall patterns or watershed restoration objectives. To solve these climate resiliency issues, several studies were conducted which investigated the impact of retrofitting such systems with a controllable outlet to increase or change detention times during rainfall events along with the novel instrumentation and methodologies necessary for …

Identifying And Assessing Bacterial Contamination In Stormwater Runoff And Receiving Streams, Songyi Liu

Doctoral Dissertations

Stormwater runoff has been recognized as a significant non-point source of pollution responsible for serious ecological impacts. Microbial pollutants represent one of the major contaminants of concern in stormwater runoff and the receiving streams. Traditionally, fecal indicator bacteria (FIB) have been used extensively to assess the microbial quality of water, particularly the extent of fecal contamination in water. However, the application of FIB as indicators of microbial contamination bears known disadvantages of cultivation-dependent techniques, such as the inability to identify the majority of microbial populations that are not amenable to cultivation under laboratory conditions. The effectiveness of a cultivation-independent sequencing …

The Performance Impacts Of Real-Time Control On Bioretention, Padmini P. Persaud

Doctoral Dissertations

Bioretention is a green infrastructure practice used to restore natural hydrologic regimes and improve stormwater quality. Extreme weather combined with demands for treatment of a growing number of priority pollutants has put a strain on these systems, making meeting performance goals difficult. The addition of smart stormwater technology has the potential to help address these issues as more control is provided to modify internal conditions and optimize sometimes conflicting outcomes. The use of real-time control is tested in this research to determine how bioretention performance is impacted by this technology. Column studies incorporating forecasts and historic rainfall were used to …

Valorization Of Secondary Agriculture Residues, Narendra Kumar

Doctoral Dissertations

Secondary agriculture residues have the potential to be major contributors as resources for energy and sustainably sourced materials production. Separating secondary agricultural residues, which have already been transported to processing centers, into individual biomass components could convert these wastes into bioproducts. Many types of pretreatments to achieve this separation involve chemicals that are hazardous for the environment. Several deep eutectic solvents (DES) that are biocompatible have been investigated for their ability to deconstruct rice hulls and sugarcane bagasse. Mass yield, enzymatic hydrolysis of the pretreated biomass, fiber analysis, and Fourier transform infrared spectroscopy have confirmed that the DES formic acid:choline …

Exposure Assessment Of Emerging Contaminants: Rapid Screening And Modeling Of Plant Uptake, Majid Bagheri

Doctoral Dissertations

"With the advent of new chemicals and their increasing uses in every aspect of our life, considerable number of emerging contaminants are introduced to environment yearly. Emerging contaminants in forms of pharmaceuticals, detergents, biosolids, and reclaimed wastewater can cross plant roots and translocate to various parts of the plants. Long-term human exposure to emerging contaminants through food consumption is assumed to be a pathway of interest. Thus, uptake and translocation of emerging contaminants in plants are important for the assessment of health risks associated with human exposure to emerging contaminants. To have a better understanding over fate of emerging contaminants …

Investigating The Role Of Iron In The Photogranulation Phenomenon, Abeera Ayaz Ansari

Doctoral Dissertations

Oxygenic photogranules (OPGs) are dense spherical microbial aggregates that are used for self-aerating wastewater treatment. Filamentous cyanobacteria are key granulating species, providing structural backbone and integrity in OPGs. Currently, the mechanisms for selecting filamentous cyanobacteria and their ability to form spherical OPGs are not well understood. Literature shows that iron (Fe) availability plays a significant role in the cyanobacterial growth and colony formation. Moreover, Fe availability is known to be dependent upon light, which is an essential growth substrate for the phototrophs. This research has investigated the role of Fe in the photogranulation phenomenon and the impact of light intensity …

Scaling Up The Oxygenic Photogranule (Opg) Wastewater Treatment Process, Joseph G. Gitau

Doctoral Dissertations

Photogranular biomass has yet to be utilized at large scale for wastewater treatment despite their potential to lower energy demand due to self-aerating capacity in addition to better process control compared to conventional technologies. An evaluation of critical driving factors affecting scaling up has yet to be undertaken. The current generation of oxygenic photogranules under hydrostatic conditions (a deviation from orthodox conditions creating other granules) limit seeding of larger reactors in time and scale. In addition, evaluating the photosynthetic productivity of granules which exist as closely commingled consortia with tightly coupled production and consumption processes, has yet to be undertaken. …

Physical And Biological Factors Affecting Oxygen Transfer In The Activated Sludge Wastewater Treatment Process, Kenneth A. Campbell

Doctoral Dissertations

“The activated sludge (AS) process is widely utilized for wastewater treatment due to its versatility and general resiliency, but is energy intensive, requiring aeration and mixing energy inputs to maintain the biochemical reaction and optimize treatment performance. This study is focused on determining different factors that influence oxygen transfer and consequently its energy demand.

AS morphology, as described by the d₁₀, d₂₀, d₃₂, specific filament length (SFL), 30 min settleability (SV₃₀), etc., does influence the OTE. Filamentous organisms increase the hydrodynamic radius of suspended particles, which dilates mixed liquor apparent viscosity (µ …

The Combined Toxic Effect Of Nanoparticles And Lead In The Presence Of Algae (Raphidocelis), Xuesong Liu

Doctoral Dissertations

"The elevated toxicity of toxic metals in the presence of nanoparticles (NPs) has raised significant concerns on the NP environmental safety. This research focuses on the impact of environmental conditions, specifically algae, on this type of toxicity. An indicator aquatic organism, Ceriodaphnia dubia (C. dubia), was used to examine the combined toxicity and toxicity mitigation from algae by monitoring its 24-h mortality. Four papers are included in this research, which focus on four aspects of the combined toxicity and the corresponding algae (Raphidocelis) impact. The first paper examines the algae impact on the combined toxicity of …

Investigation Of Urea Decomposition And Deposit Formation In Diesel Exhaust After-Treatment System, Anand Alembath

Doctoral Dissertations

“Urea-selective catalytic reduction (SCR) system has proved to be an effective solution to reduce NO_x emissions in commercial vehicle (CV) diesel engines. A significant challenge in urea injection is to comprehend its decomposition chemistry that leads to formation of undesired deposits in the exhaust system unit. Due to complex interaction of multi-phase fluid flow and transport processes, significant uncertainty is associated with the identification of interacting factors that control the deposit initiation and its growth. To meet the future ultra-low NO_x emissions and to deliver ammonia without deposit formation, there is an imminent need to develop the urea-SCR …

Designing Bifunctional Materials For In-Situ Capture And Conversion Of Volatile Organic Compounds, Anirudh Krishnamurthy

Doctoral Dissertations

”Volatile organic compounds (VOCs) are a class of organic liquid compounds with low vapor pressures, which enables them to vaporize at ambient conditions. VOCs are largely toxic, carcinogenic, and mutagenic, and have profound adverse effects on human health and the ecological environment. Many VOCs cause ruinous health effects even at very low concentrations (ppm) and therefore control of these organic compounds is essential for ensuring good air quality. A large portion of VOCs cause catastrophic health effects such as cancer or liver damage even at very low concentrations (ppm), and the control of these compounds is vital in ensuring good …

An Investigation Of Surface Water Sediment Source Tracking Using Bacterial Metagenomics And Elemental Fingerprinting, Yanchong Huangfu

Doctoral Dissertations

Excess suspended sediment in river systems commonly degrades surface water quality. A sediment source tracking approach is necessary to target management practices that will reduce significant sources of sediment in rainfall runoff and restore water quality. Sediment source tracking utilizes the biogeochemical characteristics of sediment, often paired with a mathematical model, to link eroding source materials and in-stream suspended sediment. However, there are still many questions left unanswered in using this approach, including simultaneously identifying fecal contamination sources, quantifying the reliability of sediment tracers, and methods to assess the accuracy of sediment source identification. The research herein utilized the microbial …

Evaluating Policy And Climate Impacts On Water Resources Systems Using Coupled Human-Natural Models, Hassaan Furqan Khan

Doctoral Dissertations

Extensive human intervention in the terrestrial hydrosphere means that virtually every river basin globally reflects the interaction between human and natural hydrologic processes. Thus, sustainable watershed management needs to not only account for the diverse ways humans benefit from the environment but also incorporate the impact of human actions on the natural system. Informed policy making to address our water challenges requires a comprehensive understanding of these feedbacks and how they might be affected by future changes in climate. This work develops coupled human-natural models for improved surface water and groundwater management in water-scarce regions under future changes in climate. …

Evaluation Of The Erodibility Of Soft Clays And The Influence Of Biopolymers, Pamela Judge

Doctoral Dissertations

Erosion of silts and clays is less well understood than erosion of sands. Further, current and anticipated climate change impacts along coastlines compel consideration of new approaches to coastal protection measures; seawalls and breakwaters designs now include natural and nature-based measures. The first research topic consists of the Adaptive Gradients Framework which was a theoretically-informed facilitation tool. The framework was intended to aid a collaborative and interdisciplinary decision-making process to encourage inclusion of natural and nature-based measures in coastal protection planning and design. This research is the culmination of a series of workshops and fieldtrips executed by the Sustainable Adaptive …

Origins And Seasonal Variation Of Disinfection Byproduct Precursors, Ran Zhao

Doctoral Dissertations

Disinfection byproducts (DBPs) are formed from the disinfectant (e.g., chlorine) reacting with components of natural organic matter (NOM) in water drawn from surface water supplies, and are considered as the cause of potential serious human health problems. DBP precursors originate in large reservoirs from at least three types of sources: (1) watershed or allochthonous, (2) algal or autochthonous, and (3) bottom sediments or benthic. The properties of the NOM and the DBP precursor content of that NOM are unique to each source. The first objective of this dissertation was to use temporal and spatial water quality data from a drinking …