Engineering Commons^™

Wastewater Treatment Using Encapsulated Chabazite In Polyvinyl Alcohol-Sodium Alginate Hydrogel Biofilm Carriers, Susieanna Nevada Persaud

USF Tampa Graduate Theses and Dissertations

Nitrogen discharge from wastewater is a global issue and with increased urbanization as well as industrialization, it has become even more essential to develop more efficient wastewater treatment systems. The dominant form of nitrogen in wastewater is ammonium. Biological oxidation of ammonium to nitrite and nitrate is the first step in biological nitrogen removal processes. If left untreated, nitrogen can cause toxicity to aquatic life, unsafe changes in water quality, and eutrophication.

Biofilm carriers can help to improve the efficiency of traditional activated sludge wastewater treatment systems by reducing operating costs and reducing hydraulic retention time. Biofilm carriers also promote …

Adsorption Of Long And Short Per- And Polyfluoroalkyl Substances (Pfas) Onto Granular Activated Carbon And Porous Organic Polymers, Yan Zhang

USF Tampa Graduate Theses and Dissertations

Per- and polyfluoroalkyl substances (PFAS) are man-made environmental contaminants causing increasing global concern due to their adverse effect on environmental and human health. Conventional treatment methods are ineffective in removing short-chain PFAS because of their hydrophilicity and resistance to degradation. This study is to design an appropriate adsorption system to remove both long- and short-chain PFSA at environmentally relevant concentrations and conditions. Four primary research tasks were designed to evaluate the performance of a structurally-tunable and chemically-stable porous organic polymers (POPs) for PFAS removal under realistic environmental conditions, including the assessment of POPs’ performance without co-contaminants (Chapter 2), the assessment …

Exploratory Data-Driven Models For Water Quality: A Case Study For Tampa Bay Water, Sandra Sekyere

USF Tampa Graduate Theses and Dissertations

Water, a crucial resource for sustaining life, covers approximately 70% of the earth's surface. Nonetheless, the quality of water is deteriorating rapidly due to the rapid growth of urban areas and industries, which is a worrying trend causing harm to human health and the ecosystem. Water quality forecasting has a key role in water resources management by enabling effective pollution control, ecosystem monitoring, and decision-making.

Previously, traditional statistical models were used to forecast water quality, but they were unable to examine the non-linear relationships between water quality parameters, and they assumed that all datasets were distributed normally. This study uses …

Anaerobic Digestion Of Brewery Waste Including Spent Yeast And Hops, Dhanashree Rawalgaonkar

USF Tampa Graduate Theses and Dissertations

Florida is home to more than 300 craft breweries, that brew over a million barrels of beer annually. Brewing is an energy intensive process and produces large quantities of high strength waste including spent grains, yeast, hops, and high strength wastewater. Brewery wastewater, and spent yeast have high Chemical Oxygen Demand (COD) concentrations between 5000 mg/L – 10,000 mg/L, and 200,000 mg/L – 300,000 mg/L respectively. Brewery effluent wastewater is sent to Publicly Owned Treatment Works (POTWs) which implement high surcharges based on the strength of brewery effluent (COD concentration). While some of the spent yeast and hops can be …

Resource Recovery From Crew Metabolic Wastes In Lunar And Martian Habitats: Reuse Of Effluent From An Anaerobic Membrane Bioreactor Treating Fecal Organic Matter As Fertilizer Source For Plants, Alexandra A. Smith

USF Tampa Graduate Theses and Dissertations

As humans set their sights on exploration of the Moon and Mars human focused challenges like providing potable water, supplying nutritious food to the astronaut crew, and managing their waste present themselves. There are no readily available resources on the Moon and Mars, therefore nothing should be considered unusable including the organic wastes (i.e., feces and urine) produced by the crew. Fecal matter is not currently recycled and is treated as solid waste. After collection, it is discarded out of the International Space Station where it is incinerated upon re-entry. This approach will not work on the Moon’s surface. There …

Characteristics And Hydraulic Behavior Of Adsorptive Media For Use In Permeable Reactive Barriers, Shelby Rocha

USF Tampa Graduate Theses and Dissertations

The Cargill ditch is located on the property of Se7en Wetlands, a 1600-ac treatment wetland system in Lakeland, Polk County, Florida. The Se7en Wetlands property was previously utilized for phosphate mining prior to the construction of the system. Nonpoint nutrient sources derived from remnants of abandoned phosphate mines – known as “legacy phosphorus” – become mobilized by stormwater runoff and impair surface water bodies by promoting harmful algal blooms (HABs). Thus, the Cargill ditch likely conveys nutrient rich flow resulting from legacy phosphorus and is thought to be one contributing factor in the occurrence of HABs within the treatment wetland …

Exploring Alternative Electron Donors For Heterotrophic Denitrification At A Water Reclamation Facility In Tampa Bay, Tejas Athavale

USF Tampa Graduate Theses and Dissertations

An excess of nitrogen in water can pose problems, ranging from algal blooms to creating toxic environments for marine life. Therefore, wastewater treatment plants need to remove nitrogen from wastewater during the treatment process. Biological nitrogen removal is one process these plants may use, which commonly involves nitrification and denitrification, converting nitrogen in the form of ammonia to nitrate, and then ultimately nitrogen gas. The process of denitrification often requires an electron donor, and methanol is a common choice. However, it is flammable, and therefore there is a need to explore alternative electron donors. Alternative donors can include manufactured chemicals …

Modeling Leachate Treatment Processes In Adsorbent-Amended Hybrid Constructed Wetland, Ishfaqun Nisa

USF Tampa Graduate Theses and Dissertations

Due to their efficiency in removing ammonia nitrogen, Constructed Wetlands (CW) are currently considered a very useful method for on-site leachate treatment. In recent years, the use of adsorbent media in CWs, such as zeolite and biochar, to improve pollutant removal efficiency has been explored and these studies indicate that incorporating zeolite can improve the nitrification process, while the addition of biochar can enhance the denitrification process and the removal of organic compounds. However, studies on mechanistic/process models simulating performance of adsorbent-amended CWs for treating landfill leachate are limited. This study presents simulation results for both unamended and adsorbent-amended hybrid …

Field-Base Exploratory Study Of Microbial Activity In Eight Potable Water Storage Tanks In Barbados, Katelyn M. Long

USF Tampa Graduate Theses and Dissertations

There have been many initiatives to combat the global phenomenon of water scarcity. Potable water storage tanks have become widely known among water insecure countries and communities to provide adequate water quantity and quality for consumer use. Despite ubiquitous use in many low- and middle-income communities (LMIC), knowledge of microbial activity inside potable water storage tanks is limited. Barbados is a Small Island Developing State (SIDS), labeled as a high income country, and also water scarce. The Barbados Water Authority (BWA) has adapted potable water storage tanks for hundreds of residents as a solution to water quantity and water quality …

Rehabilitation Technologies To Abate Infiltration In Sanitary Sewers, Steve Youssef

USF Tampa Graduate Theses and Dissertations

In urban coastal environments, sewer infrastructure is plagued by infiltration which seeps into aging and compromised pipes. Infiltration increases pumping costs, reduces treatment efficiency, and may trigger release of partially treated wastewater at water reclamation facilities. To restore pipes and abate infiltration, local utilities rely on structural and non-structural trenchless rehabilitation technologies. These methods are commonly used throughout the United States and the world due to their numerous benefits compared to traditional open-cut construction. However, limited data is available regarding their efficacy in reducing infiltration in sewer systems. In this study, we analysed infiltration in a small urban sewershed in …

Biochar Amended Biological Systems For Enhanced Landfill Leachate And Lignocellulosic Banana Waste Treatment, Xia Yang

USF Tampa Graduate Theses and Dissertations

Biochar is an inexpensive and environmentally friendly carbonaceous pyrolysis byproduct with a high surface area, pore volume, and adsorption capacities for inorganic and organic compounds. The goal of this dissertation is to evaluate the feasibility of biochar application in biological treatment systems for enhanced waste management. Three major objectives guided this research to provide a compressive understanding of biochar enhancement effects on biological treatment systems for contaminant removal, energy recovery, and environmental impacts as well as essential factors influencing biochar production and properties.

In Objective 1 a low-cost hybrid Constructed Wetland (CW) system modified with biochar/zeolite was developed for enhanced …

Corrosion Performance Of Carbon And Galvanized Steel In Calcium Silicate Cement, Maria Cardoso

USF Tampa Graduate Theses and Dissertations

The concrete manufacturing industry has faced challenges with reducing carbon dioxide emissions as it currently produces about 8% of the world’s anthropogenic carbon dioxide emissions. With global atmospheric carbon dioxide concentrations being higher than ever, the solution is urgent. Due to this, a more sustainable type of concrete has been proposed.Calcium silicate cement (CSC) composed of essentially the same raw materials as ordinary portland cement (OPC) cures through the consumption of carbon dioxide rather than hydration like OPC. CSC is being explored as a potential alternative to OPC, however, there is little to no information on its corrosion related durability. …

Assessment And Prevention Of Bacterial Regrowth In Stored Household Water In Eastern Coastal Madagascar, Lauren Judah

USF Tampa Graduate Theses and Dissertations

As of 2020, diarrheal diseases were the leading cause of death in Madagascar. A major cause of diarrheal illness is contaminated water, and one crucial aspect of preventing contaminated water is safe household storage. Bacterial regrowth between point-of-collection and household storage has been well established in literature. A frequently implicated source of regrowth is the storage container’s biofilm, which is a community of varying bacteria enclosed in a “slimy” extracellular polymeric substance that forms on surfaces in wet environments and anchors bacteria to those surfaces. The overall goal of this thesis was to quantify and control bacterial regrowth in household …

Modified Biosand Filtration Using Aluminum Hydroxide Filter Media To Enhance Fluoride Removal, Joshelyn Guimaray

USF Tampa Graduate Theses and Dissertations

There are over 20 countries whose citizens consume groundwater containing high levels of fluoride, including Nigeria, Mexico, India, China, and Ghana, which all have major health crises when it comes to the safety of their drinking water. Minerals like fluorite contain fluoride which is often found in groundwater aquifers. The minerals release fluoride into the groundwater. Per the World Health Organization (WHO) standard, the maximum contaminant limit for fluoride consumption should be less than 1.5 mg/L. Chronic exposure of elevated levels of fluoride can cause people to suffer debilitating health effects, such as dental and skeletal fluorosis. Dental fluorosis causes …

A Convergent Approach To Aqueous Lead (Pb) Mitigation Of A Supplemental Self-Supply Shallow Groundwater Source Accessed By Handpumps In Madagascar, Adaline Marie Buerck

USF Tampa Graduate Theses and Dissertations

The World Health Organization (WHO) has consistently listed lead (Pb) as one of the ten chemicals of major public health concern. Though the toxic nature of lead has been known since the 20th century it is still utilized in a wide variety of products due to its favorable properties. Exposure to lead still accounts for approximately 900,000 deaths annually and disproportionately impacts those in low- and middle-income countries (LMIC) due to a variety of reasons such as poverty, malnutrition, and lack of knowledge on the toxic nature of lead. Lead exposure routes include air, soil, dust, diet, and water. Though …

Evaluation Of Aluminum Dissolution, Current Density, And Pitting Patterns During Electrocoagulation, Monica Castro Carias

USF Tampa Graduate Theses and Dissertations

Electrocoagulation (EC) is a sustainable water treatment process involving the generation of coagulants on-site through the application of a voltage on metal (usually aluminum or iron alloys). The factors that impact EC system performance have been well researched, however further research is needed on the factors that impact anodic dissolution of aluminum electrodes, especially when the technology is transferred to full-scale applications. Electrode fouling is one of the factors that can impact dissolution of the anode during EC due to the formation of a protective oxide/hydroxide layer on the electrode surface. Previous studies have addressed electrode fouling by reversing polarity, …

Formation Of Trihalomethanes During Chlorination At South Cross Bayou Advanced Water Reclamation Facility, Pinellas County, Florida, Ian Grabo

USF Tampa Graduate Theses and Dissertations

South Cross Bayou Advanced Water Reclamation Facility (SCB) in Pinellas County, Florida, recently had a spike in effluent concentrations of bromodichloromethane (BDCM) and dibromochloromethane (DBCM) above the regulated limits, due to relying fully on chlorination instead of a combination of chlorination and ultraviolet light. The objective of this study was to determine the operating parameters most strongly affecting the formation of THMs. This was completed by analysis of long-term data sets obtained from SCB by multiple linear regression to create models describing THM formation. In addition, sampling of the chlorine contact chamber (CCC) was done to determine the effects of …

Carbon Diversion, Partial Nitritation/Anammox Enrichment, And Ammonium Capture As Initial Stages For Mainstream Ion Exchange-Deammonification Process, Sheyla Chero-Osorio

USF Tampa Graduate Theses and Dissertations

Eutrophication is a concerning environmental problem worldwide that results in algae blooms, oxygen depletion, damages to aquatic life and public health, water quality issues, and loss of aesthetics in water reservoirs. Nutrient (e.g., nitrogen and phosphorus) discharges from wastewater, agricultural, urban, and residential runoff promote eutrophication in receiving water bodies. In terms of nitrogen removal, conventional biological nitrogen removal (BNR) is a common technique used in many wastewater treatment plants (WWTP). However, BNR requires aeration for nitrification and organic carbon input for denitrification. In WWTP, the aeration represents a considerable investment in terms of energy costs. Recent technologies involve applying …

Efficient Management Of Nitrogen And Phosphorus At Centralized Water Reclamation Facilities, Helene Kassouf

USF Tampa Graduate Theses and Dissertations

A variety of process configurations are employed at municipal water reclamation facilities (WRFs), such as 5-stage Bardenpho, oxidation ditch, modified Ludzack-Ettinger (MLE) process, and sidestream recycle. However, all of these configurations face certain challenges in achieving optimum treatment of nitrogen and phosphorus. In this dissertation, the driving objectives were to: (1) quantitatively assess the fate of nitrogen and phosphorus (mass fluxes) at a treatment facility that employs biological nutrient removal, aerobic digestion, and sidestream recycle, (2) evaluate the performance of a microbial fuel cell (MFC) as a technology to remove nitrogen from sidestreams at a treatment plant that employs that …

Pressure Retarded Osmosis: A Potential Technology For Seawater Desalination Energy Recovery And Concentrate Management, Joshua Benjamin

USF Tampa Graduate Theses and Dissertations

Currently, a significant challenge with reverse osmosis-based desalination is reducing the energy consumption and environmental impacts of the process. This project analyzed the viability of using pressure-retarded osmosis (PRO) for energy recovery in seawater desalination facilities using brine concentrate (the draw solution) and other water sources (the feed solution) such as wastewater effluent. The primary goal of this project is to decrease the cost and overall energy consumption of seawater desalination through PRO-based energy recovery. Process modeling, statistical and sensitivity analysis, energy and cost analysis, geospatial and GIS analysis, laboratory-scale testing, water quality analysis, SEM-EDS microscopy, computational fluid dynamics (CFD), …

Shortcut Nitrogen Removal In Photo-Sequencing Batch Reactor, Experiments, Dynamic Model And Full-Scale Design, Sahand Iman Shayan

USF Tampa Graduate Theses and Dissertations

Nitrogen is one of the essential elements for life; however, inefficient use of nitrogen creates major environmental problems. Nitrogen-rich streams from urban areas, farms, and wastewater treatment plants (WWTPs) lead to surface and groundwater contamination, resulting in eutrophication, hypoxia, and notable environmental, public health and economic damage. Ammonia is a form of nitrogen that can be created during industrial or biological nitrogen fixation or decomposition of biomass. Anaerobic digesters (ADs) in WWTP generate biogas from collected sludge from primary and secondary clarifiers to achieve energy recovery in the plant. However, sidestream effluent from dewatering AD sludge contains high concentrations of …

Use Of Biochar And Zeolite For Landfill Leachate Treatment: Experimental Studies And Reuse Potential Assessment, Thanh Thieu Lam

USF Tampa Graduate Theses and Dissertations

Leachate is a highly colored liquid waste product of landfills that contains high concentrations of ammonia nitrogen (NH4+-N), refractory organic matter, and heavy metals. It is commonly disposed to local publicly owned treatment works (POTWs). With these potent characteristics, it interferes with the physical, biological, and chemical treatment processes within POTWs. Sequencing batch biofilm reactors (SBBR) and hybrid subsurface flow constructed wetlands (CW) have been used in the past to treat landfill leachate, but their design and performance can still be optimized. Addition of low-cost adsorbent materials to SBBRs and CWs, such as biochar and zeolite, have the potential to …

Sanitation Marketing In Uganda: The Impact Of Gender On Participation And Outcomes, Elizabeth Vicario

USF Tampa Graduate Theses and Dissertations

Uganda aims to reach universal access to basic sanitation under Sustainable Development Goal #6, but achieving this target by 2030 would require doubling the annual rate of progress. Women are disproportionately affected by poor sanitation due to their health needs and risk of facing violence, but they have historically been excluded from sanitation planning. Low household demand and poor service delivery have stalled progress in Uganda. Market-based sanitation (MBS) is a novel method of developing a sanitation market through stimulating demand and supporting a competitive atmosphere for product and service providers. This research studies the sanitation marketing activities implemented by …

Community Assessment Of Water Perceptions And Household Point-Of-Use Treatment Methods In Madagascar, Isabella Rose Silverman

USF Tampa Graduate Theses and Dissertations

One in four people around the world do not have access to safe drinking water, which means that two billion people globally lack access. In high-income countries, 0.02% of yearly deaths are attributed to unsafe water sources; however, an alarming 10.6% of deaths occur in Madagascar, for the same reason.

To achieve Sustainable Development Goal 6: Ensure access to water and sanitation for all, a collaboration between public health and engineering is critical. Within the public health sector, social marketing is commonly utilized to address a problem by using commercial marketing principles to change behavior for the good of society. …

Laboratory Examination Of Lead Weights Harvested From Pitcher Pumps In Eastern Madagascar, Madelyn Wilson

USF Tampa Graduate Theses and Dissertations

Previous sampling campaigns in Tamatave, Madagascar, conducted by the University of South Florida (USF) have identified lead contamination in drinking water sourced from self-supply pitcher pumps. The pitcher pump piston and foot valves were identified as the primary source of lead contamination since they are often manufactured from recycled lead acid batteries. The previous field sampling technique consisted of collecting an aliquot of a 10-15-liter composite sample from the pitcher pump for dissolved lead analysis; however, this technique (1) neglects the contribution of particulate lead, (2) does not properly account for the effects of water stagnation inside the pitcher pump …

Effects Of Nitrate On Arsenic Mobilization During Aquifer Storage And Recovery, Hania Hawasli

USF Tampa Graduate Theses and Dissertations

Aquifer storage and recovery technology is used to sustain water resources and to prevent saltwater intrusion. The injected water can come from various resources, including treated wastewater. In pilot ASR studies in the Tampa Bay region, researchers found high As concentrations in the recovered water from the oxidation of the arsenopyrite that is embedded in the aquifers. The presence of dissolved O2 in the injected water is a major factor in the arsenopyrite oxidation during ASR, however the effects of NO3- on the arsenopyrite has not been studied yet. This is an important knowledge gap because injected water may contain …

Computational Fluid Dynamics (Cfd) Analysis Of The Hydraulic Performance And Bio-Kinetics In A Full-Scale Oxidation Ditch, Kiesha C. Pierre

USF Tampa Graduate Theses and Dissertations

An oxidation ditch is a biological wastewater treatment unit process where microorganisms are utilized to transform organic matter, and nitrogen from wastewater to meet the desirable effluent concentrations. Mechanical aerators are part of these biological reactors facilitating oxygen transfer for the aerobic microorganisms, while agitating and circulating the phase constituents within the ditch. Modeling the performance of an oxidation ditch involves combining hydrodynamics, oxygen mass transfer, and bio-kinetics and is one of the grand challenges that is of paramount importance in optimization of design and operations of these facilities in an energy efficient way while meeting the targeted effluent concentrations. …

Biochar Amended Bioretention Systems For Nutrient And Fecal Indicator Bacteria Removal From Urban And Agricultural Runoffs, Md Yeasir Arif Rahman

USF Tampa Graduate Theses and Dissertations

Excessive nitrogen and fecal indicator bacteria (FIB) in stormwater runoff from urban areas or dairy farm operations impair water bodies resulting algal blooms, gastrointestinal illness, and economic losses. Recent advancements in stormwater management, including low impact development (LID) techniques, have provided engineers with a variety of tools to use in place of traditional catch basins and retention ponds. One promising LID technology for runoff management is bioretention, which consists of a shallow depression containing engineered porous media and vegetation. Prior studies have shown that modified bioretention systems that include an internal water storage zone (IWSZ) to promote denitrification can improve …

Sustainability Assessment Of A Pressure Retarded Osmosis System, Samar Al Mashrafi

USF Tampa Graduate Theses and Dissertations

Desalination has the potential to provide a stable supply of clean fresh water and meet the increasing water demands; however, this process does come with a few challenges such as high energy consumption, high energy cost, and a discharge of a highly concentrated brine. Pressure retarded osmosis (PRO) is a technology that could work as an efficient energy recovery technology for desalination since it can significantly reduce the energy consumption and dilute the brine before discharge. Studies have assessed the economic feasibility of PRO systems; however, these studies have not addressed the environmental sustainability of the systems. Thus, there is …

Development Of A Numerical Process Model For Adsorbent-Amended Constructed Wetlands, Lillian Mulligan

USF Tampa Graduate Theses and Dissertations

There is a need for alternative methods for municipal landfill leachate treatment as the high concentrations of pollutants in leachate interfere with processes at publicly owned treatment works (POTWs). Constructed wetlands (CWs) have been shown to be a sustainable alternative with good removal efficiencies for chemical oxygen demand (COD) and ammonia nitrogen (NH4+). The addition of an adsorbent media, such as zeolite and biochar, to CWs to further enhance removal efficiencies has been investigated in recent years. However, the long-term effects of zeolite and biochar addition to CWs is not well known. A model could be a useful tool to …