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Chemical Engineering

2015

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Full-Text Articles in Engineering

Synthesis Of Porous Carbon Nanosheets And Its Application In Sodium-Ion Battery, Jing-Fei Zhang, Jing Lu, Xiao-Yu Yang, Yun-Di Huang, Lin Xu, Dong-Mei Sun, Ya-Wen Tang Dec 2015

Synthesis Of Porous Carbon Nanosheets And Its Application In Sodium-Ion Battery, Jing-Fei Zhang, Jing Lu, Xiao-Yu Yang, Yun-Di Huang, Lin Xu, Dong-Mei Sun, Ya-Wen Tang

Journal of Electrochemistry

Owning to sodium’s high abundance, relatively low cost, similar chemical properties to Li and very suitable redox potential of E0(Na+/Na) = -2.71 V versus SHE which is only 0.3 V above that of lithium, rechargeable sodium ion battery hold much promise as potential alternatives to current lithium ion batteries for energy storage applications. Carbon material is regarded as the most promising anode candidate for sodium ion battery. Particularly, carbon nanosheet with porous structure and high conductivity is expected to have improved sodium ion storage properties. In this paper, we present a two-step pyrolysis-based method for facile synthesis of porous carbon …


Methods For Coating Quartz Crystals, William Patrick Dec 2015

Methods For Coating Quartz Crystals, William Patrick

Senior Honors Projects, 2010-2019

The goal of this project was to evaluate the effectiveness a procedure that can be used to coat quartz crystal microbalance crystals with titanium dioxide. A successful suspension was created by suspending titanium dioxide powder in poly(acrlic) acid and mixed in an ultra-sonication bath. By utilizing a spin-coater, the TiO2 suspension was successfully dispensed onto a QCM crystal and verified using a surface profiler and microscope. However, after QCM testing, there was no evidence that supports the TiO2 precursor aiding in photocatalytic reactions.


Polyhydroxybutyrate Production In A Photobioreactor Using Spirulina Platensis, Adrianna Mika Dec 2015

Polyhydroxybutyrate Production In A Photobioreactor Using Spirulina Platensis, Adrianna Mika

Electronic Thesis and Dissertation Repository

Biopolymers and other naturally derived chemicals continue to gain attention over petrochemical based products due to the price volatility of crude oil, increasing need to reduce greenhouse gas emissions and public awareness of environmental issues. Cyanobacterium Spirulina (Arthrospira) platensis, a commercially feasible blue-green alga, is able to synthesize poly(3-hydroxybutyrate) (PHB), a biodegradable and biocompatible polymer, as an energy storage product of photosynthesis directly from CO2. A flat plate photobioreactor (PBR) with LED illumination was designed for the cultivation of S. platensis. Computational fluid dynamics (CFD) software was used to improve airflow uniformity and mixing in the …


Applying Bayesian Machine Learning Methods To Theoretical Surface Science, Shane Carr Dec 2015

Applying Bayesian Machine Learning Methods To Theoretical Surface Science, Shane Carr

McKelvey School of Engineering Theses & Dissertations

Machine learning is a rapidly evolving field in computer science with increasingly many applications to other domains. In this thesis, I present a Bayesian machine learning approach to solving a problem in theoretical surface science: calculating the preferred active site on a catalyst surface for a given adsorbate molecule. I formulate the problem as a low-dimensional objective function. I show how the objective function can be approximated into a certain confidence interval using just one iteration of the self-consistent field (SCF) loop in density functional theory (DFT). I then use Bayesian optimization to perform a global search for the solution. …


In Situ Ir Spectroscopic Investigation Of Noble Metal Catalysts Related To The Reduction Of Automotive Exhaust Emissions, Zhiyong Wang Dec 2015

In Situ Ir Spectroscopic Investigation Of Noble Metal Catalysts Related To The Reduction Of Automotive Exhaust Emissions, Zhiyong Wang

Theses and Dissertations

The reduction of automotive exhaust emissions has been one of the hottest topics in catalysis community since 1970s. Thanks to the development of three-way catalysts, main auto-exhaust pollutants, such as carbon monoxide, nitrogen oxides and unburned hydrocarbons, can be removed simultaneously. Nowadays, diesel engines and lean-engines become more and more popular due to their high fuel-efficiency and low CO2 emissions. Unfortunately, conventional three-way catalysts are not effective at reducing the NOx emissions from these engines due to the excess oxygen in the exhaust stream. Platinum catalysts were found to be highly active for selective NO reduction with hydrocarbons in excess …


Development Of Highly Active And Stable Hybrid Cathode Catalyst For Pemfcs, Won Suk Jung Dec 2015

Development Of Highly Active And Stable Hybrid Cathode Catalyst For Pemfcs, Won Suk Jung

Theses and Dissertations

Polymer electrolyte membrane fuel cells (PEMFCs) are attractive power sources of the future for a variety of applications including portable electronics, stationary power, and automobile application. However, sluggish cathode kinetics, high Pt cost, and durability issues inhibit the commercialization of PEMFCs. To overcome these drawbacks, research has been focused on alloying Pt with transition metals since alloy catalysts show significantly improved catalytic properties like high activity, selectivity, and durability. However, Pt-alloy catalysts synthesized using the conventional impregnation method exhibit uneven particle size and poor particle distribution resulting in poor performance and/or durability in PEMFCs. In this dissertation, a novel catalyst …


Supported Group Ib-Pd Bimetallic Catalysts Prepared By Electroless Deposition And Galvanic Displacement For Selective Hydrogenation Of Acetylene, Yunya Zhang Dec 2015

Supported Group Ib-Pd Bimetallic Catalysts Prepared By Electroless Deposition And Galvanic Displacement For Selective Hydrogenation Of Acetylene, Yunya Zhang

Theses and Dissertations

Ethylene is the building block for many chemical intermediates in the petrochemical industry. The current worldwide ethylene production is over 150 million tons per year and demand increases by 3-5% annually. However, ethylene produced from steam cracking of light naptha contains up to 2% acetylene which acts as a poison for the downstream ethylene polymerization catalysts. Selective hydrogenation of acetylene in the ethylene stream using supported Pd catalysts is the industrially preferred method of lowering acetylene to acceptable ppm levels (< 5 ppm). Due to inferior selectivity at high acetylene conversion and the formation of “green oil”, or ethylene/acetylene oligomers, during reaction, small amounts of Group IB metals have been added to improve the performance of current generation catalysts. However, the bimetallic effects of the above additives have not been experimentally confirmed, possibly because the conventional methods of catalyst preparation result in both monometallic and bimetallic particles with varying compositions. This in turn makes it difficult to determine the position of the two metallic components, and bimetallic interactions typically occur only when the two metals form proximal contact instead of separate particles. In this study, a series of Ag- and Au-Pd/SiO2 bimetallic catalysts were prepared by electroless deposition (ED) with incremental and controlled coverages of Ag and Au on Pd. The selectivity of acetylene to ethylene and turnover frequencies of acetylene conversion were enhanced at high coverages of Ag and Au on Pd surfaces due to the transition of acetylene adsorption modes, which was further confirmed by the kinetics of acetylene hydrogenation. The similar performance trends for Ag- and Au-Pd/SiO2 suggest that the bimetallic effect for these catalysts was likely geometric and not electronic in nature. For comparison, a series of reverse Pd-Ag/SiO2 bimetallic catalysts where variable coverages of Pd were deposited onto Ag surfaces was prepared using galvanic displacement (GD) of Ago by Pd2+ to further explore the nature of bimetallic effects for selective acetylene hydrogenation. Unlike for the earlier case for Ag on Pd surfaces using ED, for samples prepared by GD there was considerably diffusion of Pd into the Ag lattice to give greater electronic interactions between these two metals, which limited selectivity of acetylene hydrogenation to form ethylene.


Surface Modification Of Nanodiamond And Its Incorporation In Nanodiamond/Peek Nanocomposites, Zahidul Wahab Dec 2015

Surface Modification Of Nanodiamond And Its Incorporation In Nanodiamond/Peek Nanocomposites, Zahidul Wahab

Theses and Dissertations

The continued miniaturization of electronic device components requires new lightweight polymers with high thermal stability, high thermal conductivity, low electrical conductivity, and low dielectric constant. Composites of nanodiamond (ND) and poly(ether ether ketone) (PEEK) are candidates for these applications due their unique combination of properties. The objectives of this research are to explore new routes for surface functionalization of nanodiamond (ND), develop methods for maximizing dispersion of ND as a nano-scale filler in PEEK, and characterize the effect of dispersed ND on the mechanical, thermal and dielectric properties of ND/PEEK composites. Initial attempts to disperse different kinds of commercially available, …


Impact Of Formulation And Processing Parameters On Mechanical Properties Of Magadiite/Elastomer Composites, Yating Mao Dec 2015

Impact Of Formulation And Processing Parameters On Mechanical Properties Of Magadiite/Elastomer Composites, Yating Mao

Theses and Dissertations

This work seeks a better understanding of mechanical reinforcement and energy dissipation in elastomer composites containing the layered silicate magadiite (MGD, Na2Si14O29·nH2O). We characterized the elastomer’s accessibility into MGD interlayer spaces and studied the factors that influence the composite mechanical properties. We also compare the mechanical reinforcement of MGD with montmorillonite (MMT, a layered aluminosilicate clay mineral), which is widely used as filler in other kinds of nanocomposites. The study explores the grafting chemistry, vulcanization, and reinforcement mechanism in MGD/elastomer composites, which may help us to formulate the platelet/elastomer composites with superior mechanical properties and performance in the future. We …


Preparation And Characterization Of Pt-Ru Bimetallic Catalysts Using Electroless Deposition Methods And Mechanistic Study Of Re And Cs Promoters For Ag-Based, High Selectivity Ethylene Oxide Catalysts, Weijian Diao Dec 2015

Preparation And Characterization Of Pt-Ru Bimetallic Catalysts Using Electroless Deposition Methods And Mechanistic Study Of Re And Cs Promoters For Ag-Based, High Selectivity Ethylene Oxide Catalysts, Weijian Diao

Theses and Dissertations

Pt-Ru bimetallic catalysts are widely used for direct methanol fuel cells, biomass upgrading and hydrocarbon refining and offer unique properties compared to Pt or Ru monometallic catalysts due to ensemble effects, electronic effects, and/or bifunctional effects. To achieve better performance, strong metal-metal interactions and true bimetallic surface are needed. Electroless deposition (ED) methods are used in our laboratory to synthesize such bimetallic catalysts. In this study, two series of Ru@Pt/C (Pt deposited on Ru surfaces) and Pt@Ru/C (Ru deposited on Pt surfaces) catalysts have been synthesized. Characterization data from temperature programmed reduction (TPR), selective chemisorption, X-ray photoelectron spectroscopy (XPS), and …


Development Of Ultra-Low Loading Of Compressive Pt Lattice Cathode Catalyst On Highly Stable Support For Pemfc Automotive Applications, Tianyuan Xie Dec 2015

Development Of Ultra-Low Loading Of Compressive Pt Lattice Cathode Catalyst On Highly Stable Support For Pemfc Automotive Applications, Tianyuan Xie

Theses and Dissertations

The major barriers in the commercialization of the fuel cell technology for automotive applications are the cost and durability of the Pt catalyst and the support stability at high potentials. The U.S. Department of Energy (DOE) targets direct hydrogen fuel cell systems for transportation to meet 65% peak-efficiency, 5,000 hour durability with a mass production cost of $40/kW by 2020. Currently in 2015, the system can be operated at peak energy efficiency of 60% for 3,900 hours with cost of $55/kW. To meet these targets, precious metal loadings must be greatly reduced without altering the catalyst stability. The primary objective …


Slope Stability Enhancement Of An Upstream Tailings Dam: Laboratory Testing And Numerical Modelling, Yazeed A. Alsharedah Dec 2015

Slope Stability Enhancement Of An Upstream Tailings Dam: Laboratory Testing And Numerical Modelling, Yazeed A. Alsharedah

Electronic Thesis and Dissertation Repository

Mine tailings are the byproduct of mining activities, which need to be disposed of once the ore is extracted. They can be disposed of in either dry or wet forms. The latter is most common with the tailings being disposed of in the form of slurry inside retention structures. The retention structure may be a natural, manmade, or built dam, which is the case in most of nowadays mining locations. In this thesis, improving the stability of an upstream tailings dam using soil additives is investigated. The experimental phase of this study involved laboratory tests conducted to characterize mine tailings …


Thermodynamic Method For Prediction Of Surfactant Modified Oil Droplet Contact Angle, Samuel Morton, David Keffer, R. Counce, D. Depaoli, M. Hu Dec 2015

Thermodynamic Method For Prediction Of Surfactant Modified Oil Droplet Contact Angle, Samuel Morton, David Keffer, R. Counce, D. Depaoli, M. Hu

Samuel A Morton

A model applying surfactant self-assembly theory and classical thermodynamics has been developed to aid in the prediction of solid surface cleaning by aqueous surfactant solutions. Information gained from a combination of surfactant self-assembly behavior and cleaning system parameters, such as oil species, surfactant type, temperature, alkalinity, and solid surface type has been shown to provide insight into surface cleaning. The model combines minimization of free energy, pertinent component distribution mechanisms, and surfactant self-assembly processes to provide a methodology for the predicting of oil droplet contact angles. Such predictive capabilities will allow for the development of beneficial environmental and economic changes …


High Capacity Silicon Electrodes With Nafion As Binders For Lithium-Ion Batteries, Jiagang Xu, Qinglin Zhang, Yang-Tse Cheng Dec 2015

High Capacity Silicon Electrodes With Nafion As Binders For Lithium-Ion Batteries, Jiagang Xu, Qinglin Zhang, Yang-Tse Cheng

Chemical and Materials Engineering Faculty Publications

Silicon is capable of delivering a high theoretical specific capacity of 3579 mAh g−1 which is about 10 times higher than that of the state-of-the-art graphite based negative electrodes for lithium-ion batteries. However, the poor cycle life of silicon electrodes, caused by the large volumetric strain during cycling, limits the commercialization of silicon electrodes. As one of the essential components, the polymeric binder is critical to the performance and durability of lithium-ion batteries as it keeps the integrity of electrodes, maintains conductive path and must be stable in the electrolyte. In this work, we demonstrate that electrodes consisting of …


Getting To The Root Of Bacterial Hairs: What Is “S”?, Rebecca Gaddis, Samantha O'Conner, Evan Anderson, Terri Camesano, Nancy Burnham Dec 2015

Getting To The Root Of Bacterial Hairs: What Is “S”?, Rebecca Gaddis, Samantha O'Conner, Evan Anderson, Terri Camesano, Nancy Burnham

Nancy A. Burnham

An atomic force microscope (AFM) was used to measure the steric forces of lipopolysaccharides (LPS) on the biofilm-forming bacteria, Pseudomonas aeruginosa. It is well known that LPS play a vital role in biofilm formation. These forces were characterized with a modified version of the Alexander and de Gennes (AdG) model for polymers, which is a function of equilibrium brush length, L, probe radius, R, temperature, T, separation distance, D, and an indefinite density variable, s. This last parameter was originally distinguished by de Gennes as the root spacing or mesh spacing depending upon the type of polymer adhesion; however since …


Prediction Of Organic Droplet Behavior On A Solid Surface As Influenced By Aqueous Surfactant Solutions, Samuel Morton Dec 2015

Prediction Of Organic Droplet Behavior On A Solid Surface As Influenced By Aqueous Surfactant Solutions, Samuel Morton

Samuel A Morton

This dissertation presents a model capable of predicting equilibrium oil droplet contact angles on a solid surface immersed in surfactant solution, a thorough discussion of the effects of surfactant concentration and salt addition on contact angles, and an experimental investigation into the impact of voltage application to the solid surface on oil droplet shape in an aqueous/organic/solid system. The work contained in this dissertation resulted in five journal articles and numerous presentations. The model applies current theories of surfactant self-assembly, the quasi-chemical approximation for solid surface adsorption, and various aqueous/organic/solid system properties to determine organic droplet contact angles. The computational …


Ftir Studies Of Ionic Interactions In Blends, Robert Weiss Dec 2015

Ftir Studies Of Ionic Interactions In Blends, Robert Weiss

Robert Weiss

No abstract provided.


Supercritical Carbon Dioxide Aided Preparation Of Conductive Polyurethane-Polypyrrole Composites, Robert Weiss Dec 2015

Supercritical Carbon Dioxide Aided Preparation Of Conductive Polyurethane-Polypyrrole Composites, Robert Weiss

Robert Weiss

Conductive polyurethane (PU) foams were prepared using a two-step procedure. First, PU foams were impregnated with the oxidant I2 from a scCO2 solution. Subsequently, the foams were subjected to pyrrole vapor, which polymerized within the foam in the presence of the oxidant. The reduced form of iodine as a result of the oxidative polymerization of pyrrole functions as a dopant. The conductivities of the foams ranged from 10−7 to 10−2 S/cm and the foams were flexible and not brittle. The concentration of conductive polypyrrole, i.e. the PPy–I2 charge-transfer complex, needed to achieve a conductivity of 10−4–10−3 S/cm was about 22% …


Supercritical Carbon Dioxide Aided Preparation Of Conductive Polyurethane-Polypyrrole Composites, Robert Weiss Dec 2015

Supercritical Carbon Dioxide Aided Preparation Of Conductive Polyurethane-Polypyrrole Composites, Robert Weiss

Robert Weiss

Conductive polyurethane (PU) foams were prepared using a two-step procedure. First, PU foams were impregnated with the oxidant I2 from a scCO2 solution. Subsequently, the foams were subjected to pyrrole vapor, which polymerized within the foam in the presence of the oxidant. The reduced form of iodine as a result of the oxidative polymerization of pyrrole functions as a dopant. The conductivities of the foams ranged from 10−7 to 10−2 S/cm and the foams were flexible and not brittle. The concentration of conductive polypyrrole, i.e. the PPy–I2 charge-transfer complex, needed to achieve a conductivity of 10−4–10−3 S/cm was about 22% …


Secondary Current Distributions Using Topaz2d And Linear Kinetics, E. C. Dimpault-Darcy, Ralph E. White Dec 2015

Secondary Current Distributions Using Topaz2d And Linear Kinetics, E. C. Dimpault-Darcy, Ralph E. White

Ralph E. White

Secondary current density distributions are of interest
to cell designers. The purpose of this note is to illustrate
how to use an existing numerical method to determine
these distributions for cells that contain conducting and
nonconducting bodies between the main anode and cathode.


Secondary Current Distributions Using Topaz2d And Linear Kinetics, E. C. Dimpault-Darcy, Ralph E. White Dec 2015

Secondary Current Distributions Using Topaz2d And Linear Kinetics, E. C. Dimpault-Darcy, Ralph E. White

Ralph E. White

Secondary current density distributions are of interestto cell designers. The purpose of this note is to illustratehow to use an existing numerical method to determinethese distributions for cells that contain conducting andnonconducting bodies between the main anode and cathode.


Ba-Hexaferrite Films For Next Generation Microwave Devices, Vincent Girard Harris (1962-), Zhaohui Chen, Yajie Chen, Soack Dae Yoon, Tomokuza Sakai, Anton Geiler, Aria Fan Yang, Yongxue He, Katherine S. Ziemer, Nian X. Sun, C. Vittoria Dec 2015

Ba-Hexaferrite Films For Next Generation Microwave Devices, Vincent Girard Harris (1962-), Zhaohui Chen, Yajie Chen, Soack Dae Yoon, Tomokuza Sakai, Anton Geiler, Aria Fan Yang, Yongxue He, Katherine S. Ziemer, Nian X. Sun, C. Vittoria

Carmine Vittoria

Next generation magnetic microwave devices require ferrite films to be thick (>300 μm), self-biased (high remanent magnetization), and low loss in the microwave and millimeter wave bands. Here we examine recent advances in the processing of thick Ba-hexaferrite (M-type) films using pulsed laser deposition (PLD), liquid-phase epitaxy, and screen printing. These techniques are compared and contrasted as to their suitability for microwave materials processing and industrial production. Recent advances include the PLD growth of BaM on wide-band-gap semiconductor substrates and the development of thick, self-biased, low-loss BaM films by screen printing.


Ba-Hexaferrite Films For Next Generation Microwave Devices, Vincent Girard Harris (1962-), Zhaohui Chen, Yajie Chen, Soack Dae Yoon, Tomokuza Sakai, Anton Geiler, Aria Fan Yang, Yongxue He, Katherine S. Ziemer, Nian X. Sun, C. Vittoria Dec 2015

Ba-Hexaferrite Films For Next Generation Microwave Devices, Vincent Girard Harris (1962-), Zhaohui Chen, Yajie Chen, Soack Dae Yoon, Tomokuza Sakai, Anton Geiler, Aria Fan Yang, Yongxue He, Katherine S. Ziemer, Nian X. Sun, C. Vittoria

Carmine Vittoria

Next generation magnetic microwave devices require ferrite films to be thick (>300 μm), self-biased (high remanent magnetization), and low loss in the microwave and millimeter wave bands. Here we examine recent advances in the processing of thick Ba-hexaferrite (M-type) films using pulsed laser deposition (PLD), liquid-phase epitaxy, and screen printing. These techniques are compared and contrasted as to their suitability for microwave materials processing and industrial production. Recent advances include the PLD growth of BaM on wide-band-gap semiconductor substrates and the development of thick, self-biased, low-loss BaM films by screen printing.


Independency Of Elasticity On Residual Stress Of Room Temperature Rolled Stainless Steel 304 Plates For Structure Materials, Parikin Parikin, David Allen Dec 2015

Independency Of Elasticity On Residual Stress Of Room Temperature Rolled Stainless Steel 304 Plates For Structure Materials, Parikin Parikin, David Allen

Makara Journal of Technology

Mechanical strengths of materials are widely expected in general constructions of any building. These properties depend on its formation (cold/hot forming) during fabrication. This research was carried out on cold-rolled stainless steel (SS) 304 plates, which were deformed to 0, 34, 84, and 152% reduction in thickness. The tests were conducted using Vickers method. Ultra micro indentation system (UMIS) 2000 was used to determine the mechanical properties of the material, i.e.: hardness, modulus elasticity, and residual stresses. The microstructures showed lengthening outcropping due to stress corrosion cracking for all specimens. It was found that the tensile residual stress in a …


Effect Of Fly Ash Fortification In The Manufacture Process Of Making Concrete Towards Characteristics Of Concrete In Sulfuric Acid Solution, Asep Handaya Saputra, Muhammad Shohibi, Masatoshi Kubouchi Dec 2015

Effect Of Fly Ash Fortification In The Manufacture Process Of Making Concrete Towards Characteristics Of Concrete In Sulfuric Acid Solution, Asep Handaya Saputra, Muhammad Shohibi, Masatoshi Kubouchi

Makara Journal of Technology

Fly ash is a silica or alumino silica material that can be used as a constituent of cement in the concrete manufacturing process. Utilization of fly ash aims to improve durability and minimize the reduction of concrete’s compressive strength exposed to an acidic environment, which can be achieved through the pozzolanic reaction of fly ash with Ca(OH)2 within concrete. The reduced content of Ca(OH)2 through pozzolanic reaction will minimize the tendency of ettringite formation (compounds that cause deterioration and decrease the compressive strength of concrete). In order to determine the relation between fly ash replenishment into concrete with concrete’s characteristics …


Improvement Of Quality Of Carica Papaya L. With Clove Oil As Preservative In Edible Coating Technology, Eny Kusrini, Anwar Usman, Chrispine Deksita Wisakanti, Rita Arbianti, Dedy Alharis Nasution Dec 2015

Improvement Of Quality Of Carica Papaya L. With Clove Oil As Preservative In Edible Coating Technology, Eny Kusrini, Anwar Usman, Chrispine Deksita Wisakanti, Rita Arbianti, Dedy Alharis Nasution

Makara Journal of Technology

We have studied utilization of essential clove oil, extracted from clove buds by hydrodistillation, as preservative in edible packaging technology. Preservative of essential clove oil was applied on chopped papaya fruits by using two methods, namely spray and brush. The effects of concentration of clove oil from 0.05 to 0.20% on the preservation of papaya fruits (Carica papaya L.) at room temperature (25 °C) were also evaluated. Physicochemical and in vitro microbiological activities on the papaya fruits that were stored at 25 oC and 85-90% relative humidity were investigated in details. The results indicate that the clove oil at concentration …


Oxidation Process Of H 2 O /Uv For Cod Reduction Of Wastewater From Soybean Tofu Production, Komala Pontas, Abrar Muslim Dec 2015

Oxidation Process Of H 2 O /Uv For Cod Reduction Of Wastewater From Soybean Tofu Production, Komala Pontas, Abrar Muslim

Makara Journal of Technology

Chemical Oxygen Demand (COD) reduction of wastewater from soybean tofu production was studied by conducting advanced oxidation process (AOP) using hydrogen peroxide with UV radiation catalysts in a closed cylindrical glass reactor. The hydroxyl radical (*OH) concentration from H2O2 decomposition was modeled, and exponential trends were found for the *OH concentration over radiation time and operation temperature. As a result, it was found that the maximal *OH concentration was 0.209 mol L-1 at 240 minutes and 50 °C. The *OH concentration exponentially increased following rise in operation temperature. The H2O2/UV AOP application reduced COD concentration to approximately 42.41% from 10,545 …


Doping Plasmon-Enhanced Tio2 With Zirconia To Improve Solar Energy Harvesting In Dye-Sensitized Solar Cells, Anastasia Pasche Dec 2015

Doping Plasmon-Enhanced Tio2 With Zirconia To Improve Solar Energy Harvesting In Dye-Sensitized Solar Cells, Anastasia Pasche

Electronic Thesis and Dissertation Repository

Solar energy is a promising solution towards meeting the world’s ever-growing energy demand. Dye-sensitized solar cells (DSSCs) are hybrid organic-inorganic solar cells with potential for commercial application, but are plagued by inefficiency due to their poor sunlight absorption. Silver nanoparticles have been shown to enhance the absorptive properties of DSSCs, but their plasmonic resonance causes local hot spots, resulting in cell deterioration. This thesis studies the mitigation of thermal energy loss of plasmon-enhanced DSSCs by the co-incorporation of zirconia, a well-known thermostabilizer, into the cell’s photoactive material. TiO2 was also synthesized using green bio-sourced solvents in supercritical CO2 to compare …


Improving Renewable Energy Transition Acceptance: A Simulation Gaming Approach On A Multi Actor Setting In The Netherlands, Aziiz Sutrisno, Jac A. M. Vennix, Noor Syaifudin Dec 2015

Improving Renewable Energy Transition Acceptance: A Simulation Gaming Approach On A Multi Actor Setting In The Netherlands, Aziiz Sutrisno, Jac A. M. Vennix, Noor Syaifudin

Makara Journal of Technology

The Netherlands have tried very hard to increase their renewable energy sources (RES) shares to fulfill the European Union target in 2050. However, RES performance did not show the expected result as the performance declined in 2009 producing even wider gap compare to the target. The Dutch government’s tried to incorporate all interested stakeholders by forming the Dutch energy transition task force. Nevertheless, the task force’s result is also not showing a desirable trend. Key reasons behind the Dutch low RES performance are the lack of shared understanding and positive attitude toward RES development among interested actors. This research uses …


Calibration Of Numerical Model For Shoreline Change Prediction Using Satellite Imagery Data, Sigit Sutikno, Keisuke Murakami, Dwi Puspo Handoyo, Manyuk Fauzi Dec 2015

Calibration Of Numerical Model For Shoreline Change Prediction Using Satellite Imagery Data, Sigit Sutikno, Keisuke Murakami, Dwi Puspo Handoyo, Manyuk Fauzi

Makara Journal of Technology

This paper presents a method for calibration of numerical model for shoreline change prediction using satellite imagery data in muddy beach. Tanjung Motong beach, a muddy beach that is suffered high abrasion in Rangsang Island, Riau province, Indonesia was picked as study area. The primary numerical modeling tool used in this research was GENESIS (GENEralized Model for Simulating Shoreline change), which has been successfully applied in many case studies of shoreline change phenomena on a sandy beach.The model was calibrated using two extracted coastlines satellite imagery data, such as Landsat-5 TM and Landsat-8 OLI/TIRS. The extracted coastline data were analyzed …